Lilly Miller Brands
Health Hazard 2
1
MATERIAL SAFETY DATA SHEET
Fire Hazard 1
0
2
Reactivity 0
Personal Protection B
HMIS RATING NFPA RATING
SECTION I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Trade Name: Lilly Miller Ultragreen Crabgrass Control & MSDS Number: LM-041
Lawn Food with TEAM
Generic Name: Lawn Fertilizer EPA Reg. No: 62719-150-67876
62719-331-33116
Manufacturer: Lilly Miller Brands Revision Number: New
Address: 16201 SE 98th Avenue Date Revised: December 5, 2002
Clackamas, OR 97015 Manufacturer's Phone Number: 503-451-4451
SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS
Chemical Name CAS Number % TLV PEL
10 mg/m3 15 mg/m3
Ammonium sulfate 7783-20-2 41-54
Urea 57-13-6 13-26 N/A N/A
Muriate of potash 584-08-7 5-11 N/A N/A
Sulfur coated urea 57-13-6/7704-34-9 9-20 N/A N/A
Ammonium phosphate 7783-28-0 4-7 N/A N/A
Ferrous sulfate 7720-78-7 5 N/A N/A
Iron sucrate Proprietary 4 N/A N/A
TEAM: See below
3 mg/m3 5 mg/m3
Benefin 1861-40-1 0.76
3 mg/m3 5 mg/m3
Trifluralin 1582-09-8 0.39
Key: Respirable dust, TLV = ACGIH, 8 hr. time weighted average (TWA); PEL = OSHA permissible exposure limit.
SECTION III - HAZARDS IDENTIFICATION
Emergency Overview: This product is harmful if swallowed. Wash hands and exposed skin with soap and water
after using this product.
HMIS Rating: Health: 2 Fire: 1 Reactivity: 0 Personal Protection: A
Potential Health Effects:
Routes of Entry: Inhalation, skin contact, eye contact, ingestion
Inhalation: Overexposure to dust may cause transitory upper respiratory irritation.
Skin Contact: Prolonged exposure may cause skin irritation. May cause reaction in allergic individuals.
Eye Contact: Dusts may cause irritation or corneal injury due to mechanical action.
Ingestion: Ingestion of large quantities can be harmful and irritating to the G.I. system.
Revised: December 5, 2002
Page 1 of 4
Trade Name: Lilly Miller Ultragreen Crabgrass Control & Lawn Food with TEAM MSDS Number: LM-041
Medical Conditions Aggravated by Exposure: May cause upper respiratory irritation, and may aggravate pre-
existing respiratory conditions.
Carcinogenicity: Not listed by NTP or IARC. Not regulated as a carcinogen by OSHA.
SECTION IV - FIRST AID MEASURES
Inhalation: Move to an area free from risk of further exposure. Treat symptomatically if required. No adverse
effects anticipated by this route of exposure incidental to proper handling.
Eye Contact: Flush with clean, lukewarm water at low pressure. Seek medical attention if irritation persists.
Skin Contact: Wash affected areas thoroughly with soap and warm water immediately after use of this product.
Ingestion: Ingestion of large quantities may be irritating to the GI tract, requiring symptomatic treatment.
SECTION V - FIREFIGHTING MEASURES
NFPA Rating: Health: 2 Fire: 1 Reactivity: 0 Other: 0
Flash point and Method: This product is non-flammable
Extinguishing Method: Not required.
Fire or Explosion Hazards: This product will not burn.
Special Firefighting Procedures: Not applicable.
SECTION VI - ACCIDENTAL RELEASE MEASURES
Clean-up Procedures: Pick up or shovel material into waste container taking care to minimize dust. Wet down if
necessary to control dust. Vacuum clean dust.
Personal Precautions: If dusty conditions exist, wear a face mask approved for use with dusts such as 3M 8511
N-95 or equivalent.
Environmental Precautions: Keep major spills from entering lakes and waterways.
SECTION VII - HANDLING AND STORAGE
Storage Temperature: Not affected by extremes of temperature.
Shelf Life: Indefinite.
Special Sensitivity: None.
Handling and Storage Precautions: Avoid eye contact and avoid breathing dusts if generated. Good
housekeeping is recommended to prevent the accumulation of dust.
SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION
Respiratory Protection: If dusty conditions exist, wear a face mask approved for use with dusts such as 3M 8511
N-95 or equivalent.
Eye Protection: Use safety glasses if there is potential for exposure to particles which could cause mechanical
injury to the eyes.
Skin Protection: None needed under normal conditions of use.
Engineering Controls: Product is to be used out of doors with good ambient ventilation.
Revised:December 5, 2002 Page 2 of 4
Trade Name: Lilly Miller Ultragreen Crabgrass Control & Lawn Food with TEAM MSDS Number: LM-041
SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES
Physical Form: Grayish granular powder
Odor: Negligible Specific Gravity: N/D
Bulk Density: N/D pH: N/D
Solubility in Water: Nil % Volatile by Weight (VOC): Nil
SECTION X - REACTIVITY
Stability : This is stable material.
Hazardous Polymerization: Will not occur.
Incompatibilities: None in designed use.
Decomposition Products: SOx, irritating particulate.
SECTION XI - TOXICOLOGICAL/ECOLOGICAL INFORMATION
Ecological Concerns: Lilly Miller Ultragreen Crabgrass Control & Lawn Food with TEAM is toxic to aquatic
organisms. Drift or runoff may adversely affect aquatic invertebrates and non target plants. Keep spills from
entering lakes and waterways.
SECTION XII - DISPOSAL CONSIDERATIONS
Waste Disposal Method: This material is a lawn grass nutrient and herbicide and may be disposed of by applying
to soil in accordance with manufacturer's recommendations.
SECTION XIII - TRANSPORTATION INFORMATION
DOT Shipping Name: Not regulated DOT Label: None
Technical Shipping Name: None DOT Placard: None
DOT Hazard Class: None UN/NA Number: None
SECTION XIV - REGULATORY INFORMATION
OSHA Status: This product is regulated under OSHA criteria.
TSCA Status: All applicable chemicals are registered under TSCA.
CERCLA Reportable Quantity: CERCLA reportable quantity for Trifluralin is 10 Pounds.
SARA Title III: Regulated under SARA Title III.
Section 311/312 Hazard Categories: Immediate health hazard.
Section 313 Toxic Chemicals: Benefin - 1861-40-1 & Trifluralin - 1582-09-8 are below the Section 313
DeMinimis of 1.0%
RCRA Status: Not regulated under RCRA
Revised:December 5, 2002 Page 3 of 4
Trade Name: Lilly Miller Ultragreen Crabgrass Control & Lawn Food with TEAM MSDS Number: LM-041
SECTION XV - APPROVALS
Reason for issue: Revised MSDS Approval Date: December 5, 2002 MHickman
Prepared by: Compliance Consulting Group, Inc. Supersedes Date October 22, 2001
303-795-2060
Revised by MHickman, Lilly Miller Brands, 12/5/02
SECTION XVI - DISCLAIMER
As of the date of this document, the foregoing information is believed to be accurate and is provided in good faith to
comply with applicable federal and state laws. However, no warranty or representation of law or fact, with respect
to such information, is intended or given.
Revised:December 5, 2002 Page 4 of 4
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