TECO DIAGNOSTICS
List Material Safety Data Sheet (Documentation Requirements)
Section 1 ?Product and Company Information
Product Name Calcium Emergency Telephone No.
C503-480 CHEMTREC (800) 424-9300
Catalog Number
Clinical Chemistry Reagent International CHEMTREC (703) 527-3887
Product Type
Teco Diagnostics
Company Name Company Telephone No.
1268 N. Lakeview Avenue (800) 222-9880 or (714) 693-7788 Monday - Friday 8:00-4:30 PST
Street Address
Anaheim, CA 92807 USA Fax No. (714) 693-3838
City, State, Zip Code, Country
Section 2 ?Composition/Information on Ingredients
Chemical Names Concentration CAS#
Color reagent (Mixture): O-Cresolphthalein Complexone 0.14 mM 2411-89-4
8-Hydroxyquinoline 13 mM 148-24-3
Buffer reagent (Mixture): 2-Amino-2-methyl-1-propanol 363 mM 124-68-5
Potassium Cyanide 2 mM 151-50-8
Standard: Calcium Carbonate 10 mg/dl 471-34-1
Other components either non-hazardous or at concentrations below that requiring hazardous listing.
Section 3 ?Hazards Identification
Emergency Overview:
Note: The following information applies to the component materials at higher concentrations than present in the reagent. Although lower concentrations
are present in the reagent, appropriate safety precautions should still be taken.
O-Cresolphthalein Complexone: Caution: Avoid contact and inhalation.
8-Hydroxyquinoline: Harmful. Harmful if swallowed. Target organ(s): Nerves.
2-Amino-2-methyl-1-propanol Irritant. Irritating to skin. Risk of serious damage to eyes. Harmful to aquatic organisms, may cause long-term
adverse effects in the aquatic environment. Combustible.
Potassium Cyanide: Highly Toxic (USA) Very Toxic (EU). Dangerous for the environment. Very toxic by inhalation, in contact with
skin and if swallowed. Contact with acids liberates very toxic gas. Causes burns. Very toxic to aquatic organisms;
may cause long-term adverse effects in the aquatic environment. Target organ(s): Blood. Central nervous system.
Calcium Carbonate: Irritant. Irritating to respiratory system and skin. Risk of serious damage to eyes.
HMIS Rating Health Flammability Reactivity
O-Cresolphthalein Complexone: 0 0 0
8-Hydroxyquinoline: 1* 0 1
2-Amino-2-methyl-1-propanol 2 2 1
Potassium Cyanide: 3* 0 1
Calcium Carbonate: 2 0 1
*additional chronic hazards present
NFPA Rating Health Flammability Reactivity
O-Cresolphthalein Complexone: 0 0 0
8-Hydroxyquinoline: 1 0 1
2-Amino-2-methyl-1-propanol 2 2 1
Potassium Cyanide: 3 0 1
Calcium Carbonate: 2 0 1
For additional information on toxicity, please refer to section 11.
Section 4 ?First Aid Measures
Oral Exposure
If swallowed, wash out mouth with water provided person is conscious. Call a physician.
Inhalation Exposure
If inhaled, remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician.
Dermal Exposure
In case of skin contact, flush with copious amounts of water for at least 15 minutes. Remove contaminated clothing and shoes. Call a physician.
Eye Exposure
In case of contact with eyes, flush with copious amounts of water for at least 15 minutes. Assure adequate flushing by separating the eyelids with fingers.
Call a physician.
Section 5- Fire and Explosive Hazard Data
Flammable Hazards Flash Point Autoignition Temp Flammability
2-Amino-2-methyl-1-propanol 2-Amino-2-methyl-1-propanol N/A N/A
Flammable Hazards: Yes 154.4癋 68癈 Method: closed cup
Extinguishing Media
Potassium cyanide
Suitable: Appropriate foam.
Unsuitable: Do not use carbon dioxide extinguisher on this material.
List No: L42-M18 Revision : C Prepared by: AR Approved by: JO Issue date: 08/30/07
Page 1 of 7
TECO DIAGNOSTICS
List Material Safety Data Sheet (Documentation Requirements)
Calcium
Section 5- Fire and Explosive Hazard Data (Continued)
Firefighting Measures
Protective Equipment: Wear self-contained breathing apparatus and protective clothing to prevent contact with skin and eyes.
Specific Hazard(s): Emits toxic fumes under fire conditions.
Specific Hazard(s): 2-Amino-2-methyl-1-propanol: Combustible liquid.
Specific Method(s) of Fire Fighting: Potassium cyanide: Fire fighting hazard: water spray can be used to fight fire in area containing cyanide and to cool
fire-exposed metal containers. However, direct contact of material with water or steam will cause decomposition liberating highly toxic hydrogen cyanide
gas as well as generating a highly hazardous solution of dissolved cyanide which must be kept out of sewers and watercourses. Cyanide has been found to
form explosive mixtures sometimes spontaneously with chlorates, nitrates, and nitrogen trichloride plus ammonia.
Section 6 ?Accidental Release Measures
Procedure to be Followed in Case of Leak or Spill
Ventilate the area.
Procedures of Personal Precaution
Wear personal protective equipment. Refer to section 8.
Methods for Cleaning Up and Disposal
Absorb on inert material (sand or vermiculite), then place in closed containers for disposal. Wash spill site after material pickup is complete. Follow
federal, state and local disposal regulations.
Section 7 ?Handling and Storage
Handling
User Exposure: Avoid inhalation. Avoid contact with eyes, skin, and clothing. Avoid prolonged or repeated exposure.
Storage
Suitable: Keep tightly closed. Store in a cool dry place. Avoid contact with acid.
Section 8 ?Exposure Controls / PPE
Engineering Controls
Safety shower and eyewash. Good general ventilation is satisfactory.
Personal Protective Equipment
Respiratory Protection: None required where adequate ventilation is satisfactory.
Hand: Protective gloves required.
Eye: Chemical safety goggles with side shields recommended.
Other protective equipment: Laboratory coat recommended
General Hygiene Measures
Wash contaminated clothing before reuse. Wash thoroughly after handling.
Exposure Limits, RTECS: Potassium Cyanide:
Country Source Type Value Remarks
New Zealand OEL --- --- Check ACGIH TLV
USA NIOSH Ceiling concentration 4.7 PPM (CN) / 10M ---
Exposure Limits: Potassium Cyanide:
Country Source Type Value
Poland --- NDS ---
Poland --- NDSCh ---
5 mg/m3
Poland --- NDSP
Exposure Limits: Calcium Carbonate:
Country Source Type Value
10 mg/m3
Poland --- NDS
Poland --- NDSCh ---
Poland --- NDSP ---
Remarks: {OELS ARE VALID FOR DUSTS} PYLY
Section 9 - Physical Data
Specific Gravity (g/cm3)
Boiling Point Melting Point
8-Hydroxyquinoline: 122 癈 at 0.1 mmHg O-Cresolphthalein Complexone: 181-185癈 2-Amino-2-methyl-1-propanol: 0.93
2-Amino-2-methyl-1-propanol: 165 癈 at 760 8-Hydroxyquinoline: 72.5癈 Potassium Cyanide: 1.52
mmHg 2-Amino-2-methyl-1-propanol: 30癈 Calcium Carbonate: 2.93
Potassium Cyanide: 634癈
Calcium Carbonate: 800癈
Vapor Pressure Percent Volatile Vapor Density
2-Amino-2-methyl-1-propanol: <1 mmHg at 25癈 N/A 2-Amino-2-methyl-1-propanol: 3 g/L
Evaporation Rate Solubility in Water Appearance
N/A 2-Amino-2-methyl-1-propanol: 0.1 M in H2O, Calcium Buffer Reagent: Clear Liquid
20癈 complete, colorless Calcium Color Reagent: Yellow Liquid
Calcium Carbonate: Insoluble
List No: L42-M18 Revision : C Prepared by: AR Approved by: JO Issue date: 08/30/07
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TECO DIAGNOSTICS
List Material Safety Data Sheet (Documentation Requirements)
Calcium
Section 10 ?Stability and Reactivity
Stability
Chemical Stable Conditions of Instability Conditions Materials to Avoid
to Avoid
O-Cresolphthalein Complexone Stable N/A N/A N/A
8-Hydroxyquinoline Stable May discolor on exposure to light. N/A Strong oxidizing agents, Strong acids.
2-Amino-2-methyl-1-propanol Stable Absorbs carbon dioxide from air. Air sensitive Oxidizing agents, Strong acids Copper,
Copper alloys, Brass, Aluminum.
Potassium Cyanide Stable May decompose on exposure to moist air N/A Strong oxidizing agents Avoid contact with
or water. Absorbs carbon dioxide from acid., Iodine, Permanganates, Peroxides,
air. Light sensitive. Metallic salts, Chloral hydrate, Alkaloids,
Chlorates
Calcium Carbonate Stable N/A Moisture Strong oxidizing agents, Acids,
Magnesium, Aluminum.
Hazardous Decomposition Products
O-Cresolphthalein Complexone Carbon monoxide, Carbon dioxide, Nitrogen oxides.
8-Hydroxyquinoline Carbon monoxide, Carbon dioxide, Nitrogen oxides.
2-Amino-2-methyl-1-propanol Thermal decomposition may produce carbon monoxide, carbon dioxide, and nitrogen oxides.
Potassium Cyanide Hydrogen cyanide, Nitrogen oxides, Potassium oxides.
Calcium Carbonate Carbon monoxide, Carbon dioxide, Calcium oxide.
Hazardous Polymerization
Hazardous Polymerization: Will not occur.
Section 11 ?Toxicological information
Route of exposure Signs and Symptoms of Exposure
O-Cresolphthalein Complexone: O-Cresolphthalein Complexone:
Multiple Routes: May be harmful by inhalation, ingestion, or skin To the best of our knowledge, the chemical, physical and toxicological
absorption. May cause irritation. properties of have not been thoroughly investigated.
Route of exposure Signs and Symptoms of Exposure
8-Hydroxyquinoline: 8-Hydroxyquinoline:
Skin contact: May cause skin irritation. To the best of our knowledge, the chemical, physical and toxicological
Skin absorption: May be harmful if absorbed through the skin. properties of have not been thoroughly investigated.
Eye contact: May cause eye irritation.
Inhalation: May be harmful if inhaled. Material may be irritating to
mucous membranes and upper respiratory tract.
Ingestion: Harmful if swallowed.
Target organ(s): Nerves
Route of exposure Signs and Symptoms of Exposure
2-Amino-2-methyl-1-propanol: 2-Amino-2-methyl-1-propanol:
Skin contact: Causes skin irritation. To the best of our knowledge, the chemical, physical and toxicological
Skin absorption: May be harmful if absorbed through the skin. properties of have not been thoroughly investigated.
Eye contact: Causes severe eye irritation.
Inhalation: May be harmful if inhaled. Material is irritating to mucous
membranes and upper respiratory tract.
Ingestion: May be harmful if swallowed.
Route of exposure Signs and Symptoms of Exposure
Potassium Cyanide: Potassium Cyanide:
Skin contact: May cause skin irritation. Material is extremely destructive to tissue of the mucous membranes and
Skin absorption: May be fatal if absorbed through the skin. upper respiratory tract, eyes, and skin. Inhalation may result in spasm,
Eye contact: May cause eye irritation. inflammation and edema of the larynx and bronchi, chemical pneumonitis,
Inhalation: May be fatal if inhaled. Material may be irritating to mucous and pulmonary edema. Symptoms of exposure may include burning
membranes and upper respiratory tract. sensation, coughing, wheezing, laryngitis, shortness of breath, headache,
nausea, and vomiting. Exposure can cause: Lung irritation. Cyanosis. CNS
Ingestion: May be fatal if swallowed.
depression. To the best of our knowledge, the chemical, physical and
Target organ(s): Blood. Central nervous system. Cardiovascular system.
toxicological properties of have not been thoroughly investigated.
Thyroid.
Route of exposure Signs and Symptoms of Exposure
Calcium Carbonate: Calcium Carbonate:
Skin Contact: Causes skin irritation. To the best of our knowledge, the chemical, physical, and toxicological
Skin Absorption: May be harmful if absorbed through the skin. properties have not been thoroughly investigated.
Eye Contact: Causes severe eye irritation.
Inhalation: Material is irritating to mucous membranes and upper
respiratory tract. May be harmful if inhaled.
Ingestion: May be harmful if swallowed.
List No: L42-M18 Revision : C Prepared by: AR Approved by: JO Issue date: 08/30/07
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TECO DIAGNOSTICS
List Material Safety Data Sheet (Documentation Requirements)
Calcium
Section 11 ?Toxicological information (Continued)
Toxicity Data: 8-Hydroxyquinoline
Species: Dose: Route of Application: Result:
Rat 1200 mg/kg Oral LD50
>1210 mg/m3
Rat Inhalation LC50
Mouse 20000 mg/kg Oral LD50
Mouse 43 mg/kg Intraperitoneal LD50
Mouse 83600 ug/kg Subcutaneous LD50
Irritation Data: 8-Hydroxyquinoline
Species: Dose: Route of Application: Exposure Time: Remarks
Rabbit 500 mg Skin 24 H Mild irritation effect.
Rabbit 100 mg Eyes --- Mild irritation effect.
Chronic Exposure ?Carcinogen: 8-Hydroxyquinoline
Result: This product is or contains a component that is not classifiable as to its carcinogenicity based on its IARC, ACGIH, NTP, or EPA classification.
Species: Route of Dose: Exposure Frequency: Result:
Application: Time:
Rat Oral 29 gm/kg 48 W I Tumorigenic: Equivocal tumorigenic agent by RTECS
criteria. Skin and Appendages: Other: Tumors. Tumorigenic
Effects: Testicular tumors.
Rat Intravaginal 33 gm/kg 82 W I Tumorigenic: Equivocal tumorigenic agent by RTECS
criteria. Tumorigenic Effects: Ovarian tumors.
Mouse Skin 7200 mg/kg 50 W I Tumorigenic: Equivocal tumorigenic agent by RTECS
criteria. Lungs, Thorax, or Respiration: Tumors.
Tumorigenic Effects: Ovarian tumors.
Mouse Subcutaneous 900 mg/kg 21 W I Tumorigenic: Equivocal tumorigenic agent by RTECS
criteria. Lungs, Thorax, or Respiration: Tumors.
Tumorigenic Effects: Ovarian tumors.
Mouse Implant 50 mg/kg --- --- Tumorigenic: Carcinogenic by RTECS criteria. Kidney,
Ureter, Bladder: Tumors.
Mouse Intravaginal 5600 mg/kg 35 W I Tumorigenic: Equivocal tumorigenic agent by RTECS
criteria. Blood: Leukemia Tumorigenic Effects: Ovarian
tumors.
Rat Oral 34 gm/kg 84 W I Tumorigenic: Equivocal tumorigenic agent by RTECS
criteria. Lungs, Thorax, or Respiration: Tumors.
Tumorigenic Effects: Uterine tumors.
Mouse Implant 80 mg/kg --- --- Tumorigenic: Neoplastic by RTECS criteria. Kidney, Ureter,
Bladder: Tumors.
Mouse Implant 100 mg/kg --- --- Tumorigenic: Neoplastic by RTECS criteria. Kidney, Ureter,
Bladder: Tumors. Tumorigenic: Tumors at site or
application.
Mouse Intravaginal 17 gm/kg 2Y I Tumorigenic: Equivocal tumorigenic agent by RTECS
criteria. Tumorigenic Effects: Ovarian tumors.
IARC Carcinogen List: Rating: Group 3
NTP Carcinogen List: Rating: No evidence. Species: Mouse. Route: Feed.
Chronic Exposure ?Mutagen: 8-Hydroxyquinoline
Species: Dose: Route: Cell Type: Mutation Test:
Human 25 umol/L --- HeLa cell DNA Inhibition
Rat 600 mg/kg --- S. typhimurium Body fluid assay
Mouse 100 mg/kg Intraperitoneal --- Micronucleus test
Mouse 400 ug/L --- Lymphocyte Mutation in mammalian somatic cells.
Hamster 40 umol/L --- Ovary Other mutation test systems
Hamster 7500 ug/L --- Ovary Cytogenetic analysis
Hamster 2600 ug/L --- Ovary Sister chromatid exchange
Toxicity Data: 2-Amino-2-methyl-1-propanol:
Species: Dose: Route of Application: Result:
Rat 2900 mg/kg Oral LD50
Mouse 2150 mg/kg Oral LD50
List No: L42-M18 Revision : C Prepared by: AR Approved by: JO Issue date: 08/30/07
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TECO DIAGNOSTICS
List Material Safety Data Sheet (Documentation Requirements)
Calcium
Section 11 ?Toxicological information (Continued)
Toxicity Data: Potassium Cyanide:
Species: Dose: Route of Application: Result: Remarks:
Human 2.857 mg/kg Oral LDLO ---
Rat 5 mg/kg Oral LD50 ---
Rat 4 mg/kg Intraperitoneal LD50 Lungs, Thorax, or Respiration: Other changes.
Rat 7814 ug/kg Subcutaneous LD50 ---
Rat 3600 ug/kg Intravenous LD50 Behavioral: Altered sleep time (including change in righting reflex). Behavioral:
Convulsions or effect on seizure threshold. Lungs, Thorax, or Respiration: Dyspnea.
Mouse 8.5 mg/kg Oral LD50 ---
Mouse 5991 ug/kg Intraperitoneal LD50 ---
Mouse 6500 ug/kg Subcutaneous LD50 ---
Mouse 2600 ug/kg Intravenous LD50 Peripheral Nerve and Sensation: Flaccid paralysis without anesthesia (usually
neuromuscular blockage). Behavioral: Convulsions or effect on seizure threshold. Lungs,
Thorax, or Respiration: Respiratory stimulation.
Dog 6 mg/kg Subcutaneous LD50 Behavioral: Convulsions or effect on seizure threshold.
Cat 2200 mg/kg Intravenous LD50 ---
Rabbit 5 mg/kg Oral LD50 ---
Rabbit 3972 ug/kg Intraperitoneal LD50 Blood: Other changes.
Rabbit 4 mg/kg Subcutaneous LD50 Lungs, Thorax, or Respiration: Other changes.
Rabbit 3256 ug/kg Intramuscular LD50 ---
Rabbit 7870 ug/kg Ocular LD50 Sense Organs and Special Senses (Nose, Eye, Ear, and Taste): Eye: Other. Behavioral:
Ataxia. Lungs, Thorax, or Respiration: Respiratory stimulation.
Pigeon 4 mg/kg Intramuscular LD50 ---
Chronic Exposure ?Teratogen: Potassium Cyanide:
Species: Dose: Route of Application: Exposure Time: Result:
Rat 40 mg/kg Intraperitoneal 1-15 D PREG Effects on Embryo or Fetus: Fetotoxicity (except death, e.g., stunted
fetus).
Chronic Exposure ?Mutagen: Potassium Cyanide:
Species: Dose: Cell Type: Mutation Test:
Rat 300 umol/L Liver DNA damage
Mouse 1 mmol/L Lymphocyte DNA inhibition
Mouse 1 mmol/L Mammary gland Cytogenetic analysis
Chronic Exposure ?Reproductive Hazard: Potassium Cyanide:
Species: Dose: Route: Exposure Time: Result:
Rat 65 gm/kg Oral 14 D PRE / 1-22 D PREG Effects on Fertility: Other measures of fertility
Domestic Animals 1767 mg/kg Oral 8-20W PREG / 44D POST Effects on Newborn: Weaning or lactation index (e.g., #
alive at weaning per # alive at day 4). Effects on Newborn:
Other neonatal measures or effects.
Toxicity Data: Calcium Carbonate:
Species: Dose: Route of Application: Result:
Rat 6450 mg/kg Oral LD50
Irritation Data: Calcium Carbonate:
Species: Dose: Route of Application: Exposure Time: Remarks
Rabbit 500 mg Skin 24 H Moderate irritation effect.
Rabbit 0.75 mg Eyes 24 H Severe irritation effect.
Section 12 ?Ecological information
Acute Ecotoxicity Tests: Potassium Cyanide:
Test Type: Species: Time: Value:
LC50 Fish Lepomis macrochirus (Bluegill) 96 H 0.45 mg/L
EC50 Daphnia Daphnia magna 48 H 2 mg/L
EC50 Daphnia Daphnia magna 24 H 0.53 mg/L
Section 13 - Disposal Considerations
Contact a licensed professional waste disposal service to dispose of this material.
Observe all federal, state, and local environmental regulations.
List No: L42-M18 Revision : C Prepared by: AR Approved by: JO Issue date: 08/30/07
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TECO DIAGNOSTICS
List Material Safety Data Sheet (Documentation Requirements)
Calcium
Section 14 - Transport Information
DOT IATA
O-Cresolphthalein Complexone, O-Cresolphthalein Complexone,
8-Hydroxyquinoline, 8-Hydroxyquinoline,
2-Amino-2-methyl-1-propanol & 2-Amino-2-methyl-1-propanol &
Calcium Carbonate: Calcium Carbonate:
Proper Shipping Name: None Non-Hazardous for Air Transport: Non-hazardous for air transport.
Non-Hazardous for Transport: Non-hazardous for transport.
DOT IATA
Potassium Cyanide: Potassium Cyanide:
Proper Shipping Name: Potassium cyanide Proper Shipping Name: Potassium cyanide
UN#: 1680 IATA UN Number: 1680
Class: 6.1 Hazard Class: 6.1
Packing Group: Packing Group I Packing Group: I
Hazard Label: Toxic substances.
PIH: Not PIH
Section 15 - Regulatory Information
O-Cresolphthalein Complexone: O-Cresolphthalein Complexone:
EU ADDITIONAL CLASSIFICATION US CLASSIFICATION AND LABEL TEXT
S: 22 24/25 US Statements: Caution: Avoid contact and inhalation.
Safety Statements: Do not breathe dust. Avoid contact with skin and eyes.
CANADA REGULATORY INFORMATION UNITED STATES REGULATORY INFORMATION
WHMIS Classification: This product has been classified in accordance with SARA LISTED: No
the hazard criteria of the CPR, and the MSDS contains all the information
required by the CPR.
DSL: Yes
NDSL: No
8-Hydroxyquinoline: 8-Hydroxyquinoline:
EU ADDITIONAL CLASSIFICATION US CLASSIFICATION AND LABEL TEXT
Symbol of Danger: Xn Indication of Danger: Harmful.
Indication of Danger: Harmful. Risk Statements: Harmful if swallowed.
R: 22 Safety Statements: Wear suitable protective clothing.
Risk Statements: Harmful if swallowed. US Statements: Target organ(s): Nerves.
S: 36
Safety Statements: Wear suitable protective clothing.
CANADA REGULATORY INFORMATION UNITED STATES REGULATORY INFORMATION
WHMIS Classification: This product has been classified in accordance with SARA LISTED: No
the hazard criteria of the CPR, and the MSDS contains all the information TSCA INVENTORY ITEM: Yes
required by the CPR.
DSL: Yes
NDSL: No
2-Amino-2-methyl-1-propanol: 2-Amino-2-methyl-1-propanol:
EU DIRECTIVES CLASSIFICATION US CLASSIFICATION AND LABEL TEXT
Symbol of Danger: Xi Indication of Danger: Irritant.
Indication of Danger: Irritant. Risk Statements: Irritating to skin. Risk of serious damage to eyes. Harmful
R: 36/38 52/53 to aquatic organisms, may cause long-term adverse effects in the aquatic
Risk Statements: Irritating to eyes and skin. Harmful to aquatic organisms, environment.
may cause long-term adverse effects in the aquatic environment. Safety Statements: In case of contact with eyes, rinse immediately with
S: 61 plenty of water and seek medical advice. Wear suitable protective clothing,
Safety Statements: Avoid release to the environment. Refer to special gloves, and eye/face protection. Avoid release to the environment. Refer to
instructions/safety data sheets. special instructions/safety data sheets.
US Statements: Combustible.
CANADA REGULATORY INFORMATION UNITED STATES REGULATORY INFORMATION
WHMIS Classification: This product has been classified in accordance with SARA LISTED: No
the hazard criteria of the CPR, and the MSDS contains all the information TSCA INVENTORY ITEM: Yes
required by the CPR.
DSL: Yes
NDSL: No
List No: L42-M18 Revision : C Prepared by: AR Approved by: JO Issue date: 08/30/07
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TECO DIAGNOSTICS
List Material Safety Data Sheet (Documentation Requirements)
Calcium
Section 15 - Regulatory Information (Continued)
Potassium Cyanide: Potassium Cyanide:
EU DIRECTIVES CLASSIFICATION US CLASSIFICATION AND LABEL TEXT
Symbol of Danger: T+ N Indication of Danger: Highly Toxic (USA) Very Toxic (EU).
Indication of Danger: Very toxic. Dangerous for the environment. Dangerous for the environment.
R: 26/27/28 32 50/53 Risk Statements: Very toxic by inhalation, in contact with skin and if
Risk Statements: Very toxic by inhalation, in contact with skin and if swallowed. Contact with acids liberates very toxic gas. Causes burns. Very
swallowed. Contact with acids liberates very toxic gas. toxic to aquatic organisms; may cause long-term adverse effects in the
Very toxic to aquatic organisms; may cause long-term adverse effects in the aquatic environment.
aquatic environment. Safety Statements: Keep container tightly closed. After contact with skin,
S: 7 28 29 45 60 61 wash immediately with plenty of water. Do not empty into drains. In case
Safety Statements: Keep container tightly closed. After contact with skin, of accident or if you feel unwell, seek medical advice immediately (show
wash immediately with plenty of soap-suds. Do not empty into drains. In the label where possible). This material and its container must be disposed
case of accident or if you feel unwell, seek medical advice immediately of as hazardous waste. Avoid release to the environment. Refer to special
(show the label where possible). instructions/safety data sheets.
This material and its container must be disposed of as hazardous waste. US Statements: Target organ(s): Blood. Central nervous system.
Avoid release to the environment. Refer to special instructions/safety data
sheets.
CANADA REGULATORY INFORMATION UNITED STATES REGULATORY INFORMATION
WHMIS Classification: This product has been classified in accordance with SARA LISTED: Yes
the hazard criteria of the CPR, and the MSDS contains all the information NOTES: This product is subject to SARA section 313 reporting
required by the CPR. requirements.
DSL: Yes TSCA INVENTORY ITEM: Yes
NDSL: No
Calcium Carbonate: Calcium Carbonate:
EU ADDITIONAL CLASSIFICATION US CLASSIFICATION AND LABEL TEXT
Symbol of Danger: Xi Indication of Danger: Irritant.
Indication of Danger: Irritant. Risk Statements: Irritating to respiratory system and skin. Risk of serious
R: 37/38 41 damage to eyes.
Risk Statements: Irritating to respiratory system and skin. Risk of serious Safety Statements: In case of contact with eyes, rinse immediately with
damage to eyes. plenty of water and seek medical advice. Wear suitable protective clothing,
S: 26 36/37/39 gloves, and eye/face protection.
Safety Statements: In case of contact with eyes, rinse immediately with
plenty of water and seek medical advice. Wear suitable protective clothing,
gloves, and eye/face protection.
CANADA REGULATORY INFORMATION UNITED STATES REGULATORY INFORMATION
WHMIS Classification: This product has been classified in accordance with SARA LISTED: No
the hazard criteria of the CPR, and the MSDS contains all the information TSCA INVENTORY ITEM: Yes
required by the CPR.
DSL: Yes
NDSL: No
Section 16 - Other Information
This Product is labeled in accordance with CFR21 (Food and Drugs), Section 809.10.
The information contained herein has been compiled from data presented in various technical sources believed to be accurate. We make no warranties,
express or implied, and assume no liability in connection with the use of this information. It is the user's responsibility to determine the suitability of this
information and to assure the adoption of necessary safety precautions.
N/A - Not Applicable or Not Available
List No: L42-M18 Revision : C Prepared by: AR Approved by: JO Issue date: 08/30/07
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