MATERIAL SAFETY DATA SHEET
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1. Product and Company Identification
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836-001
Product number
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Saw Blade Cleaner and Gum Remover
Cleaner - Pitch
Product name
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25-Jan-2010
Effective date
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Sprayway, Inc.
Company information
484 Vista Ave.
Addison, IL 60101 United States
United States
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General Assistance 1-630-628-3000
Company phone
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800-424-9300
Emergency telephone US
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703-527-3887
Emergency telephone outside US
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06
Version #
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10-Aug-2009
Supersedes date
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2. Hazards Identification
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CONTENTS UNDER PRESSURE. Aerosol. Corrosive. Causes skin and eye burns.
Emergency overview
Cancer hazard. Irritating to respiratory system. Prolonged exposure may cause chronic
effects.
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Potential health effects
Skin contact. Eye contact. Inhalation. Ingestion.
Routes of exposure
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This product causes eye burns. Risk of serious damage to eyes.
Eyes
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Causes skin burns. This product may be harmful if it is absorbed through the skin.
Skin
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Intentional misuse by concentrating and inhaling the product can be harmful or fatal.
Inhalation
Causes burns. Irritating to respiratory system. Prolonged inhalation may be harmful.
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Exposure by ingestion of an aerosol is unlikely. Ingestion may produce burns to the lips,
Ingestion
oral cavity, upper airway, esophagus and possibly the digestive tract. May cause delayed
lung damage. Components of the product may be absorbed into the body by ingestion.
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Prolonged or repeated exposure may cause liver and kidney damage. These effects
Target organs
have not been observed in humans.
Central nervous system. Lungs.
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May cause central nervous system disorder (e.g., narcosis involving a loss of
Chronic effects
coordination, weakness, fatigue, mental confusion, and blurred vision) and/or damage.
May cause delayed lung damage.
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Discomfort in the chest. Narcosis.
Signs and symptoms
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3. Composition / Information on Ingredients
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Components CAS # Percent
Diethylene Glycol Monobutyl Ether 112-34-5 8 - 10
Sodium Hydroxide 1310-73-2 5-8
Propane 74-98-6 1-3
n-Butane 106-97-8 1-3
Monoethanolamine 141-43-5 1-3
Crystalline Silica 14808-60-7 0.5 - 1
Non-hazardous and other components below reportable levels 60 - 80
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4. First Aid Measures
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First aid procedures
Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact
Eye contact
lenses, if present and easy to do. Continue rinsing. Get medical attention immediately.
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Product #: 836-001 Cleaner - Pitch and Gum RemoverPrint date: 25-JAN-2010
Revision date: 25-JAN-2010
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Immediately flush skin with plenty of water. Remove and isolate contaminated clothing
Skin contact
and shoes. Get medical attention immediately. For minor skin contact, avoid spreading
material on unaffected skin. Wash clothing separately before reuse.
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Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to-mouth
Inhalation
method if victim inhaled the substance. Induce artificial respiration with the aid of a
pocket mask equipped with a one-way valve or other proper respiratory medical device.
Get medical attention immediately.
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If material is ingested, immediately contact a poison control center. Have victim rinse
Ingestion
mouth thoroughly with water. Do not induce vomiting without advice from poison control
center. If vomiting occurs naturally, have victim lean forward to reduce risk of aspiration.
Do not use mouth-to-mouth method if victim ingested the substance. Induce artificial
respiration with the aid of a pocket mask equipped with a one-way valve or other proper
respiratory medical device.
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5. Fire Fighting Measures
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Runoff to sewer may cause fire or explosion hazard.
Flammable properties
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Extinguishing media
Water fog. Foam. Dry chemical powder. Carbon dioxide (CO2).
Suitable extinguishing media
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Protection of firefighters
Fire may produce irritating, corrosive and/or toxic gases.
Specific hazards arising from
the chemical
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In the event of fire and/or explosion do not breathe fumes. Wear full protective clothing,
Protective equipment and
including helmet, self-contained positive pressure or pressure demand breathing
precautions for firefighters
apparatus, protective clothing and face mask. Containers should be cooled with water to
prevent vapor pressure build up. For massive fire, use unmanned hose holders or
monitor nozzles; if this is impossible, withdraw from area and let fire burn.
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6. Accidental Release Measures
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Eliminate all ignition sources (no smoking, flares, sparks, or flames in immediate area).
Methods for containment
Stop leak if you can do so without risk. Move the cylinder to a safe and open area if the
leak is irreparable. Stop the flow of material, if this is without risk. Prevent entry into
waterways, sewers, basements or confined areas.
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Should not be released into the environment. Use a non-combustible material like
Methods for cleaning up
vermiculite, sand or earth to soak up the product and place into a container for later
disposal.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean contaminated
surface thoroughly.
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7. Handling and Storage
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Pressurized container: Do not pierce or burn, even after use. Do not handle or store near
Handling
an open flame, heat or other sources of ignition. Use only in area provided with
appropriate exhaust ventilation. Do not use if spray button is missing or defective. Do not
get this material in contact with eyes. Do not get this material in contact with skin. Do not
get this material on clothing. Wear personal protective equipment. Avoid prolonged
exposure.
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Level 1 Aerosol.
Storage
Contents under pressure. Do not puncture, incinerate or crush. The pressure in sealed
containers can increase under the influence of heat. Do not handle or store near an open
flame, heat or other sources of ignition. Avoid exposure to long periods of sunlight. Store
in cool place. Keep the container dry. Keep out of the reach of children. Store at ambient
temperature and atmospheric pressure. Do not store, incinerate, or heat this material
above 120 degrees Fahrenheit.
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Product #: 836-001 Cleaner - Pitch and Gum RemoverPrint date: 25-JAN-2010
Revision date: 25-JAN-2010
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8. Exposure Controls / Personal Protection
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Exposure limits
ACGIH
Components CAS # TWA STEL Ceiling
Diethylene Glycol Monobutyl 112-34-5 20 ppm Not established Not established
Ether
Sodium Hydroxide 1310-73-2 Not established Not established 2 mg/m3
Propane 74-98-6 1000 ppm Not established Not established
n-Butane 106-97-8 1000 ppm Not established Not established
Monoethanolamine 141-43-5 3 ppm 6 ppm Not established
Crystalline Silica 14808-60-7 0.025 mg/m3 Not established Not established
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OSHA
Components CAS # TWA STEL Ceiling
Diethylene Glycol Monobutyl 112-34-5 100 ppm Not established Not established
Ether
Sodium Hydroxide 1310-73-2 2 mg/m3 Not established Not established
Propane 74-98-6 1000 ppm Not established Not established
Monoethanolamine 141-43-5 3 ppm Not established Not established
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Personal protective equipment
Wear chemical goggles.
Eye / face protection
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Do not get this material on clothing. Wear appropriate chemical resistant gloves. Wear
Skin protection
appropriate chemical resistant clothing. Structural firefighters protective clothing provides
limited protection in fire situations ONLY; it is not effective in spill situations. Use
chemical splash goggles and face shield (ANSI Z87.1 or approved equivalent). Wear
chemical protective equipment that is specifically recommended by the manufacturer.
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When workers are facing concentrations above the exposure limit they must use
Respiratory protection
appropriate certified respirators. If permissible levels are exceeded use NIOSH
mechanical filter / organic vapor cartridge or an air-supplied respirator.
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9. Physical & Chemical Properties
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Compressed liquefied gas.
Appearance
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384.8 癋 (196.1 癈) estimated
Boiling point
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Colorless.
Color
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5.7 kJ/g estimated
Flammability (HOC)
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No
Flash back
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-156 癋 (-104.4 癈) Propellant
Flash point
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Aerosol.
Form
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Ammoniacal.
Odor
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13 - 14
pH
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Liquid.
Physical state
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85 - 105 psig @ 70F
Pressure
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Completely
Solubility
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1.0091 estimated
Specific gravity
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10. Chemical Stability & Reactivity Information
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Risk of ignition. Instability caused by elevated temperatures. May form explosive
Chemical stability
peroxides.
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Heat, flames and sparks.
Conditions to avoid
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Hazardous decomposition products Irritants. Toxic gas. May include oxides of nitrogen.
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11. Toxicological Information
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Acute LD50: 12919 mg/kg estimated, Rat, Dermal
Acute effects
Causes burns.
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Product #: 836-001 Cleaner - Pitch and Gum RemoverPrint date: 25-JAN-2010
Revision date: 25-JAN-2010
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Component analysis - LD50
Toxicology Data - Selected LD50s and LC50s
Crystalline Silica 14808-60-7 Oral LD50 Rat 500 mg/kg
Diethylene Glycol Monobutyl Ether 112-34-5 Oral LD50 Rat 3384 mg/kg; Dermal LD50 Rabbit 2700 mg/kg
Monoethanolamine 141-43-5 Oral LD50 Rat 1720 mg/kg; Dermal LD50 Rabbit 1 mL/kg; Dermal LD50 Rabbit 1025
mg/kg
n-Butane 106-97-8 Inhalation LC50 Rat 658 mg/L 4 h
Propane 74-98-6 Inhalation LC50 Rat 658 mg/L 4 h
Sodium Hydroxide 1310-73-2 Dermal LD50 Rabbit 1350 mg/kg
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Cancer hazard. Hazardous by OSHA criteria.
Carcinogenicity
IARC - Group 1 (Carcinogenic to Humans)
Crystalline Silica 14808-60-7 Monograph 68 [1997] (listed under Crystalline silica inhaled in the form of quartz or
cristobalite from occupational sources)
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Not expected to be hazardous by OSHA criteria.
Teratogenicity
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12. Ecological Information
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Components of this product are hazardous to aquatic life.
Ecotoxicity
LC50 703 mg/L estimated, Fish, 96.00 Hours,
EC50 3071 mg/L estimated, Daphnia, 48.00 Hours,
IC50 687 mg/L estimated, Algae, 72.00 Hours,
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13. Disposal Considerations
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D001: Waste Flammable material with a flash point <140 F
Waste codes
D002: Waste Corrosive material [pH <=2 or =>12.5, or corrosive to steel]
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Contents under pressure. Dispose of this material and its container at hazardous or
Disposal instructions
special waste collection point. Do not incinerate sealed containers. Do not allow this
material to drain into sewers/water supplies. If discarded, this product is considered a
RCRA ignitable waste, D001. Dispose in accordance with all applicable regulations.
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14. Transport Information
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Department of Transportation (DOT) Requirements
Basic shipping requirements:
Consumer commodity
Proper shipping name
ORM-D
Hazard class
None
Subsidiary hazard class
Additional information:
156, 306
Packaging exceptions
156, 306
Packaging non bulk
None
Packaging bulk
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IMDG
Basic shipping requirements:
AEROSOLS
Proper shipping name
2.1
Hazard class
8
Subsidiary hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
5FC
Item
None
Labels required
If <1L: Consumer Commodity
Transport Category
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Product #: 836-001 Cleaner - Pitch and Gum RemoverPrint date: 25-JAN-2010
Revision date: 25-JAN-2010
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IATA
Basic shipping requirements:
Aerosols, flammable, containing substances in Class 8,
Proper shipping name
Packing Group II
2.1
Hazard class
8
Subsidiary hazard class
1950
UN number
Additional information:
LTD QTY
Packaging exceptions
2.1, 8
Labels required
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15. Regulatory Information
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This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
US federal regulations
Standard, 29 CFR 1910.1200.
U.S. - CERCLA/SARA - Section 313 - Emission Reporting
Diethylene Glycol Monobutyl Ether 112-34-5 1.0 % de minimis concentration (applies to R-(OCH2CH2)n-OR', where n = 1,2, or 3,
R=alkyl C7 or less, or R = phenyl or alkyl substituted phenyl, R' = H or alkyl C7 or
less, or OR' consisting of carboxylic acid ester, sulfate, phosphate, nitrate, or
sulfonate, Chemical Category N230)
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Occupational Safety and Health Administration (OSHA)
Yes
29 CFR 1910.1200 hazardous
chemical
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CERCLA (Superfund) reportable quantity
Sodium Hydroxide: 1000.0000
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - Yes
Reactivity Hazard - No
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No
Section 302 extremely
hazardous substance
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Section 311 hazardous chemical Yes
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Inventory status
Country(s) or region Inventory name On inventory (yes/no)*
China Inventory of Existing Chemical Substances in China (IECSC) Yes
Europe European Inventory of New and Existing Chemicals (EINECS) No
Europe European List of Notified Chemical Substances (ELINCS) No
Japan Inventory of Existing and New Chemical Substances (ENCS) Yes
Korea Existing Chemicals List (ECL) Yes
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
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WARNING: This product contains a chemical known to the State of California to cause
State regulations
cancer.
U.S. - Pennsylvania - RTK (Right to Know) List
Crystalline Silica 14808-60-7 Present (dust)
Diethylene Glycol Monobutyl Ether 112-34-5 Environmental hazard
Monoethanolamine 141-43-5 Present
n-Butane 106-97-8 Present
Propane 74-98-6 Present
Sodium Hydroxide 1310-73-2 Environmental hazard
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16. Other Information
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HMIS?is a registered trade and service mark of the NPCA.
Further information
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Health: 3*
HMIS?ratings
Flammability: 2
Physical hazard: 0
Personal protection:
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Product #: 836-001 Cleaner - Pitch and Gum RemoverPrint date: 25-JAN-2010
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The information provided in this Safety Data Sheet is correct to the best of our
Disclaimer
knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified
in the text.
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Regulatory Compliance
Prepared by
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Product #: 836-001 Cleaner - Pitch and Gum RemoverPrint date: 25-JAN-2010
Revision date: 25-JAN-2010
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