Boat Craft Pacific A.B.N. 62 057 731 174
11/22 Babdoyle Street., Phone (07) 3806 1944
Loganholme Fax (07) 3209 7711
Queensland 4129 Email: info@boatcraft.com.au
Australia www.boatcraft.com.au
POURING FOAM
MATERIAL SAFETY DATA SHEET
SECTION 1. PRODUCT IDENTIFICATION
Trade Name Pouring Foam
Chemical Name & Synonyms Polyol/MDI two component kit
Manufacturer BoatCraft Pacific Pty. Ltd.
22 Babdoyle St.,
Loganholme Queensland 4129
Australia
Emergency Contact Telephone 07 3806 1944 ah 0417 632 894
UN No. None Allocated Hazchem None Allocated
DG Class None Allocated Poisons Schedule 6
CAS No. Mixture Pkge Group None allocated
Major recommended Use Two component Polyurethane Rigid Foam
System.
Classified as hazardous according to the criteria of Worksafe Australia.
SECTION 2. INGREDIENTS
Part A Isocyanate Component
Chemical Entity CAS Number Proportion of component
Diphenylmethane di-isocyanate prepolymer 26447-40-5 60% - 70%
containing methylene bisphenyl isocyanate 101-68-8
Polymethylene polyphenol isocyanate 9016-87-9 30% - 40%
Part B Polyol Component
Chemical Entity CAS Number Proportion of component
Polyether Polyol Mixture 9082-00-2 >60%
Chlorinated aliphatic phosphate 13674-84-5 10% - 30%
Tertiary Amines Proprietary <10%
Products
1,1 Dichloro ?1 Fluoroethane 1717-00-6 10% - 30%
SECTION 3. PHYSICAL DESCRIPTION AND PROPERTIES
Physical Data
Appearance/Odour Viscous liquids, almost odourless
Boiling Point >135篊 Tends to decompose at elevated temperatures
Specific Gravity Part A. 1.2g/mL Part B. 1.14g/mL
Vapour Pressure Very Low at 20篊
Vapour Density (air = 1) >1 at 20篊
Volatile Component 5% - 15%
pH Not Applicable
Solubility in Water Almost insoluble
BoatCraft Pacific
POURING FOAM
Product Exposure Limits `A' Component
TLV TWA isocyanate (as 璑CO) 0.02mg/cu m `Sen' notice
STEL isocyanate 0.07 mg/cu m
TLV TWA plasticiser 5 mg/cu m
Product Exposure Limits `B' Component
TLV/Polyol 5mg/ cu m
TLV/TWL Catalyst
Toxicity and Irritation Data
LD(50) for ingestion (rat) isocyanate > 2gm/kg
Polyols >4gm/kg
Catalyst No data
SECTION 4. HEALTH HAZARD
Symptoms of Exposure: Acute and Chronic Effects.
Swallowed Oral toxicity is low, and an unlikely route of entry in industrial applications.
Can result in nausea and irritation of the gastrointestinal tract.
Eye contact The liquids may be irritating to the eyes. Di-isocyanates can react with
moisture on the surface of the eyes to create a gumming layer in the eye.
Skin Liquid may be irritating to the skin and may be capable of causing chemical
burns or allergic skin reactions. Repeated or prolonged contact may lead to
dermatitic effects and may cause sensitisation in some individuals.
Temporary black staining of the skin can occur following contact with Part A
component only, and takes 3-4 days before the skin returns to normal colour.
Inhalation The vapour pressure from these products is very low at ambient temperatures
and is unlikely to cause exposure hazard from normal handling. Exposure to
greater amounts of vapour if the liquids are heated, or frequent or prolonged
exposure, can cause respiratory irritation and may cause sensitisation in
some individuals. Exposure symptoms are predominantly asthmatic like
congestion.
Systemic The ingredients may cause adverse effects including sensitisation.
and other Symptoms include itching rash and respiratory asthma-likecongestion.
effects
Emergency & First Aid Procedures
Ingestion: DO NOT INDUCE VOMITING. If conscious give water or milk to rinse out
mouth and drink. Provide liquid slowly but as much as casualty will drink.
Transport to hospital or doctor without delay. Activated charcoal may be
helpful.
Eye contact: Immediately hold the eyes open and irrigate eyes with running water for at
least 15 minutes. Ensure irrigation under eyelids by occasionally lifting the
upper and lower lids. Transport to doctor or hospital without delay. Removal
of contact lenses after an eye injury should only be undertaken by skilled
personnel. Materials containing MDI may react with moisture of the eye,
forming a thick deposit which may be difficult to wash away
Skin contact: Immediately remove all contaminated clothing including footwear. Wash
affected areas thoroughly with detergent hand cleaner and rinse with plenty of
water. Seek medical attention in event of irritation.
Inhalation: Remove to fresh air, lie patient down, keep warm and rested. If breathing is
shallow or has stopped, ensure clear airway and apply resuscitation.
Administer oxygen. Transport to hospital or doctor.
Notes to physician: Treat symptomatically.
Page 2 of 4 pages Material Safety Data Sheet 21 June 2004
BoatCraft Pacific
POURING FOAM
SECTION 5. PERSONAL PROTECTION AND HANDLING
Protective Equipment
Eyes: Goggles or face shield
Hands/feet: Rubber gloves, full overalls, safety shoes
Respiratory: Ensure adequate ventilation. Wear organic vapour respirator or self
contained breathing apparatus in enclosed areas.
Remove and wash all contaminated clothing and equipment.
Handling Procedures
Handle in well ventilated area. Always observe conditions of good industrial hygiene and safe
working practice.
SECTION 6. FIRE & EXPLOSION
Stability
Stable for minimum 2 years at room temperature. Excess heating over long periods will
degrade ingredients. .
Flammability
Products will support combustion if heated but will not spontaneously ignite or explode.
Hazardous Decomposition Products
On burning will emit toxic fumes of cyanogen, oxides of nitrogen, carbon monoxide and
carbon dioxide.
Hazardous Polymerisation
Will not occur unless the separately packed components are mixed in large quantities. This
will cause irreversible polymerization with considerable heat build up.
Incompatibility
Avoid contact with water, strong acids, alkalis, oxidising materials, alcohols amines or other
chemicals having reactive -H groups.
Fire Fighting
Toxic fumes will be evolved when this material is involved in a fire. Fire fighters must wear
full protective clothing and self contained breathing apparatus.
Extinguishing Media
Foam, carbon dioxide, dry chemical powder.
SECTION 7. STORAGE & TRANSPORT
DG Class 6.1(b)
Packaging Group & Label III
Suitable Containers Approved poisons containers
Storage Procedures Containers will develop pressure at high
temperatures. Store at room temperature under
cover in accordance with AS1940 and State Poisons
Acts.
Transport Not regulated for transport under UN and local
regulations.
Page 3 of 4 pages Material Safety Data Sheet 21 June 2004
BoatCraft Pacific
POURING FOAM
SECTION 8. SPILLS & DISPOSAL
Minor spill Absorb into waste cloth or other suitable absorbent. Avoid
contact with skin or eyes.
Major spill Contain with sand or earth, absorb with suitable absorbent, collect
and seal in properly labelled drums for disposal. Prevent run-off
into drains or waterways.
Disposal Suitable for incineration by approved agent or bury in approved
landfill according to local regulations.
SECTION 9. AUTHORISATION
Name: Ian Phillips
Title Director
Issue Date June 2004
Page 4 of 4 pages Material Safety Data Sheet 21 June 2004
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