Material Safety
Data Sheet *2
1
0
MSDS Number: CT 10096-2
DATE PREPARED: March 7, 2008
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product/Trade Name:
CertaSpray Foam (Closed Cell)
Chemical Name: Not Applicable
CAS #: Not Applicable
Common Name: CertaSpray-B (Closed Cell)
Product Use: CertaSpray closed cell spray foam is a two component HFC-blown spray foam.
When CertaSpray-A is mixed with CertaSpray-BCC under pressure in a 1:1 volumetric ratio, it
expands into a high density closed-cell foam.
MANUFACTURER INFORMATION: TELEPHONE AND E-MAIL:
CertainTeed Corporation (610) 341-7000 9 AM ?5 PM
P.O. Box 860 (Eastern Time ?USA)
Valley Forge, PA 19482-0101 CertainTeed-EHS@saint-gobain.com
EMERGENCY TELEPHONE: CHEMTREC (800) 424-9300
2. HAZARD IDENTIFICATION
Emergency Overview
This is a liquid product.
Harmful if absorbed through the skin. Causes severe eye irritation. Causes respiratory tract and
skin irritation. Contains a material which may cause birth defects. Contains a material which may
cause damage to blood, cardiovascular system, kidneys, central nervous system and liver. May
be harmful if swallowed.
Summary
Do not ingest. Avoid contact with eyes, skin, and clothing. Avoid breathing vapor or mist. Keep
container closed. Use only with adequate ventilation. Wash thoroughly after handling.
Routes of Exposure: Inhalation, skin, and eye contact.
Potential Health Effects: Eyes
Avoid contact with eyes. Causes sever irritation.
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MSDS Number: CT 10096-2
Potential Health Effects: Skin
Avoid contact with skin. Harmful if absorbed through the skin.
Potential Health Effects: Ingestion
Do not ingest. Harmful if swallowed.
Potential Health Effects: Inhalation
Avoid breathing vapor or mist.
Medical Conditions Aggravated by Exposure: None.
HMIS Ratings: Health: 2* Fire: 1 Physical Hazard: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe * = Chronic hazard
3. COMPOSITION / INFORMATION ON INGREDIENTS
CAS # Component Percent
Not Polyester Polyol 30-60
Available
Not Polyether Polyol 10-30
Available
460-73-1 1,1,1,3,3-Pentafluoropropane 5-10
78-40-0 Triethyl phosphate 1-5
13674-84-5 Tris(1-chloro-2-propyl) phosphate (TCPP) 1-5
34354-45-5 Diethanolomine 1-5
108-01-0 Dimethylaminoethanol 0.5-1.5
3855-32-1 Pentamethyldipropylenetriamine 0.5-1.5
107-21-1 Ethylene glycol 0.1-1
Component Information/Information on Non-Hazardous Components
This product is considered hazardous under the OSHA Hazard Communication Standard (29
CFR 1910.1200).
This product is a controlled product under Canadian WHMIS regulations.
4. FIRST AID MEASURES
First Aid: Eyes
Immediately flush eyes with large amounts of water for at least 15 minutes. Seek medical
attention at once.
First Aid: Skin
Remove contaminated clothing. Wash exposed areas with soap and water for at least 15
minutes. If irritation develops or persists, seek medical attention. Contaminated leather articles,
including shoes, that cannot be decontaminated should be discarded. Launder contaminated
clothing before reuse. Do not take clothing home to be laundered.
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First Aid: Ingestion
If the product is ingested, seek immediate medical attention or advice. Do not induce vomiting.
If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration. Never give
anything by mouth to a victim who is unconscious or is having convulsions. Have victim rinse
mouth thoroughly with water.
First Aid: Inhalation
If the product is inhaled, remove the affected person to fresh air. If breathing is difficult,
administer oxygen and/or artificial respiration if necessary and seek medical attention.
Notes to Physician:
Adrenalin and similar sympathomimetic drugs should be avoided following exposure as
cardiac arrhythmia may result with possible subsequent cardiac arrest. Symptomatic
treatment and supportive therapy as indicated. Following severe exposure the patient
should be kept under medical review for at least 48 hours as delayed pulmonary
oedema may develop.
5. FIRE FIGHTING MEASURES
General Fire Hazards:
See Section 9 for Flammability Properties. Cool containers with water spray.
Hazardous Combustion Products:
Combustion products may include carbon oxides, nitrogen oxides, halogenated compounds,
phosphates, hydrogen chloride and hydrogen fluoride. Carbon Monoxide is the primary
combustion byproduct of concern.
Extinguishing Media:
Use methods for the surrounding fire.
Fire Fighting Equipment/Instructions
Standard fire fighting protective equipment is recommended, including full-face, self-contained
breathing apparatus and impervious protective clothing.
NFPA Ratings: Health: 2 Fire: 1 Reactivity: 0
Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate 3 = Serious 4 = Severe
6. ACCIDENTAL RELEASE MEASURES
Containment Procedures:
Wear appropriate personal protective equipment. Stop the flow of material, if this can be done
without risk.
Clean-Up Procedures:
Ventilate the contaminated area. Absorb spilled material with inert absorbent (sand, earth).
Shovel material into an appropriate container for disposal or recovery. Dispose of in accordance
with federal, state and local regulations in a permitted waste management facility.
Evacuation Procedures:
Evacuate the area promptly. Keep upwind of the spilled material and isolate exposure.
Special Procedures:
Avoid inhalation of vapors or mists. Surfaces may become slippery after spillage.
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7. HANDLING AND STORAGE
Handling Procedures:
Avoid contact with skin and eyes. Keep container closed. Use this product with adequate
ventilation. Avoid breathing vapors or mists of this product. Wash thoroughly after handling. Do
not ingest.
Storage Procedures:
It is recommended that the product drums should be stored between 50?00癋. Keep containers
tightly closed. Keep container in a dry, well-ventilated area protected from freezing, rain, direct
sunlight and excess heat. The storage life of chemicals is 3 months. Do not store material near
food, feed or drinking water.
8. EXPOSURE CONTROL / PERSONAL PROTECTION
A: Component Exposure Limits
Ethylene glycol (107-21-1)
ACGIH: 100 mg/m3 Ceiling (aerosol only)
Engineering Controls:
Provide adequate local exhaust ventilation to maintain worker exposures below exposure limits.
PERSONAL PROTECTIVE EQUIPMENT
Personal Protective Equipment: General
Use appropriate personal protective equipment when handling this product. Eye wash fountain
and emergency showers are recommended in areas where this product may be handled/used.
Personal Protective Equipment: Eyes/Face
Wear chemical goggles; add face shield (if splashing is possible).
Personal Protective Equipment: Skin
Wear impervious gloves, such as neoprene, nitrile rubber, or butyl rubber at all times when
handling this product. Thin latex disposable gloves should be avoided for repeated or long term
use. Work clothing sufficient to prevent all skin contact should be worn.
Personal Protective Equipment: Respiratory
If ventilation is not sufficient to effectively prevent build-up of vapors, appropriate NIOSH-
approved (or equivalent) respiratory protection must be provided with NIOSH-approved (or
equivalent) cartridges for protection against organic vapors and a P100 (HEPA) particulate filter.
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MSDS Number: CT 10096-2
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Odor:
Liquid. Not Available.
Physical State: pH:
Liquid. Not Available.
Vapor Pressure: Vapor Density:
Not Available. Not Available.
Boiling Point: Melting Point:
Not Available. Not Available.
o o
Solubility (H2O): Specific Gravity:
Not Available. 1.14 g/ml at 77 F (25 C)
Flash Point: Flash Point Method:
>230癋 (110癈) Closed cup.
Lower Flammability Upper Flammability
Not Available. Not Available.
Limit: Limit:
Auto Ignition Temp.: Burning Rate:
Not Available. Not Available.
Flame Spread Index, 4 Flame Spread Method
<25 ASTM E84
inch
Smoke Index, 4 inch Smoke Index Method
<450 ASTM E84
10. CHEMICAL STABILITY AND REACTIVITY INFORMATION
Chemical Stability: Stable under normal conditions.
Conditions to Avoid: None identified
Incompatibility:
Reactive or incompatible with oxidizing materials, organic materials, metals, acids and alkalis.
Hazardous Decomposition:
May include carbon oxides, nitrogen oxides, halogenated compounds, phosphates, hydrogen
chloride, and hydrogen fluoride.
Possibility of Hazardous Reactions: None identified.
11. TOXICOLOGICAL INFORMATION
Acute Dose Effects
A: General Product Information:
Harmful if absorbed through the skin. Causes eye irritation. Causes respiratory tract and
skin irritation.
B: Component Analysis - LD50/LC50
Triethyl phosphate (78-40-0)
Oral LD50 Rat: 1311 mg/kg
Tris(1-chloro-2-propyl) phosphate (TCPP) (13674-84-5)
Inhalation LC50 Rat: 5 mg/L/4H; Inhalation LC50 Rat: >17.8 mg/L/1H; Oral LD50 Rat:
500 mg/kg; Dermal LD50 Rat: >5000 mg/kg; Dermal LD50 Rabbit: 1230 mg/kg
Dimethylaminoethanol (108-01-0)
Inhalation LC50 Rat: 6.1 mg/L/4H; Inhalation LC50 Rat: 1641 ppm/4H; Oral LD50 Rat:
1803 mg/kg; Dermal LD50 Rabbit: 1370 礚/kg
Ethylene glycol (107-21-1)
Oral LD50 Rat: 4000 mg/kg; Dermal LD50 Rabbit: 9530 礚/kg
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MSDS Number: CT 10096-2
C: Repeated Dose Effects:
Contains a material which may cause birth defects. Contains a material which may
cause damage to blood, cardiovascular system, kidneys, central nervous system and
liver.
Carcinogenicity
A: General Product Information: None identified.
B: Ethylene glycol (107-21-1)
ACGIH: A4 - Not Classifiable as a Human Carcinogen
Mutagenicity: No known significant effects or critical hazards.
Teratogenicity: No known significant effects or critical hazards.
Developmental Effects: Contains a material which can cause birth defects.
12. ECOLOGICAL INFORMATION
Ecotoxicity
A: General Product Information:
No information available for this product.
B: Component Analysis ?Ecotoxicity ?Aquatic Toxicity:
Tris(1-chloro-2-propyl) phosphate (TCPP) (13674-84-5)
Test & Species Conditions
96 Hr LC50 Brachydanio rerio 56.2 mg/L static
96 Hr LC50 Leuciscus idus 180 mg/L static
96 Hr LC50 Pimephales promelas 98 mg/L static
96 Hr LC50 Poecilia reticulata 30 mg/L static
72 Hr EC50 Scenedesmus 45 mg/L
subspicatus
96 Hr EC50 Selenastrum 4 mg/L
capricornutum
30 min EC50 Photobacterium 295 mg/L
phosphoreum
48 Hr EC50 Daphnia magna 63 mg/L
Dimethylaminoethanol (108-01-0)
Test & Species Conditions
96 Hr LC50 Pimephales promelas 81 mg/L [static
72 Hr EC50 Scenedesmus 35 mg/L
subspicatus
48 Hr EC50 Daphnia magna 98.77 mg/L
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MSDS Number: CT 10096-2
Ethylene glycol (107-21-1)
Test & Species Conditions
96 Hr LC50 Oncorhynchus mykiss 41000 mg/L
96 Hr LC50 Lepomis macrochirus 27500 mg/L
96 Hr LC50 Oncorhynchus mykiss 40761 mg/L static
96 Hr LC50 Pimephales promelas 49000 mg/L static
96 Hr LC50 Poecilia reticulata 16000 mg/L static
96 Hr EC50 Selenastrum 6500-1300 mg/L
capricornutum
30 min EC50 Photobacterium 620.0 mg/L
phosphoreum
30 min EC50 Photobacterium 620 mg/L
phosphoreum
16 Hr EC50 Pseudomonas putida 10000 mg/L
48 Hr EC50 water flea 46300 mg/L
13. WASTE DISPOSAL CONSIDERATIONS
US EPA Waste Number & Descriptions
A: General Product Information:
Wastes must be tested using methods described in 40 CFR Part 261 to determine if it
meets applicable definitions of hazardous wastes. (Check with ChemAdvisor about a
general statement of hazardous waste. Compare to Huntsman MSDS, maybe there is
nothing else we can say and that's OK too)
B: Component Waste Numbers:
No EPA-listed Waste Numbers are being shown for this product's components.
Disposal Instructions:
The generation of waste should be avoided or minimized wherever possible. Avoid dispersal of
spilled material and runoff and contact with soil, waterways, drains and sewers. Dispose of waste
material according to Federal, State, local and Provincial environmental regulations. See Section
7 for Handling Procedures; see Section 8 for Personal Protective Equipment recommendations.
14. TRANSPORTATION INFORMATION
International Transportation Regulations:
This product is not regulated as a hazardous material by the United States (DOT) or Canadian
(TDG) transportation regulations.
15. REGULATORY INFORMATION
US Federal
A: General Product Information:
Components of this product have been checked against the non-confidential TSCA
inventory by CAS Registry Number. Components not identified on this non-confidential
inventory are either exempt from listing (i.e. polymers, hydrates) or are listed on the
confidential inventory as declared by the supplier.
B: CERCLA:
This material contains one or more of the following chemicals required to be identified
under CERCLA (40 CFR 302.4).
Ethylene glycol (107-21-1)
CERCLA: 5000 lb final RQ; 2270 kg final RQ
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MSDS Number: CT 10096-2
Acute Health: Yes Chronic Health: Yes Fire: No Pressure: No Reactive: No
State Regulations
A: General Product Information:
Other state regulations may apply. Check individual state requirements.
B: Component Analysis ?State:
The following components appear on one or more of the following state hazardous
substances lists:
Component CAS CA MA MN NJ PA RI
Dimethylaminoethanol 108-01-0 No Yes No Yes Yes No
Ethylene glycol 107-21-1 Yes Yes Yes Yes Yes Yes
C: California Safe Drinking Water and Toxics Enforcement Act (Proposition 65)
The following statement(s) are provided under the California Safe Drinking Water and
Toxic Enforcement Act of 1986 (Proposition 65):
WARNING! This product contains a chemical known to the state of California to cause cancer.
Canadian WHMIS Information
A: General Product Information:
WHMIS Class D1B, D2A, D2B ?Irritating to eyes and skin.
B: Component Analysis - WHMIS IDL:
No components are listed in the WHMIS IDL.
WHMIS Classification:
WHMIS Class D1B, D2A, D2B
Additional Regulatory Information
A: General Product Information: No additional information available.
B: Component Analysis - Inventory
Component CAS # TSCA DSL
1,1,1,3,3-Pentafluoropropane 460-73-1 Yes No
1,2-Benzenedicarboxylic acid, 3,4,5,6- 20566-35-2 Yes Yes
tetrabromo-, 2-(2-hydroxyethoxy)ethyl
2-hydroxypropyl ester
Triethyl phosphate 78-40-0 Yes Yes
Tris(1-chloro-2-propyl) phosphate 13674-84-5 Yes Yes
(TCPP)
Diethanolomine 34354-45-5 Yes No
Dimethylaminoethanol 108-01-0 Yes Yes
Pentamethyldipropylenetriamine 3855-32-1 Yes Yes
Ethylene glycol 107-21-1 Yes Yes
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16. ADDITIONAL COMMENTS
Other Information:
Disclaimer: Supplier gives no warranty of merchantability or of fitness for a particular purpose.
Any product purchased is sold on the assumption the purchaser will make his own tests to
determine the quality and suitability of the product. Supplier expressly disclaims any and all
liability for incidental and/or consequential property damage arising out of the use of this product.
No information provided shall be deemed to be a recommendation to use any product in conflict
with any existing patent rights. Read the Material Safety Data Sheet before handling product.
Acronyms/definitions used in this MSDS:
ACGIH American Conference of Governmental Industrial Hygienists;
CAS # Chemical Abstracts Services Number;
CERCLA Comprehensive Environmental Response, Compensation and Liability Act;
CFR Code of Federal Regulations;
EPA Environmental Protection Agency;
HMIS Hazardous Material Identification System;
IARC International Agency for Research on Cancer;
LFL Lower Flammable Limit;
mg/m3 Milligrams per cubic meter;
NFPA National Fire Protection Association;
NIOSH National Institute for Occupational Safety and Health;
NTP National Toxicology Program;
OSHA Occupational Safety and Health Administration;
ppm Parts per million;
PEL Permissible Exposure Limit;
REL Recommended Exposure Limit;
SARA Superfund Amendments and Reauthorization Act;
RCRA Resource Conservation and Recovery Act;
Title III Emergency Planning and Community Right to Know Act;
Section 302- Extremely Hazardous Substances;
Section 313- Toxic Chemicals;
TLV Threshold Limit Value;
TWA Time Weighted Average;
UFL Upper Flammable Limit.
MSDS History
MSDS Revision Summary:
Date MSDS No. Comments
05/21/2007 CT 10096-1 New MSDS
06/15/2007 CT 10096-1 Formatting changes
06/27/2007 CT 10096-1 Additional Property Information
08/31/2007 CT 10096-1 Additional Component Information
09/10/2007 CT 10096-1 Additional to Emergency Overview
03/07/2008 CT 10096-2 Update product name
This is the end of MSDS # CT 10096-2
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