M267-2052 MED DK OAK PRO MARK STAIN
MATERIAL SAFETY DATA SHEET
RPM Wood Finishes Group
3194 Hickory Boulevard
Hudson, North Carolina 28638
828-728-8266
EMERGENCY PHONE (CHEM TREC): . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1-800-424-9300
FOR ALL INTERNATIONAL TRANSPORTATION ACCIDENTS. . . . . . . . . . . . . . . . .1-703-527-3887 (collect)
Health: 2 Flammability: 3 Reactivity 0
PRODUCT NAME: M267-2052 MED DK OAK PRO MARK STAIN
I. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
REVISION DATE: 09/06/04
SUPERCEDES: 16/07/03
MSDS NO. M267-2052
OSHA HAZ. CLASS: Flammable.
II. COMPOSITION/INFORMATION ON INGREDIENTS
CHEMICAL NAME % CAS # PEL
ethanol 51-60 64-17-5 1000 ppm TWA; 1900 mg/m3 TWA
polyketone resin 11-20 PROPRIETARY No PEL established
ethoxypropanol 1-10 1569-02-4 No PEL established
Acid Yellow 220 1-10 PROPRIETARY No PEL established
n-propyl acetate 1-10 109-60-4 200 ppm TWA; 840 mg/m3 TWA
Dipropylene glycol monomethyl ether 1-10 34590-94-8 No PEL established
isopropanol 1-10 67-63-0 400 ppm TWA; 980 mg/m3 TWA
propylene glycol monomethyl ether 1-10 107-98-2 No PEL established
chromium <1 7440-47-3 Chromium, sol. chromic, chromous salts (as
Cr): 0.5 mg/m3 TWA; Chromium, metal and
insoluble salts (as Cr): 1 mg/m3 TWA
III. HAZARDS IDENTIFICATION
Eye contact., Dermal, Inhalation, Ingestion, Absorption.
Routes of Entry:
Liver disease. Skin disease including eczema and sensitization. Respiratory disease
Medical Conditions Aggravated:
including asthma and bronchitis. Preexisting eye, skin and resiratory disorders may be
aggravated by exposure to this product.
Immediate (Acute) Health Effects
Irritation may be delayed for several hours. Can cause moderate respiratory irritation,
Inhalation:
dizziness, weakness, fatigue, nausea and headache.
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May cause skin irritation. Can cause minor skin irritation, defatting, and dermatitis.
Skin Contact:
No hazard in normal industrial use.
Can cause irritation. Can cause moderate irritation, tearing and reddening, but not
Eye Contact:
likely to permanently injure eye tissue. Contact with the eyes may cause moderate to
severe eye injury. Eye contact may result in tearing and reddening, but not likely to
permanently injure eye tissue. Temporary vision impairment (cloudy or blurred
vision) is possible. No hazard in normal industrial use.
No absorption hazard in normal industrial use. Minimal hazard in normal industrial
Skin Absorption:
use. May cause gastrointestinal discomfort.
Irritating to mouth, throat, and stomach. Can cause abdominal discomfort, nausea,
Ingestion:
vomiting and diarrhea.
Target Organ Acute Toxicity:
Ethyl alcohol respiratory system, skin, eyes, CNS, liver, blood, reproductive system
n-Propyl acetate skin, eyes, CNS, respiratory system
Dipropylene glycol, methyl ether eyes, respiratory system, CNS
Isopropyl alcohol eyes, skin, respiratory system
Propylene glycol monomethyl ether eyes, skin, respiratory system, CNS
Chromium metal respiratory system, skin, eyes
Long-Term (Chronic) Health Effects:
None of the substances have been shown to cause cancer in long term animal studies.
Carcinogenicity:
Not a carcinogen according to NTP, IARC, or OSHA.
No data available to indicate product or any components present at greater than 0.1%
Mutagenicity:
is mutagenic or genotoxic.
Upon prolonged and/or repeated exposure, can cause moderate respiratory irritation,
Inhalation:
dizziness, weakness, fatigue, nausea and headache.
Prolonged or repeated contact may cause irritation. Upon prolonged or repeated
Skin Contact:
contact, can cause minor skin irritation, defatting, and dermatitis.
Upon prolonged or repeated contact, can cause moderate to severe eye injury. Eye
Eye Contact:
contact may result in tearing and reddening, but not likely to permanently injure eye
tissue. Temporary vision impairment (cloudy or blurred vision) is possible.
Upon prolonged or repeated exposure, minimal hazard in normal industrial use. May
Skin Absorption:
cause gastrointestinal discomfort.
Eyes. Blood. Liver. Skin. Nervous System. Respiratory Tract.
Target Organ Chronic Toxicity:
No additional health information available.
Supplemental Health Hazard
Information:
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IV. FIRST AID
Remove subject to fresh air. Seek medical aid if lung irritation persists or if breathing
Inhalation:
becomes difficult. This material does not present a hazard if inhaled. Remove
individual to fresh air after an airborne exposure if any symptoms develop, as a
precautionary measure.
Immediately flush eyes with plenty of water. Get medical attention, if irritation
Eyes:
persists. Flush eyes with plenty of water for at least 20 minutes retracting eyelids
often. Tilt the head to prevent chemical from transferring to the uncontaminated eye.
Get immediate medical attention. Use an eye wash to remove a chemical from your
eye regardless of the level of hazard. Flush the affected eye for at least twenty
minutes. Tilt the head to prevent chemical from transferring to the uncontaminated
eye. Seek medical advice after flushing. Immediately flush eyes with plenty of water
for at least 20 minutes retracting eyelids often. Tilt the head to prevent chemical from
transferring to the uncontaminated eye. Get immediate medical attention and monitor
the eye daily as advised by your physician. None expected to be needed, however, use
an eye wash to remove a chemical from your eye regardless of the level of hazard.
For hot material, immediately immerse in or flush the affected area with large
Skin Contact:
amounts of cold water to dissipate heat. Cover with clean gauze and do not attempt to
remove the material yourself. Get prompt medical attention. Medical personnel: coat
with mineral oil to soften material for removal. Wash with soap and water.
Rinse mouth. Seek medical advice. Drink 3-4 glasses of water and DO NOT induce
Ingestion:
vomiting. Do not give anything by mouth to an unconscious or convulsing person. Get
medical attention. No hazard in normal industrial use. Do not induce vomiting. Seek
medical attention if symptoms develop. Provide medical care provider with this
MSDS.
Treat as thermal burns. No need to remove from skin as it will come off as healing
Notes to MD:
occurs.
V. FIRE FIGHTING MEASURES
Flammability Summary:
o
58 (CALC.) F
Flash Point:
Empty containers that retain product residue (liquid, solid/sludge, or vapor) can be
Fire Hazards:
dangerous. Do not pressurize, cut, weld, braze, solder, drill, grind, or expose
container to heat, flame, sparks, static electricity, or other sources of ignition. Any of
these actions can potentially cause an explosion that may lead to injury or death.
Container may explode in heat of fire. Vapors may be ignited by sparks, flames or
other sources of ignition if material is above the flash point giving rise to a fire (Class
B). Vapors are heavier than air and may travel to a source of ignition and flash back.
Water spray Dry chemical H2O, CO2, dry chemical, foam. Use alcohol resistant
Extinguishing Media:
foam, carbon dioxide, dry chemical, or water spray when fighting fires. Water or foam
may cause frothing if liquid is burning but it still may be a useful extinguishing agent
if carefully applied to the fire. Do not direct a water stream directly into the hot
burning liquid.
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Use methods for the surrounding fire. Flammable component(s) of this material may
Fire Fighting Instructions:
be lighter than water and burn while floating on the surface.Do not enter fire area
without proper protection including self-contained breathing apparatus and full
protective equipment. Fight fire from a safe distance and a protected location due to
the potential of hazardous vapors and decomposition products. Flammable
component(s) of this material may be lighter than water and burn while floating on the
surface. Use water spray/fog for cooling.
Hazardous Combustion Products: Carbon monoxide Toxic fumes.
VI. ACCIDENTAL RELEASE MEASURES
Exposure to the spilled material may be irritating or harmful. Follow personal
Health Consideration for Spill
Response: protective equipment recommendations found in Section VIII of this MSDS.
Additional precautions may be necessary based on special circumstances created by
the spill including; the material spilled, the quantity of the spill, the area in which the
spill occurred. Also consider the expertise of employees in the area responding to the
spill.
Prevent the spread of any spill to minimize harm to human health and the
Spill Mitigation Procedures
General Methods: environment if safe to do so. Wear complete and proper personal protective
equipment following the recommendation of Section VIII at a minimum. Dike with
suitable absorbent material like granulated clay. Gather and store in a sealed container
pending a waste disposal evaluation.
VII. HANDLING AND STORAGE
Wash thoroughly after handling. Avoid contact with material. Ground and bond
Handling:
containers when transferring material. Keep in air-tight containers- material is
hygroscopic. "Empty" containers retain product residue (liquid and/or vapor) and can
be dangerous. Use spark-proof tools and explosion-proof equipment. Remove
contaminated clothing and wash before reuse. Follow all MSDS/label precautions
even after container is emptied because it may retain product residues. Harmful or
irritating material. Avoid contact and avoid breathing the material. Use only in a well
ventilated area.
Do not store near combustible materials. Keep container closed when not in use. Keep
Storage:
away from heat, sparks, and flame. Avoid exposure to sunlight or ultraviolet (UV)
light sources. Store in a cool dry ventilated location. Isolate from incompatible
materials and conditions. Keep container(s) closed.
VIII. ENGINEERING CONTROLS AND PERSONAL PROTECTIVE EQUIPMENT
Facilities storing or using this material should be equipped with an eyewash and
Engineering Controls:
safety shower. Explosion proof exhaust ventilation should be used. No exposure
limits exist for the constituents of this product. Use local exhaust ventilation or other
engineering controls to minimize exposures and maintain operator comfort.
Protective Equipment
Respirators should be selected by and used under the direction of a trained health and
Respiratory Tract:
safety professional following requirements found in OSHA's respirator standard (29
CFR 1910.134) and ANSI's standard for respiratory protection (Z88.2-1992). A
written respiratory protection program, including provisions for medical certification,
training, fit testing, exposure assessments, maintenance, inspection, cleaning, and
convenient, sanitary storage should be implemented.
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Wear chemically resistant safety glasses with side shields when handling this product.
Eyes:
Wear additional eye protection such as chemical splash goggles and/or face shield
when the possibility exists for eye contact with splashing or spraying liquid, or
airborne material. Do not wear contact lenses. Have an eye wash station available.
Avoid skin contact by wearing chemically resistant gloves, an apron and other
Skin:
protective equipment depending upon conditions of use. Inspect gloves for chemical
break-through and replace at regular intervals. Clean protective equipment regularly.
Wash hands and other exposed areas with mild soap and water before eating,
drinking, and when leaving work.
IX. PHYSICAL DATA
COLORED LIQUID
Physical State:
MODERATELY STRONG ALCOHOL
Odor:
11.4843
Solids Vol %:
15.7745
Solids Wt %:
6.1711
Material VOC lbs/gal:
741.0943
Material VOC gms/l:
6.1711
Coatings VOC lbs/gal:
741.0943
Coatings VOC gms/l:
7.3436
Weight per gallon:
X. STABILITY AND REACTIVITY
Stable. Stable under normal conditions.
Stability Information:
Contamination. Contact with air. Visible light. Contact with water. None known.
Conditions to Avoid:
Strong oxidizing agents. Nitrogen oxides. Strong acids. Strong alkalies. Water.
Chemical Incompatibility:
Hazardous Polymerization will not occur.
Hazardous Polymerization:
XI. TOXICOLOGICAL INFORMATION
Chemical Name CAS Number LD50/LC50
Ethyl alcohol 64-17-5 Inhalation LC50 Rat : 20000 ppm/10H; Inhalation LC50 Mouse : 39
gm/m3/4H; Oral LD50 Rat : 7060 mg/kg; Oral LD50 Mouse : 3450 mg/kg
2-Propanol, 1-ethoxy- 1569-02-4 Inhalation LC50 Rat : >10000 ppm/4H; Oral LD50 Rat : 4400 mg/kg; Dermal
LD50 Rabbit : 8100 mg/kg
Acetic acid, propyl ester 109-60-4 Oral LD50 Rat : 9370 mg/kg; Oral LD50 Mouse : 8300 mg/kg; Dermal LD50
Rabbit : >20 mL/kg
Dipropylene glycol, monomethyl ether 34590-94-8 Oral LD50 Rat : 5400 uL/kg; Dermal LD50 Rabbit : 10 mL/kg
Isopropyl alcohol 67-63-0 Inhalation LC50 Rat : 16000 ppm/8H; Oral LD50 Rat : 5045 mg/kg; Oral
LD50 Mouse : 3600 mg/kg; Dermal LD50 Rabbit : 12800 mg/kg
2-Propanol, 1-methoxy- 107-98-2 Inhalation LC50 Rat : 10000 ppm/5H; Oral LD50 Mouse : 11700 mg/kg;
Dermal LD50 Rabbit : 13 gm/kg
XII. ECOLOGICAL INFORMATION
No data available. This material is not expected to be harmful to the ecology.
Overview (for ingredients):
XIII. DISPOSAL CONSIDERATIONS
Spent or discarded material is a hazardous waste.
Waste Description for Spent
Product:
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Clean up and dispose of waste in accordance with all federal, state, and local
Disposal Methods:
environmental regulations. Dispose of by incineration following Federal, State, Local,
or Provincial regulations.
If discarded, this product is considered a RCRA ignitable waste, D001.
Potential EPA Waste Codes:
Components Subject to USEPA Land Disposal Restrictions:
Chromium (total) 7440-47-3 0.1 %
XIV. TRANSPORTATION INFORMATION
Paint, 3, UN 1263, II
DOT
See 49CFR 172.101 for Special Provisions, Packaging, and Quantity Limitations.
XV. REGULATORY INFORMATION
Chemical Name Regulation CASRN %
Isopropyl alcohol SARA 313 Reportable: 67-63-0 2.98
Chromium SARA 313 Reportable: 7440-47-3 0.1
64-17-5 59.45
Ethyl alcohol California Proposition 65
Developmental Toxicity:
64-17-5 59.45
ethanol New Jersey Right To Know:
PROPRIETARY 10.34
polyketone resin New Jersey Right To Know:
1569-02-4 9.3
ethoxypropanol New Jersey Right To Know:
PROPRIETARY 3.83
Acid Yellow 220 New Jersey Right To Know:
109-60-4 3.7
n-propyl acetate New Jersey Right To Know:
XVI. ADDITIONAL INFORMATION
IMPORTANT: WHILE THE DESCRIPTIONS, DATA AND INFORMATION
Other Information:
CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE
ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY
FACTORS MAY AFFECT PROCESSING OR APPLICATION/USE, WE RECOMMEND
THAT YOU PERFORM AN ASSESSMENT TO DETERMINE THE SUITABILITY OF A
PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES
OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED, DATA
OR INFORMATION SET FORTH. IN NO CASE SHALL THE DESCRIPTIONS,
INFORMATION,OR DATA PROVIDED BE CONSIDERED A PART OF OUR TERMS
AND CONDITIONS OF SALE. FURTHER, THE DESCRIPTIONS, DATA AND
INFORMATION FURNISHED HEREUNDER ARE GIVEN GRATIS. NO OBLIGATION
OR LIABILITY FOR THE DESCRIPTION, DATA AND INFORMATION GIVEN ARE
ASSUMED. ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK.
MSDS glossary.
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