Material Safety Data Sheet
Product Name: Sure-Seal HP 250 Primer MSDS No. 302070
Date of Preparation: 09/15/2008 Revision: 011
Section 1 - Chemical Product and Company Identification
Product/Chemical Name: Sure-Seal HP-250 Primer
Chemical Formula: Mixture
General Use: Primer for EPDM Membrane
Manufacturer: Carlisle SynTec Incorporated, 1285 Ritner Highway, Carlisle, PA 17013, Phone ?800-479-6832,
24-Hour Emergency Phone Number: CHEMTREC (USA): 800-424-9300
Section 2 - Hazards Identification
Emergency Overview
Danger ?Highly flammable liquid and vapor
Warning ?Causes skin irritation
Warning ?Causes eye irritation
Warning ?May be harmful if swallowed and enters airways
Danger ?May damage fertility or the unborn child
Warning ?May cause an allergic skin reaction
Warning ?Suspected of causing genetic defects (skin)
Warning ?May cause drowsiness and dizziness
Warning ?May cause damage to organs (liver, kidney, ear) through prolonged or repeated exposure
HMIS
Potential Health Effects 1
H
Primary Entry Routes: Eye contact, ingestion, inhalation, skin absorption, skin contact.
4
F
Target Organs: Kidney and liver.
0
R
Acute Effects
PPE
Inhalation: May cause nose and/or throat irritation on short-term exposure to vapor. Aspiration into lungs can Sec. 8
cause chemical pneumonitis, which can be fatal. Overexposure may result in headache, dizziness, fatigue,
nausea and loss of consciousness.
Eye: May cause eye irritation on short-term exposure to liquid or vapor.
Skin: May cause skin irritation on short-term exposure to liquid or vapor. Solvents may be absorbed through the skin in toxic
amounts.
Ingestion: May cause irritation of gastrointestinal tract.
Carcinogenicity: IARC, NTP, and OSHA do not list this product as a carcinogen.
Medical Conditions Aggravated by Long-Term Exposure: May cause more significant skin irritation in people with pre-
existing skin conditions. Respiratory symptoms associated with pre-existing lung disorders and pre-existing heart disorders
may be aggravated by exposure to this material.
Chronic Effects: Chronic exposure may cause reversible kidney and liver injury. Reports have associated repeated and
prolonged occupational overexposure to solvents with permanent brain and nervous system damage. Repeated exposure to
Toluene has been associated with high frequency hearing loss based on animal tests.
Section 3 ?Ingredient Information
Hazardous Ingredients CAS Number % wt
Toluene 108-88-3 60-100
Heptane 142-82-5 3-7
Hydrocarbon Tackifying Resin 68478-07-9 1-5
Additional Ingredients CAS Number % wt
Section 4 - First Aid Measures
Inhalation: Remove victim to fresh air and provide oxygen if breathing is difficult. Give artificial respiration if not breathing.
Get medical attention immediately.
MSDS No. 302070 Sure-Seal HP-250 Primer 9/15/2008
Eye Contact: Immediately flush eyes with running water for at least 15 minutes. Get medical attention.
Skin Contact: Immediately flush skin with running water and remove contaminated clothing. Wash exposed area with soap and
water. Get medical attention.
Ingestion: DO NOT induce vomiting. Get medical attention immediately.
Note to Physicians: This material contains Toluene and Heptane.
Special Precautions/Procedures: Whenever possible, remove the worker from the source of contamination.
Section 5 - Fire-Fighting Measures
NFPA
Flash Point: 4.40癈 (40癋)
Flash Point Method: C.C
4
Autoignition Temperature: 536癈 (997癋)
0
1
LEL: 1.3% v/v
--
UEL: 7.0% v/v
Flammability Classification: Ignition can occur when this product is exposed to heat, Division 2 sparks, or
flame.
Extinguishing Media: In case of fire, use dry chemical, carbon dioxide, or foam. Water may not be effective as an
extinguishing agent. Water fog or spray may be used to provide a smothering effect on fire and to cool fire-exposed containers
and surrounding combustibles. Do not use a solid stream of water because it can scatter and spread the fire.
Unusual Fire or Explosion Hazards: Extremely flammable. Store and use away from all sources of heat, flame, or sparks. Do
not smoke while applying. Vapors are heavier than air and may travel along ground or may be moved by ventilation and
ignited by pilot lights, other flames, sparks, heaters, smoking, electrical motors, static discharge, or other ignition sources at
locations distant from material handling point and flash back. All containers should be grounded when material is transferred.
Hazardous Combustion Products: Toxic gases or vapors, such as carbon monoxide or carbon dioxide, may be released in a
fire.
Fire-Fighting Instructions: This product contains solvents that are dangerous fire and explosion hazards when exposed to heat
or flame.
Fire-Fighting Equipment: Because fire may produce toxic thermal decomposition products, wear a self-contained breathing
apparatus (SCBA) and full protective clothing along with a full face piece operated in pressure-demand or positive-pressure
mode.
Section 6 - Accidental Release Measures
Personal Precautions: Use personal protection recommended in Section 8.
Spill /Leak Procedures: Remove all sources of ignition. Avoid breathing vapors. Use self-contained breathing apparatus in
enclosed area. Ventilate area. Contain and remove with inert absorbent materials and non-sparking tools. For large spills, dike
far ahead of liquid spill for later disposal. Do not release into sewers or waterways.
Regulatory Requirements: Follow applicable OSHA regulations (29 CFR 1910.120).
Section 7 - Handling and Storage
Handling Precautions: Use away from all sources of heat, flame, or sparks. Do not smoke while using. Handling equipment
must be grounded to prevent sparking. Handle with non-sparking tools. Wash with soap and water before eating or drinking.
Launder contaminated clothing. KEEP OUT OF REACH OF CHILDREN.
Storage Requirements: Keep containers cool, dry, and store away from all sources of heat, flame, and sparks. Keep containers
tightly closed and store with adequate ventilation. Do not pressurize, cut, weld, or grind the containers or empty containers,
which may contain residual product and solvent vapors that may ignite explosively.
Section 8 - Exposure Controls / Personal Protection
Hazardous Ingredients:
OSHA PEL ACGIH TLV NIOSH REL NIOSH
Ingredient TWA STEL TWA STEL TWA STEL IDLH
Toluene 200 ppm 150 ppm 20 ppm None estab. 100 ppm 150 ppm 500 ppm
Heptane 500 ppm 500 ppm 400 ppm 500 ppm 85 ppm 440 ppm 750 ppm
Engineering Controls: Do not use in enclosed areas without proper explosion-proof ventilation. General and local exhaust
ventilation must be sufficient to control vapor concentrations and keep the vapor concentration below 100 ppm.
Ventilation: Provide general or local exhaust ventilation systems to maintain airborne concentrations below OSHA PELs. Local
exhaust ventilation is preferred because it prevents contaminant dispersion into the work area by controlling it at its source.
Respiratory Protection: A NIOSH approved respirator must be used if vapor concentration is 100 ppm or above.
Page 2 of 5
9/15/2008 Sure-Seal HP-250 Primer MSDS No. 302070
Protective Clothing/Equipment: Permeation resistant gloves (that meet ANSI/ISEA 105-2005) required. Protective glasses or
goggles recommended. Industrial boots to protect feet from cleaner contact. Impervious clothing is recommended to protect
skin from cleaner contact. Protective skin creams or emollients useful.
Safety Stations: Make emergency eyewash stations, safety/quick-drench showers, and washing facilities available in work area.
Contaminated Equipment: Separate contaminated work clothes from street clothes. Launder before reuse. Remove this
material from your shoes and clean personal protective equipment.
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after using this material, especially before
eating, drinking, smoking, using the toilet, or applying cosmetics.
Section 9 - Physical and Chemical Properties
Physical State: Liquid Water Solubility: Negligible
Appearance and Odor: Thin olive green to dark grey Boiling Point(癈): 110.4癈 (230.7癋)
liquid with hydrocarbon odor Freezing/Melting Point -95.0癈 (-139癋)
Odor Threshold(ppm): Not available % Volatile by Weight: 80-90
Vapor Pressure: 36.7 mm Hg at 30癈 (86癋) Evaporation Rate: (nBuAc=1): 2.1
Vapor Density (Air=1): 3.14 Voc: 727 g/l
Specific Gravity (H2O=1, at 4癈): 0.88 Flash Point: 4.40癈 (40癋)
Flash Point Method: C.C
pH: Not available
Autoignition Temperature: 536癈 (997癋)
LEL: 1.3% v/v
UEL: 7.0% v/v
Section 10 - Stability and Reactivity
Stability: Stable under normal conditions.
Possibility of Hazardous Reactions: Will not occur.
Chemical Incompatibilities: Strong oxidizing agents, acids, bases, amines.
Conditions to Avoid: Heat, sparks, and flames; ignition sources.
Hazardous Decomposition Products: Toxic gases or vapors such as carbon monoxide or carbon dioxide, may be released in a
fire.
Section 11- Toxicological Information
Toxicity Data:
This product has not been tested. No data available.
Section 12 - Ecological Information
Ecotoxicity: No data available.
Environmental Fate: No data available.
Environmental Degradation: No data available.
Soil Absorption/Mobility: No data available.
Section 13 - Disposal Considerations
Waste Disposal: Dispose of in accordance with all local, state, and federal regulations.
Section 14 - Transport Information
DOT Transportation Data (49 CFR 172.101):
Shipping Name: Adhesives, 3 Packaging Authorizations Quantity Limitations
Shipping Symbols: Flammable a) Exceptions: 173.150 a) Passenger, Aircraft, or Railcar: 5 L
Hazard Class: 3 b) Non-bulk Packaging: 173.173 b) Cargo Aircraft Only: 60 L
ID No.: UN 1133 c) Bulk Packaging: 173.242
Packing Group: II Vessel Stowage Requirements
Label: Red caution label a) Vessel Stowage: B
required. b) Other: --
Special Provisions (172.102):
149, B52, IB2, T4, TP1, TP8
Page 3 of 5
MSDS No. 302070 Sure-Seal HP-250 Primer 9/15/2008
Section 15 - Regulatory Information
EPA Regulations:
RCRA Hazardous Waste Number (40 CFR 261.33): Toluene, CAS #108-88-3, RCRA Code U220
RCRA Hazardous Waste Classification (40 CFR 261.31): Not classified
CERCLA Hazardous Substance (40 CFR 302.4): Toluene, CAS #108-88-3, RQ 1000 lb
CERCLA Reportable Quantity (RQ): Materials with a "listed" RQ may be reportable as an "unlisted hazardous substance".
See 40 CFR 302.5 (b).
SARA 313 Components (40 CFR 372.65): Toluene, CAS #108-88-3, 60-100%
SARA Toxic Release Chemicals: Toluene, CAS #108-88-3, Concentration: 1.0%, Reporting Threshold: Standard
OSHA Regulations:
Clean Water Act Hazardous Substances: Toluene, CAS #108-88-3, RQ 1000 lb
Clean Air Act SOCMI Chemicals: Toluene, CAS #108-88-3
Clean Air Act Hazardous Air Pollutants: Toluene, CAS #108-88-3, HAP Code XOV
OSHA, IARC, NTP Carcinogens: None listed.
State Regulations:
California Proposition 65 Chemicals: Toluene, CAS #108-88-3, Code D
Delaware Air Quality Management List: Toluene, CAS #108-88-3, DRQ: 1000, State: Y
Massachusetts Hazardous Substances List:
Heptane, CAS# 142-82-5, Codes: 2, 4, 5, 6
Toluene, CAS #108-88-3, Codes: 2, 4, 5, 6, F7, F8, F9
Michigan Critical Materials Register:
Toluene, CAS #108-88-3, Report Code: --, Class: --
Minnesota Hazardous Substances List:
Heptane, CAS# 142-82-5, Codes: ANO, Hazards: -, Carcinogen: No
Toluene, CAS #108-88-3, Codes: ANO, Hazards: Skin, Carcinogen: No
New Jersey RTK Hazardous Substance List:
Toluene, CAS #108-88-3, Substance #: 1866, DOT #: 1294
New York List of Hazardous Substances:
Toluene, CAS #108-88-3, RQ-Air: 1000, RQ-Land: 1, Notes: None
Pennsylvania Hazardous Substances List:
Heptane, CAS# 142-82-5, Code: - (Basic Hazard)
Toluene, CAS #108-88-3, Code: E (Environmental Hazard)
Washington Permissible Exposure Limits for Air Contaminants:
Chemical Name CAS # TWA TWA STEL STEL Ceiling Ceiling Skin
(ppm) (mg) (ppm) (mg) (ppm) (mg)
Heptane 142-82-5 400 1600 500 2000 -- -- --
Toluene 108-88-3 100 375 150 560 -- -- --
Page 4 of 5
9/15/2008 Sure-Seal HP-250 Primer MSDS No. 302070
Section 16 - Other Information
Prepared By: Research & Development
Revision Notes: Section 8 ?Revised limits for Heptane and Toluene.
Additional Hazard Rating Systems:
Disclaimer: The information contained in this document is based upon data that was supplied to Carlisle by other companies and
organizations. No warranty of merchantability or fitness for a particular purpose is expressed or implied regarding the accuracy
or completeness of the data and/or information in this material safety data sheet.
Page 5 of 5
|