SAFETY DATA SHEET
Based on Directive 2001/58/EC of the Commission of the European Communities
ACETONE-2,4-DINITROPHENYLHYDRAZONE
1. Identification of the substance/preparation and of the company/undertaking
1.1 Identification of the substance or preparation:
Synonyms: none
CAS No. : 1567-89-1 BCR number : BCR-549
EC index No. : N.A. NFPA code : N.D.
EINECS No. : N.A. Molecular weight : 238.21
RTECS No. : N.A. Formula : C9H10N4O4
1.2 Use of the substance or the preparation:
Certified reference material for laboratory use only
1.3 Company/undertaking identification:
Institute for Reference Materials and Measurements
Retieseweg
B-2440 Geel
Tel. : +32 14 57 12 11
Fax : +32 14 58 42 73
1.4 Telephone number for emergency:
+32 70 245 245
Antigifcentrum
p/a Militair Hospitaal Koningin Astrid, Bruynstraat, B-1120 Brussel
2. Composition/information on ingredients
Hazardous ingredients CAS No. Conc. Hazard Risks
in % symbol
EINECS No. (R-phrases)
acetone 2,4- 1567-89-1 100 Xi 36/37/38 (1)
dinitrophenylhydrazone
(1) For R-phrases in full: see heading 16
3. Hazards identification
- Irritating to eyes, respiratory system and skin
4. First aid measures
4.1 Eye contact:
- Consult a doctor/medical service if irritation persists
- Rinse immediately with plenty of water
- Do not apply neutralizing agents
4.2 Skin contact:
- Consult a doctor/medical service if irritation persists
- Wash immediately with lots of water
4.3 After inhalation:
- Consult a doctor/medical service if breathing problems develop
- Remove the victim into fresh air
- Unconscious: maintain adequate airway and respiration
4.4 After ingestion:
- Consult a doctor/medical service if you feel unwell
- Never give water to an unconscious person
Printing date : 07-2002 1/8
Compiled by : Brandweerinformatiecentrum voor Gevaarlijke Stoffen vzw (BIG)
Technische Schoolstraat 43 A, B-2440 Geel
( +32 14 58 45 47 http://www.big.be E-mail: info@big.be
MSDS established : Revision date : 11-04-2002
Reference number : BIG\26293GB Revision number : 001
Reason for revision : Directive 2001/58/EC
ACETONE-2,4-DINITROPHENYLHYDRAZONE
5. Fire-fighting measures
5.1 Suitable extinguishing media:
- No data available
5.2 Unsuitable extinguishing media:
- No data available
5.3 Special exposure hazards:
- On burning: release of toxic and corrosive gases/vapours e.g.:
nitrous vapours, carbon monoxide - carbon dioxide
5.4 Instructions:
- Dilute toxic gases with water spray
5.5 Special protective equipment for firefighters:
- Heat/fire exposure: compressed air/oxygen apparatus
- Heat/fire exposure: gas-tight suit
6. Accidental release measures
6.1 Personal protection/precautions: see heading 8.1/8.3/10.3
6.2 Environmental precautions:
- No data available
6.3 Methods for cleaning up:
- Shovel up the solid spill
- Clean contaminated surfaces with an excess of water
- Wash clothing and equipment after handling
7. Handling and storage
7.1 Handling:
- Reduce/avoid exposure and/or contact
- Avoid raising dust
- Remove contaminated clothing immediately
- Clean contaminated clothing
7.2 Storage:
- Meet the legal requirements.
- Keep away from: heat sources
Storage temperature : N.D. 癈
Quantity limits : N.D. kg
Storage life : N.D.
Materials for packaging :
- suitable : no data available
- to avoid : no data available
7.3 Specific uses:
- See information supplied by the manufacturer
Printing date : 07-2002 2/8
ACETONE-2,4-DINITROPHENYLHYDRAZONE
8. Exposure controls/Personal protection
8.1 Exposure limit values:
TLV-TWA : not listed
TLV-STEL : not listed
TLV-Ceiling : not listed
OES-LTEL : not listed
OES-STEL : not listed
MEL-LTEL : not listed
MEL-STEL : not listed
MAK : not listed
TRK : not listed
MAC-TGG 8 h : not listed
MAC-TGG 15 min. : not listed
MAC-Ceiling : not listed
VME-8 h : not listed
VLE-15 min. : not listed
GWBB-8 h : not listed
GWK-15 min. : not listed
Momentary value : not listed
EC : not listed
EC-STEL : not listed
Sampling methods:
- No data available
8.2 Exposure controls:
8.2.1 Occupational exposure controls:
- Work under local exhaust/ventilation
8.2.2 Environmental exposure controls: see heading 13
8.3 Personal protection:
8.3.1 respiratory protection:
- Dust production: dust mask with filter type P2
8.3.2 hand protection:
- Gloves
Suitable materials: No data available
- Breakthrough time: N.D.
8.3.3 eye protection:
- Face shield
- In case of dust production: protective goggles
8.3.4 skin protection:
- Protective clothing
- In case of dust production: head/neck protection
Suitable materials: No data available
Printing date : 07-2002 3/8
ACETONE-2,4-DINITROPHENYLHYDRAZONE
9. Physical and chemical properties
9.1 General information:
Appearance (at 20癈) : Crystalline solid / Needles
Odour : N.D.
Colour : Yellow
9.2 Important health, safety and environmental information:
pH value : N.D.
Boiling point/boiling range : N.D. 癈
Flashpoint : N.D. 癈
Explosion limits : N.D. vol% ( 癈)
Vapour pressure (at 20癈) : N.D. hPa
Vapour pressure (at 50癈) : N.D. hPa
Relative density (at 20癈) : N.D.
Water solubility : Insoluble
Soluble in : Ethanol, chloroform, ethylacetate
Relative vapour density : N.D.
Viscosity : N.D. Pa.s
Partition co雈ficient n-octanol/water : N.D.
Evaporation rate
ratio to butyl acetate : N.D.
ratio to ether : N.D.
9.3 Other information:
Melting point/melting range : 128 癈
Auto-ignition point : N.D. 癈
g/m3
Saturation concentration : N.D.
10. Stability and reactivity
10.1 Conditions to avoid/reactivity:
- No data available
10.2 Materials to avoid:
- Keep away from: heat sources
10.3 Hazardous decomposition products:
- On burning: release of toxic and corrosive gases/vapours e.g.:
nitrous vapours, carbon monoxide - carbon dioxide
11. Toxicological information
11.1 Acute toxicity:
LD50 oral rat : N.D. mg/kg
LD50 dermal rat : N.D. mg/kg
LD50 dermal rabbit : N.D. mg/kg
LC50 inhalation rat : N.D. mg/l/4 h
LC50 inhalation rat : N.D. ppm/4 h
Printing date : 07-2002 4/8
ACETONE-2,4-DINITROPHENYLHYDRAZONE
11.2 Chronic toxicity:
EC carc. cat. : not listed
EC muta. cat. : not listed
EC repr. cat. : not listed
Carcinogenicity (TLV) : not listed
Carcinogenicity (MAC) : not listed
Carcinogenicity (VME) : not listed
Carcinogenicity (GWBB) : not listed
Carcinogenicity (MAK) : not listed
Mutagenicity (MAK) : not listed
Teratogenicity (MAK) : not listed
IARC classification : not listed
11.3 Routes of exposure: ingestion, inhalation, eyes and skin
11.4 Acute effects/symptoms:
AFTER INHALATION
- Irritation of the respiratory tract
- Irritation of the nasal mucous membranes
AFTER SKIN CONTACT
- Tingling/irritation of the skin
AFTER EYE CONTACT
- Irritation of the eye tissue
11.5 Chronic effects:
- Not listed in carcinogenicity class (IARC,EC,TLV,MAK)
- Not listed in mutagenicity class (EC,MAK)
- Not listed in teratogenicity class (EC,MAK)
12. Ecological information
12.1 Ecotoxicity:
- No data available
12.2 Mobility:
- Volatile organic compounds (VOC): N.D.%
- Insoluble in water
For other physicochemical properties see heading 9.
12.3 Persistence and degradability:
- biodegradation BOD5 : N.D. % ThOD
- water : - No data available
- soil : T ? N.D. days
12.4 Bioaccumulative potential:
- log Pow : N.D.
- BCF : N.D.
12.5 Other adverse effects:
- WGK : N.D.
- Effect on the ozone layer : Not dangerous for the ozone layer
(Council Regulation (EC) 3093/94)
- Greenhouse effect : no data available
- Effect on waste water purification : no data available
Printing date : 07-2002 5/8
ACETONE-2,4-DINITROPHENYLHYDRAZONE
13. Disposal considerations
13.1 Provisions relating to waste:
- Waste material code (91/689/EEC, Council Decision 2001/118/EC, O.J. L47 of
16/2/2001): 16 05 06 (laboratory chemicals, consisting of or containing
dangerous substances, including mixtures of laboratory chemicals)
- Waste material code (Flanders): 691
- Waste code (Germany): 59302
- Hazardous waste (91/689/EEC)
13.2 Disposal methods:
- Remove to an authorized incinerator equipped with an
afterburner and a flue gas scrubber
13.3 Packaging/Container:
- Waste material code packaging (91/689/EEC, Council Decision 2001/118/EC,
O.J. L47 of 16/2/2001): 15 01 10 (packaging containing residues of or
contaminated by dangerous substances)
Printing date : 07-2002 6/8
ACETONE-2,4-DINITROPHENYLHYDRAZONE
14. Transport information
14.1 Classification of the substance in compliance with UN Recommendations
UN number :
CLASS :
SUB RISKS :-
PACKING :-
PROPER SHIPPING NAME :
14.2 ADR (transport by road)
CLASS : no data available
PACKING :
DANGER LABEL TANKS :-
DANGER LABEL PACKAGES :-
14.3 RID (transport by rail)
CLASS : no data available
PACKING :
DANGER LABEL TANKS :-
DANGER LABEL PACKAGES :-
14.4 ADNR (transport by inland waterways)
CLASS : no data available
PACKING :
DANGER LABEL TANKS :-
DANGER LABEL PACKAGES :-
14.5 IMDG (maritime transport)
CLASS : no data available
SUB RISKS : -
PACKING : -
MFAG : -
EMS : -
MARINE POLLUTANT : -
14.6 ICAO (air transport)
CLASS : no data available
SUB RISKS :-
PACKING :-
PACKING INSTRUCTIONS PASSENGER AIRCRAFT :
PACKING INSTRUCTIONS CARGO AIRCRAFT :
14.7 Special precautions in connection with : none
transport
15. Regulatory information
Not listed in Annex I of directive 67/548/EEC et sequens. Labelling
established on the basis of the available data.
Irritant
R36/37/38 : Irritating to eyes, respiratory system and skin
S(02) : (Keep out of reach of children)
S26 : In case of contact with eyes, rinse immediately with plenty of
water and seek medical advice
S36 : Wear suitable protective clothing
S(46) : (If swallowed, seek medical advice immediately and show this
container or label)
Warning - substance not yet tested completely
Printing date : 07-2002 7/8
ACETONE-2,4-DINITROPHENYLHYDRAZONE
16. Other information
The information provided on this MSDS is correct to the best of our knowledge, information
and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release
and is not to be considered as a warranty or quality specification. The information relates
only to the specific material designated and may not be valid for such material used in
combination with any other material or in any process, unless specified in the text.
N.A. = NOT APPLICABLE
N.D. = NOT DETERMINED
* = INTERNAL CLASSIFICATION
Full text of any R-phrases referred to under heading 2:
R36/37/38 : Irritating to eyes, respiratory system and skin
Exposure limits:
TLV : Threshold Limit Value - ACGIH USA 2000
OES : Occupational Exposure Standards - United Kingdom 1999
MEL : Maximum Exposure Limits - United Kingdom 1999
MAK : Maximale Arbeitsplatzkonzentrationen - Germany 2001
TRK : Technische Richtkonzentrationen - Germany 2001
MAC : Maximale aanvaarde concentratie - The Netherlands 2002
VME : Valeurs limites de Moyenne d'Exposition - France 1999
VLE : Valeurs limites d'Exposition ?court terme - France 1999
GWBB : Grenswaarde beroepsmatige blootstelling - Belgium 1998
GWK : Grenswaarde kortstondige blootstelling - Belgium 1998
EC : Indicative occupational exposure limit values - directive 2000/39/EC
Chronic toxicity:
K : List of the carcinogenic substances and processes - The Netherlands 2002
Printing date : 07-2002 8/8
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