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Material Safety Data Sheet
MILFORM?665
STAMPING AND DRAWING FLUID CONCENTRATE
DATE EFFECTIVE: 08-04-2006
1 CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
.
Manufacturer: Milacron Marketing Company, Global Industrial Fluids
3000 Disney Street
Cincinnati, OH 45209 United States
Emergency: Telephone (USA): 1-800-424-9300 (CHEMTREC)
Telephone (Outside USA): 1-703-527-3887 (CHEMTREC)
General Information: Telephone: 1-513-458-8199
Generic Name: Water Soluble Stamping and Drawing Fluid Concentrate
2 EMERGENCY INFORMATION .
Product is combustible. Product is a primary eye irritant. Product may be a primary skin irritant.
Highway spills could result in slippery conditions. No other significant health effects are associated
with this material.
3 POTENTIAL HEALTH EFFECTS OF DIRECT EXPOSURE
.
Product Product at Use Dilution
Inhalation: Container vapor space may contain hydrogen Extended exposure to mist may cause upper
sulfide. May cause respiratory irritation. respiratory irritation.
Eye Contact: Product is a primary eye irritant. Will cause stinging sensation in the eye.
Skin Contact: Product may be a primary skin irritant. Not irritating to the skin when used as directed
and good personal hygiene is practiced.
Ingestion: Not orally toxic. Swallowing small quantities may cause diarrhea,
nausea or vomiting.
Medical Conditions generally aggravated by exposure
May aggravate existing skin irritation where further defatting or skin penetration could occur.
Mild skin irritation (redness and dryness of hands) may be experienced when the diluted product has
been contaminated by certain oils, by dissolved metals, or when mix ratio is too strong. When
problems occur, use of water-resistant barrier creams may be a temporary control measure.
Contact Milacron Marketing Company, Global Industrial Fluids Technical Services at 1-513-458-8199
for specific recommendations.
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When used in applications generating high levels of mist, operator exposure can be minimized by
proper ventilation, use of mist collectors or splash guards, as appropriate. If there is doubt about
actual mist levels present, monitoring should be conducted. Contact Milacron Marketing Company,
Global Industrial Fluids at 1-513-458-8199 for specific recommendations.
Repeated excessive exposures to high amounts of triethanolamine may cause liver and kidney effects.
Based on our experience and the toxicity test results for this product, Milacron Marketing Company,
Global Industrial Fluids believes that it does not subject users to significant health risks, except as
noted above. This product has been formulated using chemicals, each having their own toxicological
properties. It is Milacron Marketing Company, Global Industrial Fluids policy to inform users of the
nature of these properties, even if they are not relevant to use in the finished product.
Toxicology testing is done by exposing animals to increasing doses of a chemical and noting the level
at which an injury or discomfort is observed. The purpose of the test is to determine if a toxic effect
may exist. Every chemical that is tested will show an adverse effect of some kind. Even water is toxic
at some level. When reviewing toxicity data, the focus should not be the toxic effect itself, but the
exposure level that caused the effect and the margin of safety between the toxic exposure level and
the level of exposure expected during product use. As a rule of thumb, the margin of safety (the ratio of
the no effect level in animals to the expected workplace exposure) when applying animal data to
human exposure should be 100 or greater. This gives a safety factor to account for differences
between animal responses and to allow for differing susceptibilities between individuals.
The NIOSH Recommended Exposure Limit for metalworking fluid mist is 0.5 mg/m? The safety
factors given below are based on the assumption that this is the worst-case exposure to this product.
Toxicity Test Results for components:
Olefin sulfide:
The manufacturer has established a recommended exposure limit of 1 mg/m?TWA for the sulfide. At
a total mist level of 0.5 mg/m? the potential exposure to olefin sulfide would be less than 0.08 mg/m?
In a four-week inhalation study, small increases in liver, adrenal and spleen weights were observed. A
no effect level of 50 mg/m?was observed in the study (margin of safety = 667 ). No pathological
effects were observed in these organs and the organ weight effects were found to be reversible.
The 4-hour LC50 for inhalation exposure in both sexes of mice and guinea pigs exceeds 4,300 mg/m?
giving a margin of safety of over 57,333 .
After a six-hour inhalation exposure at a concentration of 500 mg/m? more than half the female rats
but none of the male rats exposed died. The projected workplace exposure level to the olefin sulfide is
0.08 mg/m? The toxic effects were observed at 6,667 times workplace exposure levels.
Carcinogen Listings: NTP: No IARC: No OSHA: No
Signs and symptoms of exposure
Acute
Eye injury may result from contact with product. Skin irritation can result from improper use and
handling of product.
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4 EMERGENCY AND FIRST AID PROCEDURES
.
Eyes
In case of eye contact, flush immediately with running water for at least 15 minutes, and get prompt
medical attention.
Skin Contact
For skin contact flush with large amounts of water while removing contaminated clothing. Remove
contaminated shoes and clothing and launder before reuse. If irritation persists, get medical attention.
Diluted product is not irritating to the skin when used as recommended and good personal hygiene is
practiced.
Ingestion
If the material is swallowed, get immediate medical attention or advice. DO NOT INDUCE VOMITING.
Give two glasses of water or milk. Immediately contact a physician and obtain treatment. Swallowing
small quantities of diluted product may cause nausea, diarrhea or abdominal distress.
Inhalation
Inhalation can occur in applications where high mist levels are generated. OSHA has set a PEL of 15
mg/m?for any airborne particulate as a nuisance level of exposure. NIOSH has set a REL of 0.5 mg/m?br>
for metalworking fluid mist. If symptoms are experienced, remove source of contamination or move
victim to fresh air. If symptoms persist, get medical attention.
5 CONTROL MEASURES .
Respiratory protection
Product is not volatile.
In applications where time-weighted exposures are 0.5 to 5 mg/m? mist reduction through improved
ventilation, mist collection or process modification is recommended by NIOSH. Where this is not
possible, NIOSH recommends the use of any air purifying, half-mask respirator including a disposable
respirator, equipped with any P- or R-series particulate filter. If the average exposure will exceed 5
mg/m? NIOSH recommends use of a powered, air-purifying respirator equipped with a hood or helmet
and a HEPA filter. If respiratory problems are present when mist levels are < 0.5 mg/m? respiratory
protection should be based on the individual recommendation of a qualified health care provider.
Caution
The appropriate use and type of respirator is dependent upon use of the product and local operating
conditions.
Ventilation
For most applications, normal shop ventilation is adequate. However, when high mist levels are
generated or where machines are close together or ventilation is inadequate, operators may experience
respiratory irritation. For such applications, use of splash guards or mist collectors is recommended.
Eye protection
Proper metalworking plant eye protection required when handling product concentrate.
Other protective clothing or equipment
Use effective metalworking plant protective clothing as appropriate.
Work / Hygiene Practices
Good personal hygiene should always be followed.
Protective Gloves
Impervious gloves, such as nitrile gloves, are recommended when handling product concentrate.
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6 HAZARDOUS INGREDIENTS / IDENTITY INFORMATION
.
These ingredients may contribute to the acute product hazards listed under the Potential Health
Effects section. Other substances, not hazardous under the OSHA Hazard Communication
Standard, may be present. Further composition information may be available to health professionals
as provided in the Standard.
Component CAS # Percent
SEVERELY-HYDROTREATED NAPHTHENIC 64742-52-5 15 - 40
PETROLEUM DISTILLATES
SODIUM ALKYLBENZENE SULFONATE 78330-12-8 7 - 13
PETROLEUM SULFONIC ACID, SODIUM 68608-26-4 1-5
SALT
AMINOMETHYLPROPANOL 124-68-5 1-5
7 FIRE AND EXPLOSION HAZARD DATA
.
Extinguishing Media
Chemical foam, carbon dioxide, or dry chemical
Hazardous Combustion Products
Smoke, fumes, oxides of nitrogen, hydrogen chloride, oxides of sulfur, and oxides of carbon
Flash Point: 315 癋 (157.2 癈) Cleveland Open Cup
Lower Explosive Limit: Not Applicable
Upper Explosive Limit: Not Applicable
HMIS RATINGS
Health 1
Flammability Classification 1
Reactivity 0
NFPA RATINGS
Health 1
Flammability Classification 1
Reactivity 0
8 ACCIDENTAL RELEASE MEASURES
.
Contain the spill, collect on absorbent material, and discard as dictated by Federal, state and local
regulations that may apply. Flush area thoroughly with water.
Reportable Quantity: None
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9 WASTE DISPOSAL .
For Used Product
Disposal procedures must comply with local, county, state and Federal regulations. If pre-treatment is
needed, ultrafiltration, emulsion breaking or evaporation may be used. Contact Milacron Marketing
Company, Global Industrial Fluids at 1-513-458-8199 for assistance.
For Unused Product
Product is not a hazardous waste as defined under 40 CFR 261. Contact Milacron Marketing Company,
Global Industrial Fluids at 1-513-458-8199 for assistance.
Empty Containers
Empty containers will contain a residue which is not considered a hazardous waste under RCRA
regulations. Drums can be drained to a "drip dry" condition by inversion and can be offered for
recycling or scrap.
CAUTION: Empty containers retain residue (liquid and/or vapor) and may be dangerous. DO NOT
PRESSURIZE, CUT, WELD, BRAZE, SOLDER, DRILL, GRIND, OR EXPOSE THIS CONTAINER TO
HEAT, FLAME, SPARKS OR OTHER SOURCES OF IGNITION: IT MAY EXPLODE AND CAUSE
INJURY OR DEATH. Do not attempt to clean drums since residue is difficult to remove. Empty drums
should be completely drained, promptly bunged, and promptly returned to a drum reconditioner. Empty
disposable bulk containers should be drained, sealed, and properly discarded. Empty recyclable bulk
containers should be drained, sealed, and recycled. Empty pails and jugs should be drained and
properly discarded.
10 HANDLING AND STORAGE.
Avoid all contact of product with eyes or skin. Wash thoroughly after handling. Do not swallow. Do not
store product concentrate in direct sunlight or elevated temperatures. Use only as recommended by
Milacron Marketing Company, Global Industrial Fluids . If frozen, thaw completely at room temperature
prior to use.
Other Precautions
Product is combustible. Do not heat. Avoid open flames, sparks, and temperatures approaching the
flash point. Contains amines. Do not add sodium nitrite or other nitrosating agents to this product
because suspected cancer-causing nitrosamines may be formed.
11 PHYSICAL / CHEMICAL CHARACTERISTICS
.
Boiling Point: Not Applicable
Specific Gravity: 1.02
Evaporation Rate: Like water when diluted
Solubility (H2O): 100 % Miscible
Volatile Organic Content (by 8 %
ASTM D2369):
pH (Concentrate): Not Applicable
pH (Mix): 9.2 @ 20%
Recommended Starting 10 - 40%
Dilution:
Appearance/Odor: Clear/Chemical
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12 REACTIVITY .
Stability
Stable under normal conditions.
Conditions to avoid
Use as directed.
Materials to avoid
Avoid contact with strong acids or oxidizers to product. May react with corroding cast, gray, nodular, or
other high iron containing swarf or chips to form potentially hazardous levels of hydrogen sulfide.
Hazardous Polymerization
Will not occur.
Combustion Products
Smoke, fumes, oxides of nitrogen, hydrogen chloride, oxides of sulfur, and oxides of carbon
13 TRANSPORTATION INFORMATION
.
BY LAND
Hazardous Materials Description and Proper Shipping Name (49 CFR 172.101)
Not a Hazardous Material
U.S. Harmonized Tariff Code: 3403.99.0000
BY AIR OR VESSEL
Hazardous Materials Description and Proper Shipping Name (49 CFR 172.101)
Not a Hazardous Material
14 REGULATORY INFORMATION
.
EXPOSURE GUIDELINES
REGULATED MATERIAL NIOSH REL OSHA PEL OSHA STEL ACGIH TLV ACGIH STEL
METALWORKING FLUID MIST 0.5 mg/m?br>
MINERAL OIL (MIST) 5 mg/m? 5 mg/m? 5 mg/m?br>
CERCLA
No components of this product are present at levels which require reporting under 40 CFR 302.4.
None
EPCRA (SARA) TITLE III Extremely Hazardous Substances (302):
Hazardous Substances (311/312)
Product is a hazardous substance as defined under the OSHA Hazard Communication Standard and
may be reportable under the provisions of SARA Sections 311 and 312.
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HAZARD CATEGORIES
Acute Health: Yes
Chronic Health: No
Fire: Yes
Sudden Release of Pressure: No
Reactive: No
RCRA
Product concentrate does not meet the definition of a hazardous waste as defined under 40 CFR 261.
It is possible that in use, the product may be contaminated by metals or by chlorinated solvents and the
final waste may meet the TCLP definition. Each facility should assess each waste stream to determine
if the used fluid should be treated as a hazardous waste.
TSCA
The ingredients of this product are on the TSCA inventory.
State Right to Know
Many states have enacted Community Right-To-Know laws which require information beyond that
mandated by federal laws. Since some of these laws are inconsistent with the federal laws, the
information in this sheet may not fully meet the requirements of every state.
Toxic Substances (313)
Component CAS # Max % Comments
None %
GLOSSARY OF ABBREVIATIONS
ACGIH American Conference of Governmental Industrial Hygenists
CAS Chemical Abstracts Service
CERCLA Comprehensive Environmental Response Compensation and Liability Act
CFR Code of Federal Regulations
COC Cleveland Open Cup
DOT Department of Transportation
EPCRA Emergency Planning and Community Right-to-Know Act (aka SARA)
IARC International Agency for Research on Cancer
NIOSH National Institute for Occupational Safety and Health
NTP National Toxicology Program
OSHA Occupational Safety and Health Administration
PEL Permissible Exposure Limit
RCRA Resource Conservation and Recovery Act
REC Recommended
REL Recommended Exposure Limit
SARA Superfund Amendments and Reauthorization Act
STEL Short-Term Exposure Limit
TCLP Toxicity Characteristics Leaching Procedure
TLV Threshold Limit Value
TSCA Toxic Substances Control Act
VOC Volatile Organic Compounds
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Disclaimer
NOTE: The opinions expressed herein are those of qualified experts within Milacron Marketing
Company, Global Industrial Fluids and of their suppliers. We believe that the information contained
herein is current as of the date of this Material Safety Data Sheet. Since the use of this information and
of these opinions and the condition and use of the product are not within the control of Milacron
Marketing Company, Global Industrial Fluids , it is the user's obligation to determine the conditions of
safe use of the product.
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