Material Safety Data Sheet
Page 1 of 7 Issue date: August 2005
M-BOND 450 (Part A)
1. IDENTIFICATION OF THE MATERIAL AND SUPPLIER
Davidson Measurement Pty. Ltd
ACN: 005 031 961 ABN: 29 005 031 961
Phone: 03 9580 4366
Fax: 03 9580 6499
Email: info@davidson.com.au
Web: www.davidson.com.au
Address: 1-3 Lakewood Boulevard,
Braeside, Victoria, 3195.
Product Name: M-BOND 450 (Part A)
Manufacturer's Product Code: MGM055D
Use: High-performance, two component, solvent-thinned epoxy system specially formulated for high accuracy,
elevated-temperature transducer applications.
2. HAZARDS IDENTIFICATION
HAZARDOUS ACCORDING TO EU CRITERIA
Hazard Category: Toxic (T), Irritant (Xi), Flammable (F)
Hazard Classification: HAZARDOUS SUBSTANCE, DANGEROUS GOOD
RISK PHRASES
R11 Highly flammable
R36 Irritating to eyes.
R60 May impair fertility.
R61 May cause harm to the unborn child.
R66 Repeated exposure may cause skin dryness and cracking.
R67 Vapours may cause drowsiness and dizziness.
SAFETY PHRASES
S2 Keep out of reach of children.
S7/9 Keep container tightly closed and in a well ventilated place.
S16 Keep away from sources of ignition - No smoking.
S24/25 Avoid contact with skin and eyes.
S33 Take precautionary measures against static discharge.
S45 In case of accident or if you feel unwell, contact a doctor or Poisons Information Centre immediately and show
this container or label.
S53 Avoid exposure - obtain special instructions before use.
Poison Schedule: S6 [Aust]
This material is a Scheduled S6 Poison and must be stored, handled and used according to the appropriate regulations.
Road Transport
UN Number: 1866
Proper Shipping Name: RESIN SOLUTION(Contains METHYL ETHYL KETONE and DIACETONE ALCOHOL)
Dangerous Goods Class: 3
Packing Group: II
Warning Statement:
Avoid contact with this product. If possible use local exhaust ventilation system. Avoid all sources of ignition. Highly
flammable liquid.
Material Safety Data Sheet
Page 2 of 7 Issue date: August 2005
M-BOND 450 (Part A)
3. COMPOSITION / INFORMATION ON INGREDIENTS
SUBSTANCE NAME Proportion CAS Number
ARYL ALKYL OXIRANE RESIN > 60 % 7328-97-4
METHYL ETHYL KETONE 10 to 30 % 78-93-3
ETHYLENE GLYCOL MONOETHYL ETHER 10 to 30 % 110-80-5
DIACETONE ALCOHOL 10 to 30 % 123-42-2
PHENYL GLYCIDYL ETHER > 1% 122-60-1
EPICHLORHYDRIN < 200 ppm 106-89-8
Please Note: The epichlorhydrin component may be present as a residual from phenyl glycidyl ether and Epoxy resin
manufacturer.
All other ingredients not hazardous according to EU Criteria.
4. FIRST AID MEASURES
Swallowed:
If swallowed, DO NOT induce vomiting. If victim conscious, give 1 to 2 glasses of water to drink. Seek urgent medical
assistance.
Eye:
If material is splashed into eyes, flush with plenty of water for at least 15 minutes, ensuring eye lids are held open.
Immediately transport to hospital or doctor.
Skin:
If material is splashed onto the skin, remove any contaminated clothing and wash skin thoroughly with soap and water.
If irritation persists immediately transport to hospital or doctor.
Inhaled:
Remove victim to fresh air. Apply resuscitation if victim is not breathing - Administer oxygen if breathing is difficult.
Transport to hospital or doctor immediately.
First Aid Facilities:
Eye wash fountain, safety shower and normal wash room facilities.
Advice to Doctor:
Treat symptomatically.
In case of poisoning, contact Poisons Information Centre
In Australia call Tel: 131126
In New Zealand Tel: 034747000
5. FIRE-FIGHTING MEASURES
Fire/Explosion Hazard
SUITABLE EXTINGUISHING MEDIA: Foam, dry chemical or carbon dioxide.
HAZARDS FROM COMBUSTION PRODUCTS: On combustion or on thermal decomposition (pyrolysis), there
will be a release of oxides of carbon and oxides of nitrogen and noxious smoke.
PRECAUTIONS FOR FIRE FIGHTERS AND SPECIAL PROTECTIVE EQUIPMENT: Self-contained
breathing apparatus (SCBA) required for fire-fighting personnel. If possible to do so safely, shut off fuel to fire. Avoid
spreading burning liquid with water used for cooling fire exposed containers when using water spray, boil-over may
occur when the product temperature reaches the boiling point of water, thereby resulting in re-ignition.
HAZCHEM CODE: 3[Y]E [Aust]
Material Safety Data Sheet
Page 3 of 7 Issue date: August 2005
M-BOND 450 (Part A)
5. FIRE-FIGHTING MEASURES (Continued)
FLAMMABILITY
This product is a FLAMMABLE liquid.
Flash Point: - 6癈
Flammability Limits: LEL: 1.8 % UEL: 11.4 %
6. ACCIDENTAL RELEASE MEASURES
Emergency Procedures:
Flammable liquid. Ventilate area. Avoid all sources of ignition. Keep unnecessary people away; Isolate hazard area and
deny entry. Wear suitable protective equipment as outlined under personal protection in this MSDS.
Methods and Materials for Containment and Clean Up Procedures:
Throw diatomaceous earth onto spill. DO NOT use sawdust. Use non-sparking tools or HEPA vacuum system to pick
up. Place into properly labeled drum for later disposal.
Emergency information(Transport):
Dangerous Goods - Initial Emergency Response Guide (SAA/SNZ HB76:1997)
For LIQUIDS - Highly Flammable, Guide No: 14
7. HANDLING AND STORAGE
Precautions for Safe Handling:
Highly Flammable liquid. Avoid ignition sources. Provide adequate ventilation. Avoid exposure by all routes.
Conditions for Safe Storage:
Keep containers tightly closed, when not using the product. Store in original packages as approved by manufacturer.
Store in an area that is dry and well-ventilation away from ignition sources. Store below 27 C. Can react vigorously
with strong oxidizing agents, strong Lewis or mineral acids, and strong mineral and organic bases; especially primary
and secondary aliphatic amines. For further information please refer to the Engineering Controls of this MSDS.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Standards
No exposure standards are available for this product, however, the following exposure standards have been assigned by
[NOHSC] to the following components of the product:
METHYL ETHYL KETONE
[NOHSC]
[TWA]150 ppm 445 mg/m3
[STEL]300 ppm 890 mg/m3
References: A
ETHYLENE GLYCOL MONOETHYL ETHER
[NOHSC]
18 mg/m3
[TWA]5 ppm
Notices: Sk
Sk Notation:
The main route of most hazardous substances into the body is via inhalation, however, certain substances such as
ethylene glycol monoethyl ether can readily penetrate the skin, with resultant toxic effects. The notice 'Sk' indicates that
absorption can occur through the skin.
References: H
Material Safety Data Sheet
Page 4 of 7 Issue date: August 2005
M-BOND 450 (Part A)
8. EXPOSURE CONTROLS / PERSONAL PROTECTION (Continued)
DIACETONE ALCOHOL
(Worksafe Australia)
[TWA]50 ppm 238 mg/m3
References: H
PHENYL GLYCIDYL ETHER
[NOHSC]
6.1 mg/m3
[TWA]1 ppm
Notices: Sen
Sen Notation:
Some substances can cause a specific immune response in some people. Such substances are called sensitisers and the
development of a specific immune response is termed 'sensitisation'. Exposure to a sensitiser, once sensitisation has
occurred, may manifest itself as a skin rash or inflammation or as an asthmatic condition, and in some individuals this
reaction be extremely severe.
References: H
Engineering Controls
Flammable liquid. Maintain adequate ventilation at all times. Prevent accumulation of vapours in hollows or sumps.
Eliminate any sources of ignition.
Personal Protection Equipment
GLOVES: Neoprene or nitrile rubber.
EYES: Chemical goggles or spectacles with side shields to protect eyes.
RESPIRATORY PROTECTION: Avoid breathing of vapours. Filter capacity and respirator type depends on
exposure levels and type of contaminant. Select and use respirators in accordance with AS/NZS 1715/1716. When
vapours exceed the exposure standards then the use of a half-face respirator fitted with an organic vapour cartridge is
recommended. If entering confined spaces or if unknown levels of contaminate are a potentiality, then the use of a
Self-contained breathing apparatus (SCBA) with positive pressure air supply complying with AS/NZS 1715 / 1716, or
any other acceptable International Standard is recommended.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Deep amber, somewhat viscous liquid with acetone-like odour.
Boiling Point: Not available.
Vapour Pressure: 44 mmHg @ 20癈
Specific Gravity: 1.05
Flash Point: - 6癈
Flammability Limits: LEL: 1.8 % UEL: 11.4 %
Solubility in Water: Insoluble ( > 10 %)
Other Properties
Vapor Density (Air = 1): 3.5
Volatile Organic Compounds: 37 %
Material Safety Data Sheet
Page 5 of 7 Issue date: August 2005
M-BOND 450 (Part A)
10. STABILITY AND REACTIVITY
CHEMICAL STABILITY:
Stable under normal conditions of use.
CONDITIONS TO AVOID:
Ignition sources and mixing with incompatibles.
INCOMPATIBLE MATERIALS:
Strong mineral acids (sulfuric, nitric and hydrochloric), and oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS:
Oxides of carbon, aldehydes and acids may be formed during combustion. Reaction with some curing agents and in the
process may produce considerable heat.
HAZARDOUS REACTIONS:
Under appropriate conditions this product may rapidly and uncontrollably polymerise releasing heat, and potential
ignition and propagation of fire may result.
11. TOXICOLOGICAL INFORMATION
No adverse health effects are expected, if the product is handled in accordance with this Material Safety Data Sheet and
the product label. Symptoms and effects that may arise if the product is mishandled and overexposure occurs are:
ACUTE HEALTH EFFECTS
Swallowed:
May cause irritation to mouth, throat and stomach with effects including mucous build up, irritation to the tongue and
lips and pains in the stomach, which may lead to nausea, vomiting and diarrhoea.
Eye:
Will cause irritation to the eyes, with effects including: tearing, pain, stinging and blurred vision. Depending upon
duration of exposure, eye damage may occur.
Skin:
May cause irritation to the skin, with effects including; Redness and itchiness.
Inhaled:
May cause irritation to the nose, throat and respiratory system with effects including: Dizziness, headache, nausea,
vomiting, drowsiness and loss of co-ordination.
Chronic:
Prolonged or repeated skin contact may lead to dermatitis. Prolonged or repeated exposure may lead to permanent
irreversible injury. Repeated exposure may cause skin dryness or cracking. Vapours may cause drowsiness and
dizziness.
ETHYLENE GLYCOL MONOETHYL ETHER has been classified as a CATEGORY 2 TOXIC TO
REPRODUCTION (WORKSAFE). Probable human reproductive hazards are those substances for which there is
sufficient evidence to provide a strong presumption that human exposure might result in impairment in fertility and or
cause birth defects. This evidence is generally based upon appropriate long term animal studies, limited
epidemiological evidence or other relevant information.
EPICHLOROHYDRIN has been classified as a CATEGORY 2 CARCINOGEN (WORKSAFE).
Probable human carcinogens are those substances for which there is sufficient evidence to provide a strong presumption
that human exposure might result in the development of cancer. This evidence is generally based upon appropriate long
term animal studies, limited epidemiological evidence or other relevant information.Prolonged or repeated exposure
may lead to permanent irreversible injury.
Material Safety Data Sheet
Page 6 of 7 Issue date: August 2005
M-BOND 450 (Part A)
11. TOXICOLOGICAL INFORMATION (Continued)
Methyl Ethyl Ketone:
Inhalation LC50(rat): 23,500 mg/m3/8H
Oral LD50(rat): 2,737 mg/kg
12. ECOLOGICAL INFORMATION
No information is available for this product, however, large quantities should not be discharged to waterways, sewers or
drains.
13. DISPOSAL CONSIDERATIONS
Refer to appropriate authority in your State. Dispose of material through a licensed waste contractor. Advise flammable
and toxic nature. If large amounts of the product enter waterways, sewers or streams, immediately contact the
Environmental Protection Agency or your Local Waste Management Authority.
14. TRANSPORT INFORMATION
Road Transport
UN Number: 1866
Proper Shipping Name: RESIN SOLUTION(Contains METHYL ETHYL KETONE and DIACETONE ALCOHOL)
Dangerous Goods Class: 3
Packing Group: II
Label: Toxic (T), Irritant (Xi), Flammable (F)
Air Transport
UN Number: 1866
Proper Shipping Name: RESIN SOLUTION(Contains METHYL ETHYL KETONE and DIACETONE ALCOHOL)
Dangerous Goods Class: 3
Packing Group: II
Label: Toxic (T), Irritant (Xi), Flammable (F)
Sea Transport
UN Number: 1866
Proper Shipping Name: RESIN SOLUTION(Contains METHYL ETHYL KETONE and DIACETONE ALCOHOL)
Dangerous Goods Class: 3
Packing Group: II
Label: Toxic (T), Irritant (Xi), Flammable (F)
15. REGULATORY INFORMATION
Poison Schedule: S6 [Aust]
This product is a Scheduled (S6) Poison and must be stored, handled and used according to the appropriate regulations.
Inventory Status:
Australia (AICS) Y
United States (TSCA) Y
Canada (DSL) Y
Europe (EINECS/ELINCS) Y
Y = all ingredients are on the inventory.
Material Safety Data Sheet
Page 7 of 7 Issue date: August 2005
M-BOND 450 (Part A)
16. OTHER INFORMATION
Date of Preparation:
Issue date: August 2, 2005 Supercedes: March 29, 2000
Reasons for Update:
1. Alignment with the 2nd Edition of National Code of Practice for the Preparation of Material Safety Data Sheets
[NOHSC:2001(2003)].
2. Changes and /or addition made to all sections.
Key Legend Information:
NOHSC - National Occupational Health & Safety Commission [Aust]
SUSDP - Standard for the Uniform Scheduling of Drugs and Poisons [Aust]
TWA - Time Weighted Average [Int]
STEL - Short Term Exposure Limit [Int]
AICS - Australian Inventory of Chemical Substances
EPA - Environmental Protection Agency [Int]
NIOSH - National Institute for Occupational Safety and Health [US]
AS/NZS 1715 - Selection, use and maintenance of respiratory protective devices. [Aust/NZ]
AS/NZS 1716 - Respiratory protective devices. [Aust/NZ]
(SAA/SNZ HB76:1997) - Dangerous Goods - Initial Emergency Response Guide [Aust/NZ]
AS 1940 - The Storage and Handling of Flammable and Combustible Liquids [Aust]
Hazchem Code: Designation for fire fighters [Aust]
IATA - International Aviation Transport Authority [Int]
ICAO - International Civil Aviation Organization [Int]
IMO - International Maritime Organisation. [Int]
IMDG - International Maritime Dangerous Goods [Int]
United Nations Recommendations for the Transport of Dangerous Goods and Globally Harmonized System for the
classification and labelling of Chemicals. [Int]
EU - European Union [Int]
[Aust/NZ] = Australian/New Zealand
[Int] = International
[US] = United States of America
Principal References:
Information supplied by manufacturer.
Disclaimer
To the best of our knowledge, the information provided above meets the requirements of European Union directives for
hazardous substances which have been tested as a whole. The data provided on this Material Safety Data Sheet is from
manufacturers of the original components. All animal test data has been obtained from the public domain, NO
ANIMAL TESTS have been conducted by Davidson Pty Ltd. Davidson Pty Ltd specifically disclaims any and all form
of liability and/or responsibility for the application of this product.
END of MSDS
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