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122-99-6 65-85-0 520-45-6

File Name: 122-99-6_65-85-0_520-45-6.asp

                                      Material Safety Data Sheet
2A528D
Revision Date: 07/20/2005
Issued: 07/20/2005
OPTIPHEN ND
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Responsible Party: International Specialty Products
1361 Alps Rd.
Wayne, N.J. 07470
U.S.A.
Telephone: (973) 628-4000

Emergency Telephone Number: CHEMTREC: 1-800-424-9300 (Spill Related Emergencies)
PROSAR: 1-800-241-7439 (Health Related Emergencies)

Prepared By: Product Stewardship

Product Id: 2A528D

Product Name: OPTIPHEN ND

CAS Registry Number: 122-99-6; 65-85-0; 520-45-6

CAS Name: Ethanol, 2-Phenoxyethanol; Benzoic Acid ; 3-Acetyl-6-methyl-2H-pyran-2,4(3H)-
dione

Synonyms: Phenoxyethanol; Benzoic Acid; Dehydroacetic Acid (INCI NAMES)

2. COMPOSITION/INFORMATION ON HAZARDOUS INGREDIENTS
Components: Weight % ACGIH Threshold Limit OSHA Specifically
Values Data - Time Regulated Substances Data
Weighted Average (TWA): - Time Weighted Average
(TWA):
2-PHENOXYETHANOL 80 No TLV/TWA Established No TLV/TWA Established
122-99-6
Benzoic Acid 12 No TLV/TWA Established No TLV/TWA Established
65-85-0
3-ACETYL-6-METHYL-2H- 8 No TLV/TWA Established No TLV/TWA Established
PYRAN-2,4(3H)-DIONE
520-45-6

Statement of Hazardous Nature: Harmful if swallowed. Causes eye irritation.

3. HAZARDS IDENTIFICATION
Emergency Overview
WARNING! HARMFUL IF SWALLOWED. CAUSES SEVERE EYE IRRITATION AND MAY CAUSE TISSUE DAMAGE.

Hazard Overview
Target Organs: Eyes

Primary Entry Routes: Eyes.

Acute Health Hazards: Causes severe eye irritation.

Chronic Health Hazards: None known.

Signs and Symptoms of Overexposure
2A528D
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Eye Contact: Causes severe eye irritation may cause tissue damage.

Skin Contact: Causes mild skin irritation.

Ingestion: Harmful if swallowed.

Inhalation: Not a hazard under normal use conditions.

4. FIRST AID MEASURES
Eye Contact: Flush eyes with copious amounts of water.

Skin Contact: Wash with soap and water.

Ingestion: Slowly dilute with 1-2 glasses of water and seek medical attention. Never give
anything by mouth to an unconscious person.

Inhalation: No specific treatment is necessary since material is not likely to be hazardous by
inhalation. If exposed to excessive levels of dust or fumes, remove to fresh air and
get medical attention if cough or other symptoms develop.

5. FIRE FIGHTING MEASURES
NFPA Rating: HEALTH 1, FLAMMABILITY 1 , REACTIVITY 0

Flash Point (癋): >266

Extinguishing Media: All standard firefighting media

Unusual Fire/Explosion Hazards: Fire will produce oxides of carbon.

Special Protective Equipment: Fire fighters should wear full protective clothing, including self-contained breathing
equipment.
HMIS RATING:
HEALTH 1
FLAMMABILITY 1
PHYSICAL HAZARD 0

6. ACCIDENTAL RELEASE MEASURES
Personal Precautionary Use appropriate protective equipment. Wear self-contained breathing apparatus in
Measures: enclosed areas.

Procedure for Contain spill with sand or other inert materials.
Cleaning/Absorption:

7. HANDLING AND STORAGE
Handling: Wash thoroughly with soap and water after handling.

Storage: Store in sealed containers in a protected area.

8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: Use in a well ventilated area.

Respiratory Protection: Use in a well ventilated area.

Hand Protection: Use gloves as a standard industrial handling procedure.

Eye Protection: Safety glasses.

9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State: Liquid

Color: Yellow

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Odor: Characteristic

Odor Threshold: Not available

pH: approx. 4.0 @ 100 g/L

Specific Gravity: Not determined

Boiling Point (癋): >302

Melting Point/Freezing Point(癋): Not determined

Vapor Pressure: <0.75 mmHg

Solubility: 5g/L @ 68 癋

10. STABILITY AND REACTIVITY
Chemical Stability: Stable under normal conditions of handling, use and transportation.

Hazardous Polymerization: Will not occur

Conditions to Avoid: None anticipated

Materials to Avoid: Strong acids or alkalies. Strong oxidizing agents.

Hazardous Decomposition Oxides of carbon.
Products:

11. TOXICOLOGICAL INFORMATION
Toxicity Test:
Acute Oral LD50 (mg/kg): >2000 (Rat) (Phenoxyethanol)
1480 (Rat) (Dehydroacetic Acid)

Acute Dermal LD50 (mg/kg): >2000 (Rabbit) (Phenoxyethanol)


Sensitization: Non-Sensitizing (Guinea Pig) (Phenoxyethanol)

Skin Irritation: Non-irritant (Rabbit) (Dehydroacetic Acid)

12. ECOLOGICAL INFORMATION
Biodegradability: Readily Biodegradable, >80% (Phenoxyethanol)

Aquatic Toxicity: Fish, LC50 (96h) >100 mg/L (Phenoxyethanol)
Aquatic invertebrates, EC50 (48h) >500 mg/L (Phenoxyethanol)
Aquatic Plants, EC50 (72h) >500 mg/L (Phenoxyethanol)

Microorganism/Effect on Activated Sludge, EC10 (17h) 320 mg/L (Phenoxyethanol)
Activated Industrial Sludge, EC20 >100 mg/L (Phenoxyethanol)

LC50 0.23 mg/L (96h) (Bluegill) (IPBC)
EC50 0.696 mg/L (48h) (Daphnia magna) (IPBC)

13. DISPOSAL CONSIDERATIONS
Disposal of Waste Method: Federal, state and local disposal laws and regulations will determine the proper
waste disposal/recycling/reclamation procedure. Disposal requirements are
dependent on the hazard classification and will vary by location and the type of
disposal selected.

14. TRANSPORT INFORMATION
Land Transportation:
2A528D
Page 3 of 5
DOT (Non-Bulk):
DOT Shipping Name: NOT REGULATED

UN/NA Number: NONE

Hazard Class: NONE

DOT (Bulk):
DOT Shipping Name: NOT REGULATED

UN/NA Number: NONE

Air Transportation (IATA):
Proper Shipping Name: NOT REGULATED

UN Number: NONE

Hazard Classification: NONE

Sea Transportation (IMO):
Proper Shipping Name: NOT REGULATED

UN/ID Number: NONE

Hazard Classification: NONE

TDG (Canada):
Proper Shipping Name: NOT REGULATED

Hazard Class: NONE

15. REGULATORY INFORMATION
TSCA Inventory List: This product and/or its components is listed on TSCA.

California Proposition 65 None of the components of this product is listed on CALPROP.
Carcinogens & Reproductive
Toxicity (CRT) List:

WHMIS Ingredient Disclosure One or more components of this product is listed on the WHMIS Ingredient
List: Disclosure list.

Canada DSL Inventory List: This product and/or its components is listed on DSL.

Canada NDSL Inventory List: This product and/or its components is not listed on NDSL.

Japan Inventory of Existing & This product and/or its components is listed on ENCS.
New Chemical Substances
(ENCS):

Australia Inventory of Chemical This product and/or its components is listed on AICS.
Substances (AICS) List:

EU EINECS List: This product and/or its components is listed on EINECS.

ELINCS: This product and/or its components is not listed on ELINCS.

Components: 2-PHENOXYETHANOL
122-99-6
EPCRA (SARA Title III) Section Listed.
313 Toxic Chemical -

16. OTHER INFORMATION
Prepared By: Product Stewardship
2A528D
Page 4 of 5
Legend: N.Av.= Not Available; N.Ap.= Not Applicable

Important Note: For purposes of this MSDS, International Specialty Products, as responsible party,
provides the information herein which is intended for use by persons who have or
should obtain professional knowledge and experience in the subjects discussed.
ISP's industrial products are used as materials in the production of products by
industrial customers. ISP usually has only limited information about the products of
its customers and their composition, methods of manufacture and use. Accordingly,
ISP MAKES NO WARRANTY, EXPRESS OR IMPLIED, AS TO THE ACCURACY,
COMPLETENESS OR RELIABILITY OF INFORMATION HEREIN EXCEPT THAT
SUCH INFORMATION IS, TO THE BEST OF ISP'S KNOWLEDGE AND BELIEF,
ACCURATE AS OF THE DATE INDICATED. ISP recommends that customers
independently test and evaluate its products and their products and processes in
which ISP products are used in order to decide their safety and effectiveness.

***END OF MSDS***




2A528D
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