CHEMTREC Transportation
Emergency Phone: 800-424-
9300
Material Safety Pittsburgh Poison Control
Center
Health Emergency No.: 412-
Data Sheet 681-6669
NOTE: The CHEMTREC Transportation
Emergency Phone is to be used only in the
event of chemical emergencies involving a
spill, leak, fire, exposure or accident involving
chemicals
Section 1 - Chemical Product / Company Information
NULLIFIRE S607 Revision Date: 03/19/2008
Product Name:
Identification
PLMSDS 0117S7NL Supercedes : 10/31/2006
Number:
Waterborne Intumescent Basecoat for
Product
Fireproofing - FOR INDUSTRIAL
Use/Class:
USE ONLY
Regulatory, Department
Preparer:
Manufacturer: Carboline Company
350 Hanley Industrial Ct.
St. Louis, MO 63144
Section 2 - Composition / Information On Ingredients
Chemical Name CAS Number Weight % Less Than ACGIH TLV-TWA ACGIH TLV-STEL OSHA PEL-TWA OSHA-CEIL
PENTAERYTHRITOL 115-77-5 10.0 15 MG/M3 N/E N/E N/E
STODDARD SOLVENT 8052-41-3 5.0 100 PPM N/E 500 PPM N/E
ZINC BORATE 138265-88-0 5.0 10 MG/M3 NE NE NE
Section 3 - Hazards Identification
Emergency Overview: Use ventilation necessary to keep exposures below recommended exposure limits, if
any.
Effects Of Overexposure - Eye Contact: May cause eye irritation.
Effects Of Overexposure - Skin Contact: May cause skin irritation.
Effects Of Overexposure - Inhalation: Harmful if inhaled, may affect the brain or nervous system, causing
dizziness, headache, or nausea. May cause nose and throat irritation. Use in inadequately ventilated areas
may result in irritation headache and nausea.
Effects Of Overexposure - Ingestion: May be harmful if swallowed.
Effects Of Overexposure - Chronic Hazards: Reports have associated repeated and prolonged
occupational overexposure to solvents with permanent brain and nervous system damage. Under normal use
conditions, this product is not expected to cause adverse health effects.
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Primary Route(s) Of Entry: Skin Contact, Skin Absorption, Inhalation, Ingestion, Eye Contact
Medical Conditions Prone to Aggravation by Exposure: If you have a condition that could be aggravated
by exposure to dust or organic vapors, see a physician prior to use.
Section 4 - First Aid Measures
First Aid - Eye Contact: If material gets into eyes, flush with water immediately for 15 minutes. Consult a
physician.
First Aid - Skin Contact: Launder clothing before reuse. In case of contact, wash skin immediately with soap
and water.
First Aid - Inhalation: If inhaled, remove to fresh air. Administer oxygen if necessary. Consult a physician if
symptoms persist or exposure was severe.
First Aid - Ingestion: If swallowed do not induce vomiting. Seek immediate medical attention.
Section 5 - Fire Fighting Measures
Flash Point, F: 142F (61C) Lower Explosive Limit, %: 0.9
Upper Explosive Limit, %: 7.8
(Setaflash)
Extinguishing Media: Carbon Dioxide, Dry Chemical, Foam, Water Fog
Unusual Fire And Explosion Hazards: This is a water based product, however it does contain small amounts
of volatile organic compounds (See Section II). Vapors are heavier than air and will accumulate. Vapors will
form explosive concentrations with air. Vapors travel long distances and will flashback.
Special Firefighting Procedures: Evacuate hazard area of unprotected personnel. Use a NIOSH approved
self-contained breathing unit and complete body protection. Cool surrounding containers with water in case of
fire exposure.
Section 6 - Accidental Release Measures
Steps To Be Taken If Material Is Released Or Spilled: Eliminate all ignition sources. Handling equipment
must be grounded to prevent sparking. Evacuate the area of unprotected personnel. Wear appropriate
personal protection clothing and equipment. Follow exposure controls/personal protection guidelines in Section
8. Contain and soak up residual with an aborbent (clay or sand). Take up absorbant material and seal tightly
for proper disposal. Dispose of in accordance with local, state and federal regulations. Refer to Section 15 for
SARA Title III and CERCLA information.
Section 7 - Handling And Storage
Handling: Do not get in eyes, on skin, or on clothing. Keep container tightly closed when not in use. Wear
personal protection equipment. Do not breathe vapors. Wash thoroughly after handling. If pouring or
transferring materials, ground all containers and tools. Do not weld, heat, cut or drill on full or empty containers.
Use only in accordance with Carboline application instructions, container label and Product Data Sheet.
Storage: Protect from Freezing! Keep away from heat, sparks, open flames and oxidizing agents. Keep
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containers closed. Store in a cool, dry place with adequate ventilation.
Section 8 - Exposure Controls / Personal Protection
Engineering Controls: Use explosion-proof ventilation when required to keep below health exposure
guidelines and Lower Explosion Limit (LEL).
Respiratory Protection: Use only with ventilation to keep levels below exposure guidelines listed in Section 2.
User should test and monitor exposure levels to ensure all personnel are below guidelines. If not sure, or not
able to monitor, use MSHA/NIOSH approved supplied air respirator. Follow all current OSHA requirements for
respirator use. For silica containing coatings in a liquid state, and/or if no exposure limits are established in
Section 2 above, supplied air respirators are generally not required.
Skin Protection: Recommend impervious gloves and clothing to avoid skin contact. If material penetrates to
skin, change gloves and clothing. The use of protective creams may be beneficial to certain individuals.
Protective creams should be applied before exposure.
Eye Protection: Recommend safety glasses with side shields or chemical goggles to avoid eye contact.
Other protective equipment: Eye wash and safety showers should be readily available.
Hygienic Practices: Wash with soap and water before eating, drinking, smoking, applying cosmetics, or using
toilet facilities. Use of a hand cleaner is recommended. Launder contaminated clothing before reuse. Leather
shoes can absorb and allow hazardous materials to pass through. Check shoes carefully after soaking before
reuse. Contaminated clothing should be changed and washed before reuse. Eating, drinking and smoking in
immediate work area should be prohibited.
Section 9 - Physical And Chemical Properties
97 F (36 C) - 626 F (330 C) Heavier than Air
Boiling Range: Vapor Density:
Ammoniacal N/D
Odor: Odor Threshold:
White Liquid Slower Than Ether
Appearance: Evaporation Rate:
N/D
Solubility in H2O:
N/D 1.36
Freeze Point: Specific Gravity:
N/D N/D
Vapor Pressure: PH:
Liquid
Physical State:
(See section 16 for abbreviation legend)
Section 10 - Stability And Reactivity
Conditions To Avoid: Heat, sparks and open flames.
Incompatibility: Avoid contact with strong oxidizing agents.
Hazardous Decomposition Products: Carbon monoxide, nitrogen oxides, and unidentified organic
compounds. Consider all smoke and fumes from burning material as very hazardous. Welding, cutting or
abrasive grinding can create smoke and fumes. Do not breathe any fumes or smoke from these operations.
Hazardous Polymerization: Will not occur under normal conditions.
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Stability: This product is stable under normal storage conditions.
Section 11 - Toxicological Information
Product LD50: N/D Product LC50: N/D
Chemical Name CAS Number LD50 LC50
PENTAERYTHRITOL 115-77-5 >19500 MG/KG, ORAL RAT NOT AVAILABLE
STODDARD SOLVENT 8052-41-3 NOT AVAILABLE NOT AVAILABLE
ZINC BORATE 138265-88-0 >10000 MG/KG ORAL RAT NE
Section 12 - Ecological Information
Ecological Information: No data
Section 13 - Disposal Information
Disposal Information: Dispose of in accordance with State, Local, and Federal Environmental regulations.
Responsibility for proper waste disposal is with the owner of the waste.
Section 14 - Transportation Information
Not Regulated Packing Group: N/A
DOT Proper Shipping
Name:
N/A Hazard Subclass:N/A
DOT Technical Name:
None N/A
DOT Hazard Class: Resp. Guide
Page:
None
DOT UN/NA Number:
Additional Notes: None.
Section 15 - Regulatory Information
CERCLA - SARA HAZARD CATEGORY
This product has been reviewed according to the EPA Hazard Categories promulgated under Sections 311and
312 of the Superfund Amendment and Reauthorization Act of 1986 (SARA Title III) and is considered, under
applicable definitions, to meet the following categories:
IMMEDIATE HEALTH HAZARD, CHRONIC HEALTH HAZARD
SARA SECTION 313
This product contains the following substances subject to the reporting requirements of Section 313 of Title III
of the Superfund Amendment and Reauthorization Act of 1986 and 40 CFR part 372:
No Section 313 Substances exist in this product
TOXIC SUBSTANCES CONTROL ACT
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All components of this product are listed on the TSCA inventory.
This product contains the following chemical substances subject to the reporting requirements of TSCA 12(B) if
exported from the United States:
Chemical Name CAS Number
N-PENTANE(ENCAPSULATED) 109-66-0
n-HEPTANE 142-82-5
NONANE 111-84-2
U.S. STATE REGULATIONS AS FOLLOWS:
NEW JERSEY RIGHT-TO-KNOW
The following materials are non-hazardous, but are among the top five components in this product.
Chemical Name CAS Number
WATER 7732-18-5
AMMONIUM POLYPHOSPHATE 68333-79-9
HOMOPOLYMER DISP. MIXTURE
TITANIUM DIOXIDE 13463-67-7
MELAMINE 108-78-1
PENNSYLVANIA RIGHT-TO-KNOW
The following non-hazardous ingredients are present in the product at greater than 3%.
Chemical Name CAS Number
WATER 7732-18-5
AMMONIUM POLYPHOSPHATE 68333-79-9
HOMOPOLYMER DISP. MIXTURE
TITANIUM DIOXIDE 13463-67-7
MELAMINE 108-78-1
PLASTICIZER TRADE SECRET
CALIFORNIA PROPOSITION 65
Warning: The following ingredients present in the product are known to the state of California to cause
Cancer:
Chemical Name CAS Number
PLASTICIZER TRADE SECRET
ETHYL BENZENE 100-41-4
NAPHTHALENE 91-20-3
Warning: The following ingredients present in the product are known to the state of California to cause
birth defects, or other reproductive hazards:
No California Proposition 65 Reproductive Toxins exist
INTERNATIONAL REGULATIONS AS FOLLOWS:
CANADIAN WHMIS
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This MSDS has been prepared in compliance with Controlled Product Regulations except for the use of the 16
headings.
CANADIAN WHMIS CLASS: B3 D2B
Section 16 - Other Information
HMIS Ratings
Health: 2 Flammability: 1 Reactivity: 0 Personal Protection: X
VOLATILE ORGANIC COMPOUNDS, GR/LTR MIXED (UNTHINNED): 53
REASON FOR REVISION: Changes made in Section 2.
Legend: N.A. - Not Applicable, N.E. - Not Established, N.D. - Not Determined
The information contained herein is, to the best of our knowledge and belief accurate. However, since the
conditions of handling and use are beyond our control, we make no guarantee of results, and assume no
liability for damages incurred by use of this material. It is the responsibility of the user to comply with all
applicable federal, state, and local laws and regulations
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