PRODUCT NAME: Wolman?E CA-C Treated Wood
1. PRODUCT AND COMPANY IDENTIFICATION
REVISION DATE: 08/20/2007
Manufactured By: SUPERCEDES:
EXTERIOR WOOD, INC.
2685 Index St./PO Box 206
MSDS Number: 000000004504
Washougal, WA 98671
SYNONYMS: None
360-835-8561 Manufacturing
CHEMICAL FAMILY:
404-362-3970 Technical
DESCRIPTION / Treated Wood Products
Assistance
USE:
FORMULA: None established
2. HAZARDS IDENTIFICATION
OSHA Hazard Wood dust is classified as: carcinogenic, possible sensitizer, mild
Classification: skin irritant, possible respiratory irritant.
Routes of Entry: Inhalation, skin, eyes, ingestion
Chemical Interactions: No known or reported interactions.
Medical Conditions Aggravated: Inhalation of the dust from this material at concentrations above
the TLV can aggravate pre-existing upper respiratory and lung
diseases such as bronchitis, emphysema and asthma., Skin
diseases including eczema and sensitization
Human Threshold Response Data
Not established for product.
Odor Threshold
Ethanolamine 2.6 ppm
Not established for product.
Irritation Threshold
Ethanolamine > 5.0 ppm
Hazardous Materials Identification System / National Fire Protection Association
Classifications
Hazard Ratings : Health Flammability Physical / PPI / Special
Instability hazard.
HMIS 2* 1 0
NFPA 2 1 0
Immediate (Acute) Health Effects
Inhalation Toxicity: Airborne treated or untreated wood dust may cause nose, throat
or lung irritation.
Skin Toxicity: Handling of wood may result in skin exposure to splinters.
Prolonged and/or repeated contact with treated or untreated wood
dust may result in mild irritation.
Eye Toxicity: Treated or untreated wood dust may cause mechanical irritation.
Ingestion Toxicity: Not expected to be a route of exposure in normal industrial use.
Acute Target Organ Toxicity: Skin, Eyes, Respiratory Tract
Prolonged (Chronic) Health Effects
Carcinogenicity: IARC has classified untreated hardwood and hardwood/softwood
mix wood dust as a Group 1 human carcinogen. The wood dust
classification is based primarily on IARC's evaluation of increased
risk in the occurrence of adenocarcinomas of the nasal cavities
and paranasal sinuses associated with occupational exposures to
untreated wood dust. NTP has classified all untreated wood dust
as a carcinogen.
Reproductive and Not known or reported to cause reproductive or developmental
Developmental Toxicity: toxicity.
Inhalation: May cause respiratory sensitization and/or irritation.
Skin Contact: Treated or untreated wood dust, depending on the species, may
cause dermatitis on prolonged, repetitive contact.
Ingestion: Not expected to be a route of exposure in normal industrial use.
Sensitization: Various species of untreated wood dust can elicit an allergic
respiratory response in sensitized persons. Various species of
untreated wood dust can elicit an allergic type skin irritation in
sensitized persons.
Chronic Target Organ Respiratory Tract, Skin, Eyes
Toxicity:
Supplemental Health Hazard No additional health information available.
Information :
3. COMPOSITION / INFORMATION ON INGREDIENTS
CAS OR CHEMICAL NAME CAS # % RANGE
COPPER COMPOUNDS MIXTURE 0.1 - 2.0
Ethanolamine 141-43-5
Wood Dust Not Assigned 88 - 99.5
Ammonia (Only applies if treatment facility 7664-41-7 0-1
adds ammonia locally. Check with
treatment facility to determine applicability.)
Formaldehyde (by-product of the untreated 50-00-0 (Only 0 - 0.1
plywood article) applies to
plywood
products)
4. FIRST AID MEASURES
Inhalation: IF INHALED: Remove individual to fresh air. Seek medical attention if
breathing becomes difficult or if respiratory irritation develops. If not
breathing, give artificial respiration. Call for medical assistance.
Skin Contact: IF ON SKIN: Flush skin with water for 15 minutes. Take off all
contaminated clothing. Seek medical attention if irritation develops.
Eye Contact: IF IN EYES: Flush eyes with plenty of water for at least 15 minutes. Seek
medical attention if irritation develops.
Ingestion: IF SWALLOWED: Immediately drink water to dilute. Seek medical
attention if symptoms develop. Never give anything by mouth to an
unconscious person.
5. FIRE FIGHTING MEASURES
Flammability Summary (OSHA): Product is not known to be flammable, combustible,
pyrophoric or explosive.
Flammable Properties
Flash Point: No data.
Autoignition Temperature: No data.
Fire / Explosion Hazards: If the product is involved in a fire, toxic smokes could develop.
Dust may be ignitable if mixed with air in the presence of an
ignition source.
Extinguishing Media: Water spray
Fire Fighting Instructions: In case of fire, use normal fire-fighting equipment and the
personal protective equipment recommended in Section 8 to
include a NIOSH approved self-contained breathing
apparatus.
Hazardous Combustion During a fire, irritating and highly toxic gases may be
Products: generated by thermal decomposition or combustion.,
Hazardous combustion/decomposition products may include
but are not limited to:, Copper metal and copper oxides,
Copper Fumes
Upper Flammable / Explosive Limit, % in No data.
air:
Lower Flammable / Explosive Limit, % in No data.
air:
6. ACCIDENTAL RELEASE MEASURES
Personal Protection for No extra protection required beyond that listed in Section 8.
Emergency Situations: In case of fire, use normal fire fighting equipment.
Spill Mitigation Procedures
Air Release: Hazardous concentrations in air may be found in local spill area and
immediately downwind. Contain all solids for treatment or disposal.
Water Release: This material is insoluble in water. Notify all downstream users of
possible contamination. Contain all solids for treatment or disposal.
Land Release: Avoid dust generation. Contain all solids for treatment or disposal.
Additional Spill Information : Remove all sources of ignition. Utilize emergency response personal
protection equipment prior to the start of any response. Evacuate all
non-essential personnel. Dispose of spill residues per guidelines
under Section 13, Disposal Consideration.
7. HANDLING AND STORAGE
Handling: DO NOT BURN TREATED WOOD. Whenever possible, sawing or
machining treated or untreated wood should be performed outdoors
to avoid accumulations of airborne wood dust. Wear gloves, eye
protection, dust mask and protective clothing. Do not use treated
chips or sawdust as mulch. Wash hands thoroughly before eating,
drinking, using tobacco products, and/or using restrooms.
Storage: Keep away from unguarded flame, sparks, and heat sources.
Protect from physical damage. Maintain good housekeeping.
Incompatible Materials for oxidizers strong acids and bases
Storage:
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Ventilation: Whenever possible, sawing or machining treated or untreated wood should
be performed outdoors or in well ventilated areas to avoid accumulations of
airborne wood dust.Ventilation should be sufficient to maintain exposures
below the recommended exposure limits.
Protective Equipment for Routine Use of Product
Respiratory Protection : When sawing or cutting treated or untreated wood, wear a NIOSH approved
P95 or P100 Particulate filter respirator. FOR PLYWOOD PRODUCTS ONLY:
If Formaldehyde vapor levels exceed the recommended exposure limits,
wearing a NIOSH approved respirator is required. Formaldehyde is a by-
product of the untreated plywood article and not the result of this treatment.
Respirator Type : For plywood products only: A NIOSH approved full-face air purifying
respirator with combination formaldehyde/organic vapor cartridge and a
P100 filter. Air purifying respirators should not be used in oxygen
deficient or IDLH atmospheres or if exposure concentrations exceed ten
(10) times the published limit.
Skin Protection : Wear leather gloves. Wear long sleeve shirt, pants, and steel-toed shoes
when handling treated or untreated wood.
Eye Protection: Use safety glasses with side shields or chemical goggles when sawing or
cutting treated or untreated wood.
Protective Clothing Type: Wear leather gloves.
Exposure Limit Data
CHEMICAL NAME CAS # Name of Limit Exposure
COPPER COMPOUNDS NIOSH-IDLH 100 mg/m3
Ethanolamine 141-43-5 ACGIH 3 ppm TWA
Ethanolamine 141-43-5 ACGIH 6 ppm STEL
Ethanolamine 141-43-5 OSHA Z1 3 ppm PEL
6 mg/m3 PEL
Ethanolamine 141-43-5 NIOSH-IDLH 30 ppm
Wood Dust OSHA Z1 15.0 mg/m3 PEL Total dust.A
state-run OSHA program may
have more stringent limits for
wood dust and/or PNOR.
Wood Dust OSHA Z1 5.0 mg/m3 PEL Respirable
fraction.A state-run OSHA
program may have more
stringent limits for wood dust
and/or PNOR.
Wood Dust ACGIH 1.0 mg/m3 TWA Inhalable
fraction.(Western Red Cedar)
Wood Dust ACGIH 1.0 mg/m3 TWA Inhalable
fraction.(All other species)
Ammonia (Only applies if 7664-41-7 ACGIH 25 ppm TWA
treatment facility adds ammonia
locally. Check with treatment
facility to determine
applicability.)
Ammonia (Only applies if 7664-41-7 ACGIH 35 ppm STEL
treatment facility adds ammonia
locally. Check with treatment
facility to determine
applicability.)
Ammonia (Only applies if 7664-41-7 OSHA Z1 50 ppm PEL
treatment facility adds ammonia 35 mg/m3 PEL
locally. Check with treatment
facility to determine
applicability.)
Ammonia (Only applies if 7664-41-7 NIOSH-IDLH 300 ppm
treatment facility adds ammonia
locally. Check with treatment
facility to determine
applicability.)
Formaldehyde (by-product of 50-00-0 ACGIH 0.3 ppm Ceiling(Only applies
the untreated plywood article) to plywood products.)
Formaldehyde (by-product of 50-00-0 OSHA Reference: (Only applies to
the untreated plywood article) plywood products.)
Formaldehyde (by-product of 50-00-0 OSHA 0.75 ppm TWA(Only applies to
the untreated plywood article) plywood products.)
Formaldehyde (by-product of 50-00-0 OSHA 2 ppm STEL(Only applies to
the untreated plywood article) plywood products.)
Formaldehyde (by-product of 50-00-0 OSHA 0.5 ppm OSHA_ACT(Only
the untreated plywood article) applies to plywood products.)
Formaldehyde (by-product of 50-00-0 NIOSH-IDLH 20 ppm
the untreated plywood article) (Only applies to plywood
products.)
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: solid
Form solid
Color: green, slightly
Odor: None
Molecular Weight: None established
Specific Gravity : Not applicable
pH : Not applicable
Boiling Point: Not applicable
Freezing Point: Not applicable
Melting Point: No data
Density: solid
Vapor Pressure: Not applicable
Vapor Density: Not applicable
Viscosity: Not applicable
Fat Solubility: No data
Solubility in Water: insoluble
Partition coefficient No data
n-octanol/water:
Evaporation Rate: Not applicable
Oxidizing: The substance has no oxidizing properties
Volatiles, % by vol.: No data
VOC Content No data
HAP Content No data
10. STABILITY AND REACTIVITY
Stability and Reactivity Summary: Stable under normal conditions. Product will not undergo
hazardous polymerization.
Conditions to Avoid: Sparks, open flame, other ignition sources, and elevated
temperatures., Contact with incompatible substances
Chemical Incompatibility: strong acids, oxidizers
During a fire, irritating and highly toxic gases may be generated
Hazardous Decomposition Products:
by thermal decomposition or combustion.
Decomposition Temperature: No data
11. TOXICOLOGICAL INFORMATION
Component Animal Toxicology
Oral LD50 value:
Ethanolamine LD50 = 1,700 mg/kg Rat
Dermal LD50 value:
Ethanolamine LD50 Approximately 1,000 mg/kg Rabbit
Inhalation LC50 value:
Ethanolamine Inhalation LC50 1 HOUR > 4.8 MG/L Mouse
Ethanolamine Inhalation LC50 4 HOUR > 970 ppm Mouse
Product Animal Toxicity
Oral LD50 value: LD50 Believed to be > 5,000 mg/kg Rat
Dermal LD50 value: LD50 Believed to be > 2,000 mg/kg Rabbit
Inhalation LC50 No data
value:
Skin Irritation: Prolonged and/or repeated contact with treated or untreated wood dust may result
in mild irritation.
Eye Irritation: Treated or untreated wood dust may cause mechanical irritation.
Skin Sensitization: Various species of untreated wood dust can elicit an allergic respiratory response
in sensitized persons., Various species of untreated wood dust can elicit an
allergic type skin irritation in sensitized persons.
Subchronic / Chronic May cause respiratory sensitization and/or irritation., Treated or untreated wood
Toxicity: dust, depending on the species, may cause dermatitis on prolonged, repetitive
contact.
Reproductive and Not known or reported to cause reproductive or developmental
Developmental Toxicity: toxicity.
Ethanolamine This chemical has been tested in laboratory
animals and no evidence of teratogenicity,
embryotoxicity or fetotoxicity was seen.
Mutagenicity: Not known or reported to be mutagenic.
Ethanolamine This material was non-mutagenic in the Ames test.
Carcinogenicity: IARC has classified untreated hardwood and hardwood/softwood mix
wood dust as a Group 1 human carcinogen. The wood dust
classification is based primarily on IARC's evaluation of increased
risk in the occurrence of adenocarcinomas of the nasal cavities and
paranasal sinuses associated with occupational exposures to
untreated wood dust. NTP has classified all untreated wood dust as
a carcinogen.
Ethanolamine Mixture with nitrites can form nitrosamines which
have caused cancer in laboratory animals.
12. ECOLOGICAL INFORMATION
Overview: No data for product. Individual constituents are as follows:
Ecological Toxicity Values for: Ethanolamine
Rainbow trout (Salmo gairdneri), - (nominal, static). 96 HOUR LC50 = 150 mgl
Mosquito fish - (nominal, static). 96 HOUR LC50 = 337.5 mgl
Bluegill - (nominal, static). 96 HOUR LC50 = 329.16 mgl
Fathead minnow (Pimephales - (measured, flow-through) 96 HOUR LC50 = 2,070 mgl
promelas),
Goldfish - 24 HOUR LC50 = 190 mgl
Daphnia magna, - (nominal, static). 24 HOUR LC50= 140 mgl
Common shrimp (Crangon - (nominal, renewal). 48 HOUR LC50> 100 mgl
crangon)
Brine shrimp - 48 HOUR LC50= 7,100 mgl
13. DISPOSAL CONSIDERATIONS
CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE
USE OF THE MATERIAL. THE USER OF THE MATERIAL HAS THE RESPONSIBILITY TO
DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH
ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING
TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS
WASTES.
Waste Disposal Summary : If this product becomes a waste, it will be a nonhazardous
waste according to U.S. RCRA regulations. Dispose of in
accordance with all Local, State, Federal, and Provincial
Environmental Regulations.
Potential US EPA Waste Codes : Not applicable
14. TRANSPORT INFORMATION
Land (US DOT): NOT REGULATED AS A DOT HAZARDOUS MATERIAL
Water (IMDG): NOT REGULATED AS A HAZARDOUS MATERIAL,
Flash Point: No data.
Air (IATA): NOT REGULATED AS A HAZARDOUS MATERIAL,
Emergency Response Guide Number: Not applicable
15. REGULATORY INFORMATION
UNITED STATES:
Toxic Substances Control Act This item is exempt from TSCA and FIFRA under the
(TSCA): treated article exemption per 40 CFR 152.25(a).
EPA Pesticide Registration Number: None established
FIFRA Listing of Pesticide Chemicals Not registered in the US under FIFRA.
(40 CFR 180):
Superfund Amendments and Reauthorization Act (SARA) Title III:
Hazard Categories Sections 311 / 312 (40 CFR 370.2):
Health Immediate (Acute) Health Hazard, Delayed (Chronic) Health
Hazard
Physical None
Emergency Planning & Community Right to Know (40 CFR 355, App. A):
Extremely Hazardous Substance Section 302 - Threshold Planning Quantity:
SARA III Threshold Planning Quantity: None established
Reportable Quantity (49 CFR 172.101, Appendix):
CERCLA Reportable quantity:
SARA III Reportable quantity: None established
Supplier Notification Requirements (40 CFR 372.45), 313 Reportable Components
SARA III De minimis concentration:
Clean Air Act Toxic ARP Section 112r:
CAA 112R None established
Clean Air Act Socmi:
HON SOC None established
Clean Air Act VOC Section 111:
CAA 111 None established
Clean Air Act Haz. Air Pollutants Section 112:
CAA None established
CAA 112I None established
CAA AP None established
State Right-to-Know Regulations Status of Ingredients
Pennsylvania:
CAS # COMPONENT NAME
141-43-5 Ethanolamine
34590-94-8 Propanol, (2,methoxy-methylethoxy-)
50-00-0 Formaldehyde (by-product of the untreated plywood article)
7664-41-7 Ammonia (Only applies if treatment facility adds ammonia
locally. Check with treatment facility to determine applicability.)
PENN RTK
US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323)
PENN RTK
08 1989
ETHANOL, 2-AMINO-
US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323)
PENN RTK
08 1989
PROPANOL, (2-METHOXYMETHYLETHOXY)-
US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323)
PENN RTK
08 1989
FORMALDEHYDE
US. Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323)
PENN RTK
08 1989
AMMONIA
New Jersey:
CAS # COMPONENT NAME
141-43-5 Ethanolamine
60207-90-1 Propiconazole
COPPER COMPOUNDS
50-00-0 Formaldehyde (by-product of the untreated plywood article)
7664-41-7 Ammonia (Only applies if treatment facility adds ammonia
locally. Check with treatment facility to determine applicability.)
NJ RTK
US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated
Section 34:5A-5)
NJ RTK
12 1989
Substance no. 0835
ETHANOLAMINE
US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated
Section 34:5A-5)
NJ RTK
12 1989
Substance no. 0835
ETHANOL, 2-AMINO- ETHANOLAMINE
US. New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated
Section 34:5A-5)
NJ RTK
12 1989
Hazard Designation:
Substance no. 0835
ETHANOLAMINE
US. New Jersey Community Right-To-Know Survey, Table A: NJ Environmental Hazardous
Substances [EHS] List (N.J. Admin. Code Title 7 Section 1G-2.1)
NJ RTK
2001
Substance no. 3442
PROPICONAZOLE (1-[2-(2,4-DICHLOROPHENYL)-4-PROPYL-1,3-DIOXOLAN-2-YL]-METHYL-
1H-1,2,4-TRIAZOLE)
US. New Jersey Community Right-To-Know Survey, Table A: NJ Environmental Hazardous
Substances [EHS] List (N.J. Admin. Code Title 7 Section 1G-2.1)
NJ RTK
2001
Substance no. 2215
COPPER COMPOUNDS [EXCEPT: C.I. PIGMENT BLUE 15, C.I. PIGMENT GREEN 7, AND C.I.
PIGMENT GREEN 36]
US. New Jersey Community Right-To-Know Survey, Table A: NJ Environmental Hazardous
Substances [EHS] List (N.J. Admin. Code Title 7 Section 1G-2.1)
NJ RTK
2001
Substance no. 0946
FORMALDEHYDE
US. New Jersey Community Right-To-Know Survey, Table A: NJ Environmental Hazardous
Substances [EHS] List (N.J. Admin. Code Title 7 Section 1G-2.1)
NJ RTK
10 2006
Substance no. 0084
AMMONIA (THE REPORTABLE QUANTITY FOR ANHYDROUS AMMONIA IS BASED ON
100% OF THE ANHYDROUS AMMONIA. THE REPORTABLE QUANTITY FOR AQUEOU S
AMMONIA IS THE AMMONIA EQUIVALENT WEIGHT FOR CONCENTRATIONS OF 20% OR
GREATER.)
Massachusetts:
CAS # COMPONENT NAME
141-43-5 Ethanolamine
34590-94-8 Propanol, (2,methoxy-methylethoxy-)
50-00-0 Formaldehyde (by-product of the untreated plywood article)
7664-41-7 Ammonia (Only applies if treatment facility adds ammonia
locally. Check with treatment facility to determine applicability.)
MASS RTK
US. Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of
Massachusetts Regulations Section 670.000)
MASS RTK
04 1993
2-AMINOETHANOL ETHANOLAMINE
US. Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of
Massachusetts Regulations Section 670.000)
MASS RTK
04 1993
DIPROPYLENE GLYCOL METHYL ETHER
US. Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of
Massachusetts Regulations Section 670.000)
MASS RTK
04 1993
FORMALDEHYDE FORMALIN
US. Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of
Massachusetts Regulations Section 670.000)
MASS RTK
04 1993
AMMONIA AMMONIA, ANHYDROUS
California Proposition 65:
CAS # COMPONENT NAME
50-00-0 Formaldehyde (by-product of the untreated plywood article)
US CA CRT Carcinogenic.
US. California Safe Drinking Water & Toxic Enforcement Act (Proposition 65)
US CA CRT
12 2005
Hazard Designation:
Listed: January 1, 1988
FORMALDEHYDE (GAS)
Carcinogenic.
US CA65CRT None established
WHMIS Hazard Classification:
WHMIS None established
16. OTHER INFORMATION
MSDS REVISION STATUS : Revised to meet the ANSI standard of 16 sections
Major References : Available upon request.
THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL
OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. THE INFORMATION IN THIS MSDS SHOULD
BE PROVIDED TO ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS
PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING,
OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. THE
MANUFACTURER BELIEVES THIS INFORMATION TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF
PUBLICATION BUT, MAKES NO WARRANTY THAT IT IS. .
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