MATERIAL SAFETY DATA SHEET
MSDS Name: Grabber PRECAUTION BLUE GB20653
Revision Date: January 1, 2010
1. Product and Company Identification
Product Name: Grabber PRECAUTION BLUE
Prodcut Code: GB20653
Supplier: Grabber Construction Products
205 Mason Circle
Concord, CA 94520
Medical Emergency: CHEMTEL 1-800-255-3924, 813-248-0585 if located outside the U.S.
Product Information: 800-877-TURN (Concord, California) 8:00 a.m. - 4:00 p.m PST
2. Composition/Information on Ingredients
Chemical Description: This product is a mixture of the substances listed below with nonhazardous additions.
Dangerous components:
64742-89-8 VM&P Naptha 19.25%
74-98-6 propane 17.64%
1317-65-3 Calcium Carbonate 15.29%
106-97-8 n-butane 10.36%
64742-47-8 Mineral Spirits 4.36%
13463-67-7 titanium dioxide 1.38%
Additional information: For the wording of the listed risk phrases refer to section 3
3. Hazards Identification
Hazard description: Irritant
Extremely flammable
Physical dangers: Extremely flammable.
Irritating to eyes.
Keep out of the reach of children.
Effects of short-term
overexposure: Vapors cause irritation to the eyes, nose, throat, skin, and central nervous system. Symptoms may
include dizziness, throat irritation, headache, fatigue,swelling of eyes, and nausea.
Effects of chronic
overexposure: May cause permanent brain and nervous system damage. Repeated overexposure can also damage
kidneys, lungs, liver, heart, and blood. Intentional misuse by deliberately inhaling the contents may
be harmful or fatal.
NFPA ratings (scale 0 - 4): Health- 1
Flammability- 3
Reactivity- 3
HMIS-ratings (scale 0 - 4): Health- 1
Flammability- 3
Physical Hazard- 3
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MATERIAL SAFETY DATA SHEET
MSDS Name: Grabber CONCRETE GRAY INVERTED TIP GB20664
Revision Date: January 1, 2010
4. First Aid Measures
After inhalation: Supply fresh air; consult doctor in case of complaints.
After skin contact: Remove contaminated clothing. Wash exposed area with soap and water.
After eye contact: Move to fresh air. Rinse opened eye for several minutes under running water. If symptoms persist,
consult a doctor.
After swallowing: Contact physician or poison control center.
5. Fire Fighting Measures
Extinguishing agents: CO2, sand, extinguishing powder, or water spray. Fight larger fires with water spray or alcohol
resistant foam.
Protective equipment: No special measures required.
6. Accidental Release Measures
Personal safety
Precautions: Wear protective equipment. Keep unprotected persons away.
Environmental safety
precautions: Inform appropriate authorities in case of seepage into water course or sewage system.
Do not allow product to reach sewage systems or ground water.
Measures for cleaning/
collecting: Do not flush with water or aqueous cleansing agents. Use diluted caustic solution. Soak up
spills with inert absorbent material. Refer to section 13 for disposal information.
7. Handling and Storage
Fire/explosion protection: Do not smoke. Protect from electrostatic charges.
Storage requirements: Observe pressurized container storage regulations. Consult with your local authorities.
Keep away from sources of heat and direct sunlight. Do not warehouse in subfreezing
conditions.
8. Exposure Controls/Personal Protection
Components with limit values that require monitoring at the workplace:
106-97-8 n-butane
REL 1900 mg/m? 800 ppm
Protective hygienic measures: Keep away from foodstuffs and animal feed. Wash hands after use.
Breathing equipment: Use suitable respiratory protective device in case of insufficient ventilation. A respirator is
generally not necessary when using this product outdoors or in large open areas. In cases
of inadequate ventilation, a respiratory protective device should be worn to prevent
overexposure.
Protection of hands: Protective gloves. The glove material has to be impermeable and resistant to the substance.
No glove recommendation can be given.
Eye protection: Tightly sealed goggles
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MATERIAL SAFETY DATA SHEET
MSDS Name: Grabber CONCRETE GRAY INVERTED TIP GB20664
Revision Date: January 1, 2010
9. Physical and Chemical Properties
General Information:
Form: Aerosol
Color: According to trade name description in section 1.
Odor: Solvent
Boiling point/Boiling range: -44癈 (-47癋)
Flash point: -19癈 (-2癋)
Ignition temperature: 365.0癈 (689癋)
Auto igniting: Product is not self-igniting.
Danger of explosion: Stable at normal temperatures. Can may burst when exposed to temperatures exceeding
120 degrees fahrenheit. In use, may form flammable/explosive vapour-air mixture.
Lower Explosion Limit: 0.9 Vol %
Upper Explosion Limit: 10.9 Vol %
Vapor Pressure: 40 PSI, 2750 hPa
Density at 20癈 (68癋): 0.82884 g/cm?br>
Specific Gravity: Between 0.77 and 0.85 (Water equals 1.00)
VOC content: 533.6 g/l / 4.45 lb/gl
VOC content
(less exempt solvents): 52.6 %
Water: 22.1 %
Solids content: 24.3 %
10. Stability and Reactivity
Conditions to be avoided: Do not allow the can to exceed 120 degrees Fahrenheit. Stable at normal temperatures.
Possibility of Hazardous
Reactions: No dangerous reactions known.
11. Toxicological Information
Primary effect on the skin: No irritant effect.
Primary effect on the eye: Irritating effect.
Sensitization: No sensitizing effects known.
12. Ecological Information
Other information: This product does not contain any chloroflourocarbons (CFC's),chlorinated solvents, lead, mercury,
cadmium, hexavalent chromium, polybrominated biphenyl (PBB), or polybrominated diphenyl ether
(PDBE). No specific ecological data is available for this product.
Acquatic toxicity: Hazardous for water, do not empty into drains.
13. Disposal Considerations
DISPOSAL METHOD: Dispose of in accordance with local, state, and federal regulations. Do not puncture, incinerate, or
compact. Partially empty cans must be disposed of responsibly. Do not heat or cut empty containers with
electric or gas torches.
Recommendation: Empty cans should be recycled.
14. Transportation Information
Hazard class: 2.1
Identification number: N/A
Label: 2.1
ADR/RID class: 2 5F Gases
UN-Number: 1950
IMDG Class: 2.1
Packaging group: II
EMS Number: F-D,S-U
Marine pollutant: No
ICAO/IATA Class: 2.1
Propper shipping name: Aerosols, Flammable, Consumer Commodity ORM-D
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MATERIAL SAFETY DATA SHEET
MSDS Name: Grabber CONCRETE GRAY INVERTED TIP GB20664
Revision Date: January 1, 2010
15. Regulatory Information
SARA Section 355 (extremely hazardous substances):
None of the ingredients in this product are listed.
SARA Section 313 (Specific toxic chemical listings):
None of the ingredients is listed.
TSCA (Toxic Substances Control Act):
All ingredients are listed.
PROPOSITION 65 Chemicals known to cause cancer:
100-41-4 ethyl benzene
1333-86-4 Carbon black
Canadian WHMIS: Class A, B5---Flammable Aerosols
EPA: A= Known human carcinogen
B= Probable human carcinogen
C= Possible human carcinogen
D= Not classifiable as to human carcinogenicity: Inadequate human and animal evidence of
carcinogenicity (or no data is available).
A= Known human carcinogen B= Probable human carcinogen
C= Possible human carcinogen
D= Not classifiable as to human carcinogenicity: Inadequate human and animal evidence of carcinogenicity (or no data is
available).
IARC: Group 2B: The ingredient is possibly carcinogenic to humans. There is limited evidence of
carcinogenicity.
Group 3: The ingredient is unclassifiable as to its carcinogenicity to humans.
13463-67-7 titanium dioxide 2B
ACGIH TLVs: A1-designates a confirmed human carcinogen.
A2-designates a suspected human carcinogen.
A3-designates an animal carcinogen.
A4-designates "not classifiable as a human carcinogen".
13463-67-7 titanium dioxide A4
NIOSH:
13463-67-7 titanium dioxide
1333-86-4 Carbon black
16. Other Information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product
features and shall not establish a legally valid contractual relationship.
Contact: Regulatory Affairs
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