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MSDS Material Safety Data Sheet
CAS

71-43-2 108-88-3 91-20-3 100-41-4 95-13-6 1330-20-7 100-42-5 75-15-0 74-90-8

File Name: 71-43-2_108-88-3_91-20-3_100-41-4_95-13-6_1330-20-7_100-42-5.asp

                MATERIAL SAFETY DATA SHEET
SECTION I
PRODUCT INFORMATION
LIGHT OIL
Product Name:
BY-PRODUCT
Material Type:
CHEMICAL INTERMEDIATE
Product Use:
Manufacture's ESSAR Steel Algoma Inc.
Name & Address: 105 West Street
Sault Ste. Marie Ontario, Canada P6A 7B4
Emergency Phone (705) 945-4058 (8:00 am ?4:00 pm) Revision Date:
September 1, 2007
Numbers: (705) 945-2271 (after hours)
B2, D1, D2
WHMIS Class:
Coal Tar Distillate, (PIN #1136)
TDG Information:


SECTION II
INGREDIENT LISTING
*TWAEV Toxicity
Ontario Regulation
(833)
(*PPM/mg/m3)
Ingredient: CAS. No. % LD50 LC50
Benzene 71-43-2 71 0.5 PPM* 930 mg/kg 13,700 PPM
Toluene 108-88-3 13 100 PPM <870 mg/kg 8800 PPM
Naphthalene 91-20-3 4.5 10 PPM 533 mg/kg N/A
Ethyl Benzene 100-41-4 2.8 100 PPM 3500 mg/kg N/A
Indene 95-13-6 2.8 10 PPM N/A N/A
Xylene 1330-20-7 2.8 100 PPM 5400 mg/kg 6350 PPM
Styrene 100-42-5 1.9 50 PPM 5000 mg/kg 5640 PPM
Carbon Disulfide 75-15-0 0.4 10 PPM 3020 mg/kg 2300 PPM
Hydrogen Cyanide 74-90-8 <0.1 C4.7 PPM 3.7 mg/kg 484 PPM
* Benzene Designated Substance Regulation (839)



* TWAEV = Time Weighted Average Exposure Value
*PPM = Parts Per Million
*mg/m3 = Milligrams Per Cubic Metre
SECTION III
PHYSICAL DATA
Liquid N/A
Physical State: PH:
Boiling Point: (0C) 80 0.87
Specific Gravity(H20 =1):
Melting Point: (0C) 5.5 >90
% Volatile by Volume:
100 @ 260C 1(Carbon Tet = 1)
Vapour Pressure: (mmHg) Evaporation Rate:
Yellow Liquid/Sweet
2.77 g/l
Vapour Density: (Air =1) Appearance & Odour:
Odour
Slight N/A
Solubility in H20: Coefficient Water/Oil Distribution

SECTION IV
FIRE AND EXPLOSION HAZARD DATA
Flash Point: ( 0C) Closed Cup: -11
Flammable: YES: X NO:
LEL: 1.4 UEL: 8.0
Flammable Limits:
Carbon Dioxide, Dry Chemical or Foam
Extinguishing
Media:
Flowing liquid can produce static discharge ground all
Susceptibility to Mechanical Impact: or
transfer containers
Static Discharge:
Fire fighters must wear self-contained breathing apparatus. Do
Fire Fighting Procedures:
not cut or weld on steel containers.

SECTION V
REACTIVITY DATA
Stable
Stability:
None
Incompatible Materials:
Thermal decomposition will produce oxides of carbon and nitrogen.
Decomposition Products:


SECTION VI
TOXICOLOGICAL INFORMATION
Acute Effects:
Toxic by inhalation, skin absorption or ingestion. Material is irritation to the skin, eyes, mucous membranes
or upper respiratory tract. Over exposure may cause narcotic effects, drowsiness, fatigue, or confusion.
Severe over exposure may cause tremors, convulsions and death or to respiratory paralysis.


Chronic Effects:
Prolonged skin or eye exposure can cause drying of the skin and eyes. Chronic exposure can impact the
blood forming systems. Benzene has been designated as carcinogenic by I.A.R.C. and the A.C.I.G.H. and is
linked to Leukemia and Aplastic anemia with target organs being bone marrow and peripheral blood-
forming tissues. Benzene has also been linked to carcinogenic effects in the female reproductive system.
See lethal Dose and Concentration information listed in section II.



2
SECTION VII
FIRST AID MEASURES
Remove to fresh air and give artificial respiration if required. Get medical aid.
Inhalation:

Wash thoroughly with soap and water. Launder contaminated clothing.
Skin Contact:

Flush with clean water for 15 minutes. Seek medical aid.
Eye Contact:

Do not induce vomiting. Seek medical aid immediately.
Ingestion:


SECTION VIII
PREVENTIVE MEASURES
Use a N.I.O.S.H. approved respirator adequate for potential exposure.
Respiratory Protection:

Protective Gloves/Clothing: Use rubber gloves and clothing as required, to prevent skin contact.

Use face shield or chemical splash goggles for splash hazards.
Eye Protection:

Use adequate ventilation to prevent overexposure to vapour.
Ventilation:

Contain spill. Eliminate all sources of ignition. Cover spilled material
Spill Cleanup:
with sand or other inert material. Use proper protective equipment and
non-sparking tools during cleanup.
Dispose of waste per applicable environmental legislation.
Waste Disposal:

Avoid contact with oxidizing materials. Store as a flammable liquid.
Handling/Storage:
Ground and bond containers for liquid transfer.

SECTION IX
SPECIAL PRECAUTIONS
Avoid inhalation or skin contact with liquid. Ground and bond all containers. Avoid sources of ignition.
Product contains Benzene which has been designated as carcinogenic by I.A.R.C and the A.C.G.I.H.


SECTION X
PREPARATION INFORMATION
Prepared by:
ESSAR Steel Algoma Inc. MSDS Inquiries
Occupational Health and Safety Department Phone: (705) 945-4058
U = Unknown
N/A = Not applicable


3

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