Page 1/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 14.05.2004 Reviewed on 14.05.2004
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: AGC Leitsilberlack Switch
?Application of the substance / the preparation Masking material
?Manufacturer/Supplier:
Wieland Dental + Technik GmbH & Co.KG
Schwenninger Str. 13
75179 Pforzheim
Telefon + 49 (07231)-37050, Telefax + 49 (07231)-357959
?Further information obtainable from: Abteilung Umweltschutz
2 Composition/information on ingredients
?Chemical characterization
?Description: Lacquer on the basis of the following fillers, resins and other components.
?Dangerous components:
CAS: 1569-02-4 1-ethoxypropan-2-ol Xi; R 10-36 10-25%
EINECS: 216-374-5
CAS: 64-17-5 ethanol F; R 11 5-10%
EINECS: 200-578-6
CAS: 108-93-0 cyclohexanol Xn; R 20/22-37/38 1-5%
EINECS: 203-630-6
?Additional information: For the wording of the listed risk phrases refer to section 16.
3 Hazards identification
?Hazard description:
Xi Irritant
F Highly flammable
?Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline
for preparations of the EU" in the latest valid version.
R 11 Highly flammable.
R 36 Irritating to eyes.
?Classification system:
The classification is acco rding to th e latest ed ition s o f t he EU-lists, an d extend ed by company and
literature data.
4 First-aid measures
?After inhalation:
Su pp ly fresh air. If required, pro vide art ificial respiratio n. Keep pat ient warm. Co ns ult do ct or if
symptoms persist.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Generally the product does not irritate the skin.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: Call a doctor immediately.
?Information for doctor:
?The following symptoms may occur:
Dizziness GB
(Contd. on page 2)
DR
Page 2/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 14.05.2004 Reviewed on 14.05.2004
Trade name: AGC Leitsilberlack Switch
(Contd. of page 1)
Headache
5 Fire-fighting measures
?Suitable extinguishing agents: CO2, sand, extinguishing powder. Do not use water.
?For safety reasons unsuitable extinguishing agents: Water
?Special hazards caused by the substance, its products of combustion or resulting gases:
Can form explosive gas-air mixtures.
?Protective equipment:
Do not inhale explosion gases or combustion gases.
Mount respiratory protective device.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection:
Prevent seepage into sewage system, workpits and cellars.
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
?Handling:
?Information for safe handling: Ensure good ventilation/exhaustion at the workplace.
?Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage:
?Requirements to be met by storerooms and receptacles: Store in a cool location.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Keep receptacle tightly sealed.
8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
64-17-5 ethanol
OES Long-term value: 1920 mg/m? 1000 ppm
108-93-0 cyclohexanol
OES Long-term value: 208 mg/m? 50 ppm
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes. GB
(Contd. on page 3)
DR
Page 3/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 14.05.2004 Reviewed on 14.05.2004
Trade name: AGC Leitsilberlack Switch
(Contd. of page 2)
Avoid contact with the eyes and skin.
?Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation.
?Protection of hands: Plastic gloves
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on fu rther marks of
qu ality an d varies from manufact urer to manu facturer. As th e produ ct is a preparat ion of several
substances, the res istance of the glove material can not be calculated in advance and has therefore to
be checked prior to the application.
?Penetration time of glove material
The exact break trou gh time has to be found out by the manufacturer of the protective gloves and has
to be observed.
?Eye protection: Safety glasses
9 Physical and chemical properties
?General Information
Form: Fluid
Colour: Red
Odour: Characteristic
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 56-132癈
?Flash point: -10癈
?Ignition temperature: 255癈
?Self-igniting: Product is not selfigniting.
?Danger of explosion: Produ ct is not explosive. However, formation of explosive air/v apour
mixtures are possible.
?Explosion limits:
Lower: 1.3 Vol %
Upper: 12.0 Vol %
?Density at 20癈: 1.5 g/cm?br>
?Solubility in / Miscibility with
water: Not miscible or difficult to mix.
?Solvent content:
Organic solvents: 26.0 %
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known. GB
?Dangerous decomposition products: Flammable gases/vapours
(Contd. on page 4)
DR
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 14.05.2004 Reviewed on 14.05.2004
Trade name: AGC Leitsilberlack Switch
(Contd. of page 3)
11 Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for classification:
1569-02-4 1-ethoxypropan-2-ol
Oral LD50 4900 mg/kg (Ratte)
Dermal LD50 9500 mg/kg (rab)
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: Irritating effect.
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
Th e pro duct sho ws th e following d angers according to th e calculation method of th e Gen eral EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant
12 Ecological information
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow product to reach ground water, water course or sewage system.
13 Disposal considerations
?Product:
?Recommendation
Contact manufacturer for recycling information.
Must be specially treated adhering to official regulations.
?European waste catalogue
08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (M FSU) OF
COA TINGS (PA INTS, VA RNISHES A ND VITREOUS ENA M ELS), A DHESIVES,
SEALANTS AND PRINTING INKS
08 01 00 wastes from MFSU and removal of paint and varnish
08 01 11 waste paint and varnish containing organic solvents or other dangerous substances
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
?Recommended cleansing agents: Alcohol
14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID class: 3 (F 1) Flammable liquids.
?UN-Number: 1993
?Packaging group: II
?Hazard label 3
GB
(Contd. on page 5)
DR
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 14.05.2004 Reviewed on 14.05.2004
Trade name: AGC Leitsilberlack Switch
(Contd. of page 4)
?Description of goods: 1993 FLAMMABLE LIQUID, N.O.S. (1-ethoxypropan-2-ol, ETHANOL (ETHYL
ALCOHOL))
?Maritime transport IMDG:
?IMDG Class: 3
?UN Number: 1993
?Label 3
?Packaging group: II
?EMS Number: F-E,S-E
?Marine pollutant: No
?Proper shipping name: FLAM MABLE LIQUID, N.O.S. (1-et ho xyp ro pan -2-ol, ETHA NOL (ETHYL
ALCOHOL))
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: 3
?UN/ID Number: 1993
?Label 3
?Packaging group: II
?Proper shipping name: FLAMMABLE LIQUID, N.O.S. (1-ethoxypropan-2-ol, ETHANOL)
15 Regulatory information
?Labelling according to EU guidelines:
Th e prod uct h as been clas sified an d marked in acco rd an ce with EU Directives / Ordinance on
Hazardous Materials.
?Code letter and hazard designation of product:
Xi Irritant
F Highly flammable
?Risk phrases:
11 Highly flammable.
36 Irritating to eyes.
?Safety phrases:
7/9 Keep container tightly closed and in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
24/25 Avoid contact with skin and eyes.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
60 This material and its container must be disposed of as hazardous waste.
?National regulations:
?Technical instructions (air):
Class Share in %
NK 26.0
GB
(Contd. on page 6)
DR
Page 6/6
Material Safety Data Sheet
According to 91/155 EEC
Printing date 14.05.2004 Reviewed on 14.05.2004
Trade name: AGC Leitsilberlack Switch
(Contd. of page 5)
?Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
11 Highly flammable.
20/22 Harmful by inhalation and if swallowed.
36 Irritating to eyes.
37/38 Irritating to respiratory system and skin.
?Department issuing MSDS: Abteilung Umweltschutz GB
?Contact: Herr Selzer
DR
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