Page 1/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 04.12.2009 Revision: 04.12.2009
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: Spezialleitsilberlack Nr.24
?Application of the substance / the preparation Coating material
?Manufacturer/Supplier:
Wieland Dental + Technik GmbH & Co.KG
Schwenninger Str. 13
75179 Pforzheim
Telefon + 49 (07231)-37050, Telefax + 49 (07231)-357959
?Further information obtainable from:
Abteilung Umweltschutz
Marcus.Mueller@wieland-dental.de
?Information in case of emergency:
+49 (07231)-37050
( Be kindly advised that this number can only be contacted at usual office hours.)
2 Hazards identification
?Hazard description:
F Highly flammable
?Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
Has a narcotizing effect.
R 11 Highly flammable.
R 67 Vapours may cause drowsiness and dizziness.
?Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature
data.
3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 1569-02-4 1-ethoxypropan-2-ol R 10-67 10-25%
EINECS: 216-374-5
CAS: 64-17-5 ethanol F; R 11 10-25%
EINECS: 200-578-6
CAS: 67-64-1 acetone Xi, F; R 11-36-66-67 5-10%
EINECS: 200-662-2
CAS: 141-78-6 ethyl acetate Xi, F; R 11-36-66-67 1-5%
EINECS: 205-500-4
1%
CAS: 84-74-2 dibutyl phthalate Repr. Cat. 2, 3; T, N; R 61-62-50
EINECS: 201-557-4
?Additional information: For the wording of the listed risk phrases refer to section 16.
4 First-aid measures
?General information:
Take affected persons out of danger area and lay down.
Immediately remove any clothing soiled by the product.
(Contd. on page 2)
GB
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Page 2/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 04.12.2009 Revision: 04.12.2009
Trade name: Spezialleitsilberlack Nr.24
(Contd. of page 1)
?After inhalation:
Take affected persons into fresh air and keep quiet.
Seek medical treatment in case of complaints.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing:
Rinse out mouth and then drink plenty of water.
Seek immediate medical advice.
5 Fire-fighting measures
?Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?For safety reasons unsuitable extinguishing agents: Water with full jet
?Protective equipment: No special measures required.
?Additional information
Collect contaminated fire fighting water separately. It must not enter the sewage system.
6 Accidental release measures
?Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Keep away from ignition sources.
Ensure adequate ventilation
?Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
?Handling:
?Information for safe handling: Store in cool, dry place in tightly closed receptacles.
?Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage:
?Requirements to be met by storerooms and receptacles: Store in a cool location.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions:
Keep receptacle tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
?Storage class: 3A (VCI Konzept)
8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
64-17-5 ethanol
WEL Long-term value: 1920 mg/m? 1000 ppm
(Contd. on page 3)
GB
DR
Page 3/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 04.12.2009 Revision: 04.12.2009
Trade name: Spezialleitsilberlack Nr.24
(Contd. of page 2)
67-64-1 acetone
WEL Short-term value: 3620 mg/m? 1500 ppm
Long-term value: 1210 mg/m? 500 ppm
141-78-6 ethyl acetate
WEL Short-term value: 400 ppm
Long-term value: 200 ppm
84-74-2 dibutyl phthalate
WEL Short-term value: 10 mg/m?br>
Long-term value: 5 mg/m?br>
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures: Wash hands before breaks and at the end of work.
?Respiratory protection: Not required.
?Protection of hands:
Protective gloves
?Material of gloves Nitrile rubber, NBR
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
The determined penetration times according to EN 374 part III are not performed under practical conditions.
Therefore a maximum wearing time, which corresponds to 50% of the penetration time, is recommended.
?Eye protection:
Tightly sealed goggles
?Body protection: Protective work clothing
9 Physical and chemical properties
?General Information
Suspension
Form:
Grey
Colour:
Characteristic
Odour:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: Undetermined.
12癈
?Flash point:
Product is not selfigniting.
?Self-igniting:
Product is not explosive. However, formation of explosive air/vapour
?Danger of explosion:
mixtures are possible.
?Explosion limits:
1.3 Vol %
Lower:
19.0 Vol %
Upper:
1.7 g/cm?br>
?Density at 20癈:
(Contd. on page 4)
GB
DR
Page 4/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 04.12.2009 Revision: 04.12.2009
Trade name: Spezialleitsilberlack Nr.24
(Contd. of page 3)
?Solubility in / Miscibility with
Not miscible or difficult to mix.
water:
?Viscosity:
411 mm?s
Kinematic at 23癈:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions Reacts with oxidizing agents.
?Dangerous decomposition products: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for classification:
84-74-2 dibutyl phthalate
Oral LD50 8000 mg/kg (Ratte)
Dermal LD50 20000 mg/kg (rbt)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: Irritating effect.
?Sensitization: No sensitizing effects known.
12 Ecological information
?General notes: Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
13 Disposal considerations
?Product:
?Recommendation
Must be specially treated adhering to official regulations.
Contact manufacturer for recycling information.
?European waste catalogue
11 00 00 WASTES FROM CHEMICAL SURFACE TREATMENT AND COATING OF METALS AND
OTHER MATERIALS; NON-FERROUS HYDRO-METALLURGY
11 01 00 wastes from chemical surface treatment and coating of metals and other materials (for example
galvanic processes, zinc coating processes, pickling processes, etching, phosphating, alkaline
degreasing, anodising)
11 01 98 other wastes containing dangerous substances
?Uncleaned packaging:
?Recommendation:
Packagings that may not be cleansed are to be disposed of in the same manner as the product.
?Recommended cleansing agents: Water, if necessary together with cleansing agents.
GB
(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 04.12.2009 Revision: 04.12.2009
Trade name: Spezialleitsilberlack Nr.24
(Contd. of page 4)
14 Transport information
?Land transport ADR/RID (cross-border)
3 (F1) Flammable liquids.
?ADR/RID class:
33
?Danger code (Kemler):
1263
?UN-Number:
III
?Packaging group:
3
?Hazard label
1263 PAINT (with a flash point below 23癈 and viscous according 2.2.3.1.4)
?Description of goods:
(vapor pressure at 50癈 at most 110 kPa)
?Limited quantities (LQ) LQ7
3
?Transport category
?Tunnel restriction code D/E
?Maritime transport IMDG:
3
?IMDG Class:
1263
?UN Number:
3
?Label
III
?Packaging group:
F-E,S-E
?EMS Number:
No
?Marine pollutant:
PAINT
?Proper shipping name:
?Air transport ICAO-TI and IATA-DGR:
3
?ICAO/IATA Class:
1263
?UN/ID Number:
3
?Label
III
?Packaging group:
PAINT
?Proper shipping name:
15 Regulatory information
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
?Code letter and hazard designation of product:
F Highly flammable
?Risk phrases:
11 Highly flammable.
67 Vapours may cause drowsiness and dizziness.
?Safety phrases:
9 Keep container in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
(Contd. on page 6)
GB
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 04.12.2009 Revision: 04.12.2009
Trade name: Spezialleitsilberlack Nr.24
(Contd. of page 5)
33 Take precautionary measures against static discharges.
60 This material and its container must be disposed of as hazardous waste.
?National regulations:
?Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
?Other regulations, limitations and prohibitive regulations
?Substances of very high concern (SVHC) according to REACH, Article 57
84-74-2 dibutyl phthalate
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
11 Highly flammable.
36 Irritating to eyes.
50 Very toxic to aquatic organisms.
61 May cause harm to the unborn child.
62 Possible risk of impaired fertility.
66 Repeated exposure may cause skin dryness or cracking.
67 Vapours may cause drowsiness and dizziness.
?Department issuing MSDS: Abteilung Umweltschutz
?Contact: Herr Marcus M黮ler
GB
DR
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