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MSDS Material Safety Data Sheet
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1477-55-0 25068-38-6 2855-13-2 616-47-7 68738-77-2

File Name: 1477-55-0_25068-38-6_2855-13-2_616-47-7_68738-77-2.asp

HT 181 HARDENER FOR FILLER                                                        MATERIAL SAFETY DATA SHEET
PART NO: CS-601 (Sub-component of CS-460) Page 1 of 6
CS-621 (Sub-component of CS-462)




Effective Date: 3/18/2008




1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
HMIS RATING
Trade name: RP 1510 HARDENER 1 HEALTH 3
3 0 FLAMMABILITY 1
Chemical family: Amine REACTIVITY 0
NFPA RATING PROTECTIVE
Intended Use or Product Type: Heat resistant Hardener EQUIPMENT


SHIPPER EMERGENCY INFORMATION

Clock Spring Company, L.P. Emergency telephone number
14107 Interdrive West (CHEMTREC): (800) 424-9300
Houston, TX 77032 Other Calls: (800) 471-0060


2. COMPOSITION / INFORMATION ON INGREDIENTS
EXPOSURE LIMITS CARCINOGEN
STATUS
OSHA CAS# CHEMICAL IDENTITY AGGIH OSHA MFR IARC NTP OSHA
TWA STEL PEL STEL
1477-55-0 1,3-Benzenedimethanamine NE 0.1 NE NE NE NR NR NR
Common Name: m-Xylylenediamine mg/m3

25068-38-6 Phenol, 4,4'(1- NE NE NE NE NE NR NR NR
methylethylidene)bis-, polymer
with (chloromethyl) oxirane
Common Name: Bisphenol A Diglycidyl Ether
Polymer

2855-13-2 Cyclohexanemethanamine, 5- NE NE NE NE NE NR NR NR
amino-1,3,3-trimethyl-
Common Name: Isophoronediamine

616-47-7 1H-Imidazole, 1-methyl- NE NE NE NE NE NR NR NR
Common Name: 1-Methylimidazole
? 68738-77-2 1,3 Benzenedimethanamine, NE NE NE NE NE NR NR NR
polymer with diglycidyl ether of
bisphenol A and 2,2,4-trimethyl
1,6 hexane diamine
Common name MXDA/TMD/DGEBA adduct
intermidiate


NE - Not Established NR - Not Reviewed




MSDS NO: 6011
HT 181 HARDENER FOR FILLER MATERIAL SAFETY DATA SHEET
PART NO: CS-601 (Sub-component of CS-460) Page 2 of 6
CS-621 (Sub-component of CS-462)


3. HAZARDS IDENTIFICATION

Emergency Overview: Danger! Corrosive - Cause skin and eye burns. Harmful if absorbed through skin. May cause
allergic skin and respiratory reactions.

Primary Route(s) of Entry: Dermal; heated product may produce inhalable vapors.

Acute Exposure: Danger! Corrosive. Causes skin and eye burns.


4. FIRST AID MEASURES

First aid for ingestion:
If conscious, give plenty of water to drink. Do NOT induce vomiting. Call a physician.

First aid for skin:
Wash with soap and water. Remove contaminated clothing and launder before re-use.

First aid for inhalation:
Remove to fresh air. Give oxygen and/or artificial respiration, if needed. Call a physician.

First aid for eyes:
Immediately flush eyes with water for 15 minutes. Call a physician.

Overexposure Effects:
Danger! Corrosive. Causes skin and eye burns. Causes allergic skin and respiratory reactions. Absorption through
skin may cause nausea, vomiting or other signs of illness.

Medical Conditions Aggravated by Exposure:
Skin and eye conditions.

Additional Information:
Referral to a physician is recommended if there is any question about the serious of any injury.

5. FIRE FIGHTING MEASURES
o o
Flash Point: >250 F (>121 C)
Flash Point Method Used: PMCC
Flammable Limits in Air (lower - % by volume): Not established yet
Flammable Limits in Air (upper - % by volume): Not established yet

Fire Fighting Extinguishing Media: Carbon dioxide, dry chemical, foam, water.
Fire Fighting Equipment: Use self-contained breathing apparatus.
Fire and Explosion Hazards: Decomposition and combustion products may be toxic.


6. ACCIDENTAL RELEASE MEASURES
Spill control:
Remove spillage by absorbing in absorbent material. Avoid contact.

MSDS NO: 6011
HT 181 HARDENER FOR FILLER MATERIAL SAFETY DATA SHEET
PART NO: CS-601 (Sub-component of CS-460) Page 3 of 6
CS-621 (Sub-component of CS-462)

7. HANDLING AND STORAGE

Handling precautions:
Danger! Corrosive. Causes skin and eye burns. Harmful if absorbed through skin. May cause allergic skin and
respiratory reactions. Do not get in eyes, on skin, on clothing. Avoid breathing vapor or mist. Keep container closed. Use
with adequate ventilation. Wash thoroughly after handling.

Other handling information:
Nuisance dust may be generated when sanding or sawing cured material.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION

Skin protection:
Impermeable gloves and protective clothing.

Respiratory Protection:
Use NIOSH approved organic vapor cartridge respirator when vapor/mist exposure is likely.

Eye protection:
Full face shield.

Engineering controls:
General mechanical and local exhaust in accordance with ACGIH recommendations.

9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Clear
Color: Amber
Physical State: Liquid
Solubility in Water: Moderate
Vapor Pressure: Not determined
Specific Gravity: 1.03 - 1.05 (water = 1)
o o
Boiling Point: >400 F (>204 C)
Evaporation Rate: Not determined
Vapor Density: Not determined
VOC: 52.5 g/L

Percent Volatile: Less than 1%.

10. STABILITY AND REACTIVITY
Conditions to avoid:
Excessive heat for prolonged periods of time.
Stability:
Stable.
Incompatibility:
Strong oxidizing agents, acids, metal-organic compounds.
Hazardous Decomposition Products:
Combustion may form toxic materials, such as carbon dioxide, carbon monoxide.
Hazardous Polymerization: Will not occur.
MSDS NO: 6011
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PART NO: CS-601 (Sub-component of CS-460) Page 4 of 6
CS-621 (Sub-component of CS-462)




11. TOXICOLOGICAL INFORMATION

Sensitization:
Possible in susceptible individuals.

Skin Irritation: .
Corrosive. Causes burns.

Eye Irritation:
Corrosive. Causes burns.
,

12. ECOLOGICAL INFORMATION


13. DISPOSAL CONSIDERATIONS

Waste disposal method:
Consult qualified local or corporate personnel for method that will comply with local, state and federal health and
environmental regulations.

14. TRANSPORT INFORMATION:

DOT: Non-Bulk

Proper shipping name: Polyamines, liquid, corrosive, n.o.s.

Technical name: Isophorone diamine, Metaxylenediamine

Hazard class: 8

UN number: UN 2735

Packing group: PG III

Label: Corrosive




MSDS NO: 6011
HT 181 HARDENER FOR FILLER MATERIAL SAFETY DATA SHEET
PART NO: CS-601 (Sub-component of CS-460) Page 5 of 6
CS-621 (Sub-component of CS-462)

15. REGULATORY INFORMATION

U.S. FEDERAL REGULATIONS

OSHA Status: This Material Safety Data Sheet (MSDS) has been prepared in compliance with the federal OSHA Hazard
Communication Standard 29 CFR 1910.1200. This product is considered to be a hazardous chemical under that
standard.

TSCA Inventory Status: Chemical components listed on TSCA Inventory.

SARA Title III: Section 313 - Toxic Chemical(s): This product does not contain a toxic chemical for routine annual Toxic
Chemical Release Reporting' under Sec. 313 (40 CFR 372).

RCRA: Not a hazardous waste under RCRA (40 CFR 261) but handle with care due to corrosive effect on skin and eyes.

California Proposition 65: The following is required composition information. This product contains the following
chemicals which are listed on the California list of Known Carcinogens and reproductive Toxins.

Chemical Name: Oxirane, (phenoxymethyl)
CASRN: 122- 60-1
Common Name: Phenyl Glycidyl Ether
% in Composition: 0.00
Comment: Warning! This chemical is known to the state of California to cause cancer.

Pennsylvania Right to Know: The following is required composition information:

Chemical Name: 1,3Benzenedimethanamine
CASRN: 1477-55-0
Common Name: m-Xylylenediamine
Comment: Hazardous Substance.

Chemical Name: Cyclohexanemethanamine, 5-amino-1,3,3-trimethyl-
CASRN: 2855-13-2
Common Name: Isophoronediamine
Comment: Not on Pennsylvania Hazardous Substance List.

Chemical Name: Phenol, 4,4'(1-methylethylidene)bis-, polymer with (chloromethyl) oxirane
CASRN: 25068-38-6
Common Name: Bisphenol A Diglycidyl Ether Polymer
Comment: Not on Pennsylvania Hazardous Substance List.

Chemical Name: 1H-Imidazole, 1-methyl-
CASRN: 616-47-7
Common Name: 1-Methylimidazole
Comment: Not on Pennsylvania Hazardous Substance List.

VOC's: 52.5 grams/liter (state of California).




MSDS NO: 6011
HT 181 HARDENER FOR FILLER MATERIAL SAFETY DATA SHEET
PART NO: CS-601 (Sub-component of CS-460) Page 6 of 6
CS-621 (Sub-component of CS-462)


16. OTHER INFORMATION:
MSDS No. 6011
Approved by: Jim Souza
Title: SH&E Manager

Revision Summary: The following sections have been modified since the last effective date: 1,4

Disclaimer: This material will not be sold for use in products for which prolonged contact with mucous membranes or abraded skin, or implantation
within the human body, is specifically intended. Because of the wide range of such potential uses, Clock Spring Company, L.P. is not able to
recommend this material as safe and effective for such uses and assumes no liability for any such uses.




MSDS NO: 6011

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