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SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Builder (including pink versions) DATE PREPARED: January 1, 2009
GENERAL USE: Fingernail overlay resin SUPPERSEDES: May 1, 2008
PRODUCT DESCRIPTION: polyurehthane acrylate prepolymer resin TELEPHONE NUMBER: +1 423 756 3668
blend EMERGENCY TELEPHONE NUMBER:
+1 423 667 4992
MANUFACTURER'S NAME
Just for Toes Prosthetic Nail System
ADDRESS TELEPHONE NUMBER:
1225 Taft Hwy +1 423 756 3668
(CITY, STATE AND POSTAL CODE) COUNTRY EMERGENCY TELEPHONE NUMBER:
Chattanooga, TN 37377 USA +1 423 667 4992
SECTION 2 - HAZARDOUS INGREDIENTS
COMPONENTS % (by CAS# EINECS # Hazard RISK PHRASES (Full
weight) Symbol Text Section 16)
Polyurthane acrylate prepolymer resin 52-70 N/A N/A Xi R-36/38
Polyurethane methacrylate prepolymer 25-35 N/A N/A Xi R-36/38
resin
Tripropyleneglycol diacrylate 0-5 42978-66-5 256-032-2 Xi R-36/38
1-hydroxycyclohexylphenylketone 1-2 947-19-3 213-426-9 none none
Benzophenone 1-2 119-61-9 204-337-6 none none
Silica 1-3 11294552-5 231-545-4 none none
CI77891 (TiO2) 0-0.1 13463-67-7 236-675-5 none none
CI75470 (carmine red) 0-0.1 1328-60-5 215-527-3 none none
c) Indicates an employee's skin exposure shall be prevented or reduced to the extent necessary in the circumstances through the use of gloves or other appropriate
equipment.
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Clear or pigmented liquid. Will support combustion. May cause complictions if swallowed. Known allergen upon over exposure in some cases. Avoid skin contact.
Inhillation of mist or liquid can cause respiratory irritation. Hazard symbols for the product - see section XV below Risk Phrases - see section XV below
POTENTIAL HEALTH EFFECTS
INHALATION: No significant adverse health effects are expected to occur upon short-term eposure. Prolonged exposure to mists may cause an allergic reaction.
Mists are defined as liquids that are in vaporous form. This would not be how the material is desigend to be used or applied.
SKIN: No allergic reaction is expected to occur upon short term exposure. Idividuals who are know to have allergies to acrylics, acrylic acids, carboxylic acids,
epoxy resins or other UV cured products should avoid skin contact.
EYES: No adverse effects are known for this product upon short-term exposure to the eyes. It is best to avoid contact with the eye region and surrounding skin.
INGESTION: Non-toxic material. May cause gastric distress, but this is highly unlikely. Do not induce vomiting if ingested. If vomiting occurs, avoid aspriration of
vomitus into the lungs.
CARCINOGENICITY: NTP? NO IARCH MONOGRAPHS? NO OSHA REGULATED? NO
Known to not be a carcinogen.
SECTION 4 - FIRST AID MEASURES
All information contained herein is accurate to the best of the knowledge at McConnell Labs, Inc.
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INHALATION: In case of exposure to a high concentration of vapor or mist, remove person to fresh air. If breathing has stopped, administer artificial respiration and
seek medical attention. There has never been any incidence of any inhalation incidnce known to the manufacturer.
SKIN: Remove contaminated clothing and wash contact area with soap and water for 15 minutes. Particular attention should be paid to hair, nose, ears and other
areas not easily cleaned. See section 8 . Note to physician: effects can be delayed 24-48 hours.
EYES: Flush with plenty of water for at least 15 minutes and seek medical attention.
INGESTION: If appreciable quantities are swallowed, seek medical attention.
SECTION 5 - FIRE FIGHTING MEASURES
GENERAL HAZARDS: Product will support combustion. Products of combustion will include compounds of carbon, nitrogen and oxygen including carbon monoxide.
EXTINGUISHING MEDIA: Carbon dioxide, water fog, dry chemical and chemical foam.
FIRE FIGHTING PROCEDURES: Firefighters must wear a full-face self-contained breathing apparatus in possitive pressure mode. Do not use solid stream of water
since stream will cause fire to scatter and spread fire. Fine water spray can be used to keep fire-exposed containers cool.
UNUSUAL FIRE AND EXPLOSION HAZARDS: Closed containers can explode due to build-up of presure due to extreme heat.
HAZARDOUS COMBUSTION PRODUCTS: Smoke, fumes, oxides of carbon, nitrogen containing compounds.
SECTION 6 - ACCIDENTAL RELEASE MEASURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: WILL SUPPORT COMBUSTION. Do not wash to sanitary sewer. All spills can be polymerized
into a plastic with the use of UV light source: sunlight, UV light lamp. If no light source is readily available, use a trowel or shovel to gather the material into a
container, transport to a UV light source and polymerize. Polymerized material can be disposed of in accordance with local, state and ferderal regulations.
SECTION 7 - HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE: Keep container closed when not in use. Protect containers from abuse. Do not expose containers to UV
light (including sunlight), peroxides or other free-radical reaction initiators. Do not expose material to temperatures in excess of 60 0C. Do not expose to open
flame. This mateial will support combustion. Keep this material and all chemicals out of the reach of children. Avoid prolinged contact with skin, mucous
membranes, eyes, open wounds,
SECTION 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION
HAZARDOUS COMPONENTS: NIOSH ACGIH
TWA ppm TWA mg/m3 STEL ppm STEL mg/m3 TWA ppm TWA mg/m3 STEL ppm STEL mg/m3
Polyurethane acrylate prepolymer n/a n/a n/a n/a n/a n/a n/a n/a
tripropyleneglycol diacrylate n/a n/a n/a n/a n/a n/a n/a n/a
1-hydroxycylohexylphenylketone n/a n/a n/a n/a n/a n/a n/a n/a
benzophenone n/a n/a n/a n/a n/a n/a n/a n/a
PERSONAL PROTECTION:
REPIRATORY PROTECTION (SPECIFY TYPE): None required while threshold limits are kept below maximum allowable concentrations; if TWA exceeds limits, HIOSH
approved respirator must be worn. Refer to 28 CFR 1910.134 or European Standard EN 149 for complete regulations.
PROTECTIVE GLOVES: Nitrile, neoprene, or latex. For large quantities, long neoprene glove are required with cuffs.
EYE PROTECTION: Safety glasses or splash goggles. For large exposure situations, a full-face splash shield is required.
All information contained herein is accurate to the best of the knowledge at McConnell Labs, Inc.
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OTHER PROTECTIVE CLOTHING OR EQUIPMENT: Safety eyewash station.
WORK / HYGENIC PRACTICES: Always practive safe workplace habits. Minimize body contact with this as well as all chemicals in general.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE AND ODOR VAPOR PRESSURE
Clear or pigmented liquid not applicable
pH SPECIFIC GRAVITY (WATER = 1)
not applicable 1.1
BOILING POINT / BOILING RANGE SOLUBILITY IN WATER
not applicable not soluble
FLASH POINT VISCOSITY
>212 F / 100 C 30,000 cps
FLAMMABLE LIMITS VAPOR DENSITY (AIR = 1)
not applicable <1
AUTOIGNITION TEMPERATURE EVAPORATION RATE (WATER = 1)
not applicable not applicable
SECTION 10 - STABILITY AND REACTIVITY
STABILILTY STABLE UNSTABLE CONDITIONS TO AVOID: Temperatures over 60 oC, open flame, UV light
(including sunlight)
X
INCOMPATABILITY (MATERIALS TO AVOID): Strong oxidizers, peroxides, UV light sources, sunlight, temperatures over 60 0C and loss of inhibitor.
HAZARDOUS DECOMPOSITION OR BYPRODUCTS: Decomposition will not occur if handled and stored properly. In case of fire, oxides of carbon, oxides of nitrogen,
hydrocarbons, fumes and smoke may be produced.
HAZARDOUS POLYMERIZATION MAY OCCUR WILL NOT OCCUR CONDITIONS TO AVOID: Temperatures over 60 oC, open flame, UV light
(including sunlight)
X
SECTION 11 - TOXICOLOGICAL INFORMATION
CAS # LD50 of Ingredient LC50 of Ingredient
HAZARDOUS COMPONENTS
EINECS # (Specify Species and Route) (Specify Species)
N/A >2000 n/a
Polyurthane acrylate prepolymer resin
N/A skin/rat
42978-66-5 >2000 n/a
triproplyeneglycol diacrylate
256-032-2 skin/rat
947-19-3 >2000 n/a
1-hydroxycyclohexylphenylketone
213-426-9 skin/rat
119-61-9 >2000 n/a
benzophenone
204-337-6 skin/rat
SECTION 12 - ECOLOGICAL INFORMATION
Biologic Degredation: Biodegredation: n.a Maximum permissible toxic concentrations:
Behavior in environmental compartments: Distribution: log p(o/w): n.a. no bioaccumulation to be Algeal toxicity: Sc. Quadricauda IC5: n.a.
expected Bacterial toxicity: M. aeruginosa EC5: n.a.
Ecotoxic effects: Protazoa: E. sulcatum EC5: n.a.
Biological effects: Further ecological data:
Fish toxicity: L. macrochirus LC50: n.a Degradability:
Daphnia toxicity: Daphnia magna EC50:n.a. BOD5: n.a.
COD: n.a.
TOD: n.a.
SECTION 13 - DISPOSAL CONSIDERATIONS
Product: Chemicals must be disposed of in compliance with federal, state and local regulations.
Container: Container must be disposed of in accordance with federal, state and local regulations.
All liquid material should be exposed to UV light or any other free-radical reaction initiator
SECTION 14 - TRANSPORT INFORMATION
PROPER SHIPPING NAME: Polyurehtane prepolymer resin IATA CLASS / Packing Group: Not Regulated
DOT HAZARD CLASS / Packing Group: Not Regulated IMDG HAZARD CLASS: Not Regulated
All information contained herein is accurate to the best of the knowledge at McConnell Labs, Inc.
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REFERENCE: Not Applicable RID / ADR Dangerous Gods Code: Not Regulated
UN/NA ID NUMBER: None UN TDG Class/ Pack Group: Not Regulated
LABEL: None Hazard Identification Number (HIN): Not Regulated
HAZARD SYMBOLS: None
Note: Transportation information provided is for reference only. Client is urged to consult CFR 49 parts 100-177, IMDG, IATA, EU, United Nations TDG and WHIMIS
(Canada) TDG information manuals for detailed regulations and exceptions covering specific container sizes, packaging materials and methods of shipping.
SECTION 15 - REGULATORY INFORMATION
TSCA (USA - Toxic Substance Control Act)
SARA TITLE III (USA - Superfund Amedments and Reauthorization Act)
311 / 312 Hazard Catagories: None
313 Reporatable Ingredients: None
CERCLA (USA - Comprehensive Response and Liability Act) : None
California Prop 65, Safe Drinking Water and Toxic Enforcement Act of 1986
There is nothing known to the State of California to cause cancer or reproductive toxicity.
CFR (Canadian Cntrolled Products Regulations):
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS conains information required by the
Controlled Products Regulations. WHIMIS Classification: None
IDL / NDSL (Canadian Domestic Substances List / Non-Domestic Substances List)
Components of this product identified by CAS number are listed on the DSL or NDSL, or are othersise in comliance with the New Substances Notification (NSN)
regulations. Only ingredients classified as "hazardous" are listed in Section 2 unless otherwise indicated.
EINECS (European Inventory of Existing Commercial Chemical Substances)
Components of this product identified by CAS numbers are on the European Inventory of Existing Commercial Chemical Substances.
WGK Water Index: 1 VbK Index: AIII
RISK PHRASES: SYMBOL(S) REQUIRED FOR LABEL SAFETY PHRASES:
R-36/38 Iriitating to eyes and skin IRRITANT S-24/25 Avoid contact with skin and eyes.
S-26 In case of contact with eyes, rinse
immediately
S-41 In case of fire and/or explosion,
donot breath fumes
EU DIRECTIVES: DIRECTIVE 91/155/EEC amended by Drirective 93/112/EEC and Directive 2001/58/EC : Safety Data Sheets
Dangerous preparations: Directive 1999/45/EC amended by Directive 2001/60/EC - OJEC L226 - 22/08/2001 and
Directive 2006/08/EC - 24/01/2006.
Commission Directive 2004/73/EC of 29 Apil 2004 adapting to technical progress for the 29th time Council Directive
67/548/EEC on the approximation of the laws, regulations and administrative provisions relating to the classification,
packaging and labelling of dangerous substances (Official Journal L216 - 16/06/2004).
SECTION 16 - OTHER INFORMATION
EXPLANATIONS TO R-PHRASES IN SECTION 2:
R-36/38 Irritating to eyes and skin.
R-24 Toxic in contact with skin.
R-43 May cuase sensitization by skin contact.
All information contained herein is accurate to the best of the knowledge at McConnell Labs, Inc.
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