MATERIAL SAFETY DATA SHEET
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1. Product and Company Identification
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Product Name Citrus Blast Graffiti Remover
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Mixture
CAS #
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Cleaner
Product use
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Graffiti Solutions Canada
Manufacturer
7785 Franktown Road
Richmond, ON K0A 2Z0 CA
Phone: 613-838-5842
Phone: 866-906-9273
Fax: 613-838-5843
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613-996-6666
CANUTEC
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LEGEND Health * 2
3
HMIS/NFPA
Flammability 3
Severe 4
2 0
Serious 3
Physical Hazard 0
Moderate 2
Slight 1 Personal Protection
X
Minimal 0
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2. Hazards Identification
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DANGER -- CORROSIVE
Emergency overview
May cause sensitization by skin contact.
Flammable liquid - may release vapours that form flammable mixtures at or above
the flash point. Containers may explode when heated.
Contains a potential mutagen.
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Potential short term health effects
Eye, Skin contact, Skin absorption, Inhalation, Ingestion.
Routes of exposure
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Monoethanolamine is corrosive to the eyes.
Eyes
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Monoethanolamine is corrosive to rabbit skin. This product may be harmful if it is
Skin
absorbed through the skin. May cause skin sensitization, an allergic reaction, which
becomes evident on re-exposure to this material.
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Excessive intentional inhalation may cause respiratory tract irritation and central
Inhalation
nervous system effects (headache, dizziness).
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Harmful if swallowed.
Ingestion
Acute oral exposure of monoethanolamine has caused necrosis of the gastric and
intestinal mucosa.
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Blood. Gastrointestinal tract. Eyes. Kidney. Liver. Respiratory system. Skin.
Target organs
Based on published data, if contact is repeated and prolonged, monoethanolamine may
cause liver and kidney damage. These effects have not been observed in humans.
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This product may be harmful if it is absorbed through the skin. Prolonged or repeated
Chronic effects
exposure to dilutions can cause drying, defatting and dermatitis.
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Symptoms may include redness, edema, drying, defatting and cracking of the skin.
Signs and symptoms
Symptoms of overexposure may be headache, dizziness, tiredness, nausea and
vomiting.
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3. Composition / Information on Ingredients
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Ingredient(s) CAS # Percent (w/w)
Diacetone alcohol 123-42-2 30 - 60
HMIRC#7216 15 - 40
Aryl alcohol
5989-27-5 10 - 30
D-Limonene
141-43-5 1-5
Monoethanolamine
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This product has been granted a trade secret exemption. The granted date associated with
Composition comments
this trade secret exemption is February 27, 2009.
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4. First Aid Measures
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First aid procedures
Immediately flush the contaminated eye(s) with lukewarm gently flowing water for at
Eye contact
least 30 minutes, while holding the eyelid(s) open. Take care not to rinse contaminated
water into the unaffected eye (or face).
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Under running water, remove contaminated clothing, shoes and leather goods.
Skin contact
Continuously flush the contaminated area with lukewarm gently flowing water for at least
30 minutes.
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If symptoms develop, move victim to fresh air. If symptoms persist, obtain medical
Inhalation
attention. If breathing has stopped, trained personnel should administer CPR
immediately.
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Do not induce vomiting. If vomiting occurs naturally, have victim lean forward to reduce
Ingestion
risk of aspiration. Never give anything by mouth if victim is unconscious, or is
convulsing. Obtain medical attention.
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Symptoms may be delayed.
Notes to physician
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Keep away from sources of ignition. No smoking. Avoid contact with eyes and skin.
General advice
Keep out of reach of children. Immediate medical attention is required. Ensure that
medical personnel are aware of the material(s) involved, and take precautions to protect
themselves. Show this safety data sheet to the doctor in attendance. If you feel unwell,
seek medical advice (show the label where possible).
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5. Fire Fighting Measures
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Flammable by WHMIS/OSHA criteria. Vapors may travel to a source of ignition and
Flammable properties
flash back. Containers may explode when heated.
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Extinguishing media
Carbon dioxide. Alcohol foam. Water spray. Dry chemical. Water Fog. Polymer foam.
Suitable extinguishing media
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Unsuitable extinguishing media Not available
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Protection of firefighters
Not available
Specific hazards arising from
the chemical
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Firefighters should wear full protective clothing including self contained breathing
Protective equipment for
apparatus.
firefighters
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May include and are not limited to: Oxides of carbon. Oxides of nitrogen.
Hazardous combustion products
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Explosion data
Not available
Sensitivity to mechanical
impact
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Not available
Sensitivity to static discharge
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6. Accidental Release Measures
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Keep unnecessary personnel away. Do not touch or walk through spilled material. Do
Personal precautions
not touch damaged containers or spilled material unless wearing appropriate protective
clothing. Keep people away from and upwind of spill/leak.
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Stop leak if you can do so without risk. Prevent entry into waterways, sewers,
Methods for containment
basements or confined areas. Use water spray to reduce vapors or divert vapor cloud
drift.
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Before attempting clean up, refer to hazard data given above. Small spills may be
Methods for cleaning up
absorbed with non-reactive absorbent and placed in suitable, covered, labelled
containers. Prevent large spills from entering sewers or waterways. Contact emergency
services and supplier for advice. Never return spills in original containers for re-use.
Large Spills: Wet down with water and dike for later disposal. After removal flush
contaminated area thoroughly with water.
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7. Handling and Storage
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Use good industrial hygiene practices in handling this material. Do not get this material
Handling
in your eyes, on your skin, or on your clothing.
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Keep out of reach of children. Do not store at temperatures above 120癋 (49癈).Store
Storage
in a closed container away from incompatible materials.
#17780 Page 2 of 8 Issue date 04-Mar-2009
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8. Exposure Controls / Personal Protection
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Exposure limits
Ingredient(s) Exposure Limits
Aryl alcohol ACGIH-TLV
Not established
OSHA-PEL
Not established
Diacetone alcohol ACGIH-TLV
TWA: 50 ppm
OSHA-PEL
TWA: 50 ppm
D-Limonene ACGIH-TLV
Not established
OSHA-PEL
Not established
Monoethanolamine ACGIH-TLV
TWA: 3 ppm
STEL: 6 ppm
OSHA-PEL
TWA: 3 ppm
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Aryl alcohol has an AIHA WEEL exposure limit of 10ppm (8hr TWA).
Engineering controls Provide adequate ventilation. General ventilation normally adequate.
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Personal protective equipment
Wear chemical goggles.
Eye / face protection
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Rubber gloves. Confirm with a reputable supplier first.
Hand protection
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As required by employer code.
Skin and body protection
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Where exposure guideline levels may be exceeded, use an approved NIOSH respirator.
Respiratory protection
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General hygiene considerations Handle in accordance with good industrial hygiene and safety practice. When using do
not eat or drink. Wash hands before breaks and immediately after handling the product.
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9. Physical & Chemical Properties
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Yellow
Appearance
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Yellow
Color
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Liquid
Form
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Lemon.
Odor
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Not available
Odor threshold
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Liquid
Physical state
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10.1
pH
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Not available
Melting point
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-61 癈 (-77.80 癋)
Freezing point
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64 癈 (147.20 癋)
Boiling point
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28 癈 (82.40 癋) Tag Closed Cup
Flash point
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Not available
Evaporation rate
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Not available
Flammability limits in air, lower, %
by volume
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Not available
Flammability limits in air, upper, %
by volume
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Not available
Vapor pressure
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Not available
Vapor density
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Not available
Specific gravity
#17780 Page 3 of 8 Issue date 04-Mar-2009
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Not available
Octanol/water coefficient
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Not available
Solubility (H2O)
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Not available
Auto-ignition temperature
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Not available
VOC (Weight %)
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Not available
Viscosity
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Not available
Percent volatile
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10. Chemical Stability & Reactivity Information
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Stable under recommended storage conditions.
Chemical stability
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Do not mix with other chemicals. Avoid high temperatures. Reacts violently with acids.
Conditions to avoid
This product may react with oxidizing agents.
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Acids. Oxidizing agents.
Incompatible materials
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Hazardous decomposition products May include and are not limited to: Oxides of carbon. Oxides of nitrogen.
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Hazardous polymerization does not occur.
Possibility of hazardous reactions
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11. Toxicological Information
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Monoethanolamine has a dermal LD50 (rabbit) of 1.0 mL/Kg (1018 mg/kg: specific
Acute effects
gravity at 20癈 = 1.018 g/mL)
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Component analysis - LC50
Ingredient(s) LC50
Aryl alcohol 8.8 mg/l/4h rat
Diacetone alcohol Not available D-
Limonene Not available
Monoethanolamine 1210 mg/m3 mouse
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Component analysis - Oral LD50
Ingredient(s) LD50
Aryl alcohol 1230 mg/kg rat
Diacetone alcohol 4000 mg/kg rat
D-Limonene 4400 mg/kg rat; 5600 mg/kg mouse
Monoethanolamine 1720 mg/kg rat; 700 mg/kg mouse
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Effects of acute exposure
Monoethanolamine is corrosive to the eyes.
Eye
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Monoethanolamine is corrosive to rabbit skin. This product may be harmful if it is
Skin
absorbed through the skin. May cause skin sensitization, an allergic reaction, which
becomes evident on re-exposure to this material.
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Excessive intentional inhalation may cause respiratory tract irritation and central
Inhalation
nervous system effects (headache, dizziness).
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Harmful if swallowed.
Ingestion
Acute oral exposure of monoethanolamine has caused necrosis of the gastric and
intestinal mucosa.
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Contains a potential skin sensitizer.
Sensitization
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This product may be harmful if it is absorbed through the skin. Based on published data,
Chronic effects
if contact is repeated and prolonged, monoethanolamine may cause liver and kidney
damage. These effects have not been observed in humans.
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Non-hazardous by WHMIS/OSHA criteria.
Carcinogenicity
IARC - Group 3 (Not Classifiable)
D-Limonene 5989-27-5 Monograph 73 [1999] (overall evaluation downgraded from 2B to 3 with supporting
evidence from other relevant data)
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Aryl alcohol has caused an increase in chromosomal aberrations in Chinese hamster
Mutagenicity
ovary cells.
Diacetone alcohol has caused in vitro mutagenic effects in rat liver cells.
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Non-hazardous by WHMIS/OSHA criteria.
Reproductive effects
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Non-hazardous by WHMIS/OSHA criteria.
Teratogenicity
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12. Ecological Information
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Components of this product have been identified as having potential environmental
Ecotoxicity
concerns.
Ecotoxicity - Freshwater Algae Data
Aryl alcohol Trade Secret 3 Hr EC50 Anabaena variabilis: 35 mg/L
Monoethanolamine 141-43-5 72 Hr EC50 Scenedesmus subspicatus: 15 mg/L
Ecotoxicity - Freshwater Fish Species Data
Aryl alcohol Trade Secret 96 Hr LC50 Pimephales promelas: 460 mg/L [static]; 96 Hr LC50 Lepomis macrochirus:
10 mg/L [static]
Diacetone alcohol 123-42-2 96 Hr LC50 Lepomis macrochirus: 420 mg/L
D-Limonene 5989-27-5 96 Hr LC50 Pimephales promelas: 0.702 mg/L [flow-through]
Monoethanolamine 141-43-5 96 Hr LC50 Pimephales promelas: 227 mg/L [flow-through]; 96 Hr LC50 Brachydanio
rerio: 3684 mg/L [static]; 96 Hr LC50 Lepomis macrochirus: 329.16 mg/L [static]; 96 Hr
LC50 Oncorhynchus mykiss: 150 mg/L [static]
Ecotoxicity - Microtox Data
Aryl alcohol Trade Secret 5 Min EC50 Photobacterium phosphoreum: 63.7 mg/L; 15 min EC50 Photobacterium
phosphoreum: 63.7 mg/L; 30 min EC50 Photobacterium phosphoreum: 71.4 mg/L; 5 min
EC50 Photobacterium phosphoreum: 50 mg/L
Monoethanolamine 141-43-5 30 Min EC50 Photobacterium phosphoreum: 13.7 mg/L; 17 Hr EC50 Pseudomonas
putida: 110 mg/L; 2 Hr EC50 Nitrosomonas: 12200 mg/L
Ecotoxicity - Water Flea Data
Aryl alcohol Trade Secret 48 Hr EC50 water flea: 23 mg/L
Diacetone alcohol 123-42-2 48 Hr EC50 water flea: 8750 mg/L
Monoethanolamine 141-43-5 48 Hr EC50 Daphnia magna: 65 mg/L
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Not available
Environmental effects
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Not available
Aquatic toxicity
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Not available
Persistence / degradability
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Not available
Bioaccumulation / accumulation
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Not available
Partition coefficient
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Not available
Mobility in environmental media
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Not available
Chemical fate information
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Not available
Other adverse effects
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13. Disposal Considerations
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Not available
Waste codes
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Dispose in accordance with all applicable regulations.
Disposal instructions
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Not available
Waste from residues / unused
products
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Not available
Contaminated packaging
#17780 Page 5 of 8 Issue date 04-Mar-2009
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14. Transport Information
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U.S. Department of Transportation (DOT)
Basic shipping requirements:
Flammable liquids, corrosive, n.o.s. (D-LIMONENE)
Proper shipping name
3 (8)
Hazard class
UN2924
UN number
III
Packing group
Additional information:
B1, IB3, T7, TP1, TP28
Special provisions
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Packaging exceptions
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ERG number
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Transportation of Dangerous Goods (TDG - Canada)
Basic shipping requirements:
FLAMMABLE LIQUID, CORROSIVE, N.O.S.
Proper shipping name
(D-LIMONENE)
3 (8)
Hazard class
UN2924
UN number
III
Packing group
Additional information:
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Special provisions
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15. Regulatory Information
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This product has been classified in accordance with the hazard criteria of the Controlled
Canadian federal regulations
Products Regulations and the MSDS contains all the information required by the
Controlled Products Regulations.
Canada - WHMIS - Ingredient Disclosure List
Aryl alcohol Trade Secret 1%
Diacetone alcohol 123-42-2 1%
D-Limonene 5989-27-5 1%
Monoethanolamine 141-43-5 1%
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This product is a "Hazardous Chemical" as defined by the OSHA Hazard
US Federal regulations
Communication Standard, 29 CFR 1910.1200.
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Occupational Safety and Health Administration (OSHA)
Yes
29 CFR 1910.1200 hazardous
chemical
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CERCLA (Superfund) reportable quantity
Potassium hydroxide: 1000.0000
Sodium dodecylbenzene sulfonate: 1000.0000
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Superfund Amendments and Reauthorization Act of 1986 (SARA)
Immediate Hazard - Yes
Hazard categories
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
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No
Section 302 extremely
hazardous substance
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Section 311 hazardous chemical Yes
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Not available
Clean Air Act (CAA)
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Not available
Clean Water Act (CWA)
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Not available
Safe Drinking Water Act (SDWA)
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Not available
Drug Enforcement Agency (DEA)
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Not available
Food and Drug Administration
(FDA)
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Controlled
WHMIS status
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Class B - Division 2 - Flammable Liquid, Class D - Division 2B, Class E - Corrosive
WHMIS classification
Material
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WHMIS labeling
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WARNING: This product contains a chemical known to the State of California to cause
State regulations
birth defects or other reproductive harm.
U.S. - California - 8 CCR Section 339 - Director's List of Hazardous Substances
Diacetone alcohol 123-42-2 Present
Monoethanolamine 141-43-5 Present
U.S. - Illinois - Toxic Air Contaminants
Monoethanolamine 141-43-5 Present
U.S. - Massachusetts - Right To Know List
Aryl alcohol Trade Secret Present
123-42-2
Diacetone alcohol Present
Monoethanolamine Present
141-43-5
U.S. - Minnesota - Hazardous Substance List
Aryl alcohol Trade Secret Present
Diacetone alcohol 123-42-2 Present
Monoethanolamine 141-43-5 Present
U.S. - New Jersey - Right to Know Hazardous Substance List
Aryl alcohol Trade Secret sn 2079
Diacetone alcohol 123-42-2 sn 0606
D-Limonene 5989-27-5 Sn 2643 (flammable, liquid, toxic, flash point less than 23癈); sn 2642 (flammable, liquid,
toxic, flash point between 23癈 and 61癈); sn 2644 (liquid, toxic); sn 2645 (solid, toxic)
Monoethanolamine 141-43-5 sn 0835
U.S. - Pennsylvania - RTK (Right to Know) List
Aryl alcohol Trade Secret Present
Diacetone alcohol 123-42-2 Present
Monoethanolamine 141-43-5 Present
U.S. - Rhode Island - Hazardous Substance List
Diacetone alcohol 123-42-2 Toxic
Monoethanolamine 141-43-5 Toxic; Flammable
#17780 Page 7 of 8 Issue date 04-Mar-2009
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Inventory name
Country(s) or region Inventory name On inventory (yes/no)*
Canada Domestic Substances List (DSL) Yes
Canada Non-Domestic Substances List (NDSL) No
United States & Puerto Rico Toxic Substances Control Act (TSCA) Inventory Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
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16. Other Information
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Information contained herein was obtained from sources considered technically accurate
Disclaimer
and reliable. While every effort has been made to ensure full disclosure of product
hazards, in some cases data is not available and is so stated. Since conditions of actual
product use are beyond control of the supplier, it is assumed that users of this material
have been fully trained according to the requirements of all applicable legislation and
regulatory instruments. No warranty, expressed or implied, is made and supplier will not
be liable for any losses, injuries or consequential damages which may result from the
use of or reliance on any information contained in this document.
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04-Mar-2009
Issue date
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15-Jan-2008
Effective date
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15-Jan-2011
Expiry date
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Dell Tech Laboratories Ltd. (519) 858-5021
Prepared by
#17780 Page 8 of 8 Issue date 04-Mar-2009
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