MSDS
Secure Set
Identity as Used on Label and List: "A" Component Page 1 "A"
Section I: Product Identification and Use
Product Identification: SECURE SET
Product Use Water activated polyurethane resin
GRA Services, LLC
5020 East 2nd Street
Edmond, OK 73034
(405)330-2395
Section II: Ingredients
Ingredients Percent CAS# P.E.L.
4.4 Diphenylmethane-diisocyanate Trade Secret 101-68-6 0.02 ppm, ceiling
Modified MDI Trade Secret Not Listed
Section III: Physical Data
Physical State: Liquid
Odor and Appearance: Pale Yellow Liquid with faint odor
Odor Threshold (ppm): Not established
Decomposes at 646oF
Boiling Point
Freezing Point Not Determined
Vapor Pressure mmGH (@20oC): <0.001 mmHG
Vapor Density (Air=1) Not Known
Evaporation Rate: Not applicable
PH: Not applicable
Specific Gravity: 1.2
Coeff. Water/Oil Base Unknown
Section IV: Fire and Explosion Hazard Data
Flammability No
Means of extinction: Water fog, carbon dioxide or dry chemicals
450oF C.O.C. Method
Flashpoint and Method:
Upper UEL: Not Determined
Lower UEL: Not Determined
Autoignition temperature: Not applicable
Hazardous combustion products Carbon monoxide, nitrogen oxides, carbon dioxide. Firefighters should wear self-
contained breathing apparatus with full-face piece.
Sensitivity to impact: None
Sensitivity to static discharge: None
Section V: Reactivity Data
Stable
Incompatibility with other substances: Yes ?Water, amines, strong bases
Reactivity & Conditions: Yes ?Storage of open or sealed containers in moist or wet environments
Hazardous decomposition products: None
Secure Set
"A" Component
Section VI: Toxicological Properties Page 2 "A"
Effects of acute exposure to product: Skin rash and sensitization of fair skin persons.
Effects of chronic exposure to product: Lung irritation and emphysema.
Exposure Limits: NIOSH-REL, 0.005 ppm TWA and 0.002 ppm STEL (MDI)
Irritancy of Product: Yes
Sensitization of Product: Yes
Carcinogenicity: No
Teratogenicity: None
Reproductive Toxicity: None
Mutagenicity: None
Synergistic Products: None
OSHA Regulated: No
Section VII: Preventative Measures
Personal Protective Equipment
Gloves: Nitrile rubber gloves
Respirator (specify): NIOSH/MSHA self contained in OSHA defined space.
Eye (specify): Chemical splash guard goggles.
Footwear (specify): Boots
Clothing (specify): Impervious clothing
Engineering Controls: Provide sufficient ventilation to maintain exposure below TLV
Handling Procedure: Use only in well ventilated areas unless recommended respiratory protection is used.
Keep body contact and splash to a minimum. Do not cut empty steel drums with a
welding torch.
Leak & Spill Procedure: Cover spill with absorbent material, remove from surface and place in open
container. Spills may be a slipping hazard.
Water Disposal: Any disposal practice must be in compliance with all Federal, State, Provincial and
Local laws and regulations. Product as sold is not a RCRA hazardous.
Waste when disposed: Slowly stir the isocyanate waste into the decontaminated solution described above
using 10 parts of the solution for each part of the isocyanate. Let stand for 48 hours,
allowing the evolved carbon dioxide to vent away. Neutralize the waste, neither
liquid or solid is hazardous waste under RCRA, 40 CFT 261.
Handling Procedures and Equipment: Never spray product. Do not drink, smoke or eat during handling. Avoid eye
contact.
Store at 50oF to 100oF.
Storage Requirements:
Shipping Instructions: None
Section VIII: First Aid Measures
Eyes: Flush with large amounts of water for 15 minutes, lifting upper and lower lids
occasionally. Obtain immediate medical attention.
Skin: Thoroughly wash exposed area with soap and water. Remove contaminated clothing.
Launder contaminated clothing before reuse. Consult a physician if irritation
develops.
Ingestion: Do Not Induce Vomiting. Give victim large amounts of water to drink. Keep person
warm, quite and seek medical attention. If vomiting occurs spontaneously, keep head
below hips to prevent aspiration of liquids into lungs. Aspiration or material into the
lungs due to vomiting can cause chemical pneumonitis which can be fatal.
Inhalation: If affected, move individual to fresh air. If breathing is difficult, administer oxygen.
If breathing has stopped, give artificial respiration. Keep person warm, quiet and
seek immediate medical attention.
MSDS
Secure Set
Identity as Used on Label and List: "B" Component Page 1 "B"
Section I: Product Identification and Use
Product Identification: SECURE SET
Product Use Water activated polyurethane resin
GRA Services, LLC
5020 East 2nd Street
Edmond, OK 73034
(405)330-2395
Section II: Ingredients
Ingredients Percent CAS# LD50 of Ingredient
Polyether polyol Trade Secret 025214-63-5 Not Listed
1,1 Dichloro-1Fluoroethane Trade Secret 1717-00-6 Not Listed
This product contains the following toxic chemicals subject to the reporting requiements of Section 313 of the Title III of the
Superufnd Amendments and Reauthorization Act of 1986 and 40 CFR part 372.
Section III: Physical Data
Physical State: Liquid
Odor and Appearance: Liquid with faint odor
Odor Threshold (ppm): Not established
Boiling Point Product decomposes at higher temperature
Freezing Point Not Determined
Vapor Pressure mmGH (@20oC): Nill
Vapor Density (Air=1) > 1.0
Evaporation Rate: Not applicable
PH: Not applicable
Specific Gravity: 1.052
Coeff. Water/Oil Base Unknown
Section IV: Fire and Explosion Hazard Data
Flammability Yes
Means of extinction: Water fog, carbon dioxide or dry chemicals
405oF PMCC ASTM D93
Flashpoint and Method:
Upper UEL: Not Determined
Lower UEL: Not Determined
Autoignition temperature: Not applicable
Hazardous combustion products Carbon monoxide, nitrogen oxides, carbon dioxide.
Sensitivity to impact: None
Sensitivity to static discharge: None
Section V: Reactivity Data
Stable
Incompatibility with other substances: Yes ?Water, amines, strong bases
Reactivity & Conditions: Yes ?Storage of open or sealed containers in moist or wet environments
Hazardous decomposition products: Combustion may produce carbon dioxide and toxic carbon monoxide.
Unidentified organic compounds may be formed during combustion.
Secure Set
Section VI: Toxicological Properties Page 2 "B"
"B" Component
Effects of acute exposure to product: Skin rash and sensitization of fair skin persons.
Effects of chronic exposure to product: Lung irritation and emphysema. Skin Reaction.
Exposure Limits: None
Irritancy of Product: Yes
Sensitization of Product: Yes
Carcinogenicity: No
Teratogenicity: None
Reproductive Toxicity: None
Mutagenicity: None
Synergistic Products: None
OSHA Regulated: No
Section VII: Preventative Measures
Personal Protective Equipment
Gloves: Nitrile rubber gloves
Respirator (specify): NIOSH/MSHA self contained in OSHA defined space.
Eye (specify): Chemical splash guard goggles.
Footwear (specify): Boots
Clothing (specify): Impervious clothing
Engineering Controls: Provide sufficient ventilation to maintain exposure below TLV
Handling Procedure: Use only in well ventilated areas unless recommended respiratory protection is used.
Keep body contact and splash to a minimum. Do not cut empty steel drums with a
welding torch.
Leak & Spill Procedure: Cover spill with absorbent material, remove from surface and place in open
container. Spills may be a slipping hazard.
Water Disposal: Any disposal practice must be in compliance with all Federal, State, Provincial and
Local laws and regulations. Product as sold is not a RCRA hazardous waste when
disposed.
Handling Procedures and Equipment: Store containers upright, avoid eye and skin contact.
Store at 50oF to 100oF.
Storage Requirements:
Shipping Instructions: None
Section VIII: First Aid Measures
Eyes: Flush with large amounts of water for 15 minutes, lifting upper and lower lids
occasionally. Obtain immediate medical attention.
Skin: Thoroughly wash exposed area with soap and water. Remove contaminated clothing.
Launder contaminated clothing before reuse. Consult a physician if irritation
develops.
Ingestion: Do Not Induce Vomiting. Give victim large amounts of water to drink. Keep person
warm, quite and seek medical attention. If vomiting occurs spontaneously, keep head
below hips to prevent aspiration of liquids into lungs. Aspiration or material into the
lungs due to vomiting can cause chemical pneumonitis which can be fatal.
Inhalation: If affected, move individual to fresh air. If breathing is difficult, administer oxygen.
If breathing has stopped, give artificial respiration. Keep person warm, quiet and
seek immediate medical attention.
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