CHRISTRIO
Manufacturer of Beauty Products
1950 Compton Ave. Ste. 103
Corona, CA. 92881
Phone: (951) 808 ?4730 Fax: (951) 808 ?4734
MATERIAL SAFETY DATA SHEET
Section I: Product and Company Identification
Product name: Clean The Green
Chemical Name: N/A
CHRISTRIO CORP.
Manufacturer:
Family Name: N/A 1950 Compton Ave. #103
Corona, CA. 92881
Product Use: To prevent/treat fungal growth Emergency Phone #: 800 535- 5053
International Phone #: 1-352-323-3500
Information Contact: (951) 808 ?4730
Product #:
Section II: Product composition/Ingredients
Exposure Limits Carcinogen
Chemical Identity CAS# INCI Name %
OSHA ACGIH IARC/NTP/
OSHA
TWA/STEL TWA/STEL
Heptane 142-82-5 Heptane 400ppm 400ppm Not Listed 40
Ethyl Acetate 141-78-6 Ethyl Acetate 400ppm 400ppm Not Listed 40
Isopropyl Alcohol 67-63-0 Isopropyl Alcohol 150ppm 150ppm Not Listed 19
Tolnaftate 2398-96-1 Tolnaftate N/DA N/DA Not Listed 1
Hazard symbols: Xi, F Risk Phrases: R20, R36, R66, R67 Safety Phrases: S16, S26, S67
N/E ?None Established
N/R ?Not Reviewed
ND/A ?No Data Available
N/A ?Not Available
Section III: Hazard Identification
EMERGENCY OVERVIEW
May be slightly toxic.
May cause moderate skin injury (reddening & swelling).
May cause chemical burn in eye.
Suspect respiratory tract irritation hazard.
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Protential Health Effects, Sign and Symptoms of Exposure:
Primary Route of Entry Inhalation, skin contact, eye contact.
Eye Exposure causes eye irritation. Symptoms include stinging, tearing,
redness and swelling.
Skin Can cause skin irritation. Prolonged or repeated contact may dry skin.
Symptoms may include redness, burning, drying, cracking, and skin
burns.
Ingestion Swallowing small amounts during normal handling is not likely to
cause harmful effects; swallowing large amounts may be harmful. This
material can get into the lungs during swallowing or vomiting.
Inhalation Vapor and mist are irritating to mucous membranes. Breathing small
amount during normal handling is not likely to cause harmful effects.
Breathing large amounts may be harmful. Symptoms usually occur at
air concentrations higher than the recommended exposure limits
Sub-Chronic effects May cause headaches, nausea, vomiting and narcotic effect if over
exposed.
NOTE: Refer to Section 11, Toxicological Information for details.
Section IV: First Aid Measure
First Aid for Eye If symptoms develop, move individual away from exposure and into
fresh air. Flush eyes gently for 15 minutes with water while holding
eyelids apart. If symptoms persist or there is any visual difficulty, seek
medical attention.
First Aid for Skin Remove contaminated clothing and wash exposed area with soap and
water. If symptoms persist, seek medical attention.
First Aid for Inhalation Remove to fresh air. If breathing is difficult, administer oxygen. If
symptoms persist, seek medical attention.
First Aid for Ingestion If individual is drowsy or unconscious, do not give any thing by
mouth: place individual on the left side with head down. Seek medical
attention for advice about whether to induce vomiting. If possible, do
not leave individual unattended.
Section V: Fire fighting Measures
Flash Point Flammable Limit Auto-ignition Temperature
(篎/篊) (Vol %) (Vol %)
TAG CLOSED 40癋 ND/A
Method:
Extinguishing Media: Foam, dry chemical, cold water spray
Fire Fighting Instructions: Cool fire exposed containers with water, remove away from building.
Use self-contained breathing apparatus to fight fire.
Unusual Hazards: When exposed to heat and flame, material is a fire explosion hazard.
It may produce toxic products CO, Carbon Dioxide and oxides of
nitrogen.
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Section VI: Accident Release Measures
Spill or Release Procedure: Eliminate all sources of heat and ignition. Use absorbent material for
spills and dike it, wash spilled material into retaining containers.
Place containers in well ventilated area.
Section VII: Handling and Storage
Handling: Keep containers in cool and dry. Keep away from heat, light and
ignition sources.
Storage: Store in well ventilated area. Store @ 70 + 15癋, allow some air space
above liquid level. Keep containers closed while not in use.
Explosion Hazard: Vapors are heavier than air and may travel along the ground or may be
moved by ventilation and ignited by pilot lights, other flames, sparks,
heaters, smoking or other ignition sources at locations distant from
material handling point. Never use welding or cutting torch on or neat
drum (even empty) because product (even just residue) can ignite
explosively.
Section VIII: Exposure Controls/Personal Protective Equipment
Engineering Control Use process enclosures, local exhaust ventilation or other engineering
controls to control airborne levels below recommended exposure
limits. Use explosion-proof ventilation equipment.
Personal Protective Equipment
Eye/Face Protection Chemical splash goggles in compliance with OSHA regulations are
advised; however, OSHA regulations also permit other types of safety
glasses.
Skin Protection Wear resistant gloves. To prevent repeated or prolonged skin contact,
wear impervious clothing and boots.
Respirator Protection Use organic vapor mask and local exhaust vents.
Section XI: Physical and Chemical Properties
Odor & Odor Special %
Appearance pH Viscosity
Threshold Gravity Volatile
Clear liquid N/A (H2O=1):0.98 W/W 99+
Hydrocarbon Odor
Decomposition Octanol/Water Vapor Vapor Evaporation Ignition Solubility
Boiling
Point/ Temperature Partitioning Pressure Density Rate in Water
Freezing (20C)
Coefficient
Point Log Po/w
N/A N/A N/A (Air=1):1 N/A N/A Insoluble
170?br>
Flash Point Flammable Limit Auto-ignition Temperature
(篎/篊) (vol%) (vol%)
ND/A ND/A ND/A
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Section X: Stability and Reactivity
Stability: Stable Incompatibility (Materials to Avoid):
Avoid oxidizing agents, acids & bases (heat).
Hazardous Decomposition Products: Heated Hazardous Polymerization: Will not occur.
material produce NO2, CO2, CO.
Condition to Avoid: Heat, flame, ignition sources.
Section XI: Toxicological Information
Acute Oral Acute Dermal Acute Inhalation Irritation-Skin Irritation-Eye
Toxicity Toxicity Toxicity
Mouse:LD50=4100mg N/A Mouse:LC50=45gm Rabbit LD50=>20 ND/A
/m3/2H gm/kg
Sensitization Mutagenicity Sub-chronic Toxicity
Hamster fibroblast 9g/L sex N/DA
ND/A ND/A
Chromosome loss/Non-disjunction: S.
Cerevisiae 24400ppm
Section XII: Ecological Information
Acute Toxicity Acute Toxicity to Acute Toxicity Toxicity to
Bioconcentration
Fish Invertebrate to Algae Sewage Bacteria
Fathead Minnow:
ND/A ND/A ND/A ND/A
230mg/L 96Hdaphid
LC50=2500 mg/L/96H
Chemical Fate Information
Biodegradability May evaporate at a moderate extent in both soil and water. Half
life of 1 day in water.
Chemical Oxygen Demand ND/A
Section XIII: Disposable Concentrations
Dispose of diking materials and absorbent in compliance with State, Local, and Federal regulations.
Section XIV: Transport Information
DOT/UN
Shipping Name: UN1993
Identification Number: N/A
Marine Pollutant: No
Special Provisions: None
Emergency Response Guidebook (ERG) #: N/A
IATA (DGR)
Proper Shipping Name: Non-regulated Material
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Class or Division: N/A
UN or ID Number: N/A
Packaging Instructions: None
Emergency Response Guidance (ICAO) #:
IMO (IMDG):
Proper Shipping Name: Non-Regulated Material
Class of Division: N/A
UN or ID Number: N/A
Special Provision & Storage/Segregation: None
Emergency Schedule (EmS)#: N/A
Other Information: Flash point > 100篊
Section XV: Regulatory Informatio
US Federal Regulations:
US Federal Regulations:
Clean Air act: This product contains the following Hazardous Air Pollutant ( HAP's):
HAP/ODS ?None
Clean Water Act: The following ingredients are listed as hazardous pollutants under the
Priority Pollutant List CWA: None
FDA: Food Packaging This product has not been clear by the FDA for use in food packaging
Status and/or other applications and indirect food packaging additive.
Occupational Safety and This product is considered to be hazardous under the OSHA Hazard
Health Act Communication Standard. It's hazards are:
?Immediate (acute) health hazard
?Fire hazard
RCRA This product contains the following chemicals considered to be
hazardous waste under RCRA (40 CFR 261).Ethyl Acetate CAS # 141-
78-6 RCRA Code: U112
This product contains the following chemicals regulated under SARA
SARA Title III: Section
302 (TPQ) 302: None
SARA Title III: Section
302(RQ)
SARA Title III: This product is considered to be hazardous under OSHA Hazard
Section 311-312 Communication Standard and is regulated under Section 311-312 (40 CFR
370). Is hazard are:
?Immediate (acute) health hazard
?Fire hazard
SARA Title III: Section This product contains the following chemicals which are subject to the
313 reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act of 1986 and 40 CFR part 372:
Isopropyl Alcohol CAS #67-63-0.
TSCA Section 8 (b): This product contains chemical listed on the TSCA inventory or otherwise
Inventory complies with TSCA pre-manufacture notification requirements.
State Regulations:
CA Right-to-Know law: Ethyl Acetate CAS # 141-78-6; Heptane CAS #142-82-5: Isopropyl
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Alcohol CAS # 67-63-0.
CA No Significant Risk Rule:
MA Right-to-Know Law: Ethyl Acetate CAS # 141-78-6; Heptane CAS # 142-82-5; Isopropyl
Alcohol CAS # 67-63-0.
NJ Right-to-Know Law: Ethyl Acetate CAS # 141-78-6; Heptane CAS # 142-82-5; Isopropyl
Alcohol CAS # 67-63-0.
PA Right-to-Know Law: Ethyl Acetate CAS # 141-78-6; Heptane CAS # 142-82-5; Isopropyl
Alcohol CAS # 67-63-0.
FL Right-to-Know Law: Ethyl Acetate CAS # 141-78-6; Heptane CAS # 142-82-5; Isopropyl
Alcohol CAS # 67-63-0.
MN Right-to-Know Law: Ethyl Acetate CAS # 141-78-6; Heptane CAS # 142-82-5; Isopropyl
Alcohol CAS # 67-63-0.
International Regulations:
CDSL: Canadian Inventory Ethyl Acetate CAS # 141-78-6; Heptane CAS # 142-82-5;
(on Canadian Transitional List) Isopropyl Alcohol CAS # 67-63-0.
Isopropyl Alcohol CAS # 67-63-0.
EINECS: European Inventory:
?Hazard Symbol: F: Flammable
?Risk Phrases: R11:
?Safety Phrases: S7, S16:
Ethyl Acetate (205-500-4)
?Hazard Symbol: Xi: Irritant; F: Flammable
?Risk Phrases: R11, R36, R66, R67:
?Safety Phrases: S16, S26, S33:
Tolnaflate (N/A)
?Hazard symbol (N/A), R values (N/A), S Values (N/A)
Section XVI: Other Information
Hazard Rating System
NFPA: Health 2/ Flammability 3/ Reactivity 0
HMIS: Health 2/ Flammability 3/ Reactivity 0
Revised: July 3rd, 2009
Revised Sections since Last Version Section 2 contents and format update throughout.
The information presented herein was obtained from sources considered to be liable. However, this
information is provided without any warranty, expressed or implied, regarding its correctness or
suitability for consumers intended to use and/or application. For this and other reasons, we assume
no responsibility and expressly disclaim liability for loss, damage or expense arising out of any way
connected with handling, storage, use or disposal of the product. This MSDS was prepared
expressly for this product. Use the materials only directed. If the product is used as a component of
other product, the information contained within the MSDS may not be applicable. If one could
have any concerns with or problems understanding this MSDS form, please direct all questions to
INFOTRAC, Chemical Emergency Resources System at (800) 535-5053.
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