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MSDS Material Safety Data Sheet
CAS

7732-18-5 13463-67-7 1317-65-3 66402-68-4 50-00-0

File Name: 7732-18-5_13463-67-7_1317-65-3_66402-68-4_50-00-0.asp

                                  MATERIAL                SAFETY               DATA        SHEET
KOOL RAY CLASSIC LIQUID SHADE, WHITE Page: 1
3/12/2008

PRODUCT NAME: KOOL RAY CLASSIC LIQUID SHADE, WHITE HMIS CODES: H F R P
PRODUCT CODE: 09-1316-II-01 100X

================== SECTION I - MANUFACTURER IDENTIFICATION =================

MANUFACTURER'S NAME: CONTINENTAL PRODUCTS COMPANY
ADDRESS : 1150 East 222 Street
Euclid, OH 44117

EMERGENCY PHONE : (800)255-3924 DATE PRINTED : 3/12/2008
INFORMATION PHONE : (216)531-0710 NAME OF PREPARER : John Stevens

========== SECTION II - HAZARDOUS INGREDIENTS/SARA III INFORMATION =========
VAPOR PRESSURE WEIGHT
REPORTABLE COMPONENTS CAS NUMBER mm Hg @ TEMP PERCENT
------------------------------------------------------------------------------------------------------------------------------------
Water (nonhazardous) 7732-18-5 72.4
ACGIH TLV: Not Established
OSHA PEL: Not Established
+*# Rutile Titanium Dioxide 13463-67-7 21.67271
ACGIH TLV: 10 mg/M3 (TWA)
OSHA PEL: 15 mg/M3 (Total Dust)
CALCIUM CARBONATE 1317-65-3 9.8
ACGIH TLV: 10 mg/M3 (inhalable total particulate matter containing
no asbestos and < 1% crystalline silica TWA)
OSHA PEL: 15 mg/M3 (Total Dust); 5 mg/M3 (Respirable Fraction)
Calcined China Clay 66402-68-4 4.9
ACGIH TLV: 3mg/M3 Respirable; 10mg/M3 Total
OSHA PEL: 5mg/M3 Respirable; 15mg/M3 Total
# FORMALDEHYDE 50-00-0 .00039
ACGIH TLV: 0.3 ppm (Ceiling)
OSHA PEL: .75ppm TWA; 0.5ppm Action Level; STEL 2 ppm
see 29 CFR 1910.1048
RQ 100 lbs
Formaldehyde is known to the State of California to cause cancer (prop 65).



* Indicates toxic chemical(s) subject to the reporting requirements of section 313 of Title III and of 40 CFR 372.
+ indicates toxic chemical(s) subject to the reporting requirements of section 311 and 312 of Title III and of 40 CFR
372.


# Indicates a Chronic hazard. See warning in Section IX.
CONTACT CONTINENTAL PRODUCTS COMPANY IF CALIFORNIA PROPOSITION 65 INFORMATION IS NEEDED.


=============== SECTION III - PHYSICAL/CHEMICAL CHARACTERISTICS ============

BOILING RANGE: 212 F SPECIFIC GRAVITY (H2O=1): 1.2191
VAPOR DENSITY: HEAVIER THAN AIR EVAPORATION RATE: SLOWER THAN ETHER
COATING V.O.C.: 0.0 lb/gl MATERIAL V.O.C.: 0.0 lb/gl
SOLUBILITY IN WATER: NOT SOLUBLE READILY SOLUBLE
ODOR: CHARACTERISTIC PAINT ODOR APPEARANCE : WHITE LIQUID

================= SECTION IV - FIRE AND EXPLOSION HAZARD DATA ==============

FLASHPOINT : DOES NOT FLASH METHOD USED: SETAFLASH
FLAMMABLE LIMITS IN AIR BY VOLUME- LOWER: n/a UPPER: n/a
MATERIAL SAFETY DATA SHEET
KOOL RAY CLASSIC LIQUID SHADE, WHITE Page: 2
3/12/2008


EXTINGUISHING MEDIA: Carbon Dioxide, dry chemical or foam. If water, fog nozzles
preferred.


SPECIAL FIREFIGHTING PROCEDURES
Water may be used to cool closed containers to prevent pressure build-up when exposed to extreme heat. Firefighting
personnel should wear self-contained breathing apparatus.




UNUSUAL FIRE AND EXPLOSION HAZARDS
Isolate from heat, electrical equipment, sparks, and open flame. Closed containers may explode (due to the build-up of
steam pressure) when exposed to extreme heat.




======================== SECTION V - REACTIVITY DATA =======================

STABILITY: Stable
CONDITIONS TO AVOID
Heat, sparks, open flame and fire. Material is subject to freezing. Do not store above 120 Degrees Fahrenheit.


INCOMPATIBILITY (MATERIALS TO AVOID)
Strong oxidizing agents.


HAZARDOUS DECOMPOSITION OR BYPRODUCTS
BY FIRE: Normal products of incomplete combustion. May produce fumes when heated to decomposition, as in welding. Fumes
may contain carbon monoxide/dioxide or oxides of nitrogen.




HAZARDOUS POLYMERIZATION: WILL NOT OCCUR

==================== SECTION VI - HEALTH HAZARD DATA =======================

INHALATION HEALTH RISKS AND SYMPTOMS OF EXPOSURE
May cause headache, nausea, eye or skin irritation. Irritation of the throat and nose has been observed in people
exposed to formaldehyde vapor levels in excess of 1 ppm. Normal breathing may be seriously impaired at levels above 10
ppm and serious lung damage can occur at levels exceeding 50 ppm. Formaldehyde solutions can cause severe eye and
moderate skin irritation. Repeated skin exposure to solutions of 2% or more formaldehyde has caused allergic skin
reactions. Formaldehyde was found to be weakly mutagenic in a number of in vitro genotoxicity tests, but inactive in
vivo. Lifetime inhalation of formaldehyde vapor at concentrations above 5 ppm for 6 hours per day, caused nasal tumors
in laboratory animals.




CARCINOGENICITY:
NTP CARCINOGEN: Yes
IARC MONOGRAPHS: Yes
OSHA REGULATED: Yes

MEDICAL CONDITIONS GENERALLY AGGRAVATED BY EXPOSURE
Respiratory difficulties or preexisting skin sensitization. Repeated exposure to emitted vapors may cause irritation to
the upper respiratory tract. May aggravate an existing skin dermatitis condition.




EMERGENCY AND FIRST AID PROCEDURES
INHALATION: Remove to fresh air. Administer artificial respiration or oxygen if breathing is difficult. Call for prompt
medical attention. EYES: Flush immediately with large amounts of water for at least 15 minutes. Get medical attention.
SKIN: Wash affected area with soap and water. Remove and launder contaminated clothing. Consult a physician if
MATERIAL SAFETY DATA SHEET
KOOL RAY CLASSIC LIQUID SHADE, WHITE Page: 3
3/12/2008

irritation persists. INGESTION: Do not induce vomiting. Keep at rest. Call a physician immediately.




=========== SECTION VII - PRECAUTIONS FOR SAFE HANDLING AND USE ============

STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
Dike spill area. Ventilate area if necessary. Recover free liquid by addition of inert absorbent to spill area. Sweep up
and place material in a suitable disposal container. Wash down spill area with copius quantities of water. Wet floors
may be slippery. Post appropriate warnings.




WASTE DISPOSAL METHOD
Disposal must be made in accordance with Local, State, and Federal regulations. Incineration or landfilling must be in
an approved facility. Do not incinerate closed containers.




PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING
Store out of the sun and away from heat, sparks, and open flame. Keep containers closed and upright to prevent leakage.
Do not store below 40 Degrees Fahrenheit or above 120 Degrees Fahrenheit for extended periods. Do not reuse product
container for any purpose.




OTHER PRECAUTIONS
Do not get in eyes. Avoid skin contact. Do not take internally. Prevent prolonged or repeated breathing of vapor or
spray mist. Keep out of reach of children. Do not get in eyes. Avoid skin contact. Do not take internally. Containers
should be grounded when pouring. Prevent prolonged or repeated breathing of vapor or spray mist. Keep out of reach of
children. This material is electrically conductive. Do not apply by electrostatic spray equipment unless the equipment
is modified and intended for the application of conductive coatings.




===================== SECTION VIII - CONTROL MEASURES ======================

RESPIRATORY PROTECTION
Observe the OSHA Respiratory Protection Standard (29 CFR 1910.134) and OSHA Formaldehyde Standard (29 CFR 1910.1048) for
respirator selection and use. Selection of the most appropriate respirator will depend on the specific work environment
and should be made only by a person familiar with the working conditions and with the benefits and limitations of
respiratory protection products.




VENTILATION
Ventilation should dilute to below LEL and TLV to be considered adequate. All applications areas should be ventilated in
accordance with the applicable regulations found in 29 CFR, Part 1910.
Respiratory protection should be provided in accordance with 29 CFR, Part 1910.134.




PROTECTIVE GLOVES
Recommended if skin contact is likely.


EYE PROTECTION
Chemical goggles or safety eyewear with splash shields is recommended.


OTHER PROTECTIVE CLOTHING OR EQUIPMENT
Suitable barrier cremes, impervious clothing and boots are recommended to reduce repeated contact with material and
limit contamination.




WORK/HYGIENIC PRACTICES
MATERIAL SAFETY DATA SHEET
KOOL RAY CLASSIC LIQUID SHADE, WHITE Page: 4
3/12/2008

Wash hands with soap and water before eating or using the washroom. Smoke in smoking areas only. Remove and wash
contaminated clothing before reuse.




========================= SECTION IX - DISCLAIMER ==========================
Titanium Dioxide - IARC concludes there is inadequate evidence for the carcinogenicity of titanium dioxide in humans and
sufficient evidence for the carcinogenicity of titanium dioxide in experimental animals. IARC's overall evaluation is
titanium dioxide is possibly carcinogenic to humans (Group 2B). (IARC Monographs VOL 93(2006) TITANIUM DIOXIDE)


THIS PRODUCT CONTAINS FORMALDEHYDE, WHICH IS A POTENTIAL CANCER HAZARD TO HUMANS. FORMALDEHYDE IS KNOWN TO CAUSE BIRTH
DEFECTS OR OTHER REPRODUCTIVE HARM. FORMALDEHYDE MAY CAUSE IRRITATION AND SENSITIZATION OF THE SKIN AND RESPIRATORY
SYSTEM, MAY CAUSE EYE AND THROAT IRRITATION, AND IS ACUTELY TOXIC.
Risk of cancer depends on duration and level of exposure. See OSHA Standard 1910.1048
FORMALDEHYDE IS LISTED BY THE IARC IN GROUP 1 AS CARCINOGENIC TO HUMANS. (IARC Monographs VOL 88(2004) FORMALDEHYDE)
NTP LISTS FORMALDEHYDE AS REASONABLY ANTICIPATED TO BE A HUMAN CARCINOGEN.
California Proposition 65 warning: Formaldehyde is known to the State of California to cause cancer.


All components of this product are listed on the U.S. TSCA Inventory.
THE INFORMATION AND THE RECOMMENDATIONS CONTAINED HEREIN ARE BASED UPON DATA BELIEVED TO BE CORRECT. HOWEVER, NO
GUARANTEE OR WARRENTY OF ANY KIND, EXPRESSED OR IMPLIED, IS MADE WITH RESPECT TO THE INFORMATION ABOVE.

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