Safety Data Sheet according to Regulation (EU) No. 1907/2006
European Nail Factory
Revision date : 05.09.2007 Revision no. : 1,00
G4C FRENCH GEL WHITE
00642-0045
1. Identification of the substance/preparation and of the company/undertaking
Identification of the substance or preparation
G4C FRENCH GEL WHITE
Art.-No.:
16-644000
Use of the substance/preparation
Cosmetic
Company/undertaking identification
European Nail Factory
In der Salzheck 7
D-56332 Dieblich
Telephone ++49 (0) 26 07-96 60-0
Telefax ++49 (0) 26 07-96 60-29
Contact person
www.europeannailfactory.com
Internet:
Inquiry office
Emergency telephone :++49 (0) 2607 / 96600 European Nail Factory GmbH, available during open hours
Responsible for the safety data sheet: sds@gbk-ingelheim.de
2. Hazards identification
Classification
Indications of danger : Irritant, Dangerous for the environment
R-phrases :
Irritating to eyes, respiratory system and skin.
May cause sensitization by skin contact.
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
3. Composition/information on ingredients
( preparation )
Chemical characterization
Preparation based on polyurethane acrylate oligomer
Hazardous components
EC-No. CAS-No. Chemical name Quantity Classification
aliphatic urethan acrylate oligomer < 60 % Xi R36/37/38
221-950-4 3290-92-4 Propylidynetrimethyl trimethacrylate < 25 % N R51-53
42978-66-5 (1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-etha
256-032-2 < 15 % Xi, N R36/37/38-43-51-53
nediyl)] diacrylate
213-426-9 947-19-3 Hydroxycyclohexyl phenyl ketone < 5 % Xi R36
Full text of each relevant R phrase can be found in heading 16.
4. First aid measures
General information
Remove contaminated soaked clothing immediately.
Call a physician immediately.
GB - EN Page 1 of 6
Safety Data Sheet according to Regulation (EU) No. 1907/2006
European Nail Factory
Revision date : 05.09.2007 Revision no. : 1,00
G4C FRENCH GEL WHITE
00642-0045
After inhalation
Move to fresh air in case of accidental inhalation of vapours or decomposition products.
In the event of persistent symptoms receive medical treatment.
After contact with skin
Wash off immediately with soap and plenty of water.
Consult a doctor if skin irritation persists.
After contact with eyes
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
Seek medical treatment by eye specialist.
After ingestion
Do not induce vomiting.
Rinse out mouth and give plenty of water to drink.
Never give anything by mouth to an unconscious person.
Summon a doctor immediately.
5. Fire-fighting measures
Suitable extinguishing media
Foam, carbon dioxide (CO2), dry chemical, water-spray.
Extinguishing media which must not be used for safety reasons
Full water jet
Special exposure hazards arriving from substance or preparation itself, combustion products,
resulting gases
Fire may produce:
Carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx).
Special protective equipment for fire-fighters
In case of fire, wear suitable respiratory equipment with positive air supply.
Protective suit
Additional information
Cool containers at risk with water spray jet.
Fire residues and contaminated firefighting water must be disposed of in accordance with the local
regulations.
6. Accidental release measures
Personal precautions
Use personal protective clothing.
Ensure adequate ventilation.
Environmental precautions
Do not discharge into the drains/surface waters/groundwater.
Methods for cleaning up/taking up
Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder).
Shovel into suitable container for disposal.
7. Handling and storage
Handling
Advice on safe handling
GB - EN Page 2 of 6
Safety Data Sheet according to Regulation (EU) No. 1907/2006
European Nail Factory
Revision date : 05.09.2007 Revision no. : 1,00
G4C FRENCH GEL WHITE
00642-0045
Keep container tightly closed.
Handle and open container with care.
Avoid contact with skin, eyes and clothing.
Ensure adequate ventilation, especially in confined areas.
Advice on protection against fire and explosion
No special protective measures against fire required.
Storage
Requirements for storage rooms and vessels
Keep container tightly closed in a dry, cool and well-ventilated place.
Keep at temperatures between 5癈 and 40癈.
Protect from light. Keep away from heat.
Further information on storage conditions
Keep away from food, drink and animal feeding stuffs.
10
Storageclass (VCI)
8. Exposure controls/personal protection
Exposure limit values
Exposure controls
Occupational exposure controls
Ensure adequate ventilation, especially in confined areas.
Protective and hygiene measures
Wash hands before breaks and immediately after handling the product.
Avoid contact with skin, eyes and clothing.
Do not inhale vapours.
When using, do not eat, drink or smoke.
Remove and wash contaminated clothes before re-use.
Respiratory protection
In case of insufficient ventilation wear suitable respiratory equipment (gas filter type A).
Hand protection
Protective gloves resistant to chemicals made off butyl, Minimum coat thickness 0,7 mm, Permeation
resistance (wear duration) approx. 480 minutes, i.e. protective glove made by www.kcl.de.
This recommendation refers exclusively to the chemical compatibility and the lab test conforming to EN
374 carried out under lab conditions.
Requirements can vary as a function of the use. Therefore it is necessary to adhere additionally to the
recommendations given by the manufacturer of protective gloves.
Eye protection
Tightly fitting goggles
Eye wash bottle with pure water.
Skin protection
Long sleeved clothing.
9. Physical and chemical properties
General information
Physical state Viscous
Colour White
Odour Like acrylate
GB - EN Page 3 of 6
Safety Data Sheet according to Regulation (EU) No. 1907/2006
European Nail Factory
Revision date : 05.09.2007 Revision no. : 1,00
G4C FRENCH GEL WHITE
00642-0045
Important health, safety and environmental information
Test method
Changes in the physical state
Flash point > 100 癈
Flammability
n. d.
Lower explosion limits
n. d.
Ignition temperature
Density (at 20 癈) : 1,1 g/cm?br>
Immiscible
Water solubility :
at (20 癈)
10. Stability and reactivity
Conditions to avoid
To avoid thermal decomposition, do not overheat.
Materials to avoid
Oxidizing agents., Peroxides, copper and copper alloys
Strong bases.
Hazardous decomposition products
Carbon monoxide (CO), carbon dioxide (CO2) and nitrogen oxides (NOx)
Additional information
No decomposition if stored and applied as directed.
11. Toxicological information
Empirical data on effects on humans
Irritating to eyes, respiratory system and skin.
May cause sensitization by skin contact.
12. Ecological information
Further information
Do not flush into surface water or sanitary sewer system.
Hazard to waters
Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
13. Disposal considerations
Advice on disposal
Can be landfilled after chemical and physical treatment, when in compliance with local regulations.
Where possible recycling is preferred to disposal.
Waste disposal number of waste from residues/unused products
070601 WASTES FROM ORGANIC CHEMICAL PROCESSES; wastes from the MFSU of fats,
grease, soaps, detergents, disinfectants and cosmetics; aqueous washing liquids and mother
liquors
Classified as hazardous waste.
Contaminated packaging
GB - EN Page 4 of 6
Safety Data Sheet according to Regulation (EU) No. 1907/2006
European Nail Factory
Revision date : 05.09.2007 Revision no. : 1,00
G4C FRENCH GEL WHITE
00642-0045
Empty containers should be taken for local recycling, recovery or waste disposal.
Contaminated packaging should be emptied as far as possible and after appropriate cleansing may be
taken for reuse.
Packaging that cannot be cleaned should be disposed of like the product.
14. Transport information
Land transport (ADR/RID)
ADR/RID class 9
M6
Classification code :
Hazard-no. 90
UN number 3082
Hazard label 9
ADR/RID packing group III
LQ 7
Limited quantity :
Description of the goods
Environmentally hazardous substance, liquid, n.o.s. (Propylidynetrimethyl trimethacrylate,
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate)
Remarks (land transport)
LQ 7: combination packaging: 5 l / 30 kg (total gross mass); trays: 5 l / 20 kg (total gross mass).
Inland waterways transport
Marine transport
9
IMDG code
UN number 3082
Marine pollutant No
EmS F-A; S-F
5 L / 30 kg
Limited quantity :
IMDG packing group III
Hazard label 9
Description of the goods
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (propylidynetrimethyl trimethacrylate,
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)diacrylate)
Remarks (marine transport)
Limited quantities (section 3.4): combination packaging: 5 l / 30 kg (total gross mass); trays: 5 l / 20 kg
(total gross mass).
Air transport
ICAO/IATA-DGR 9
UN/ID number 3082
Hazard label 9
914
IATA-packing instructions - Passenger
IATA-max. quantity - Passenger 450 L
IATA-packing instructions - Cargo 914
IATA-max. quantity - Cargo 450 L
ICAO packing group III
Y914 / 30 kg
Limited quantity Passenger
Description of the goods
ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (propylidynetrimethyl trimethacrylate,
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)diacrylate, mixture)
GB - EN Page 5 of 6
Safety Data Sheet according to Regulation (EU) No. 1907/2006
European Nail Factory
Revision date : 05.09.2007 Revision no. : 1,00
G4C FRENCH GEL WHITE
00642-0045
15. Regulatory information
Labelling
Indication of danger Xi - Irritant; N - Dangerous for the environment
Additional advice on labelling According to the EC hazardous substance regulations in compliance with
the EC cosmetic product regulations this product must not be labelled as a
hazardous substance.
According to ruling EC Directives the product must be labelled as
hazardous substance as follows:
Hazardous component(s) to be indicated on label
(1-methyl-1,2-ethanediyl)bis[oxy(methyl-2,1-ethanediyl)] diacrylate
R phrases
36/37/38 Irritating to eyes, respiratory system and skin.
43 May cause sensitization by skin contact.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S phrases
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
37 Wear suitable gloves.
61 Avoid release to the environment. Refer to special instructions / Safety data sheets.
National regulatory information
Water contaminating class 2 - water contaminating
1999/13/EC (VOC) 0%
16. Other information
Full text of R-phrases referred to under sections 2 and 3
36 Irritating to eyes.
36/37/38 Irritating to eyes, respiratory system and skin.
43 May cause sensitization by skin contact.
51 Toxic to aquatic organisms.
51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
53 May cause long-term adverse effects in the aquatic environment.
Other data
Data of items 4 to 8, as well as 10 to 12, do partly not refer to the use and the regular employing of the
product (in this sense consult information on use and on product), but to liberation of major amounts in
case of accidents and irregularities.
The information describes exclusively the safety requirements for the product (s) and is based on the
present level of our knowledge.
The delivery specifications are contained in the corresponding product sheet.
This data does not constitute a guarantee for the characteristics of the product(s) as defined by the legal
warranty regulations.
"(n.a. = not applicable; n.d. = not determined)"
(The data for the hazardous ingredients were taken respectively from the last version of the
sub-contractor's safety data sheet.)
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