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MSDS Material Safety Data Sheet
CAS

9016-87-9 101-68-8 75-45-6 1717-00-6

File Name: 9016-87-9_101-68-8_75-45-6_1717-00-6.asp

MATERIAL SAFETY DATA SHEET

FOR

TOUCH N' FOAM
PROFESSIONAL?br>
SYSTEM 200, SYSTEM 600

A COMPONENT & B COMPONENT
MATERIAL SAFETY DATA SHEET
SECTION I - PRODUCT INFORMATION
Product: Touch 'n Foam Professional ?, System 200, System 600
A Component and B Component

Manufacturer: Emergency Telephone Chemtrec:
Number 1-800-424 9300
Convenience Products
866 Horan Drive Information Telephone 1-636-349 5333
Fenton, MO 63026-2416 U.S.A. Number (during regular
business hours):
Revised on
11/26/2002
Prepared by Jay ZHANG Approved by Joe Lott

SECTION II - HAZARDOUS INGREDIENTS/IDENTITY INFORMATION

A Component
CHEMICAL NAME CAS NO. OSHA PEL ACGIH TLV PERCENTAGE

Polymeric Diphenylmethane 9016-87-9 NE* NE* 40-55
Diisocyanate (MDI)
4,4-Diphenylmethane 101-68-8 0.02ppm CEIL 0.005ppm TWA 40-55
Diisocyanate
Chlorodifluoromethane 1,000ppm 1,000ppm TWA 5-15
75-45-6 TWA
(HCFC-22)

B Component
CHEMICAL NAME CAS NO. OSHA PEL ACGIH TLV PERCENTAGE

Polyol Blend Proprietary NE* NE* 35-75
Mixture NE*

Flame Retardant Proprietary NE* NE* 3-30
Mixture NE*

Catalyst Proprietary NE* NE* <1
Mixture NE*

1,1-Dichloro-1-Fluoroethane 1717-00-6 NE* NE* 2-15
(HCFC-141b)
Chlorodifluoromethane 75-45-6 1,000ppm 1,000ppm TWA 10-20
TWA
(HCFC-22)
*Not established

None of the ingredients in both A and B component is listed by IARC, NTP, OSHA, or ACGIH as a
carcinogenic substance.

A Component Health 2 Flammability 1 Reactivity 1
Hazard Rating: HMIS
B Component Health 1 Flammability 1 Reactivity 0




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SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS
A Component B Component
HCFC-22 -41.4癋 at 1 ATM
HCFC-22 -41.4癋 at 1 ATM
Boiling Point HCFC-141b 89.6癋
MDI 392癋 at 5 mm Hg
Polyol Blend NE*
HCFC-22 136 psia at 70癋
HCFC-22 136 psia at 70癋
Vapor Pressure HCFC-141b 10 psia at 68癋
MDI 0.00016mmHg@68癋
Polyol Blend NE*
Vapor Density HCFC-22 2.98 at 1 ATM
HCFC-22 2.98 at 1 ATM
(AIR = 1) HCFC-141b 4.0 at 1 ATM
HCFC-22 1.17 at 86癋
Specific Gravity HCFC-22 1.17 at 86癋
HCFC-141b 1.25 at 50癋
(H20 = 1) MDI 1.2
Polyol Blend 1.1
HCFC-22 None HCFC-22 None
Flash Point
MDI > 400癋 closed cup Polyol Blend NE*

Solubility in Water Insoluble Soluble

Appearance Clear, off yellow viscous liquid with slight
Dark brown color with earthy, musty odor
and Odor odor
*Not established
SECTION IV - FIRE AND EXPLOSION HAZARD DATA
Extinguishing Media
U2 units in boxes: Water fog, foam, CO2, or dry chemical
Cured foam: Water fog, foam, CO2, or dry chemical
Fire Fighting Procedures
U2 units in boxes: Keep containers cool. Wear self-contained breathing apparatus and turnout gear. Hazardous
decomposition products include CO, CO2, oxides of nitrogen, and traces of HCN, HF, HCl,
Tin Oxide, Cl, PO & Silicon Dioxide.
Cured foam: Wear self-contained breathing apparatus. Hazardous decomposition products include CO, CO2,
oxides of nitrogen, and traces of HCN, HF, HCl, Tin Oxide, Cl, and PO.
Unusual Hazards
Units in boxes: High temperatures will increase the pressure in the tanks, which may lead to rupturing.
Cured foam: This product is combustible. Do not expose to high heat, sparks, or open flame.

SECTION V - REACTIVITY DATA
Stability
U2 units in boxes are considered stable under normal storage and handling conditions. Do not store above
120癋. The mixing of the "A" Component and "B" Component during use produces heat and expansion. Cured
foam will slowly deteriorate when exposed to UV light.
Incompatibility
Water, alcohols, strong bases, finely powdered metal such as aluminum,
A Component:
Magnesium or zinc, and strong oxidizers.
Strong alkali or alkaline earth metals, finely powdered metals such as
B Component:
Aluminum, magnesium, or zinc, strong oxidizers, and strong acids.
/Hazards to Avoid:
Avoid high heat; i.e., flames, extremely hot metal surfaces, heating elements, combustion engines, etc.
Contaminated A component with water may form CO2. Do not dispense only one tank at a time. Both
A & B components must be used together.




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SECTION VI ?TOXICOLOGICAL INFORMATION
Concentration of ingredients (section II) must be considered to determine effects of the "A" component mixture
and "B" component mixture. Although these mixtures have not been tested, it is assumed that the mixture
presents the same health hazards as do the ingredients present at 1% or higher level. Proper personnel
protection and adequate ventilation should be provided to avoid exceeding the exposure limits listed in section
II.

Inhalation MDI vapors from A component or spray mist may cause irritation of the mucous membranes
of the nose, throat or trachea, which may cause chest discomfort, coughing, and allergic asthma-like sensitivity.
Air-borne overexposure well above the PEL may result additionally in eye irritation, headache, chemical
bronchitis, asthma-like findings or pulmonary edema.
Inhaling concentrated fluorocarbons from A component and/or B component can cause unconsciousness,
drowsiness, respiratory depression, rapid heartbeat and other symptoms. Persons with preexisting heart
disease may be at increased risk from exposure.

Skin Contact: with both A component and B component may result in localized irritation, reddening or swelling.
Prolonged or repeated exposure may lead to sensitization and/or dermatitis. Uncured foam forms a quick bond with
skin and hard to remove after it is cured.

Eyes Contact: with MDI of A component may result in eye irritation and mild corneal opacity due to adhesive
character. B component may have irritating effect to eyes.

Ingestion: A component may cause irritation of mucous membranes in the mouth and digestive tract. B
component may have slight effect of such.

Emergency and First Aid Procedures
A component or B component material
Skin - If frostbitten, warm skin slowly with water; otherwise, wash affected areas with soap and water at least 15
minutes. Remove contaminated clothing and launder before reuse. Get immediate medical attention.
Eyes - Immediately flush with large quantities of water for a minimum of 15 minutes. Use fingers to assure that
eyelids are separated and that eye is being irrigated. Get immediate medical attention.
Ingestion - If swallowed, dilute with water. DO NOT INDUCE VOMITING. Never give fluids or induce vomiting if
the victim is unconscious or having convulsions. Get immediate medical attention.
Inhalation - Remove to fresh air. Get immediate medical attention.

Foam
Skin - Remove wet foam immediately from skin with soft cloth, and then clean with acetone or nail polish
remover. If irritation persists get medical attention. Dried foam is hard to remove from skin. If foam dries on
skin, apply generous amounts of petroleum jelly or lanolin, leave on for one hour, wash thoroughly, and repeat
process until foam is removed. Do not attempt to remove dried foam with solvents.
Eye - In case of eye contact, flush with water for 15 minutes. Get immediate medical attention.
Ingestion - In case of ingestion, get immediate medical attention.

SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE
"A" Side
Spills/Leaks - Evacuate and ventilate spill area, dike spill to prevent entry into water system, wear full protective
equipment including respiratory equipment during clean up.
If transportation spill involved, call CHEMTREC @ 1-800-424-9300. If temporary control of isocyanate vapor is
required, a blanket of protein foam (available at most fire departments) may be placed over the spill. Transfer
as much liquid as possible via pump or vacuum device into closed but not sealed containers for disposal.
Absorb the isocyanate with sawdust or other absorbent and shovel into open top containers. Do not make
pressure tight. Transport to a well-ventilated area (outside) and treat with neutralizing solution consisting of a
mixture of 90% water, 3-8% ammonia and 2-7% detergent. Add about 10 parts of neutralizer per part of
isocyanate with mixing. Allow standing for 48 hours letting evolved carbon dioxide escape. Decontaminate spill
area using neutralizing solution and letting stand over affected areas for at least 10 minutes.
Waste Disposal - Dispose according to federal, state, and local regulations. - Do not discharge into waterways
or sewer systems.
Container Disposal - Dispose according to federal, state, and local regulations.


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"B" Side
Spills/Leaks - Evacuate and ventilate spill area, dike spill to prevent entry into water system, wear full protective
equipment including respiratory equipment during clean up. If transportation spill involved, call CHEMTREC @
1-800-424-9300. Transfer as much liquid as possible via pump or vacuum device into closed but not sealed
containers for disposal. Absorb the material with sawdust or other absorbent and shovel into containers and
transport to a well-ventilated area.
Waste Disposal - Do not discharge into waterways or sewer systems. Dispose according to federal, state, and
local regulations.
Container Disposal - Dispose according to federal, state, and local regulations

Storage: Store in a cool, dry place. Ideal storage temperature is 60癋 - 80癋. Storage above 90癋 will shorten
the shelf life. Since the containers are pressurized, do not store above 120癋 (49癈) in order to avoid excessive
pressure build up and possible container rupture. Protect containers from physical abuse.

SECTION VIII - PERSONAL PROTECTION

Respiratory Protection Use only in well-ventilated areas. Wear NIOSH / MSHA approved, positive pressure,
supplied air respirator when vapor level is exceed the guideline listed in section II in this MSDS.
Clothing Wear rubber butyl or nitrite rubber gloves, coveralls, long sleeve shirts, and head covering to avoid
skin contact. Contaminated equipment / clothing should be cleaned after each use or disposed.
Eye Protection Wear face shield and goggles, or safety glasses.
Ventilation If ventilation is not enough to maintain P.E.L. exhaust area.

SECTION IX - OTHER REGULATORY INFORMATION
TSCA ?Inventory Status: all chemicals contained in this product are listed on TSCA inventory.
SARA - This product contains a toxic chemical that may be subject to the reporting requirements of Section 313
of the Emergency Planning and Community Right-to-Know Act of 1986 (40CFR 372).
NAME CAS NO. AMOUNT
Diphenylmethane Diisocyanate 101-68-8 40-55% of "A" Side
Chlorodifluoromethane (HCFC-22) 5-15% of "A" Side
75-45-6
Chlorodifluoromethane (HCFC-22) 10-20% of "B" Side
75-45-6
1,1-Dichloro-1-Fluoroethane (HCFC-141b) 2-15% of "B" Side
1717-00-6
CERCLA - Reportable Quantity - yes ...(40CFR 302.4)......(5000 lb. of Methylene bisphenyl isocyanate)
RCRA Hazardous Waste - No
DOT Proper Shipping Name

System 200 & System 600 Compressed gas, NOS (Chlorodifluoromethane, Nitrogen)
Diphenylmethane Diisocyanate (cas# 101-68-8) is cited on certain state lists as follow:
NJ2=New Jersey environmental hazardous substance (present at greater than or equal to 1.0%)
NJ3=New Jersey workplace hazardous substance (present at greater than or equal to 1.0%)
PA1=Pennsylvania hazardous substance (present at greater than or equal to 1.0%)
PA3=New Jersey environmental hazardous substance (present at greater than or equal to 1.0%)



The above information is accurate to the best of our knowledge. However, since safety standards, data, and
government regulations are subject to change and the conditions of handling and use or misuse are beyond our
control, Convenience Products makes no warranty, either express or implied, with respect to the completeness
or continuing accuracy of the information contained herein and disclaims all liability for reliance thereon. User
should satisfy himself that he has all current data relevant to his particular use.




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