MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER - FRESH SCENT - CONCENTRATE (Product No. 13, Twist 'n
Fill(TM) System) 06/11/2008
Material Safety Data Sheet
Copyright, 2008, 3M Company. All rights reserved. Copying and/or downloading of this information for the purpose of properly
utilizing 3M products is allowed provided that: (1) the information is copied in full with no changes unless prior written agreement is
obtained from 3M, and (2) neither the copy nor the original is resold or otherwise distributed with the intention of earning a profit
thereon.
SECTION 1: PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: 3M(TM) DEODORIZER - FRESH SCENT - CONCENTRATE (Product No. 13, Twist 'n
Fill(TM) System)
MANUFACTURER: 3M
DIVISION: Building & Commercial Services Division
ADDRESS: 3M Center
St. Paul, MN 55144-1000
EMERGENCY PHONE: 1-800-364-3577 or (651) 737-6501 (24 hours)
Issue Date: 06/11/2008
Supercedes Date: 09/06/2005
Document Group: 20-4425-3
Product Use:
Intended Use: Deodorizer
Specific Use: Long-lasting deodorizer leaves a fresh, clean scent.
SECTION 2: INGREDIENTS
Ingredient C.A.S. No. % by Wt
POLYALKOXY ALCOHOLS 69013-18-9 30 - 60
FRAGRANCE (NJTSN 04499600-6517) Trade Secret 15 - 40
WATER 7732-18-5 10 - 30
SORBITAN POLYETHOXY MONOLAURATE 9005-64-5 10 - 30
DYE 3844-45-9 < 0.05
SECTION 3: HAZARDS IDENTIFICATION
3.1 EMERGENCY OVERVIEW
Specific Physical Form: Liquid
Odor, Color, Grade: Clear; dark blue color; strong fragrance
General Physical Form: Liquid
Immediate health, physical, and environmental hazards: May cause severe eye irritation.
3.2 POTENTIAL HEALTH EFFECTS
Eye Contact:
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MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER - FRESH SCENT - CONCENTRATE (Product No. 13, Twist 'n
Fill(TM) System) 06/11/2008
Severe Eye Irritation: Signs/symptoms may include significant redness, swelling, pain, tearing, cloudy appearance of the cornea, and
impaired vision.
Skin Contact:
Mild Skin Irritation: Signs/symptoms may include localized redness, swelling, and itching.
Inhalation:
Respiratory Tract Irritation: Signs/symptoms may include cough, sneezing, nasal discharge, headache, hoarseness, and nose and
throat pain.
Ingestion:
Gastrointestinal Irritation: Signs/symptoms may include abdominal pain, stomach upset, nausea, vomiting and diarrhea.
SECTION 4: FIRST AID MEASURES
4.1 FIRST AID PROCEDURES
The following first aid recommendations are based on an assumption that appropriate personal and industrial hygiene practices are
followed.
Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes. Get immediate medical attention.
Skin Contact: Wash affected area with soap and water. If signs/symptoms develop, get medical attention.
Inhalation: Remove person to fresh air. If signs/symptoms develop, get medical attention.
If Swallowed: Do not induce vomiting unless instructed to do so by medical personnel. Give victim two glasses of water. Never
give anything by mouth to an unconscious person. Get medical attention.
SECTION 5: FIRE FIGHTING MEASURES
5.1 FLAMMABLE PROPERTIES
> 212 篎 [Test Method: Tagliabue Closed Cup]
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
Class IIIB Combustible Liquid
OSHA Flammability Classification:
5.2 EXTINGUISHING MEDIA
Ordinary combustible material. Use fire extinguishers with class A extinguishing agents (e.g., water, foam).
5.3 PROTECTION OF FIRE FIGHTERS
Special Fire Fighting Procedures: Wear full protective equipment (Bunker Gear) and a self-contained breathing apparatus (SCBA).
Unusual Fire and Explosion Hazards: Not applicable.
Note: See STABILITY AND REACTIVITY (SECTION 10) for hazardous combustion and thermal decomposition
information.
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MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER - FRESH SCENT - CONCENTRATE (Product No. 13, Twist 'n
Fill(TM) System) 06/11/2008
SECTION 6: ACCIDENTAL RELEASE MEASURES
Accidental Release Measures: Observe precautions from other sections. Call 3M- HELPS line (1-800-364-3577) for more
information on handling and managing the spill. Evacuate unprotected and untrained personnel from hazard area. The spill should be
cleaned up by qualified personnel. Ventilate the area with fresh air. For large spill, or spills in confined spaces, provide mechanical
ventilation to disperse or exhaust vapors, in accordance with good industrial hygiene practice. Warning! A motor could be an ignition
source and could cause flammable gases or vapors in the spill area to burn or explode. Contain spill. For larger spills, cover drains
and build dikes to prevent entry into sewer systems or bodies of water. Working from around the edges of the spill inward, cover with
bentonite, vermiculite, or commercially available inorganic absorbent material. Mix in sufficient absorbent until it appears dry.
Collect as much of the spilled material as possible. Clean up residue with detergent and water. Collect the resulting residue
containing solution. Place in a closed container approved for transportation by appropriate authorities. Dispose of collected material
as soon as possible.
In the event of a release of this material, the user should determine if the release qualifies as reportable according to
local, state, and federal regulations.
SECTION 7: HANDLING AND STORAGE
7.1 HANDLING
Keep out of the reach of children. This product is not intended to be used without prior dilution as specified on the product label.
Avoid breathing of vapors, mists or spray. Avoid skin contact. Avoid eye contact. Do not eat, drink or smoke when using this
product. Wash exposed areas thoroughly with soap and water. Avoid contact with oxidizing agents.
7.2 STORAGE
Keep container in well-ventilated area. Store away from oxidizing agents.
SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION
8.1 ENGINEERING CONTROLS
Use in a well-ventilated area. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical
Dispenser, special ventilation is not required.
8.2 PERSONAL PROTECTIVE EQUIPMENT (PPE)
8.2.1 Eye/Face Protection
Avoid eye contact. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, eye
contact with the concentrate is not expected to occur.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, the following eye protection is
recommended: Indirect Vented Goggles.
8.2.2 Skin Protection
Avoid skin contact. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM) Chemical Dispenser, skin
contact with the concentrate is not expected to occur.
If the product is not used with the Twist 'n Fill system or if there is an accidental release, select and use gloves and/or protective
clothing to prevent skin contact based on the results of an exposure assessment. Consult with your glove and/or protective clothing
manufacturer for selection of appropriate compatible materials. Gloves made from the following materials are recommended: Butyl
Rubber, Neoprene
8.2.3 Respiratory Protection
Avoid breathing of vapors, mists or spray. NOTE: When used as directed and diluted and dispensed with a TWIST 'n FILL(TM)
Chemical Dispenser, respiratory protection is not required.
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MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER - FRESH SCENT - CONCENTRATE (Product No. 13, Twist 'n
Fill(TM) System) 06/11/2008
If the product is not used with the Twist 'n Fill system or if there is an accidental release, select one of the following NIOSH
approved respirators based on airborne concentration of contaminants and in accordance with OSHA regulations: Half facepiece or
fullface air-purifying respirator with organic vapor cartridges and N95 particulate prefilters. Consult the current 3M Respiratory
Selection Guide for additional information or call 1-800-243-4630 for 3M technical assistance.
8.2.4 Prevention of Swallowing
Do not eat, drink or smoke when using this product. Wash exposed areas thoroughly with soap and water.
8.3 EXPOSURE GUIDELINES
None Established
SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES
Liquid
Specific Physical Form:
Clear; dark blue color; strong fragrance
Odor, Color, Grade:
Liquid
General Physical Form:
> 212 篎 [Test Method: Tagliabue Closed Cup]
Flash Point
No Data Available
Flammable Limits - LEL
No Data Available
Flammable Limits - UEL
> 212 篎
Boiling point
<=27 psia [@ 131 篎]
Vapor Pressure
1 [Ref Std: WATER=1]
Specific Gravity
6 - 8.5
pH
Complete
Solubility in Water
10 - 30 % [Test Method: calculated per CARB title 2]
Volatile Organic Compounds
20 - 60 %
Percent volatile
122 - 366 g/l [Test Method: calculated per CARB title 2]
VOC Less H2O & Exempt Solvents
< 100 centipoise
Viscosity
SECTION 10: STABILITY AND REACTIVITY
Stability: Stable.
Materials and Conditions to Avoid: Strong oxidizing agents
Hazardous Polymerization: Hazardous polymerization will not occur.
Hazardous Decomposition or By-Products
Substance Condition
Carbon monoxide During Combustion
Carbon dioxide During Combustion
SECTION 11: TOXICOLOGICAL INFORMATION
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MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER - FRESH SCENT - CONCENTRATE (Product No. 13, Twist 'n
Fill(TM) System) 06/11/2008
Please contact the address listed on the first page of the MSDS for Toxicological Information on this material and/or its
components.
SECTION 12: ECOLOGICAL INFORMATION
ECOTOXICOLOGICAL INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
CHEMICAL FATE INFORMATION
A 3M Product Environmental Data Sheet (PED) is available.
SECTION 13: DISPOSAL CONSIDERATIONS
Waste Disposal Method: Incinerate in an industrial or commercial facility in the presence of a combustible material. As a disposal
alternative, dispose of waste product in a facility permitted to accept chemical waste.
EPA Hazardous Waste Number (RCRA): Not regulated
Since regulations vary, consult applicable regulations or authorities before disposal.
SECTION 14:TRANSPORT INFORMATION
ID Number UPC ID Number UPC
70-0713-1130-5 00-48011-20121-9 70-0713-1131-3 00-48011-23896-3
Please contact the emergency numbers listed on the first page of the MSDS for Transportation Information for this
material.
SECTION 15: REGULATORY INFORMATION
US FEDERAL REGULATIONS
311/312 Hazard Categories:
Fire Hazard - No Pressure Hazard - No Reactivity Hazard - No Immediate Hazard - Yes Delayed Hazard - No
STATE REGULATIONS
CHEMICAL INVENTORIES
The components of this product are in compliance with the chemical notification requirements of TSCA.
All applicable chemical ingredients in this material are listed on the European Inventory of Existing Chemical Substances (EINECS),
or are exempt polymers whose monomers are listed on EINECS.
All the components of this product are listed on China's Inventory of Chemical Substances.
The components of this product are in compliance with notification requirements in the Philippines.
The components of this product are listed on the Canadian Domestic Substances List.
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MATERIAL SAFETY DATA SHEET 3M(TM) DEODORIZER - FRESH SCENT - CONCENTRATE (Product No. 13, Twist 'n
Fill(TM) System) 06/11/2008
INTERNATIONAL REGULATIONS
This MSDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29 CFR 1910.1200.
SECTION 16: OTHER INFORMATION
NFPA Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Special Hazards: None
National Fire Protection Association (NFPA) hazard ratings are designed for use by emergency response personnel to address the hazards that are
presented by short-term, acute exposure to a material under conditions of fire, spill, or similar emergencies. Hazard ratings are primarily based on the
inherent physical and toxic properties of the material but also include the toxic properties of combustion or decomposition products that are known to
be generated in significant quantities.
HMIS Hazard Classification
Health: 2 Flammability: 1 Reactivity: 0 Protection: X - See PPE section.
Hazardous Material Identification System (HMIS? hazard ratings are designed to inform employees of chemical hazards in the workplace. These
ratings are based on the inherent properties of the material under expected conditions of normal use and are not intended for use in emergency
situations. HMIS?ratings are to be used with a fully implemented HMIS?program. HMIS?is a registered mark of the National Paint and Coatings
Association (NPCA).
Revision Changes:
Section 1: Product use information was modified.
Section 1: Division name was modified.
Copyright was modified.
Section 1: Initial issue message was modified.
Section 14: ID Number(s) and/or UPC(s) Template 1 was added.
Section 2: Ingredient table was added.
Section 8: Exposure guidelines information - none - was added.
DISCLAIMER: The information in this Material Safety Data Sheet (MSDS) is believed to be correct as of the date issued. 3M
MAKES NO WARRANTIES, EXPRESSED OR IMPLIED, INCLUDING, BUT NOT LIMITED TO, ANY IMPLIED WARRANTY
OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE OR COURSE OF PERFORMANCE OR USAGE OF
TRADE. User is responsible for determining whether the 3M product is fit for a particular purpose and suitable for user's method of
use or application. Given the variety of factors that can affect the use and application of a 3M product, some of which are uniquely
within the user's knowledge and control, it is essential that the user evaluate the 3M product to determine whether it is fit for a
particular purpose and suitable for user's method of use or application.
3M provides information in electronic form as a service to its customers. Due to the remote possibility that electronic transfer may
have resulted in errors, omissions or alterations in this information, 3M makes no representations as to its completeness or accuracy.
In addition, information obtained from a database may not be as current as the information in the MSDS available directly from 3M.
3M MSDSs are available at www.3M.com
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