The Valspar Corporation
Material Safety Data Sheet
1. PRODUCT AND COMPANY IDENTIFICATION
Material Identification
Product ID: 038.9910925
Product Name: GLAZETITE II 501
Product Use: Paint product.
Print date: 14/Feb/2008
Revision Date: 14/Feb/2008
Company Identification
The Valspar Corporation - Architectural Coatings Division
1191 Wheeling Road
Wheeling, IL 60090
Manufacturer's Phone: 1-847-520-8580
24-Hour Medical Emergency 1-888-345-5732
Phone:
2. COMPOSITION / INFORMATION ON HAZARDOUS INGREDIENTS
Common Name Approx. Chemical name
CAS-No. Weight %
PROPRIETARY INERT 20 - 25 PROPRIETARY INERT
CRYSTALLINE SILICA 15 - 20 QUARTZ (Si02)
14808-60-7
TALC 15 - 20 TALC (MG3H2(SI03)4)
14807-96-6
MINERAL SPIRITS 15 - 20 Petroleum distillates, hydrotreated light
64742-47-8
TITANIUM DIOXIDE 5 - 10 Titanium dioxide
13463-67-7
PROPRIETARY RESIN 5 - 10 PROPRIETARY RESIN
EXEMPT MINERAL SPIRITS 5 - 10 Stoddard solvent
8052-41-3
If this section is blank there are no hazardous components per OSHA guidelines.
3. HAZARDS IDENTIFICATION
Primary Routes of Exposure:
Inhalation
Ingestion
Skin absorption
Emergency Overview:
This section not in use.
This product contains ingredients that may contribute to the following potential acute health effects:
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Inhalation Effects:
Harmful if inhaled. May affect the brain, nervous system, or respiratory system, causing dizziness, headache, nausea or
respiratory irritation.
Eye Contact:
May cause moderate eye irritation.
Skin Contact:
Contains a component which is a known or suspected skin sensitizer.
Acute Ingestion:
None known
Other Effects:
None known
This product contains ingredients that may contribute to the following potential chronic health effects:
Prolonged exposure to respirable crystalline quartz silica may cause delayed chronic injury (silicosis). Notice: Reports
have associated repeated and prolonged occupational overexposure to solvents with permanent brain and nervous system
damage. Intentional misuse by deliberately concentrating and inhaling the contents may be harmful or fatal. Contains a
component which is a known or suspected skin sensitizer. Possible sensitization.
See Section 11 for toxicological information about Mutagens, Teratogens and Carcinogens.
If this section is blank, no information is available.
4. FIRST AID MEASURES
Inhalation:
If affected by inhalation, move victim to fresh air. If symptoms persist, seek medical attention. If inhaled, remove to fresh
air. If not breathing give artificial respiration, preferably mouth-to-mouth. If breathing is difficult give oxygen. Get medical
attention.
Eye Contact:
In case of contact, or suspected contact, immediately flush eyes with plenty of water for at least 15 minutes and get
medical attention immediately after flushing.
Skin Contact:
In case of contact, immediately flush skin with plenty of soap and water for at least 15 minutes. If irritation persists get
medical attention.
Ingestion:
If swallowed , do not induce vomiting. Give large quantities of water. If available, give several glasses of milk. Never give
anything by mouth to an unconscious person. Get medical attention immediately.
Medical conditions aggravated by exposure: Any respiratory or skin condition.
5. FIRE FIGHTING MEASURES
Flash point (Fahrenheit): 105?F ( 41?C) TCC/PM
Lower explosive limit: 1%
Upper explosive limit: 6%
Autoignition temperature: Not available. ?F ( ?C)
Sensitivity to impact: No.
Sensitivity to static discharge: Can be sensitive to static discharge hazards. Please see
bonding and grounding information in Section 7.
Hazardous combustion products: See Section 10.
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Unusual fire and explosion hazards:
Contaminated rags, wipes, saw dust, etc., may catch fire spontaneously. Store waste under water in closed metal
containers or in approved self-closing containers designed to prevent spontaneous combustion until disposed of in
compliance with applicable regulations. Contains oxidizable materials.
Extinguishing media:
Carbon dioxide, dry chemical, foam and/or water fog.
Fire fighting procedures:
Use water spray to cool nearby containers and structures exposed to fire.
6. ACCIDENTAL RELEASE MEASURES
Action to be taken if material is released or spilled:
Ventilate area. Avoid breathing of vapors. Use self-containing breathing apparatus or airmask for large spills in a
confined area. Wipe, scrape or soak up in an inert material and put in a container for disposal. See section 5, "Unusual
Fire and Explosion Hazards", for proper container and storage procedures. Remove sources of ignition. Remove with
inert absorbent and non sparking tools. Avoid all personal contact.
7. HANDLING AND STORAGE
Precautions to be taken in handling and storage:
Keep away from heat, sparks, and flames. Keep container closed when not in use. Do not store above 120 degrees F.
(49 degrees C). Based on flash point and vapor pressure, suitable storage should be provided in accordance with OSHA
regulation 1910.106, Ontario OH&S regulation 851 section 22. Empty containers may contain product residue, including
flammable or explosive vapors. Do not cut, puncture or weld on or near container. All label warnings must be observed
until the container has been commercially cleaned or reconditioned. If the product is used near or above the flashpoint,
an ignition hazard may be present. Activities, uses, or operations which liberate vapor (such as mixing or free fall of
liquids) may also present an ignition hazard. Please ensure containers and other interconnected equipment are properly
bonded and grounded at all times.
8. PERSONAL PROTECTIVE EQUIPMENT AND EXPOSURE CONTROLS
Personal Protective Equipment
Eye and face protection:
Avoid contact with eyes. Wear chemical goggles if there is the possibility of contact or splashing in the eye.
Skin protection:
Gloves: Neoprene or other nonporous. Neoprene or plastic apron and protective clothing covering exposed skin areas.
Respiratory protection:
If exposure cannot be controlled below applicable limits, use the appropriate NIOSH approved respirator such as an air
purifying respirator with organic vapor cartridge and dust/mist filter. Consult the respirator manufacturer's literature to
ensure that the respirator will provide adequate protection. Read and follow all respirator manufacturer's instructions.
Ventilation
Required when spraying or applying in confined area. Ventilation equipment should be explosion proof.
Exposure Guidelines
OSHA Permissible Exposure Limits (PEL's)
Common Name Approx. TWA (final) Ceilings limits (final) Skin designations
CAS-No. Weight %
PROPRIETARY INERT 20 - 25 5 mg/m?Respirable
fraction.
15 mg/m?Total dust.
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Common Name Approx. TWA (final) Ceilings limits (final) Skin designations
CAS-No. Weight %
CRYSTALLINE SILICA 15 - 20 Respirable. Listed.
14808-60-7 Total dust. Listed.
TALC 15 - 20 Respirable. Listed.
14807-96-6 Total dust. Listed.
TITANIUM DIOXIDE 5 - 10 15 mg/m?Total dust.
13463-67-7
EXEMPT MINERAL SPIRITS 5 - 10 2900 mg/m?500 ppm
8052-41-3
ACGIH Threshold Limit Value (TLV's)
Common Name Approx. TWA STEL Ceiling limits Skin designations
CAS-No. Weight %
10 mg/m3
PROPRIETARY INERT 20 - 25
Inhalable particles.
3 mg/m3
Respirable particles.
CRYSTALLINE SILICA 15 - 20 0.05 mg/m?br>
14808-60-7 Respirable fraction.
TALC 15 - 20 2 mg/m?br>
14807-96-6 Respirable fraction.
The value is for
particulate matter
containing no
asbestos and <1%
crystalline silica.
TITANIUM DIOXIDE 5 - 10 10 mg/m?br>
13463-67-7
EXEMPT MINERAL SPIRITS 5 - 10 100 ppm
8052-41-3
If this section is blank, no information is available.
9. PHYSICAL PROPERTIES
Odor: Normal for this product type.
Physical State: Liquid
pH: Not determined.
Vapor pressure: 2 mmHG @ 68?F ( 20?C)
Vapor density (air = 1.0): 5.1
Boiling point: 307?F ( 153?C)
Solubility in water: Insoluble.
Coefficient of water/oil distribution: Not determined.
Density (lbs per US gallon): 13.49
Specific Gravity: 1.62
Evaporation rate (butyl acetate = 1.0): .1
10. STABILITY AND REACTIVITY
Stability: Stable
Conditions to Avoid: None known.
Incompatibility: None known.
Hazardous Polymerization: None anticipated.
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10. STABILITY AND REACTIVITY
Hazardous Decomposition Products: Silicon dioxide. Carbon monoxide and carbon dioxide.
Metal oxide fumes.
Sensitivity to static discharge: Can be sensitive to static discharge hazards. Please see
bonding and grounding information in Section 7.
11. TOXICOLOGICAL INFORMATION
Mutagens:
None known.
Teratogens:
None known.
Contains crystaline silica. The IARC has determined that crystaline silica inhaled in the form of quartz or cristobablite from
occupational sources is carcinogenic to humans (group 1). Refer to IARC monograph 68 in conjunction with the use of
these materials. Risk of cancer depends on the duration and level of exposure. In coatings products, risk is due primarily
to inhalation of sanding dusts or respirable particles in spray mists. The NTP has also determined that crystaline silica is a
known human carcinogen in the form of fine, breathable particles. Risk of cancer depends on duration and level of
exposure in coatings products, risk is due primarily to inhalation of sanding dust or respirable particles in spray mist.
Contains TIO2 which is listed by IARC as a possible human carcinogen (Group 2B) based on animal data. Neither long
term animal studies, nor human epidemiology studies of workers exposed to TIO2 provide an adequate basis to conclude
TIO2 is carcinogenic. TIO2 is not classified as a carcinogen by NTP, U.S. OSHA, or the U.S. EPA.
Common Name Approx. IARC Group 1 - Human IARC Group 2A - Limited IARC Group 2B -
CAS-No. Weight % Evidence Human Data Sufficient Animal Data
CRYSTALLINE SILICA 15 - 20 Monograph 68, 1997;
14808-60-7 (inhaled in the form of
quartz or cristobalite from
occupational sources)
TITANIUM DIOXIDE 5 - 10 2B Possible Carcinogen
13463-67-7
Common Name Approx. NTP Known NTP Suspect NTP Evidence of
CAS-No. Weight % Carcinogens Carcinogens Carcinogenicity
CRYSTALLINE SILICA 15 - 20 Known carcinogen.
14808-60-7
TALC 15 - 20 male rat-some evidence;
14807-96-6 female rat-clear
evidence; male mice-no
evidence; female mice-
no evidence
Common Name Approx. OSHA Select OSHA Possible Select ACGIH Carcinogens
CAS-No. Weight % Carcinogens Carcinogens
CRYSTALLINE SILICA 15 - 20 Group A2 Suspected
14808-60-7 human carcinogen.
12. ECOLOGICAL DATA
Not available at this time.
13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with federal, state and local regulations.
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14. TRANSPORTATION INFORMATION
U.S. Department of Transportation
Proper Shipping Name: PAINT
Hazard Class: COMBUSTIBLE LIQUID
UN ID Number: UN1263
Packing Group: III
U.S. Highway & Rail Shipments
The supplier may apply one of the following exceptions: Combustible Liquid, Consumer Commodity, Limited Quantity,
Viscous Liquid, Does Not Sustain Combustion, or others, as allowed under 49CFR Hazmat Regulations. Please consult
49CFR Subchapter C to ensure that subsequent shipments comply with these exceptions.
International Air Transport Association:
Proper Shipping Name: Paint
Hazard Class: 3
UN ID Number: UN1263
Packing Group: III
International Maritime Organization:
Proper Shipping Name: PAINT
Hazard Class: 3
Non-Bulk UN ID Number: UN1263
Packing Group: III
15. REGULATORY INFORMATION
U.S. FEDERAL REGULATIONS:
SARA 311/312 Hazard Class:
Acute: Yes
Chronic: Yes
Flammability: Yes
Reactivity: No
Sudden Pressure: No
U.S. STATE REGULATIONS:
Pennsylvania Right To Know:
CRYSTALLINE SILICA 14808-60-7
EXEMPT MINERAL SPIRITS 8052-41-3
PROPRIETARY RESIN Trade Secret
MINERAL SPIRITS 64742-47-8
TALC 14807-96-6
PROPRIETARY INERT Trade Secret
TITANIUM DIOXIDE 13463-67-7
California Proposition 65:
WARNING: This product contains a chemical known to the State of California to cause cancer.
Rule 66 status of product Not photochemically reactive.
INTERNATIONAL REGULATIONS - Chemical Inventories
TSCA Inventory: All components of this product are in compliance with U.S.
TSCA Chemical Substance Inventory Requirements.
Product ID: 038.9910925
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Canada Domestic Substances List: Not all components in this product are listed on the Domestic
Substances List.
16. OTHER INFORMATION
HMIS Codes
Health: 2
Flammability: 2
Reactivity: 1
PPE: X - See Section 8 for Personal Protective Equipment (PPE).
Abbreviations:
OSHA - Occupational Safety and Health Administration, IARC - International Agency for Research on Cancer, NIOSH -
National Institute of Occupational Safety and Health, NTP - National Toxicology Program, ACGIH - American Conference
of Governmental Industrial Hygienists, SCAQMD - South Coast Air Quality Management District, TSCA - Toxic
Substances Control Act, IATA - International Air Transport Association, IMO - International Maritime Organization, DOT -
Department of Transportation, NA - Not applicable, NOT ESTAB - Not established, N.A.V. - Not available, RQ -
Reportable quantity, WT - Weight, MG/CU M - Milligrams per cubic meter, G/L - Grams per liter, MM - Millimeters,
MPPCF - Millions of particles per cubic foot, PPM - parts per million, PPT - parts per thousand, TCC/PM - Tag closed
cup / Pensky-Martens, PB - Lead, PEL - Permissible exposure level, TWA - Time Weighted Average, STEL - Short term
exposure limit, C - Celsius, F - Fahrenheit.
Disclaimer:
The data on this sheet represent typical values. Since application variables are a major factor in product performance, this
information should serve only as a general guide. Valspar assumes no obligation or liability for use of this information.
UNLESS VALSPAR AGREES OTHERWISE IN WRITING, VALSPAR MAKES NO WARRANTIES, EXPRESS OR
IMPLIED, AND DISCLAIMS ALL IMPLIED WARRANTIES INCLUDING WARRANTIES OF MERCHANTABILITY OR
FITNESS FOR A PARTICULAR USE OR FREEDOM FROM PATENT INFRINGEMENT. VALSPAR WILL NOT BE
LIABLE FOR ANY SPECIAL, INCIDENTAL OR CONSEQUENTIAL DAMAGES. Your only remedy for any defect in this
product is the replacement of the defective product, or a refund of its purchase price, at our option. This MSDS contains
additional information required by the state of Pennsylvania.
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