Pacific Scientific Energetic Materials Co.
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1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: Cartridge Assembly
TRADE NAME(S) / SYNONYM(S): fire extinguisher cartridge; BNCP E3A, 170's,
or 'SINGLE PIN' FIREX (replaces 2-100170)
NATIONAL STOCK NUMBER (NSN): 1377-01-037-8538
PRODUCT NUMBER(S): 2-102670-1 [30903951]
2-101435-1 (in-house, w/o protective features)
2-102670-2 [30903801]
2-101435-2 (in-house, w/o protective features)
MSDS NUMBER / SPECIFYING LETTER: 00233 X (COMMERCIAL [1.4C] VERSION)
REVISION DATE: 7 June 2001
SHIPPING REFERENCE NUMBER: US DOT Competent Authority: EX-0106015
MANUFACTURER: TELEPHONE NUMBERS:
Danaher Corporation - (520) 796-1100 [6am-4pm MST]
Pacific Scientific Energetic Materials Co. (520) 796-1243 FAX
7073 West Willis Road, #5002 (800) 535-5053 Infotrac [24-hr]
Chandler, Arizona 85226-5111 [website - www.psemc.com]
2. COMPOSITION / INFORMATION ON INGREDIENTS
HAZARDOUS INGREDIENTS (* - below required reporting levels per OSHA, 29 CFR ?1900.1200)
COMPONENT NAME / CAS NUMBER: hexanitrostilbene (HNS) / 20062-22-0
WEIGHT PERCENTAGE: < 1 %*
COMPONENT NAME / CAS NUMBER: tetraammine-cis-bis(5-nitro-2H-
tetraazolato-N 2 ) cobaltIII perchlorate
(BNCP) / 178959-25-6
WEIGHT PERCENTAGE: < 1 %*
COMPONENT NAME / CAS NUMBER: zirconium, metal powder / 7440-67-7
WEIGHT PERCENTAGE: < 0.1 %*
COMPONENT NAME / CAS NUMBER: potassium perchlorate (KP) / 7778-74-7
WEIGHT PERCENTAGE: < 0.1 %*
COMPONENT NAME / CAS NUMBER: graphite [C] / 7782-42-5
WEIGHT PERCENTAGE: < 0.1 %*
COMPONENT NAME / CAS NUMBER: difluoroethene-hexafluoropropene-tetra-
fluoroethene terpolymer / 25190-89-0
WEIGHT PERCENTAGE: < 0.1 %*
NET EXPLOSIVE WEIGHT (NEW): 332 - 362 mg
Pacific Scientific Energetic Materials Co.
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fire extinguisher cartridge
MSDS NUMBER: REVISION: 7 June 2001
00233
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
WARNING: Explosive Product ! Do not attempt to manually fight fires. Product
may be sensitive to shock, impact, friction, electrostatic discharge, high pressure or
high temperature. Product may ignite and explode if exposed to any of these
conditions, releasing toxic fumes, heat, shock waves and container fragments.
POTENTIAL HEALTH EFFECTS (ACUTE AND CHRONIC)
EYES: The product is sealed preventing exposure to the hazardous ingredients
inside. If product seal ruptures exposing hazardous ingredients inside, discard
product avoiding contact with the eyes. Exposure to ignition products may cause eye
irritation.
SKIN: The product is sealed preventing exposure to the hazardous ingredients inside.
If product seal ruptures, discard product avoiding contact with the skin. Poses little or
no immediate hazard. Exposure to ignition products may cause skin irritation.
INHALATION: The product is sealed preventing exposure to the hazardous
ingredients inside. Exposure to ignition products may cause respiratory irritation.
Ignition products will contain zirconium, cobalt, chlorine and fluorine compounds, plus
nitrogen oxides.
INGESTION: Not a hazard in normal industrial use. If product seal ruptures, discard
product using proper protection. Some ingredients are highly poisonous by ingestion.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Pre-existing pulmonary diseases
such as emphysema, asthma, etc. may be aggravated by overexposure to ignition products.
CARCINOGENICITY (CANCER) LISTING STATUS
OSHA, NTP & NIOSH: Neither the product nor its hazardous components are listed
IARC: 2B - Limited Evidence [cobalt compound]
ACGIH: A3 - Animal Carcinogen [inorganic cobalt compound, as cobalt]
REFER TO SECTION 11, TOXICOLOGICAL INFORMATION, FOR ADDITIONAL DATA.
4. FIRST AID MEASURES
EYES: If exposed to container fragmentation, bandage eyes and transport. If exposed to
ignition byproducts, remove contact lenses immediately, flush with water for at least 15
minutes, occasionally lifting upper and lower eyelids. Seek medical attention if needed.
SKIN: Wash off any residue with soap and warm water. Seek medical attention if irritation
develops.
INHALATION: Remove to fresh air. If breathing has stopped, give artificial respiration. If
breathing is difficult, administer oxygen. Seek immediate medical attention.
INGESTION: Seek immediate medical attention.
Pacific Scientific Energetic Materials Co.
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fire extinguisher cartridge
MSDS NUMBER: REVISION: 7 June 2001
00233
NOTE TO PHYSICIAN: Supportive care. Product ignition produces small quantities of
zirconium, cobalt, chlorine and fluorine compounds, plus nitrogen oxides. Treatment based
on judgement of the physician in response to reactions of the patient.
5. FIRE FIGHTING MEASURES
FLAMMABLE PROPERTIES
FLASH POINT: not applicable
METHOD USED: not applicable
LOWER FLAMMABLE LIMIT: self-oxidizing
UPPER FLAMMABLE LIMIT: self-oxidizing
AUTOIGNITION TEMPERATURE: 480癋 ( 250癈) [BNCP]
FIRE AND EXPLOSION HAZARD: WARNING - Explosive Product ! Product may be
sensitive to shock, impact, friction, electrostatic discharge, high pressure or high
temperature. Must not be confined if burning. Product may deflagrate or detonate if
exposed releasing toxic fumes, heat, shock waves and container fragments.
EXTINGUISHING MEDIA: Permanently-installed, automatic water sprinkler / deluge system
is recommended.
FIRE FIGHTING INSTRUCTIONS: Do not attempt to manually fight fires. In case of fire,
personnel should immediately evacuate the area, using as much protective cover as possible
and activate deluge and alarm systems.
HAZARDOUS COMBUSTION PRODUCTS: Extreme heat and toxic gases containing
zirconium, cobalt, chlorine and fluorine compounds; plus nitrogen oxides may be emitted
during ignition.
6. ACCIDENTAL RELEASE MEASURES
SMALL SPILL: If product seal ruptures, barricade area, eliminate ignition sources, use a
soft bristle brush and a conductive rubber pan or rubber shovel to clean-up spills. Use
conductive containers and ground all containers when transferring the spilled material. Refer
to Section 9 for the proper desensitizing agent to wet and desensitize the spilled material.
LARGE SPILL
SOIL SPILL: Remove all contaminated soil to dispose of as hazardous waste.
AIR RELEASE: Not applicable
WATER SPILL: Flush with copious amounts of water. Collect water to dispose of as
hazardous waste.
OCCUPATIONAL SPILL: If product seal ruptures, barricade area and eliminate ignition
sources. Refer to SMALL SPILL above.
7. HANDLING AND STORAGE
HANDLING: Handling and use of explosives and related dangerous materials must be
limited to personnel who are specifically authorized and trained in this area.
Pacific Scientific Energetic Materials Co.
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fire extinguisher cartridge
MSDS NUMBER: REVISION: 7 June 2001
00233
Refer to the Department of Defense Contractors Safety Manual number DOD4145.26M,
including sources listed within, and any other appropriate information for detailed instructions
regarding proper handling, storage, use and disposal of explosives and related dangerous
material.
STORAGE: Store in approved storage magazines only. Storage and handling must conform
to appropriate quantity / distance requirements, barricading, grounding and personnel
material limits. Keep product cool and dry in storage.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
PERSONAL PROTECTIVE EQUIPMENT (PPE)
EYE PROTECTION: Industrial safety glasses or goggles must be worn when handling
any type of explosive product.
SKIN PROTECTION
GLOVES: Impervious, static-dissipative gloves are recommended if product
seal ruptures.
CLOTHING: High cotton-content clothing and underclothing, as well as
conductive shoes or legstat(s), wristat(s) and a static-dissipative coat, are
recommended to avoid static electricity build-up.
EMERGENCY WASH FACILITY: Eye washing capability is required.
RESPIRATORY PROTECTION: Appropriate NIOSH / MSHA-approved respiratory
protection is recommended if exposed to particulate matter, and, for protection against
toxic gaseous ignition products, but should not be necessary with normal handling.
OTHER PROTECTION: None indicated.
ENGINEERING CONTROLS: Effective shielding is recommended for personnel when
handling these devices. Humidity control (i.e. higher relative humidity, > 60% as
recommended by DOD) reduces or prevents static electricity build-up. Explosion-proof
equipment is required when operating with exposed explosive materials.
VENTILATION
LOCAL: Not required.
SPECIAL: Explosion-proof electrical is required, where applicable.
MECHANICAL: General-coverage, moderate-flow, is recommended for particulate
and ignition product removal.
EXPOSURE GUIDELINES:
COMPONENT: tetraammine-cis-bis(5-nitro-2H-tetrazolato-N 2 )
cobaltIII perchlorate (BNCP)
OSHA TWA: 0.1 mg/m 3 [cobalt (Co) dust / fume]
OSHA STEL: not found
ACGIH TWA: 0.02 mg/m 3 [as cobalt (Co), inorganic compound]
ACGIH STEL: not found
Pacific Scientific Energetic Materials Co.
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fire extinguisher cartridge
MSDS NUMBER: REVISION: 7 June 2001
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OTHER(S): NIOSH TWA: 0.05 mg/m 3 [cobalt (Co) dust / fume]
IDLH: 20 mg/m 3 [as cobalt (Co)]
COMPONENT: zirconium, metal powder [Zr]
OSHA TWA: 5 mg/m 3
OSHA STEL: not found
ACGIH TWA: 5 mg/m 3
ACGIH STEL: 10 mg/m 3
OTHER: NIOSH TWA: 5 mg/m 3
NIOSH STEL: 10 mg/m 3
IDLH: 50 mg/m 3
COMPONENT: graphite [C]
OSHA TWA: 15 million parts / ft3 3
[2.5 mg/m (respirable frxn) - 1989 vacated PEL]
OSHA STEL: not found
ACGIH TWA: 2 mg/m 3 [respirable fraction]
ACGIH STEL: not found
OTHER: NIOSH TWA: 2.5 mg/m 3 [respirable fraction]
IDLH: 1250 mg/m 3
COMPONENTS: hexanitrostilbene (HNS)
potassium perchlorate
difluoroethene-hexafluoropropene-tetrafluoroethene terpolymer
OSHA TWA: 15 mg/m 3 [total],
5 mg/m 3 [respirable dust fraction] (PNOR)
OSHA STEL: not found
ACGIH TWA: 10 mg/m 3 [inhalable particulate],
3 mg/m 3 [respirable particulate] (PNOS)
ACGIH STEL: not found
OTHER: none found
9. PHYSICAL AND CHEMICAL PROPERTIES
APPEARANCE: metallic ordnance hardware
ODOR: odorless
PHYSICAL STATE: solid
pH @ 25癈: not determined
VAPOR PRESSURE: not applicable, sealed product
VAPOR DENSITY: not applicable, sealed product
BOILING POINT: not applicable
Pacific Scientific Energetic Materials Co.
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MELTING POINT: not applicable
SOLUBILITY IN H2 O: negligible
SPECIFIC GRAVITY (H2 O=1): greater than 1
BULK DENSITY: greater than 1, identical to specific gravity
CHEMICAL FAMILY: not applicable
MOLECULAR WEIGHT: not applicable
MOLECULAR FORMULA: not applicable
VISCOSITY: not applicable
EVAPORATION RATE: not applicable, sealed product
480癋 ( 250癈) by auto-ignition [BNCP]
DECOMPOSITION TEMP:
DESENSITIZING AGENT: CAUTION: The product may only be desensitized if large
volumes of water or mineral oil come in contact with the
explosive components inside. Sealed units should be
shunted and disposed of in accordance with Section 13.
VOC CONTENT: none
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY: This explosive product is stable if handled properly. Avoid
conditions listed below.
CONDITIONS TO AVOID: Shock, impact, friction, electrostatic discharge, high pressure,
high temperature, open flame and chemical or physical contamination.
INCOMPATIBILITY WITH OTHER MATERIALS: The product is sealed preventing exposure
to the hazardous ingredients inside. If the seal ruptures, remove all other hazardous
materials.
HAZARDOUS DECOMPOSITION PRODUCTS: Extreme heat and toxic gases containing
zirconium, cobalt, chlorine and fluorine compounds, plus nitrogen oxides may be emitted
during ignition.
HAZARDOUS POLYMERIZATION: Will not occur.
11. TOXICOLOGICAL INFORMATION
HEALTH HAZARDS / TOXICOLOGY: The product is sealed preventing exposure to the
hazardous ingredients inside. If the seal ruptures, remove all other hazardous materials.
HNS and BNCP (as a nitro compound of an aromatic hydrocarbon): Skin absorption and
inhalation are usual routes of entry for these materials. The effects of acute exposure are
the reduction of oxygen-carrying power of the blood and depression of the nervous system.
Chronic exposure may cause anemia, moderate cyanosis, fatigue, slight dizziness,
headache, insomnia and weight loss. Prolonged chronic exposure may lead further to liver
and/or kidney damage, manifesting as acute yellow atrophy and toxic hepatitis or fatty
degeneration of the kidneys.
LD50 : no data found
Pacific Scientific Energetic Materials Co.
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fire extinguisher cartridge
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BNCP (as a cobalt compound): Low toxicity by ingestion. Ingestion of soluble salts
produces nausea and vomiting by local irritation; possibly can cause liver and kidney
damage. Locally, cobalt has been shown to cause dermatitis and hypersensitivity of the
skin. Animal carcinogen (AGCIH) and suspected human carcinogenicity. Further reports,
state both confirmed and questionable carcinogen with experimental neoplastigenic and
tumorigenic data.
LD50 : no data found
potassium perchlorate and BNCP (as a perchlorate): Severe irritant to skin, eyes and
mucous membranes. Implicated in aplastic anemia. Absorption can cause
methemoglobinemia and kidney injury. An experimental teratogen.
LD50 : no data found
zirconium: Inhalation may lead to lung granulomas. Fine zirconium powder readily
generates respirable dust, which is retained in the lungs. Fine powder imbeds in skin, eyes
and other exposed tissues.
LD50 : no data found
graphite: Moderately toxic by intravenous route. Experimental reproductive effects.
LD50 : 440 mg/kg; intravenous; mouse
difluoroethene-hexafluoropropene-tetrafluoroethene terpolymer: ACGIH recommends that air
concentrations of thermal decompositon products (fumes) of PTFE, a closely-related
fluoropolymer, be controlled at 'as low as possible' levels. No toxicological information
found, except references to 'polymer fume fever'.
LD50 : no data found
12. ECOLOGICAL INFORMATION
The product is sealed preventing exposure to the hazardous ingredients inside. If the seal
ruptures, the small amount of hazardous ingredients inside should have no ecological
impact.
13. DISPOSAL CONSIDERATIONS
RCRA HAZARDOUS WASTE CODES (product as manufactured):
D003 - reactive characteristic
WASTE DISPOSAL METHOD: Explosives or related dangerous material should be
destroyed by open burning / open detonation in an approved incinerator, or by another
approved method such as chemical treatment / destruction. Contaminated property must not
be buried.
REGULATIONS GOVERNING TREATMENT, STORAGE AND DISPOSAL OF HAZARDOUS WASTE IS SUBJECT
TO CHANGE AND REINTERPRETATION. SINCE THE OWNER OF THE WASTE IS RESPONSIBLE FOR
PROPER DISPOSAL, CHECK WITH FEDERAL, STATE AND LOCAL ENVIRONMENTAL AGENCIES IF IN DOUBT
OF THE REQUIREMENTS OF APPLICABLE LAWS, RULES AND REGULATIONS. TREATMENT, STORAGE AND
DISPOSAL MUST BE IN ACCORDANCE WITH ALL APPLICABLE FEDERAL, STATE AND LOCAL LAWS, RULES
AND REGULATIONS.
Pacific Scientific Energetic Materials Co.
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14. TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION INFORMATION: This product is regulated as
a US DOT Hazardous Material. Applicable regulations are found in title 49 of the Code of
Federal Regulations. An authorized carrier in full compliance with these regulations must be
used to transport this product. This product may not be mailed through the US Postal
system.
UN PROPER SHIPPING NAME / NUMBER: Cartridges, power device / UN0276
UN CLASSIFICATION CODE: 1.4C
PACKAGING GROUP: II
LABEL(S) REQUIRED: EXPLOSIVE 1.4C, CARGO AIRCRAFT ONLY
APPLICABLE PACKAGING SECTION: 49 CFR ?173.62 non-bulk [PI-134], plus
special provision 110 per 49 CFR ?172.102
DOT REPORTABLE QUANTITY (RQ): 100 lbs. (45.4 kg) per 49 CFR ?172.101,
Appendix (D003 reactivity)
OTHER TRANSPORTATION INFORMATION: For general emergency response guidance,
actions, and potential hazards, refer to the "2000 Emergency Response Guidebook" or
2000ERG, GUIDE NUMBER 114.
15. REGULATORY INFORMATION
U.S. REGULATIONS
FEDERAL
OSHA: Regulated under 29 CFR ?1910.1200
TSCA: All hazardous components should be reported on the inventory.
CERCLA RQ: 100 lbs. (45.4 kg) [D003 reactivity]
SARA - SECTION 302 TPQ: Not an Extremely Hazardous Substance.
- SECTION 304 RQ: See CERCLA RQ.
- SECTION 313: Reportable [cobalt compound]
STATES
CALIFORNIA PROPOSITION 65: The product and its hazardous components
are not on their list.
NEW JERSEY RIGHT-TO-KNOW: The product (as EXPLOSIVES C) and the
components, zirconium, potassium perchlorate, HNS and BNCP (as a cobalt
compound and a perchlorate, inorganic, n.o.s.), are on the Right-to-Know
Hazardous Substance List (rev. 3/93), which consists of both the Workplace
Hazardous Substance List and the Environmental Hazardous Substance List.
Zirconium and potassium perchlorate are on the Special Health Hazard
Substance List.
Pacific Scientific Energetic Materials Co.
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PENNSYLVANIA RIGHT-TO-KNOW: The components that are listed,
zirconium, potassium perchlorate, graphite and BNCP (as a cobalt compound),
are on the Hazardous Substance List. Cobalt compounds are included as
Environmental Hazards. None are included as Special Hazardous Substances.
INTERNATIONAL REGULATIONS
To be determined
16. OTHER INFORMATION
HMIS RATINGS (Sealed product rating):
HEALTH: 1 FLAMMABILITY: 0 REACTIVITY: 4
PERSONAL PROTECTION: A + X
CERCLA or NFPA RATINGS (SCALE 0-4): not yet determiined
REVISION HISTORY
Initial issue: 24 June 99, ANSI Z400.1
PREPARED BY: J. Geving - Environmental, Health & Safety
THE INFORMATION, RECOMMENDATIONS AND SUGGESTIONS IN THIS DATA SHEET ARE BASED ON AVAILABLE DATA BELIEVED TO BE ACCURATE AND
RELIABLE. IT IS THE RESPONSIBILITY OF THE USER TO DETERMINE THE SUITABILITY FOR USE OF THIS PRODUCT OR USE IN COMBINATION W I T H A N Y
OTHER DEVICE, MATERIAL OR PROCESS. NO WARRANTY, EITHER EXPRESSED OR IMPLIED, IS MADE CONCERNING THE EFFECTS OF USE OR THE
RESULTS TO BE OBTAINED, NOR DOES PACIFIC SCIENTIFIC ENRGETIC MATERIALS COMPANY ASSUME ANY LIABILITY ARISING OUT OF USE, STORAGE,
HANDLING OR DISPOSAL OF THE PRODUCT REFERRED TO HEREIN. TO PROMOTE SAFE USE OF THIS PRODUCT, THE USER SHOULD NOTIFY HIS
EMPLOYEES, AGENTS, CONTRACTORS AND CLIENTS OF THE PRODUCT HAZARDS AND SAFETY INFORMATION AFTER BECOMING FAMILIAR WITH THIS DATA.
Copyright 2001 Pacific Scientific Energetic Materials Co. All Rights Reserved
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