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Material Safety Data Sheet
According to 91/155 EEC
Printing date 16.12.2005 Reviewed on 16.12.2005
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: AGC Leitsilberlack
?Application of the substance / the preparation Masking material
?Manufacturer/Supplier:
Wieland Dental + Technik GmbH & Co.KG
Schwenninger Str. 13
75179 Pforzheim
Telefon + 49 (07231)-37050, Telefax + 49 (07231)-357959
?Further information obtainable from: Abteilung Umweltschutz
* 2 Composition/information on ingredients
?Chemical characterization
?Description: Lacquer on the basis of the following fillers, resins and other components.
?Dangerous components:
CAS: 1569-02-4 1-ethoxypropan-2-ol R 10-67 25-50%
EINECS: 216-374-5
CAS: 64-17-5 ethanol F; R 11 10-25%
EINECS: 200-578-6
CAS: 67-64-1 acetone Xi, F; R 11-36-66-67 5-10%
EINECS: 200-662-2
CAS: 141-78-6 ethyl acetate Xi, F; R 11-36-66-67 1-5%
EINECS: 205-500-4
3 Hazards identification
?Hazard description:
Xi Irritant
F Highly flammable
?Information concerning particular hazards for human and environment:
R 11 Highly flammable.
R 36 Irritating to eyes.
?Classification system:
The classification is acco rding to th e latest ed ition s o f t he EU-lists, an d extend ed by company and
literature data.
4 First-aid measures
?General information: Take affected persons out of danger area and lay down.
?After inhalation:
Su pp ly fresh air. If required, pro vide art ificial respiratio n. Keep pat ient warm. Co ns ult do ct or if
symptoms persist.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: Drink plenty of water and provide fresh air. Call for a doctor immediately.
GB
(Contd. on page 2)
DR
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 16.12.2005 Reviewed on 16.12.2005
Trade name: AGC Leitsilberlack
(Contd. of page 1)
* 5 Fire-fighting measures
?Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?For safety reasons unsuitable extinguishing agents: Not applicable
?Special hazards caused by the substance, its products of combustion or resulting gases:
Can form explosive gas-air mixtures.
?Protective equipment:
Do not inhale explosion gases or combustion gases.
Mount respiratory protective device.
6 Accidental release measures
?Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
?Measures for environmental protection:
Do not allow product to reach sewage system or any water course.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
7 Handling and storage
?Handling:
?Information for safe handling: Ensure good ventilation/exhaustion at the workplace.
?Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
?Storage:
?Requirements to be met by storerooms and receptacles: Store in a cool location.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Store in cool, dry conditions in well sealed receptacles.
* 8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
64-17-5 ethanol
OES Long-term value: 1920 mg/m? 1000 ppm
67-64-1 acetone
OES Short-term value: 3620 mg/m? 1500 ppm
Long-term value: 1210 mg/m? 500 ppm
New, IOELV
141-78-6 ethyl acetate
OES Short-term value: 400 ppm
Long-term value: 200 ppm
Rev
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Wash hands before breaks and at the end of work.
(Contd. on page 3)
GB
DR
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 16.12.2005 Reviewed on 16.12.2005
Trade name: AGC Leitsilberlack
(Contd. of page 2)
Avoid contact with the eyes and skin.
?Respiratory protection: Use suitable respiratory protective device in case of insufficient ventilation.
?Protection of hands: Plastic gloves
?Material of gloves
Chloroprene rubber, CR
PVC or PE gloves
?Penetration time of glove material
The exact break trou gh time has to be found out by the manufacturer of the protective gloves and has
to be observed.
?Eye protection: Safety glasses
?Body protection: Protective work clothing
9 Physical and chemical properties
?General Information
Form: Fluid
Colour: Grey
Odour: Characteristic
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 56-132癈
?Flash point: 12癈
?Ignition temperature: 255癈
?Self-igniting: Product is not selfigniting.
?Danger of explosion: Produ ct is not explosive. However, formation of explosive air/v apour
mixtures are possible.
?Explosion limits:
Lower: 1.3 Vol %
Upper: 19.0 Vol %
?Vapour pressure at 20癈: 59 hPa
?Density at 20癈: 1.7 g/cm3
?Solubility in / Miscibility with
water: Not miscible or difficult to mix.
?pH-value: Not applicable
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided:
No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous decomposition products: Flammable gases/vapours
11 Toxicological information
?Acute toxicity:
?Primary irritant effect:
?on the skin: No irritant effect.
?on the eye: Irritating effect.
(Contd. on page 4)
GB
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 16.12.2005 Reviewed on 16.12.2005
Trade name: AGC Leitsilberlack
(Contd. of page 3)
?Sensitization: No sensitizing effects known.
?Additional toxicological information:
Th e pro duct sho ws th e following d angers according to th e calculation method of th e Gen eral EU
Classification Guidelines for Preparations as issued in the latest version:
Irritant
12 Ecological information
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow product to reach ground water, water course or sewage system.
13 Disposal considerations
?Product:
?Recommendation
Contact manufacturer for recycling information.
Must be specially treated adhering to official regulations.
?European waste catalogue
08 00 00 WASTES FROM THE MANUFACTURE, FORMULATION, SUPPLY AND USE (M FSU) OF
COA TINGS (PA INTS, VA RNISHES A ND VITREOUS ENA M ELS), A DHESIVES,
SEALANTS AND PRINTING INKS
08 01 00 wastes from MFSU and removal of paint and varnish
08 01 11 waste paint and varnish containing organic solvents or other dangerous substances
?Uncleaned packaging:
?Recommendation:
Packagings that may not be cleansed are to be disposed of in the same manner as the product.
?Recommended cleansing agents: Alcohol
* 14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID class: 3 (F1) Flammable liquids.
?Danger code (Kemler): 33
?UN-Number: 1993
?Packaging group: II
?Hazard label 3
?Description of goods: 1993 FLAMMABLE LIQUID, N.O.S. (vapor pressure at 50癈 at most 110 kPa)
(ETHANOL (ETHYL ALCOHOL), ACETONE)
?Maritime transport IMDG:
?IMDG Class: 3
?UN Number: 1993
(Contd. on page 5)
GB
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 16.12.2005 Reviewed on 16.12.2005
Trade name: AGC Leitsilberlack
(Contd. of page 4)
?Label 3
?Packaging group: II
?EMS Number: F-E,S-E
?Marine pollutant: No
?Proper shipping name: FLAMMABLE LIQUID, N.O.S. (ETHANOL (ETHYL ALCOHOL), ACETONE)
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: 3
?UN/ID Number: 1993
?Label 3
?Packaging group: II
?Proper shipping name: FLAMMABLE LIQUID, N.O.S. (ETHANOL (ETHYL ALCOHOL), ACETONE)
* 15 Regulatory information
?Labelling according to EU guidelines:
Th e prod uct h as been clas sified an d marked in acco rd an ce with EU Directives / Ordinance on
Hazardous Materials.
?Code letter and hazard designation of product:
Xi Irritant
F Highly flammable
?Risk phrases:
11 Highly flammable.
36 Irritating to eyes.
?Safety phrases:
7/9 Keep container tightly closed and in a well-ventilated place.
16 Keep away from sources of ignition - No smoking.
24 Avoid contact with skin.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
60 This material and its container must be disposed of as hazardous waste.
?National regulations:
?Technical instructions (air):
Class Share in %
NK 60.0
?Waterhazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for
any specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
11 Highly flammable.
36 Irritating to eyes.
66 Repeated exposure may cause skin dryness or cracking.
(Contd. on page 6)
GB
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Material Safety Data Sheet
According to 91/155 EEC
Printing date 16.12.2005 Reviewed on 16.12.2005
Trade name: AGC Leitsilberlack
(Contd. of page 5)
67 Vapours may cause drowsiness and dizziness.
?Department issuing MSDS: Abteilung Umweltschutz
?Contact: Herr Selzer
?* Data compared to the previous version altered.
GB
DR
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