Material Safety Data Sheet
1. Chemical product and company identification
Product name WS3-908H
MSDS# 01113
Code 01113-AE
Product use Lubricant
Manufacturer Castrol Industrial North America, Inc.
150 W. Warrenville Road
Naperville, IL 60563
Supplier Castrol Industrial North America, Inc.
150 W. Warrenville Road
Naperville, IL 60563
Product Information: 1-800-621-2661
EMERGENCY SPILL 1 (800) 424-9300 CHEMTREC (USA)
INFORMATION:
2. Composition/information on ingredients
Ingredient name CAS # % by weight
Distillates (petroleum), solvent-dewaxed heavy paraffinic (Highly refined 64742-65-0 35 - 40
mineral oil)
triethanolamine 102-71-6 5 - 10
fatty acids, tall-oil, compds. with 2-amino-2-methyl-1-propanol 67701-21-7 5 - 10
2-Amino-2-methylpropanol 124-68-5 1-5
alcohols C12 - 15 63393-82-8 1-5
Oxazolidine,4,4-Dimethyl- 51200-87-4 0.1 - 1
3-Iodo-2-propynyl butylcarbamate 55406-53-6 0.1 - 1
3. Hazards identification
Physical state Liquid.
Color Yellow. to Amber.
Emergency overview WARNING!
CAUSES EYE IRRITATION.
CAUSES SKIN IRRITATION.
CAUSES RESPIRATORY TRACT IRRITATION.
Do not ingest. Do not get in eyes, on skin or clothing. In accordance with good industrial hygiene
and safety work practices, airborne exposures should be controlled to the lowest extent practicable.
Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling.
Routes of entry Dermal contact. Eye contact. Inhalation. Ingestion.
Potential Health Effects
Eyes Causes eye irritation.
Skin Causes skin irritation.
Inhalation Causes respiratory tract irritation.
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Ingestion Ingestion may cause gastrointestinal irritation and diarrhea.
Medical conditions None identified.
aggravated by
overexposure
See toxicological Information (section 11)
4. First aid measures
Eye Contact In case of contact, immediately flush eyes with plenty of water for at least 15 minutes. Get medical
attention if irritation develops.
Skin Contact Immediately wash exposed skin with soap and water. Remove contaminated clothing and shoes.
Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention if
irritation develops.
Inhalation If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult,
give oxygen. Get medical attention if irritation develops.
Ingestion Do NOT induce vomiting unless directed to do so by medical personnel. Never give anything by
mouth to an unconscious person. Get medical attention if symptoms appear.
5. Fire-fighting measures
Flammability of the product May be combustible at high temperature.
Products of combustion These products are carbon oxides (CO, CO2), nitrogen oxides (NO, NO2...). Some metallic oxides.
Unusual fire/explosion This material is not explosive as defined by established regulatory criteria.
hazards
Non-explosive in presence of open flames, sparks and static discharge, of shocks, of heat.
Fire fighting media and In case of fire, use water fog, foam, dry chemicals, or carbon dioxide.
instructions
Protective clothing (fire) Fire-fighters should wear positive pressure self-contained breathing apparatus (SCBA) and full
turnout gear.
6. Accidental release measures
Personal Precautions Immediately contact emergency personnel. Keep unnecessary personnel away. Use suitable
protective equipment (See Section: "Exposure controls/personal protection"). Follow all fire
fighting procedures (See Section: "Fire-fighting measures").
Environmental If emergency personnel are unavailable, contain spilled material. For small spills add absorbent
precautions and clean-up (soil may be used in the absence of other suitable materials) scoop up material and place in a
sealed, liquid-proof container for disposal. For large spills dike spilled material or otherwise
methods
contain material to ensure runoff does not reach a waterway. Place spilled material in an
appropriate container for disposal. Minimize contact of spilled material with soils to prevent
runoff to surface waterways. See Section 13 for Waste Disposal Information.
Personal protection in Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be
case of a large spill sufficient; consult a specialist BEFORE handling this product.
7. Handling and storage
Handling Do not ingest. Do not get in eyes, on skin or on clothing. Avoid contact with skin and clothing. In
accordance with good industrial hygiene and safety work practices, airborne exposures should be
controlled to the lowest extent practicable. Use only with adequate ventilation. Wash thoroughly
after handling.
Storage Keep container tightly closed. Keep container in a cool, well-ventilated area. Empty containers may
contain harmful, flammable/combustible or explosive residue or vapors. Do not cut, grind, drill,
weld, reuse or dispose of containers unless adequate precautions are taken against these
hazards.
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8. Exposure controls/personal protection
Occupational exposure
limits
Occupational exposure limits
Ingredient name
Distillates (petroleum), solvent-dewaxed ACGIH (United States).
STEL: 10 mg/m3 15 minute(s). Form: Oil mist, mineral
heavy paraffinic (Highly refined mineral oil)
TWA: 5 mg/m3 8 hour(s). Form: Oil mist, mineral
OSHA (United States).
TWA: 5 mg/m3 8 hour(s). Form: Oil mist, mineral
triethanolamine ACGIH TLV (United States, 9/2004).
TWA: 5 mg/m3 8 hour(s).
fatty acids, tall-oil, compds. with 2-amino- None assigned.
2-methyl-1-propanol
2-Amino-2-methylpropanol None assigned.
alcohols C12 - 15 None assigned.
Oxazolidine,4,4-Dimethyl- None assigned.
3-Iodo-2-propynyl butylcarbamate None assigned.
Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
Control Measures
vapors below their respective occupational exposure limits.
Hygiene measures Wash hands after handling compounds and before eating, smoking, using lavatory, and at the
end of day.
Personal protection
Eyes Avoid contact with eyes. Safety glasses with side shields.
Skin and Body Avoid contact with skin and clothing. Wear suitable protective clothing.
Respiratory Use only with adequate ventilation. In accordance with good industrial hygiene and safety work
practices, airborne exposures should be controlled to the lowest extent practicable.
Hands Wear suitable gloves.
Not available.
Consult local authorities for acceptable exposure limits.
9. Physical and chemical properties
Physical state Liquid.
pH 9 to 9.5 at 5%
Odor Mild.
Color Yellow. to Amber.
Specific Gravity 0.94 to 0.96
950 kg/m3 (0.95 g/cm3) at 15.6癈
Density
Solubility Easily soluble in cold water, hot water.
Dispersion properties See solubility in water.
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10. Stability and reactivity
Stability and Reactivity The product is stable.
Conditions to avoid None known.
Incompatibility with Reactive with oxidizing agents.
various substances
Hazardous Decomposition Not available.
Products
Hazardous polymerization Will not occur.
11. Toxicological information
Ingredient name Test Result Route Species
poly(oxy-1,2-ethanediyl), alpha- LD50 >2000 mg/kg Oral Rat
(carboxymethyl)-omega,-
(9-octadecenyloxy)-(z).
3-Iodo-2-propynyl butylcarbamate LD50 1470 mg/kg Oral Rat
LD50 >2000 mg/kg Dermal Rabbit
LC50 6.89 mg/l (4 hour Inhalation Rat
(s))
Chronic toxicity
No component of this product at levels greater than 0.1% is identified as a carcinogen by
Carcinogenic
ACGIH or the International Agency for Research on Cancer (IARC). No component of this
effects
product present at levels greater than 0.1% is identified as a carcinogen by the U.S. National
Toxicology Program (NTP) or the U.S. Occupational Safety and Health Act (OSHA).
No component of this product at levels greater than 0.1% is classified by established regulatory
Mutagenic
criteria as a mutagen.
effects
No component of this product at levels greater than 0.1% is classified by established regulatory
Reproductive
criteria as a reproductive toxin.
effects
No component of this product at levels greater than 0.1% is classified by established regulatory
Teratogenic
criteria as teratogenic or embryotoxic.
effects
Alkanolamine: This product contains an alkanolamine. In all metalworking fluids containing
Other chronic toxicity
amines, there is a potential for forming nitrosamines which are animal carcinogens. Therefore, no
data
nitrites or related nitrosating agents should be added to such compositions.
This product contains a preservative that may release trace amounts of formaldehyde during use.
Employers are required under 29 CFR 1910.1048, Formaldehyde, to determine if formaldehyde
levels exceed 0.1 ppm in the workplace. Employers may be required to provide employee
information and training regarding the hazards of formaldehyde, unless the employer can show,
using objective data, that the employees are not exposed to formaldehyde at or above 0.1 ppm.
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ACGIH STEL=0.3 ppm.
12. Ecological information
Ecotoxicity No testing has been performed by the manufacturer.
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13. Disposal considerations
Waste information Waste must be disposed of in accordance with federal, state and local environmental control
regulations.
RCRA Waste Code(s) USED OIL
Remarks No additional remark.
Consult your local or regional authorities.
14. Transport information
Not classified as hazardous for transport (DOT, TDG, IMO/IMDG, IATA/ICAO)
15. Regulatory information
U.S. Federal regulations US INVENTORY (TSCA): In compliance.
This product is not regulated under Section 302 of SARA and 40 CFR Part 355.
SARA 311/312 MSDS distribution - chemical inventory - hazard identification: WS3-908H :
Immediate (Acute) Health Hazard
SARA 313
Form R - Reporting This product does not contain any hazardous ingredients at or above regulated thresholds.
requirements
Supplier notification This product does not contain any hazardous ingredients at or above regulated thresholds.
CERCLA Sections 102a/103 Hazardous Substances (40 CFR Part 302.4):: This material is not
regulated under CERCLA Sections 103 and 107.
State regulations Florida:triethanolamine
Massachusetts RTK:triethanolamine; 2-Amino-2-methylpropanol; 1H-benzotriazole
Minnesota:triethanolamine
Pennsylvania RTK:triethanolamine (generic environmental hazard); 2-Amino-2-methylpropanol
(generic environmental hazard)
WARNING: This product contains a chemical known to the State of California to cause cancer.
Acetaldehyde; 1,4-dioxane; Formaldehyde
WARNING: This product contains a chemical known to the State of California to cause cancer and
birth defects or other reproductive harm.
Ethylene oxide
Inventories AUSTRALIAN INVENTORY (AICS): Not listed.
CANADA INVENTORY (DSL): Not listed.
CHINA INVENTORY (IECS): Not listed.
EC INVENTORY (EINECS/ELINCS): In compliance.
JAPAN INVENTORY (ENCS): Not listed.
KOREA INVENTORY (ECL): Not determined.
PHILIPPINE INVENTORY (PICCS): Not listed.
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16. Other information
Label Requirements WARNING!
CAUSES EYE IRRITATION.
CAUSES SKIN IRRITATION.
CAUSES RESPIRATORY TRACT IRRITATION.
Health 2
HMIS?Rating : National Fire
1 Fire hazard
Flammability 1 Protection
2 0
Health Instability
Physical 0 Association Specific hazard
Hazard (U.S.A.)
Personal B
protection
Other special PETROLEUM OIL: STEL = 10 mg/M3. Using terminology of the International Agency for
Research on Cancer (IARC), the petroleum distillates listed in Section II are classified by the
considerations
supplier as severely processed. Not all those listed in Section II may be present. The supplier has
stated that these distillates do not require a carcinogen label as defined by OSHA 29 CFR
1910.1200.
History
Date of issue 04/05/2005.
Date of previous issue No Previous Validation.
Prepared by Product Stewardship
Notice to reader
All reasonably practicable steps have been taken to ensure this data sheet and the health, safety and environmental information
contained in it is accurate as of the date specified below. No warranty or representation, express or implied is made as to the
accuracy or completeness of the data and information in this data sheet.
The data and advice given apply when the product is sold for the stated application or applications. You should not use the
product other than for the stated application or applications without seeking advice from us.
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Group shall not be responsible for any damage or injury resulting from use, other than the stated product use of the material,
from any failure to adhere to recommendations, or from any hazards inherent in the nature of the material. Purchasers of the
product for supply to a third party for use at work, have a duty to take all necessary steps to ensure that any person handling or
using the product is provided with the information in this sheet. Employers have a duty to tell employees and others who may be
affected of any hazards described in this sheet and of any precautions that should be taken.
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