Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, United States, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5965 - 6003
Page 1 of 15
MSDS Preparation Date: January 8, 2010
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
SUPERSATURATED
:
Product Name
Supersaturated Red (No. 5965)
Supersaturated Green Shoe Blue (No.5968)
Supersaturated Ultra Blue (No.5969)
Supersaturated Chrome Green (No.5971)
Supersaturated Emerald Green (No.5972)
Supersaturated Phthalo Green (No.5973)
Supersaturated Imperial Green (No. 5974)
Supersaturated Magenta (No.5975)
Supersaturated Brilliant Red (No. 5976)
Supersaturated Spectrum Red (No.5977)
Supersaturated Purple (No.5979)
Supersaturated Iron Red (No.5980)
Supersaturated Chrome Yellow (No.5981)
Supersaturated Yellow Ochre (No.5982)
Supersaturated Raw Sienna (No.5983)
Supersaturated Orange (No.5984)
Supersaturated Burnt Umber (No.5985)
Supersaturated Raw Umber (No.5986)
Supersaturated Burnt Sienna (No.5987)
Supersaturated Lemon Yellow (No.5988)
Supersaturated Prussian Blue (No.5990)
Supersaturated Navy Blue (No.5991)
Supersaturated Paynes Gray (No. 5992)
Supersaturated Leather (No.5993)
Supersaturated Grass Green (No.5994)
Supersaturated Cerulean Blue (No.5996)
Supersaturated Hunter Green (No.5997)
Supersaturated Van Dyke Brown (No.5998)
Supersaturated Base - Neutral (No.6001)
Supersaturated Base - White (No. 6002)
Supersaturated Base - Velour Black (No.6003)
: Paint
Product Use
Mixture.
Chemical Family :
Supplier's name and address:
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, United States
06902
24 Hr. Emergency Tel # (800) 424-9300
:
:
*- Chronic hazard 0 - Minimal 1 - Slight 2 - Moderate 3 - Serious 4 - Severe
HMIS Rating
Health: *1 Flammability: 1 Reactivity: 0
WHMIS Classes:
TOXIC
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, United States, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5965 - 6003
Page 2 of 15
MSDS Preparation Date: January 8, 2010
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
OSHA PEL
ACGIH TLV
TWA STEL PEL STEL
Ingredients % (weight)
CAS #
Supersaturated - Brilliant Red
3.00 - 7.00
Silica, crystalline quartz, N/Av
14808-60-7 0.025 mg/m? (10)/(%SiO2 N/Av
respirable dust (respirable + 2) mg/m3
fraction)
Supersaturated - Paynes Gray
0.00 - 0.00
Iron oxide red N/Av
1309-37-1 5 mg/m? 10 mg/m? N/Av
(respirable
fraction)
Supersaturated - Paynes Gray
Supersaturated - Imperial Green
0.10 - 1.00
Carbon black N/Av
1333-86-4 50 ppm (240
20 ppm N/Av
mg/m3)
(skin)
Supersaturated Base - Velour Black
3.00 - 7.00
Silica, crystalline-cristobalite N/Av
14464-46-1 0.025 mg/m3 N/Av N/Av
Supersaturated Burnt Umber
1.00 - 5.00
Manganese dioxide N/Av
1313-13-9 N/Av N/Av N/Av
Supersaturated Chrome Green
15.00 - 40.00
Chrome oxide N/Av
1308-38-9 N/Av N/Av N/Av
Supersaturated Chrome Yellow
1.00 - 5.00
Silica, crystalline-cristobalite N/Av
14464-46-1 0.025 mg/m3 N/Av N/Av
0.50 - 1.50
Glycol ether N/Av
111-46-6 N/Av N/Av N/Av
Supersaturated Green Shoe Blue,
Supersaturated Emerald Green,
Supersaturated Navy Blue, Supersaturated
Grass Green
1.00 - 5.00
Propylene glycol N/Av
57-55-6 N/Av N/Av N/Av
Supersaturated Hunter Green
5.00 - 10.00
Silica, crystalline-cristobalite N/Av
14464-46-1 0.025 mg/m3 N/Av N/Av
Supersaturated Lemon Yellow,
Supersaturated Van Dyke Brown,
Supersaturated Base - Neutral
0.10 - 1.00
Silica, crystalline-quartz N/Av
14808-60-7 (10)/(%SiO2
0.025 mg/m3 N/Av
+ 2) mg/m3
Supersaturated Phthalo Green
0.50 - 1.50
1-Propanol, 2-amino-2-methyl- 124-68-5
Supersaturated White
0.00 - 0.00
No hazardous ingredients N/Av
N/Av N/Av N/Av N/Av
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, United States, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5965 - 6003
Page 3 of 15
MSDS Preparation Date: January 8, 2010
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Liquid. Multiple colors. Irritating to eyes, respiratory system and skin. Harmful if inhaled or swallowed Contains material which can cause
cancer.
***POTENTIAL HEALTH EFFECTS***
: None reported by the manufacturer.
Target organs
: Inhalation: YES Skin Absorption: YES Skin & Eyes:YES Ingestion: YES
Routes of exposure
Potential acute health effects :
Causes eye irritation. May cause conjunctivitis, irritation, and inflammation of mucous membranes. May cause
Eyes:
burning sensation, redness and tearing (watering). Possible severe irritation.
Skin: Irritating to skin. Possible irritation, defatting or dermatitis (rash). Components of the product may be absorbed into the
body through the skin. May cause central nervous system depression.
Inhalation: Can cause irritation of the respiratory tract. Prolonged exposure to vapors may be harmful to health. If higher
concentrations are inhaled, additional symptoms may include coughing, shortness of breath, headache, nausea,
vomiting, dizziness, drowsiness and other central nervous system effects. May cause mucous membrane irritation.
Other adverse effects: Asphyxia. Severe lung irritation or lung damage, loss of appetite. Sanding and grinding dusts
may be harmful if inhaled. Contains particles which may cause lung damage if inhaled in large quantities.
Ingestion: Lung aspiration hazard. This product may be aspirated (inhaled) into the lungs during ingestion. May cause lung
inflammation. May cause mucous membrane irritation. Ingestion may cause symptoms similar to inhalation. May
cause gastrointestinal irritation. Gastrointestinal irritation may include abdominal pain, nausea, diarrhea and vomiting.
Other adverse effects: intoxication.
Potential chronic health effects
: Prolonged skin contact may defat the skin and produce dermatitis. May cause allergic skin
reaction. Harmful by skin absorption. May cause central nervous system depression.
Prolonged inhalation of vapors may cause lung damage, including chronic bronchitis.
Contains crystalline silica; prolonged exposure by inhalation of particles can cause serious
lung damage, including silicosis.
Medical conditions aggravated by overexposure
: None expected, when used as intended.
Additional health hazards : Exposure to respirable silica is not possible under normal conditions of use. Crystalline
Silica has been classified as a carcinogen in dry powder form only.
Potential environmental effects
: None reported by the manufacturer.
SECTION 4 - FIRST AID MEASURES
: If breathed in, move person into fresh air. If breathing has stopped, give artificial respiration.
Inhalation
If breathing is difficult, give oxygen by qualified medical personnel only. Seek immediate
medical attention/advice.
: Flush with plenty of water. Wash off with soap and plenty of water. Remove and wash
Skin contact
contaminated clothing before re-use. If irritation persists, seek prompt medical attention.
: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If
Eye contact
irritation persists, seek prompt medical attention.
: Call a physician or Poison Control Centre immediately. Do NOT induce vomiting. Guard
Ingestion
against aspiration into lungs by having the individual turn on their left side.
: Treat symptomatically.
Notes For Physician
SECTION 5 - FIRE FIGHTING MEASURES
Fire hazards/conditions of flammability
: Not flammable under normal conditions of handling. This product will not burn, due to its
water content.
Flammability classification (OSHA 29 CFR 1910.1200)
: OSHA Combustible Liquid IIIB.
: Not applicable.
Flash point
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, United States, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5965 - 6003
Page 4 of 15
MSDS Preparation Date: January 8, 2010
: Not applicable. Not available.
Flash point Method Auto-ignition temperature :
Lower flammable limit (% by vol.) Upper flammable limit (% by vol.)
: Not applicable. : Not applicable.
Suitable extinguishing media
: Dry chemical, foam, carbon dioxide and water fog.
Explosion data: Sensitivity to mechanical impact / static discharge
: Not expected to be sensitive to mechanical impact or static discharge.
Special fire-fighting procedures/equipment
: Firefighters should wear an approved full-face, self-contained breathing apparatus (SCBA)
and impervious clothing. Water may be ineffective on fire, but may be helpful in cooling
unburned containers. Do not use a solid water stream as it may scatter and spread fire. If
water is used, fog nozzles are preferable.
Hazardous combustion products
: Oxides of carbon, nitrogen, and sulphur. Oxygen. Acrid fumes, toxic gases.
: None known.
Oxidizing properties
SECTION 6 - ACCIDENTAL RELEASE MEASURES
: All persons dealing with clean-up should wear the appropriate protective equipment
Personal precautions
including self-contained breathing apparatus. Avoid breathing vapors. Wear resistant
clothing and boots.
: Prevent product from entering drains, sewers, waterways and soil.
Environmental precautions
: Eliminate all ignition sources if safe to do so. Ventilate area of release. Use only
Spill response/cleanup
non-sparking tools and equipment in the clean-up process. Contain and absorb spilled
liquid with non-combustible, inert absorbent material (e.g. sand), then place absorbent
material into a container for later disposal (see Section 13).
: Should not be released into the environment. Recover free liquid or cover with inert
Containment
absorbent material and place into appropriate container for disposal.
SECTION 7 - HANDLING AND STORAGE
: Use with adequate ventilation. Avoid breathing vapor or mist. Avoid contact with skin and
Safe Handling procedures
eyes. Wash hands thoroughly after using this product, and before eating, drinking or
smoking. Avoid breathing of dust created by cutting, sanding, or grinding. Sanding and
grinding dusts may be harmful if inhaled. Do not re-use empty containers. Do not
puncture container. Keep in properly labeled containers. Wear suitable protective
equipment. Do not ingest.
: Store in a cool, dry, well-ventilated area. Keep away from excessive heat, open flames,
Storage requirements
sparks and other possible sources of ignition. Do not freeze. Keep container tightly closed
when not in use. Store in upright position only. Keep out of the reach of children. Empty
product containers may contain hazardous product residue.
: Oxidizing agents. Acids and bases. Aluminum. Ammonium salts. Other: magnesium,
Incompatible materials
chlorinated rubber.
Special packaging materials
: Liquid-proof glass, plastic or non-corrodible metal containers are recommended.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Ventilation and engineering measures
: Use general or local exhaust ventilation to maintain air concentrations below recommended
exposure limits. Use explosion-proof equipment. Discharge exhaust only in area away from
ignition sources.
: Use NIOSH/MSHA approved full-face respirator with an organic vapor cartridge if the
Respiratory protection
recommended exposure limit is exceeded. In order to avoid inhalation of spray-mist and
sanding dust, all spraying and sanding must be done wearing adequate respirator.
Respirators should be selected based on the form and concentration of contaminants in air,
and in accordance with OSHA (29 CFR 1910.134) or CSA Z94.4-02.
: Wear impervious gloves, such as neoprene or nitrile rubber.
Skin protection
: Safety glasses with side-shields or chemical splash goggles.
Eye / face protection
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, United States, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5965 - 6003
Page 5 of 15
MSDS Preparation Date: January 8, 2010
Other protective equipment
: Emergency showers and eyewash facilities should be nearby. Depending on conditions of
use, safety shoes and additional protective clothing may also be necessary.
General hygiene considerations
: Wash hands thoroughly after using this product, and before eating, drinking or smoking.
Wash hands before breaks and at the end of workday.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Liquid. : Liquid in multiple colors.
Physical state : Appearance
Not available. : Not available.
Odor : Odor threshold
Not available.
pH :
100 癈 (No. 5992) : 1.0-1.4
Boiling point : Specific gravity
100 - 187.2 癈 (No.5968,
5972, 5991, 5994, 5997)
100 - 165癈 (No.5973)
100 - 245.6 (No.5981)
100-190 (Nos. 5974,
5976)
: Not available.
Melting/Freezing point Coefficient of water/oil distribution
: Not available.
: Soluble
Vapor pressure (mmHg @ 20?C / 68?F) Solubility in water
: 0.6 -760
0.06 - 760 (No.5981)
760 (No.5983)
0.2 -760 (No.5990)
17 (Nos. 5976, 5974,
5992)
: Heavier than air.
Vapor density (Air = 1) Evaporation rate (n-Butyl acetate = 1)
: Slower than n-butyl acetate
: 61.17 (except as noted
Volatile organic Compounds (VOC's) (lbs/gal;g/l) Volatiles (% by weight)
below)
: 0.80 -0.85 /
95.00-102.58 (except as
47.31 (No.5971)
noted below)
65.03 (No.5977)
52.3 (No. 5980)
0.22 (No. 5992)
53.92 (No.5982)
0.17 / 20.84 (No.5979)
59.57 (No.5983)
0.36 / 44.15 (No.5990)
50.85 (No.5985)
0.77 / 92.46 (No.6001)
63.29 (No.5986)
0.93 / 111.27 (No.6002)
57.65 (No.5988)
1.04 / 125.59 (No.5980)
61.97 (No.5993)
1.05 / 126.3 (No.5987)
61.73 (No.5996)
1.12 - 1.18 / 134.42 -
53.95 (No.5997)
142.59 (No.5968, 5981,
55.48 (No. 5998)
5986)
47.72 (No.6001-6003)
1.21 / 145.51 (No.5994)
60.52 (No. 5974)
1.31 / 157.86 (No.5972)
60.87 (No. 5976)
50.66 (No. 5992)
: Not available.
Viscosity
Special Remarks On Fire Hazards
: Not flammable under normal conditions of use. This product will not burn, due to its water
content. May spatter if the temperature exceeds the boiling point. Vapors may irritate eyes.
May irritate skin.
SECTION 10 - REACTIVITY AND STABILITY DATA
: Stable under normal conditions.
Stability and reactivity
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, United States, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5965 - 6003
Page 6 of 15
MSDS Preparation Date: January 8, 2010
: Will not occur.
Hazardous polymerization
: High temperatures. Keep away from excessive heat, open flames, sparks and other
Conditions to avoid
possible sources of ignition. Oxidizing agents. Do not freeze.
Materials To Avoid And Incompatibility
: See Section 7 (Handling and Storage) section for further details.
Hazardous decomposition products
: See hazardous combustion products.
SECTION 11 - TOXICOLOGICAL INFORMATION
LC50(4hr) LD50
Ingredients inh, rat oral dermal
Supersaturated - Brilliant Red
N/Av 500 mg/kg
Silica, crystalline quartz, N/Av
respirable dust
Supersaturated - Paynes Gray
N/Av >10000 mg/kg
Iron oxide red N/Av
Supersaturated - Paynes Gray
Supersaturated - Imperial Green
450 ppm/4H (rat) 470 mg/kg (rat); 320 mg/kg
Carbon black 400 mg/kg (rabbit)
(rabbit)
Supersaturated Base - Velour Black
N/Av N/Av
Silica, crystalline-cristobalite N/Av
Supersaturated Burnt Umber
N/Av 3478 mg/kg (rat)
Manganese dioxide N/Av
Supersaturated Chrome Green
N/Av N/Av
Chrome oxide N/Av
Supersaturated Chrome Yellow
N/Av N/Av
Silica, crystalline-cristobalite N/Av
N/Av 12,565 mg/kg (rat)
Glycol ether 11,890 mg/kg (rabbit)
Supersaturated Green Shoe Blue, Supersaturated Emerald Green, Supersaturated Navy Blue, Supersaturated Grass
Green
N/Av 20,000 mg/kg (rat)
Propylene glycol 20,800 mg/kg (rabbit)
Supersaturated Hunter Green
N/Av N/Av
Silica, crystalline-cristobalite N/Av
Supersaturated Lemon Yellow, Supersaturated Van Dyke Brown, Supersaturated Base - Neutral
N/Av N/Av
Silica, crystalline-quartz N/Av
Supersaturated Phthalo Green
N/Av N/Av
1-Propanol, 2-amino-2-methyl- N/Av
Supersaturated White
N/Av N/Av
No hazardous ingredients N/Av
: Low order of toxicity for normal industrial handling.
Toxicological data
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, United States, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5965 - 6003
Page 7 of 15
MSDS Preparation Date: January 8, 2010
: Contains crystalline silica. Crystalline silica is classified as carcinogenic by IARC (Group 1),
Carcinogenic status
the ACGIH (Category A2) and the NTP (Group 1 - Known human carcinogen). Contains
crystalline silica; prolonged exposure by inhalation of particles can cause serious lung
damage, including silicosis. Crystalline Silica has been classified as a carcinogen in dry
powder form only. Exposure to respirable silica is not possible under normal conditions of
use.
Nos. 5974, 5992, 5997, 6003: This product contains Carbon black, an IARC Group 2B
carcinogen.
: Not expected to have other reproductive effects.
Reproductive effects
: Not expected to be a teratogen.
Teratogenicity
: Nos. 5974, 5992, 5997, 6003: Contains Carbon black. Carbon black is suspected of
Mutagenicity
causing mutations in non-reproductive cells, based on animal data.
: Not expected to have other reproductive effects.
Reproductive Effects
: Eyes, skin, respiratory system and digestive system.
Irritancy
: Contains a chemical or chemicals which may cause skin sensitization. This product
Sensitization to material
contains: Propylene glycol (No.5997, 5968, 5972, 5991, 5994); Chromium oxide
(No.5971).
: None reported by the manufacturer.
Synergistic materials
SECTION 12 - ECOLOGICAL INFORMATION
: None known or reported by the manufacturer.
Environmental effects
Important environmental characteristics
: None known or reported by the manufacturer.
: No data is available on the product itself.
Ecotoxicological
SECTION 13 - DISPOSAL CONSIDERATIONS
: See Section 7 (Handling and Storage) section for further details.
Handling for Disposal
: Dispose in accordance with all applicable federal, state, provincial and local regulations.
Methods of Disposal
Contact your local, state, provincial or federal environmental agency for specific rules. Do
not puncture or incinerate. Contact waste disposal services.
SECTION 14 - TRANSPORTATION INFORMATION
Packing
Regulatory
Group
UN Number Shipping Name
Information Class Label
Not regulated
Not regulated.
None
TDG -None-
None.
TDG
Additional
information
Not regulated
Not regulated.
None
49CFR/DOT -None-
None.
49CFR/DOT
Additional
information
Not regulated
Not regulated.
None
ICAO/IATA -None-
None.
ICAO/IATA
Additional
information
Not regulated
Not regulated.
None
IMDG -None-
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, United States, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5965 - 6003
Page 8 of 15
MSDS Preparation Date: January 8, 2010
None.
IMDG
Additional
information
SECTION 15 - REGULATORY INFORMATION
US Federal Information:
All ingredients are listed on the TSCA Inventory, or are exempted materials.
SARA Section 313: This material is not subject to SARA notification requirements, since it does not contain any Toxic Chemical
Constituents above de minimus concentrations.
US State Right to Know Laws:
California Proposition 65: This product contains a chemical known to the State of California to cause cancer and/or reproductive
harm. This product contains: Crystalline, silica. Carbon black is listed when found in unbound, airborne particles of respirable
size. (No.5997)
Canadian Regulations:
Canadian Environmental Protection Act (CEPA): All ingredients are listed on the DSL, or are exempted materials.
Canadian WHMIS Classification: D2A, D2B; D2B (No.6002).
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the
information required by the CPR.
SECTION 16 - OTHER INFORMATION
: ACGIH: American Conference of Governmental Industrial Hygienists
Legend
IARC: International Agency for Research on Cancer
N/Ap: not applicable
N/Av: not available
NIOSH: National Institute of Occupational Safety and Health
NTP: National Toxicology Program
OSHA: Occupational Safety and Health Administration
: Information obtained from sources including original supplier's Material Safety Data Sheet,
References
and references including RTECS and CCOHS Cheminfo.
Prepared for:
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, United States
06902
Telephone: (203) 708 8900
http://http://www.rosco.com/
Prepared by:
ICC The Compliance Center Inc.
Canada: 1-888-977-4834
USA: 1-888-442-9628
http://www.thecompliancecenter.com
DISCLAIMER OF LIABILITY
Every effort has been made to ensure that the safety information on this sheet is accurate, but because Rosco Laboratories, Inc.
has no control over the conditions under which the product will be used, liability is limited exclusively to replacement or refund of
the purchase price of this product. Except as stated herein, there are no express or implied warranties, including implied
warranties of merchantability or fitness for a particular purpose. Rosco Laboratories, Inc. assumes no liability for injury or
incidental or consequential damages arising out of storage, handling or use of this product.
Preparation Date: March 1, 2008
MSDS Reviewed Date: February 12, 2009
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, United States, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5965 - 6003
Page 9 of 15
MSDS Preparation Date: January 8, 2010
:2
Revision No.
: Added 5974, 5976, 5992.
Revision Information
END OF DOCUMENT
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, USA, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5989
Page 10 of 15
MSDS Preparation Date: January 8, 2010
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
SUPERSATURATED
:
Product Name
Supersaturated Turquoise
: Paint
Product Use
: Mixture
Chemical Family
Supplier's name and address:
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, United States
06902
: (800) 424-9300
24 Hr. Emergency Tel #
:
* - Chronic hazard 0 - Minimal 1 - Slight 2 - Moderate 3 - Serious 4 - Severe
HMIS Rating
*1
Health: Flammability: 1 Reactivity: 0
WHMIS Classes:
TOXIC
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
OSHA PEL
ACGIH TLV
TWA STEL PEL STEL
Ingredients % (weight)
CAS #
1.0 - 5.0
2-Butoxyethanol N/Av
111-76-2 50 ppm (240
20 ppm N/Av
mg/m3)
(skin)
0.1 - 1.0
Silica, crystalline-quartz N/Av
14808-60-7 (10)/(%SiO2
0.025 mg/m3 N/Av
+ 2) mg/m3
1.0 - 5.0
Silica, crystalline-cristobalite N/Av
14464-46-1 0.025 mg/m3 N/Av N/Av
1.0 - 5.0
Propylene glycol N/Av
57-55-6 N/Av N/Av N/Av
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Liquid. Color as per product name. Irritating to eyes, respiratory system and skin. Harmful if inhaled or swallowed. Contains material which
can cause cancer.
***POTENTIAL HEALTH EFFECTS***
: None reported by the manufacturer.
Target organs
: Inhalation: YES Skin Absorption: YES Skin & Eyes:YES Ingestion: YES
Routes of exposure
Potential acute health effects :
Causes eye irritation. May cause conjunctivitis, irritation, and inflammation of mucous membranes. May cause
Eyes:
burning sensation, redness and tearing (watering). Possible severe irritation.
Skin: Irritating to skin. Possible irritation, defatting or dermatitis (rash). Components of the product may be absorbed into the
body through the skin. May cause central nervous system depression.
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, USA, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5989
Page 11 of 15
MSDS Preparation Date: January 8, 2010
Inhalation: Can cause irritation of the respiratory tract. Prolonged exposure to vapors may be harmful to health. If higher
concentrations are inhaled, additional symptoms may include coughing, shortness of breath, headache, nausea,
vomiting, dizziness, drowsiness and other central nervous system effects. May cause mucous membrane irritation.
Other adverse effects: Asphyxia. Severe lung irritation or lung damage, loss of appetite. Sanding and grinding dusts
may be harmful if inhaled. Contains particles which may cause lung damage if inhaled in large quantities. Very toxic
in particulate form upon inhalation.
Ingestion: Lung aspiration hazard. This product may be aspirated (inhaled) into the lungs during ingestion. May cause lung
inflammation. May cause mucous membrane irritation. Ingestion may cause symptoms similar to inhalation. May cause
gastrointestinal irritation. Gastrointestinal irritation may include abdominal pain, nausea, diarrhea and vomiting. Other
adverse effects: intoxication. May cause central nervous system depression.
Potential chronic health effects
: Prolonged skin contact may defat the skin and produce dermatitis. May cause allergic skin
reaction. Harmful by skin absorption. May cause central nervous system depression.
Prolonged inhalation of vapors may cause lung damage, including chronic bronchitis.
Contains crystalline silica; prolonged exposure by inhalation of particles can cause serious
lung damage, including silicosis. Contains a chemical which may cause kidney damage.
This product contains: 2-butoxyethanol.
Medical conditions aggravated by overexposure
: None expected, when used as intended.
Additional health hazards : Exposure to respirable silica is not possible under normal conditions of use. Crystalline
Silica has been classified as a carcinogen in dry powder form only.
Potential environmental effects
: None reported by the manufacturer.
SECTION 4 - FIRST AID MEASURES
: If breathed in, move person into fresh air. If breathing has stopped, give artificial respiration.
Inhalation
If breathing is difficult, give oxygen by qualified medical personnel only. Seek immediate
medical attention/advice.
: Flush with plenty of water. Wash off with soap and plenty of water. Remove and wash
Skin contact
contaminated clothing before re-use. If irritation persists, seek prompt medical attention.
: Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If
Eye contact
irritation persists, seek prompt medical attention.
: Call a physician or Poison Control Centre immediately. Do NOT induce vomiting. Guard
Ingestion
against aspiration into lungs by having the individual turn on their left side.
: Treat symptomatically.
Notes For Physician
SECTION 5 - FIRE FIGHTING MEASURES
Fire hazards/conditions of flammability
: Not flammable under normal conditions of handling. This product will not burn, due to its
water content.
Flammability classification (OSHA 29 CFR 1910.1200)
: OSHA Combustible Liquid IIIB.
: Not applicable.
Flash point
: Not applicable. : Not available.
Flash point Method Auto-ignition temperature
Lower flammable limit (% by vol.) Upper flammable limit (% by vol.)
: Not applicable. : Not applicable.
Suitable extinguishing media
: Dry chemical, foam, carbon dioxide and water fog.
Explosion data: Sensitivity to mechanical impact / static discharge
: Not expected to be sensitive to mechanical impact or static discharge.
Special fire-fighting procedures/equipment
: Firefighters should wear an approved full-face, self-contained breathing apparatus (SCBA)
and impervious clothing. Water may be ineffective on fire, but may be helpful in cooling
unburned containers. Do not use a solid water stream as it may scatter and spread fire. If
water is used, fog nozzles are preferable.
Hazardous combustion products
: Oxides of carbon, nitrogen, and sulphur. Oxygen. Acrid fumes, toxic gases.
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, USA, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5989
Page 12 of 15
MSDS Preparation Date: January 8, 2010
: None expected.
Oxidizing properties
SECTION 6 - ACCIDENTAL RELEASE MEASURES
: All persons dealing with clean-up should wear the appropriate protective equipment
Personal precautions
including self-contained breathing apparatus. Avoid breathing vapors. Wear resistant
clothing and boots.
: Prevent product from entering drains, sewers, waterways and soil.
Environmental precautions
: Eliminate all ignition sources if safe to do so. Ventilate area of release. Use only non-
Spill response/cleanup
sparking tools and equipment in the clean-up process. Contain and absorb spilled liquid
with non-combustible, inert absorbent material (e.g. sand), then place absorbent material
into a container for later disposal (see Section 13).
: Should not be released into the environment. Recover free liquid or cover with inert
Containment
absorbent material and place into appropriate container for disposal.
SECTION 7 - HANDLING AND STORAGE
: Use with adequate ventilation. Avoid breathing vapor or mist. Avoid contact with skin and
Safe Handling procedures
eyes. Wash hands thoroughly after using this product, and before eating, drinking or
smoking. Avoid breathing of dust created by cutting, sanding, or grinding. Sanding and
grinding dusts may be harmful if inhaled. Do not re-use empty containers. Do not puncture
container. Keep in properly labeled containers. Wear suitable protective equipment. Do not
ingest.
: Store in a cool, dry, well-ventilated area. Keep away from excessive heat, open flames,
Storage requirements
sparks and other possible sources of ignition. Do not freeze. Keep container tightly closed
when not in use. Store in upright position only. Keep out of the reach of children. Empty
product containers may contain hazardous product residue.
: Oxidizing agents. Acids and bases. Aluminum. Ammonium salts. Other: magnesium,
Incompatible materials
chlorinated rubber.
Special packaging materials
: Liquid-proof glass, plastic or non-corrodible metal containers are recommended.
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Ventilation and engineering measures
: Use general or local exhaust ventilation to maintain air concentrations below recommended
exposure limits. Use explosion-proof equipment. Discharge exhaust only in area away from
ignition sources.
: Use NIOSH/MSHA approved full-face respirator with an organic vapor cartridge if the
Respiratory protection
recommended exposure limit is exceeded. In order to avoid inhalation of spray-mist and
sanding dust, all spraying and sanding must be done wearing adequate respirator.
Respirators should be selected based on the form and concentration of contaminants in air,
and in accordance with OSHA (29 CFR 1910.134) or CSA Z94.4-02.
: Gloves impervious to the material are recommended.
Skin protection
: Safety glasses with side-shields or chemical splash goggles.
Eye / face protection
Other protective equipment
: Emergency showers and eyewash facilities should be nearby. Depending on conditions of
use, safety shoes and additional protective clothing may also be necessary.
General hygiene considerations
: Wash hands thoroughly after using this product, and before eating, drinking or smoking.
Wash hands before breaks and at the end of workday.
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
Liquid. : Color as per product name
Physical state : Appearance
Not available. : Not available.
Odor : Odor threshold
Not available.
pH :
168.3 - 187.2 癈 : 1.0-1.4
Boiling point : Specific gravity
Not available.
Melting/Freezing point : Coefficient of water/oil distribution
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, USA, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5989
Page 13 of 15
MSDS Preparation Date: January 8, 2010
: Not available.
: Soluble
Vapor pressure (mmHg @ 20?C / 68?F) Solubility in water
: 0.6 -760
: Heavier than air.
Vapor density (Air = 1) Evaporation rate (n-Butyl acetate = 1)
: Slower than n-butyl acetate
: 61.17
Volatile organic Compounds (VOC's) (lbs/gal;g/l) Volatiles (% by weight)
: 1.52 / 182.73
: Not available.
Viscosity
Special Remarks On Fire Hazards
: Not flammable under normal conditions of use. This product will not burn, due to its water
content. May spatter if the temperature exceeds the boiling point. Vapors may irritate eyes.
May irritate skin.
SECTION 10 - REACTIVITY AND STABILITY DATA
: Stable under normal conditions.
Stability and reactivity
: Will not occur.
Hazardous polymerization
: High temperatures. Keep away from excessive heat, open flames, sparks and other
Conditions to avoid
possible sources of ignition. Oxidizing agents. Do not freeze.
Materials To Avoid And Incompatibility
: See Section 7 (Handling and Storage) section for further details.
Hazardous decomposition products
: See hazardous combustion products.
SECTION 11 - TOXICOLOGICAL INFORMATION
LC50(4hr) LD50
Ingredients inh, rat oral dermal
450 ppm/4H (rat) 470 mg/kg (rat); 320 mg/kg
2-Butoxyethanol 400 mg/kg (rabbit)
(rabbit)
N/Av N/Av
Silica, crystalline-quartz N/Av
N/Av N/Av
Silica, crystalline-cristobalite N/Av
N/Av 20,000 mg/kg (rat)
Propylene glycol 20,800 mg/kg (rabbit)
: Low order of toxicity for normal industrial handling.
Toxicological data
: Contains Crystalline silica. Crystalline silica is classified as carcinogenic by IARC (Group 1),
Carcinogenic status
the ACGIH (Category A2) and the NTP (Group 1 - Known human carcinogen). Contains
crystalline silica; prolonged exposure by inhalation of particles can cause serious lung
damage, including silicosis. Crystalline Silica has been classified as a carcinogen in dry
powder form only. Exposure to respirable silica is not possible under normal conditions of
use.
Contains 2-Butoxyethanol. 2-Butoxyethanol is classified as a confirmed animal carcinogen
by ACGIH (Group A3).
Not expected to have other reproductive effects.
Reproductive effects :
Not expected to be a teratogen.
Teratogenicity :
Not expected to be mutagenic in humans.
Mutagenicity :
Not expected to have other reproductive effects.
Reproductive Effects :
Eyes, skin, respiratory system and digestive system.
Irritancy :
Contains a chemical or chemicals which may cause skin sensitization. This product
Sensitization to material :
contains: Propylene glycol.
: None reported by the manufacturer.
Synergistic materials
SECTION 12 - ECOLOGICAL INFORMATION
: None known or reported by the manufacturer.
Environmental effects
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, USA, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5989
Page 14 of 15
MSDS Preparation Date: January 8, 2010
Important environmental characteristics
: None known or reported by the manufacturer.
: No data is available on the product itself.
Ecotoxicological
SECTION 13 - DISPOSAL CONSIDERATIONS
: See Section 7 (Handling and Storage) section for further details.
Handling for Disposal
: Dispose in accordance with all applicable federal, state, provincial and local regulations.
Methods of Disposal
Contact your local, state, provincial or federal environmental agency for specific rules. Do
not puncture or incinerate. Contact waste disposal services.
SECTION 14 - TRANSPORTATION INFORMATION
Packing
Regulatory
Group
UN Number Shipping Name
Information Class Label
Not regulated
Not regulated.
None
TDG -None-
None.
TDG
Additional
information
Not regulated
Not regulated.
None
49CFR/DOT -None-
None.
49CFR/DOT
Additional
information
Not regulated
Not regulated.
None
ICAO/IATA -None-
None.
ICAO/IATA
Additional
information
Not regulated
Not regulated.
None
IMDG -None-
None.
IMDG
Additional
information
SECTION 15 - REGULATORY INFORMATION
US Federal Information:
All ingredients are listed on the TSCA Inventory, or are exempted materials.
SARA Section 313: This material is not subject to SARA notification requirements, since it does not contain any Toxic Chemical
Constituents above de minimus concentrations.
US State Right to Know Laws:
California Proposition 65: This product contains a chemical known to the State of California to cause cancer and/or reproductive
harm. This product contains: Crystalline, silica.
Canadian Regulations:
Canadian Environmental Protection Act (CEPA): All ingredients are listed on the DSL, or are exempted materials.
Canadian WHMIS Classification: D1A, D2A, D2B.
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the
information required by the CPR.
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, USA, 06902
Phone: (203) 708 8900
SUPERSATURATED MSDS No.:5989
Page 15 of 15
MSDS Preparation Date: January 8, 2010
SECTION 16 - OTHER INFORMATION
: ACGIH: American Conference of Governmental Industrial Hygienists
Legend
IARC: International Agency for Research on Cancer
N/Ap: not applicable
N/Av: not available
NIOSH: National Institute of Occupational Safety and Health
NTP: National Toxicology Program
OSHA: Occupational Safety and Health Administration
: Information obtained from sources including original supplier's Material Safety Data Sheet,
References
and references including RTECS and CCOHS Cheminfo.
Prepared for:
Rosco Laboratories Inc.
52 Harbor View Avenue
Stamford, CT, USA, 06902
Phone: (203) 708 8900
http://http://www.rosco.com/
Prepared by:
ICC The Compliance Center Inc.
Canada: 1-888-977-4834
USA: 1-888-442-9628
http://www.thecompliancecenter.com
DISCLAIMER OF LIABILITY
Every effort has been made to ensure that the safety information on this sheet is accurate, but because Rosco Laboratories, Inc.
has no control over the conditions under which the product will be used, liability is limited exclusively to replacement or refund of
the purchase price of this product. Except as stated herein, there are no express or implied warranties, including implied
warranties of merchantability or fitness for a particular purpose. Rosco Laboratories, Inc. assumes no liability for injury or
incidental or consequential damages arising out of storage, handling or use of this product.
: January 3, 2007 MSDS Reviewed Date: January 8, 2010
Preparation Date:
END OF DOCUMENT
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