SAFETY DATA SHEET
Print Date : 2004-06-23. Date of issue : 2004-06-23.
Identification of the substance/preparation and of the
1.
company/undertaking
:
Product name MAHOGANY WOODFILLER
AK2013
:
Product Code
: Industrial applications.
Product Use
: Yes.
Used by Spraying
Becker Acroma Ltd
:
Manufacturer
Rookwood Way
Haverhill
Suffolk, CB9 8PQ
+44 (0)1440 703611
: Becker Acroma, +44 (0)1440 708158
Emergency telephone
number
Composition/information on ingredients
2.
Substances presenting a health or environmental hazard within the meaning of the Dangerous Substances
Directive 67/548/EEC.
Chemical name* CAS No. EC Number % R-Phrases
1317-95-9 50-100 Xn; R20
Crystalline Silica
64742-94-5 265-198-5 15-20 R10
Solvent naphtha (petroleum), heavy arom.
Xn; R65
Xi; R37
R66
N; R51/53
107-98-2 203-539-1 5-10 R10
1-Methoxypropan-2-ol
64742-88-7 265-191-7 1-5 R10
Solvent naphtha (petroleum), medium aliph.
Xn; R65
1569-02-4 216-374-5 1-5 R10
1-ethoxy-2-propanol
Xi; R36
0,1-0,5 N; R51/53
Dyestuff C.I. Solvent Red 233
* Occupational Exposure Limit(s), if available, are listed in section 8
Hazards identification
3.
: Flammable.
Physical/Chemical
Hazards
: Harmful by inhalation.
Human health hazards
First aid measures
4.
: In all cases of doubt, or when symptoms persist, seek medical attention. If
General
unconscious, place in recovery position and seek medical advice. Never give
anything by mouth to an unconscious person.
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: Remove to fresh air. Keep person warm and at rest. If breathing is irregular or
Inhalation
stopped, administer artificial respiration. If breathing is difficult, give oxygen.
Get medical attention.
: Immediately irrigate copiously with clean water for 5-10 minutes, keeping
Eye Contact
eyelids open. Get medical attention.
: Remove contaminated clothing and shoes. Wash skin thoroughly with soap and
Skin Contact
water or use a suitable skin cleaner. Do NOT use solvents or thinners.
: Seek immediate medical attention. Keep person warm and at rest. DO NOT
Ingestion
induce vomiting. If vomiting, hold down the head to reduce the risk of getting
stomach content into the lungs.
: Rinse with water until the pain ceases. During rinsing, remove clothes, which
Burns
are not burnt on, from the damaged area. In severe cases, rinse with tepid water
for 30-40 minutes or until medical staff arrive. If possible, protect the burnt area
with a bandage, clean towel or similar. Prevent shock.
Fire-fighting measures
5.
Extinguishing media
: In case of fire, use water spray (fog), foam, dry chemicals, or CO 2. Closed
Suitable
containers may be cooled with water spray.
: Do NOT use a jet of water, water from buckets etc., which may spread the fire.
Not suitable
: Refer to MSDS: # Section 10
Hazardous thermal
decomposition products
Accidental release measures
6.
: Avoid contact with skin and eyes. Avoid inhalation of vapors and spray mist.
Personal precautions
Refer to protective measures listed in sections 7 and 8. Keep unnecessary
personnel away. No smoking.
: Prevent entry into sewers, basements or confined areas; dike if needed. Absorb
Spill
with DRY earth, sand or other non-combustible material. In case of a major
spill, contact the Fire Department.
Keep away from sources of ignition and ventilate the area.
Handling and storage
7.
: Vapors are heavier than air and may spread along floors. Vapors may form
Handling
explosive mixtures with air. Prevent the creation of flammable or explosive
concentrations of vapors in air and avoid vapor concentrations higher than the
occupational exposure limits. Avoid contact with skin and eyes. Eating,
drinking and smoking should be prohibited in area where this product is
handled. Personal Protective Equipment, see section 8. Keep away from
incompatibles mentioned in section 10.
The product must not be used near open flames or other sources of ignition. Use
approved electrical equipment to avoid explosion. The product may charge
electrostatically. Always connect containers to ground, and from the source to
the recipient container, when transferring from one to another. Only
non-sparking tools should be used.
: Keep container tightly closed. Store in a dry, cool and well-ventilated area.
Storage
Storage temperature: refer to the Technical Data Sheet. Keep away from
incompatibles mentioned in section 10.
Store in accordance with applicable regulations for flammable liquids. Isolate
from sources of heat, sparks, open flame and other sources of ignition.
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: Never use pressure to empty: container is not a pressure vessel. Always keep in
Packaging materials
containers made from the same material as the original one.
Exposure controls/personal protection
8.
: Provide exhaust ventilation or other engineering controls to keep the airborne
Engineering measures
concentrations of vapours below their respective Occupational Exposure
Limits. Ensure that eyewash stations and safety showers are close to the
workstation location.
: Wash hands, forearms, and face thoroughly after handling and before eating,
Hygiene measures
smoking, using lavatory, and at the end of the day. Always immediately wash
contaminated skin. Apply a suitable skin lotion.
EH40-MEL (United Kingdom (UK), 2003). Notes: Respirable
Crystalline Silica
TWA: 0,1 mg/m3 8 hour(s).
UK Solvent Industry Association (United Kingdom (UK), 2000).
Solvent naphtha (petroleum), heavy arom.
TWA: 50 ppm 8 hour(s).
TWA: 300 mg/m3 8 hour(s).
EH40-OES (United Kingdom (UK), 2002). Skin
1-Methoxypropan-2-ol
STEL: 560 mg/m3 15 minute(s).
STEL: 150 ppm 15 minute(s).
TWA: 375 mg/m3 8 hour(s).
TWA: 100 ppm 8 hour(s).
Personal protective equipment
: Wear appropriate respirator when ventilation is inadequate. If exposure to dust
Respiratory system
cannot be avoided by local exhaust ventilation, suitable dust filter must be used.
: Wear safety glasses or other suitable protective equipment if there is a risk of
Eyes
splashing.
: Wear suitable protective clothing. Cotton or cotton/synthetic overalls are
Skin and body
normally suitable. Do NOT use clothes, which readily charge electrostatically.
: Wear suitable gloves.
Hands
Physical and chemical properties
9.
: Liquid.
Physical state
Color : Brownish-red.
1.424 g/cm3
:
Density
: Closed cup: 34癈 (93.2癋). (ASTM 6450)
Flash point
Auto-ignition temperature : The lowest known value is 277癈 (530.6癋) (1-Methoxypropan-2-ol).
: Lowest Lower : 0.6%-v/v, Highest upper : 14%-v/v.
Explosion Limits
: The highest known value is 1.2 kPa (9 mm Hg) (at 20癈)
Vapor Pressure
(1-Methoxypropan-2-ol). Weighted average: 0.46 kPa (3.45 mm Hg) (at 20癈)
: >35癈 (95癋)
Boiling Point
: Not applicable.
VOC Content
10. Stability and reactivity
: The product is stable.
Stability
: Slightly reactive to reactive with OXIDIZING AGENTS, acids.
Reactivity
: These products are carbon oxides (CO, CO2). Some metallic oxides.
Hazardous thermal
decomposition products
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11. Toxicological information
: Exposure to component solvent vapor concentrations in excess of the stated
Inhalation
occupational exposure limit may result in adverse health effects such as mucous
membrane and respiratory system irritation and adverse effects on the kidneys,
liver and central nervous system. Symptoms and signs include headaches,
dizziness, fatigue, muscular weakness, drowsiness and, in extreme cases, loss of
consciousness.
: Can cause irritation and temporary damage if splashes come in contact with the
Eye Contact
eye.
: Repeated or prolonged contact with the preparation may cause removal of
Skin Contact
natural fat from the skin, resulting in non-allergic contact dermatitis and
absorption through the skin.
: Ingestion may lead to stomach pains, nausea, vomiting and other symptoms,
Ingestion
similar to those caused by inhalation.
12. Ecological information
: There is no data available on the preparation itself.
Ecotoxicity
13. Disposal considerations
: 080111
European Waste
Catalogue (EWC)
: The classification of the product may meet the criteria for a hazardous waste
Hazardous Waste
: Do not allow to enter drains or watercourses. Ship for treatment/disposal in
Methods of disposal
accordance with local regulations.
14. Transport information
: 1263
UN number
: 3
ADR/RID Class
: 31(c)
ADR/RID Item number
: Paint
Proper shipping name
: III
Packing Group
:
ADR/RID label
3
: 3
IMDG Class
: III
Packing Group
:
IMDG label
3
: 310
Medical First Aid Guide
(MFAG)
: 3-05
Emergency Schedules
(EmS)
: Not pollutant.
Marine pollutant
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: 3
IATA-DGR Class
:
IATA label
3
15. Regulatory information
Classification
:
Hazard symbol(s)
Harmful
:
Classification
: R10- Flammable.
Risk Phrases
R20- Harmful by inhalation.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
: S16- Keep away from sources of ignition - No smoking.
Safety Phrases
S23- Do not breathe spray or vapor.
S51- Use only in well-ventilated areas.
Crystalline Silica
:
Contains
Other Information
: Not applicable.
Additional Warning
Phrases
: Not applicable.
Restriction to Market
Directive
16. Other information
R10- Flammable.
Full text of R phrases referred :
R20- Harmful by inhalation.
to in Sections 2 and 3 United
R65- Harmful: may cause lung damage if swallowed.
Kingdom (UK)
R36- Irritating to eyes.
R37- Irritating to respiratory system.
R66- Repeated exposure may cause skin dryness or cracking.
R51/53- Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
R52/53- Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic
environment.
Xn - Harmful
Full text of classifications :
Xi - Irritant
referred to in Sections 2 and 3
N - Dangerous for the environment.
United Kingdom (UK)
Date of printing : 2004-06-23.
Version : 1
Date of issue : 2004-06-23.
Date of Previous Issue : No Previous Validation.
Notice to Reader
The information in this Safety Data Sheet is based on the present state of our knowledge, and on current EU regulations and
national laws. It provides guidance on health, safety and environmental aspects of the product, and should not be constructed as any
guarantee of technical performance or suitability for particular applications. The product should not be used for purposes other
than those shown in Section 1, without first referring to the supplier and obtaining written handling instructions. As the specific
conditions of the use of the product are outside the supplier's control, the user is responsible for ensuring that the requirements of
relevant legislation are complied with.
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