Material Safety Data Sheet
PRODUCT AND COMPANY IDENTIFICATION
Product Name: BRUSH ON GEL
Manufacture: Tres Chic Nails Version Number: 01
MSDS / Product Code: 10107
P.O. Box 24500
Rochester, NY 14624 Issued Date: 01-01-08
Telephone Number: 585-247-6060 Fax Number: 585-429-9897
TELEPHONE NUMBERS ?24 HOUR EMERGENCY ASSISTANCE:
Infotrac Domestic - 800-535-5053 Infotrac International - 352-323-3500
1. COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Identity CAS Numbers EINECS#: INCI Name Exposure Limits Carcinogen %
OSHA ACGIH
IARC/NTP/OSHA
TWA/STEL TWA/STEL
Polyurethane Acrylate Exempt N/E Polyurethane N/E N/E Not Listed 70-
Oligomer Acrylate Oligomer 75
Tetraethylene glycol 109-17-1 203-653-1 PEG-4 N/E N/E Not Listed 15-
Dimethacrylate Dimethacrylate 20
Ethyl Methacrylate 97-63-2 202-597-5 Ethyl Methacrylate 100 ppm 100 ppm Not Listed 5-10
Hydroxycyclohexyl 947-19-3 213-426-9 Hydroxycyclohexyl N/E N/E Not Listed 1-3
phenyl ketone phenyl ketone
D&C Violet #2 81-48-1 201-353-5 Violet 2/CI60725 N/E N/E Not Listed 0-1
N/E ?None Established N/DA ?No Data Available
N/R ?Not Reviewed N/A ?Not Applicable
Xi,F Risk Phrases: R22, R36/37/38, R43 Safety Phrases: S18, S24/25, S36/37, S38, S46
Hazard Symbols:
2. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
This information is based on findings from related or similar materials.
?Flammable liquid and vapor!
?May be slightly toxic.
?May cause moderate skin injury (reddening & swelling).
?May cause chemical burn in eye.
Potential Health Effects, Signs and Symptoms of Exposure:
Primary Route of Entry No specific information available.
Eye Contains materials that are essentially nonirritating, but contact may cause slight transient
irritation. Material may act as a Lachrymator (a substance which increases the flow of tears).
Skin Contains materials that may cause moderate skin injury (reddening and swelling) and/or
sensitization. Prolonged contact may cause blister formation (burns). Since irritation may not
occur immediately, contact can go unnoticed.
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Material Safety Data Sheet
Ingestion May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation May cause respiratory tract irritation with presence of monomer. Vapors may cause dizziness or
suffocation.
Sub-Chronic Effects No specific information available. Limited tests showed no evidence of teratogenicity in animals.
A lifetime skin painting study with mice showed no evidence of carcinogenicity.
NOTE: Refer to Section 11, Toxicological Information for Details
3. FIRST AID MEASURES
First Aid for Eye Flush with plenty of water for 15 minutes, occasionally lifting the upper and lower eyelids.
Get medical aid. Do NOT allow victim to rub or keep eyes closed.
First Aid for Skin Remove contaminated clothing and wash contact area with soap and water for 15 minutes.
Get medical aid if systems persist. Wash clothing before reuse.
First Aid for Inhalation In case of exposure to a high concentration of vapor or mist, remove person to fresh air. If
breathing has stopped, administer artificial respiration and seek medical attention.
First Aid for Ingestion Never give anything by mouth to an unconscious person. Get medial aid. Do NOT induce
vomiting. If conscious and alert, rinse mouth and drink 2 to 4 cupfuls of milk or water.
4. FIRE FIGHTING MEASURES
Flash Point(癋/癈) Flammable Limit(vol%) Auto-ignition Temperature(vol%)
110癋/43癈 Penske-Martin No Data No Data
Method:
Extinguishing Media: Use carbon dioxide or dry chemical for small fires; aqueous foam or water for large fires.
Fire Fighting Instructions: Remove all ignition sources. Wear self-contained breathing apparatus and complete personal
protective equipment when entering confined areas where potential for exposure to vapors or
products of combustion exists.
Unusual Hazards: High temperatures and fire conditions may cause rapid and uncontrolled polymerization which
Can result in explosions and the violent rupture of storage vessels or containers. Avoid the use
of a stream of water to control fires since frothing can occur.
5. ACCIDENTAL RELEASE MEASURES
Spill or Release Eliminate all sources of heat and ignition. Use absorbent material for spills and dike it, wash spill
Procedures material into retaining containers. Place containers in a well ventilated area. Consult an expert on
disposal of recovered material and ensure conformity to local disposal regulations. Keep
unnecessary and unprotected personnel from entering. Contain and recover liquid when possible.
Use non-sparking tools and equipment. Collect liquid in an appropriate container or absorb with
an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do
not use combustible materials, such as sawdust. Do not flush to sewer! US Regulations
(CERCLA) require reporting spills and releases to soil, water and air in excess of reportable
quantities. The toll free number for the US Coast Guard National Response Center is (800) 424-
8802. EU Regulations require the consultation of Directive 98/24/EC. If a leak or spill has not
ignited, use water spray to disperse the vapors, to protect personnel attempting to stop leak, and
to flush spills away from exposures.
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Material Safety Data Sheet
6. HANDLING AND STORAGE
Handling Ground and bond containers when transferring material. Avoid contact with skin and eyes, and clothing. Use
with adequate ventilation and avoid breathing in vapor. Keep container closed when not in use. Avoid contact
with heat, sparks and flame. Remove all contaminated clothing, shoes, belts and other leather goods
immediately. Incinerate leather goods (including shoes). Wash contaminated clothing thoroughly before
reuse. Wash skin thoroughly with soap and water after handling. Solvents should not be used to clean skin
because of increased penetration potential. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
empty containers to heat, sparks, or open flames.
Material is extremely light sensitive. Use extreme care and do not expose to natural or UV light, unless
using material for its intended use. Since the material is very photosensitive any type of light may initiate the
curing process.
Storage Keep away from heat, sparks, and flame. Store in a tightly closed container. Store in a cool, dry, well-
ventilated place, away from any type of light. Store at temperatures below 100癋/38篊.
Store product in a totally opaque container.
Explosion Hazard High temperatures and fire conditions may cause rapid and uncontrolled polymerization which can
result in explosions and the violent rupture of storage vessels or containers.
7. EXPOSURE CONTROLS/PERSONAL PROTECTIVE EQUIPMENT
Engineering Controls Local exhaust recommended to control exposure which may result from operations generating
aerosols and hot operations generating vapors.
Personal Protective Equipment
General To identify additional Personal Protective Equipment (PPE) requirements, it is recommended that
a hazard assessment in accordance with the OSHA PPE Standard (29CFR1910.132), or European
Standard EN166 be conducted before using this product . Provide eye wash stations and safety
showers. Wear impervious clothing to prevent ANY contact with this product, such as gloves,
apron, boots, or whole body suit. Nitrile rubber is better than PVC.
Eye/Face Protection Wear safety glasses. Wear coverall chemical splash goggles and face shield when possibility exists
for eye and face contact due to splashing or spraying material.
Skin Protection Use impermeable clothing to prevent ANY contact with this product, such as gloves, apron, boots,
or whole body suit. Nitrile rubber is better than PVC.
Respiratory Protection A NIOSH/MSHA approved air purifying respirator with an organic vapor cartridge or canister
may be permissible under certain limited circumstances where airborne concentrations are
expected to exceed exposure limits.
Protection provided by nuisance level organic vapor dust masks can be used, however the use of
the respirator is limited. Follow OSHA respirator regulations found in 29 CFR 1910.134 or
European Standard EN 149.
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Material Safety Data Sheet
8. PHYSICAL AND CHEMICAL PROPERTIES
Odor & Odor Specific
Appearance Viscosity % Volatile
PH
Threshold Gravity
Clear, semi-viscous Characteristic acrylate (H2O=1):
NA N/DA By Volume: <0.5
liquid odor 1.15
Solubility
Octanol/Water
Boiling Point/ Decomposition Vapor Vapor Evaporation
In Water
Partitioning Coefficient Ignition
Freezing Point Temperature Pressure: Density Rate
Log Po/W (20癈)
N/A N/A N/A (mm Hg) @ 20癈:<0.01 No Data No Data No Data Insoluble
Flash Point(癋/癈) Flammable Limit(vol%) Auto-ignition Temperature (vol%)
110癋/43癈 Penske-Martin No Data No Data
9. STABILITY AND REACTIVITY
Stability Incompatibility (Materials to Avoid):
Normally Stable Polymerization initiators including peroxides, strong
oxidizing agents, copper, copper alloys, carbon steel,
iron, rust and string bases.
Hazardous Decomposition Products: Hazardous Polymerization:
Fumes produced when heated to decomposition may include: May occur -- Uncontrolled polymerization may
carbon monoxide, carbon dioxide cause rapid evolution of heat and increased pressure
that could result in violent rupture of sealed storage
vessels or containers.
Conditions to Avoid:
Storage <100癋/38篊 , exposure to light, loss of dissolved air, loss of polymerization inhibitor, contamination with incompatible
materials.
10. TOXICOLOGICAL INFORMATION
Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity Irritation ?skin Irritation ?Eye
No information available No information available No information available No information available No information available
Further hazardous properties cannot be excluded. The product should be handled with care when dealing with chemicals.
Sensitization Mutagenicity Sub-chronic Toxicity
No information available No information available No information available
11. ECOLOGICAL INFORMATION
Ecotoxicological Information
Acute Toxicity Acute Toxicity Acute Toxicity Toxicity to Sewage
Bioconcentration
To Fish To Invertebrates To Algae Bacteria
No information available No information available No information available No information available No information available
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Material Safety Data Sheet
Chemical Fate Information
No information available
Biodegradability
No information available
Chemical Oxygen Demand
To the best of our knowledge, the ecotoxocological and chemical fate properties have not been thoroughly investigated.
Do not allow to enter drinking water supplies, wastewater, or soil.
12. DISPOSABLE CONSIDERATIONS
Dispose of diking materials and absorbent in compliance with State, Local, and Federal regulations. Residual vapors may explode on
ignition; do not cut, drill, or weld on or near the container. Mix with compatible chemical which is less flammable and incinerate.
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste
facility. Processing, use or contamination of this product may change the waste management options. State and local disposal
regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state
and local requirements. For EU Member States, please refer to any relevant Community provisions relating to waste. In their absence,
it is useful to remind the user that national or regional provisions may be in force.
13. TRANSPORT INFORMATION
DOT (49 CFR 172)
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl methacrylate, acrylic esters), 3, UN1993, PGIII
Identification Number: UN1993
Marine Pollutant: No
Special Provisions: N/A
Emergency Response Guidebook (ERG) #: 128
IATA (DGR):
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl methacrylate, acrylic esters), 3, UN1993, PGIII
Class or Division: 3.2
UN or ID Number: UN1993
Packaging Instructions:
Emergency Response Guidance (ICAO)#:
IMO (IMDG):
Proper Shipping Name: Flammable liquids, n.o.s., (ethyl methacrylate, acrylic esters), 3, UN1993, PGIII
Class or Division: 3
UN or ID Number: UN1993
Special Provisions & Stowage/Segregation: None
Emergency Schedule (EmS)#:
Other Information: Flash point = 43篊
14. REGULATORY INFORMATION
US Federal Regulations
Clean Air Act: HAP/ODS This product contains hazardous air pollutants (HAP's), as defined by the U. S.
Clean Air Act. They are as follows:
?NONE
This product does not contain any Class1 or Class 2 ODS.
Clean Water Act: Priority Pollutant This product contains the following Hazardous Substances as defined by the
CWA:
?NONE
This product does not contain any substances that are a Priority Pollutant or
Toxic Pollutant under the CWA.
FDA: Food Packaging Status This product has not been cleared by the FDA for use in food packaging and /or
other applications as an indirect food additive.
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Material Safety Data Sheet
Occupational Safety and Health Act This product is considered to be a hazardous chemical under the OSHA Hazard
Communication Standard. Its hazards are:
?Immediate (acute) health hazard
?Delayed (chronic) health hazard
?Reactive hazard
RCRA This product is considered to be a hazardous waste under RCRA (40 CFR 261)
RCRA Code:
?Ethyl methacrylate, CAS# 97-63-2, RCRA Code: U118
?Characteristic of Ignitability, RCRA Code: D001
SARA Title III: Section 302 (TPQ) This product contains no chemicals regulated under Sec. 302 as extremely
hazardous substances that carry a TPQ.
SARA Title III: Section 302 (RQ) This product contains chemicals regulated under Section 304 as extremely
hazardous chemicals for emergency release notification ("CERCLA" List):
?Ethyl Methacrylate CAS# 97-63-2, RQ(Lbs): 1000
This product is considered to be hazardous under the OSHA Hazard Communication
SARA Title III: Section 311-312:
Standard and is regulated under Section 311-312 ( 40 CFR 370 ). Its hazards are:
?IMMEDIATE (acute) HEALTH HAZARD
?DELAYED (CHRONIC) HEALTH HAZARD
?REACTIVE HAZARD
SARA Title III: Section 313: This product contains no chemicals subject to the reporting requirements of Section
313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and
40 CFR Part 372.
TSCA Section 8(b): Inventory: This product contains chemicals listed on the TSCA inventory or otherwise
complies with TSCA premanufacture notification requirements.
TSCA Significant New Use Rule: None of the chemicals listed have a SNUR under TSCA.
State Regulations
CA Right-to-Know Law: NONE
California No Significant Risk Rule: NONE
MA Right-to-Know Law: Ethyl Acetate CAS #97-63-2
NJ Right-to-Know Law: Ethyl Acetate CAS #97-63-2
PA Right-to-Know Law: Ethyl Acetate CAS #97-63-2
FL Right-to-Know Law: Ethyl Acetate CAS #97-63-2
MN Right-to-Know Law: NONE
International Regulations
CDSL: Canadian Inventory Ethyl methacrylate CAS #97-63-2 is on the DSL List. WHMIS = B2, D2B.
(on Canadian Transitional List) Tetraethylene glycol dimethacrylate, CAS# 109-17-1 is not on the DSL List.
WHMIS = n/da Hydroxycyclohexyl phenyl ketone CAS #947-19-3 is on the DSL
list. WHMIS = n/da
D&C Violet #2, CAS# 81-48-1 is not on the DSL List. WHMIS = n/da
EINECS: European Inventory: QF2:
?Hazard Symbols: Xi: Irritant, F: Flammable
?RISK PHRASES: R22: Harmful if swallowed, R36/37/38: Irritating to eyes,
respiratory system, and skin, R43: May cause sensitization by skin contact.
?SAFETY PHRASES: S18: Handle and open container with care, S24/25:
avoid contact with skin and eyes, S36/37: Wear suitable protective clothing
and gloves, S38: in case of insufficient ventilation, wear suitable respiratory
equipment, S46: If swallowed seek medical advice immediately and show this
container or label.
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Material Safety Data Sheet
15. OTHER INFORMATION
Hazard Rating System (Pictograms)
NFPA: HMIS:
Health
2
Flammability
2
Flammability
2
2 1
Health 1
Reactivity
1
Reactivity
D
*D
*D
*Respiratory protection may be necessary depending on conditions of use. Refer to Section VIII of this MSDS for respiratory protection guidelines.
OSHA PEL for nuisance dust: 15 mg/m3 (total dust)
5 mg/m3 (respirable dust)
ACGIH PEL for nuisance dust: 10 mg/m3
Revised Sections since Last Version: Format Update, section 2 <,> changed to ranges
Disclaimer:
The data contained herein is based upon information that Tr鑣 Chic Nails believes to be reliable. Users of this product have the
responsibility to determine the suitability of use and to adopt all necessary precautions to ensure the safety and protection of property
and persons involved in said use. All statements or suggestions are made without warranty, express or implied, regarding accuracy of
the information, the hazards connected with the use of the material or the results to be obtained from the use thereof.
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