Page : 1
MATERIAL SAFETY DATA SHEET Revised edition no : 2
According to 2001/58EC Date : 14 / 3 / 2006
Supersedes : 2 / 12 / 2005
Wash & Wax 32104354
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY
: Wash & Wax
Trade name
: Cleaning product.
Type of product
Floor protection
: Industrial.
Use
For professional use only.
: Ecover Belgium NV
Company identification
Industrieweg 3
2390 Malle Belgium
: sds@ecover.com
e-mail:
: +32 (0)3 309 25 00
Phone
: +32 (0)3 311 72 70
Fax
: +32 (0)70 245 245 (Antipoison Centre Belgium)
Emergency phone nr
: See address above.
Responsible for placing on the
market
2. HAZARDS IDENTIFICATION
: Not classified as dangerous product.
Hazards identification
Symptoms relating to use
: None under normal conditions.
- Inhalation
: Prolonged or repeated contact may cause skin to become dry.
- Skin contact
: Irritation to eyes.
- Eye contact
: Bitrex makes it virtually impossible to ingest this product.
- Ingestion
3. COMPOSITION / INFORMATION ON INGREDIENTS
: Preparation
Substance / Preparation
: This product contains hazardous components (Directive 67/548/EEC).
Components
: Regulation (CE) No. 648/2004 of 31 March 2004 on detergents:
Composition
< 5% : - Nonionic surfactants
5% - 15% : - Anionic surfactants
Perfumes - Preservatives
AMYL CINNAMAL, 2 - (4 - TERT - BUTYLBENZYL)PROPIONALDEHYDE,
LINALOOL, CITRONELLOL, LIMONENE.
2-BROMO-2-NITROPROPANE-1,3-DIOL
Substance name Contents CAS No EC No Index No Classification
Sodium Lauryl Ether Sulfate : Between 1 and 10 % 68891-38-3 POLYMER ----- Xi; R38-41
Ethoxylated Fatty Alcohol C12-18 : Between 1 and 10 % 68213-23-0 ----- ----- Xn; R22
Xi; R41
Perfume : Between 0.1 and 1 % ----- ----- ----- Xn; R65
R43
N; R51-53
Limonene (D-) : Between 0.01 and 0.1 % 5989-27-5 227-813-5 601-029-00-7 R10
Xi; R38
R43
N; R50-53
2-bromo-2-nitropropane-1,3-diol : Between 0.01 and 0.1 % 52-51-7 200-143-0 603-085-00-8 Xn; R21/22
Xi; R37/38-41
N; R50
Linalool : Between 0.01 and 0.1 % 78-70-6 201-134-4 -----
Amyl Cinnamal : Between 0.01 and 0.1 % 122-40-7 ----- -----
2-(4-tert-Butyl benzyl) : Between 0.01 and 0.1 % 80-54-6 201-289-8 ----- Xn; R22
propionaldehyde (Lilial) R43
Citronellol : Between 0.01 and 0.1 % 106-22-9 203-375-0 ----- Xi; R38
R43
Ecover Belgium NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgium
Page : 2
MATERIAL SAFETY DATA SHEET Revised edition no : 2
According to 2001/58EC Date : 14 / 3 / 2006
Supersedes : 2 / 12 / 2005
Wash & Wax 32104354
3. COMPOSITION / INFORMATION ON INGREDIENTS (continued)
N; R51-53
: SODIUM LAURETH SULFATE
INCI
Alcohol(C12-18)EO(>5-10)
Perfume
LIMONENE
2-BROMO-2-NITROPROPANE-1,3-DIOL
LINALOOL
AMYL CINNAMAL
2 - (4 - TERT - BUTYLBENZYL)PROPIONALDEHYDE
CITRONELLOL
4. FIRST AID MEASURES
First aid measures
: Not relevant.
- Inhalation
: Rinse affected area thoroughly with water to remove concentrated product.
- Skin contact
Remove contaminated clothing.
: Rinse immediately and for a long time with plenty of water. Seek medical attention
- Eye contact
if the irritation persists. Inadequate first aid may lead to persisting eye complaints.
: Wash out mouth and do not induce vomiting! Let the victim drink 2 glasses of water
- Ingestion
on his own. Administer 100 mg of Dimethicone within 1 hour. Same treatment in
case of ingestion of > 60 ml and seek medical attention immediately.
: Treat symptomatically if heavy vomiting and diarrhoea persist (water and
Note to physician
electrolyte). Carry out gastric intubation after having administered Dimethicone and
only in case of ingestion of more than 5 swallows without having resulted in
vomiting.
: No specific recommendations.
Workplace equipment
5. FIRE-FIGHTING MEASURES
: None.
Specific hazards
Extinguishing media
: All extinguishing media can be used.
- Suitable extinguishing media
: None.
- Unsuitable extinguishing media
: Exercise caution when fighting any chemical fire.
Protection against fire
See Heading 8.
6. ACCIDENTAL RELEASE MEASURES
: Spill area may be slippery.
Personal precautions
Avoid contact with skin and eyes.
See Heading 8.
: Avoid release to the environment.
Environmental precautions
Prevent entry to sewers and public waters.
: Recover spilled material as much as possible in a clean container for reuse. Spilled
Clean up methods
product must be collected with sand or an inert absorbent material and dispose of
as chemical waste. Rinse away remainder with water.
7. HANDLING AND STORAGE
: Not expected to be a fire/explosion hazard under normal conditions of use.
Protection against fire
: Store in a cool and frost-free place.
Storage
: Avoid contact with skin and eyes.
Handling
Ecover Belgium NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgium
Page : 3
MATERIAL SAFETY DATA SHEET Revised edition no : 2
According to 2001/58EC Date : 14 / 3 / 2006
Supersedes : 2 / 12 / 2005
Wash & Wax 32104354
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Personal protection
: Wear waterproof gloves when taking up intensively material which is accidentally
- Skin protection
released.
: Wear safety goggles when clearing accidentally released material.
- Eye protection
: Not relevant.
- Respiratory protection
Environment protection see ?6
9. PHYSICAL AND CHEMICAL PROPERTIES
: Liquid.
Physical state at 20 癈
: Yellow.
Colour
: Orange/mint.
Odour
: 7
pH value (concentrated product)
: 1,04 kg/l
Density
: <50 mPa.s
Viscosity at 25癈 [mPa.s] (Brookfield
LVT)
: Good.
Solubility in water
: >100
Flash point [癈]
: 0.3
Volatile Organic Compounds (%)
: None.
Explosion limits
: None.
Oxidising properties
10. STABILITY AND REACTIVITY
: No decomposition under normal conditions of storage and use.
Stability and reactivity
: Do not store <0癈 and >40癈.
Conditions to avoid
: Do not mix with other cleaning products.
Materials to avoid
: None under normal conditions.
Hazardous decomposition products
11. TOXICOLOGICAL INFORMATION
Skin irritation (RBC test: Denaturation : 226
Index) (ppm)
Evaluation of the security for the
human health
: Not or only slightly irritant due to the composition.
- Dermal
: Not or only slightly irritant due to the composition.
- Ocular
: Hardly toxic (LD 50 rat-oral-theoretical 5000-15000 ppm).
- Ingestion
Bitrex makes it virtually impossible to ingest this product.
: This product contains sensitizing fragrance components > 100 ppm: see ?2 and
Sensitization
15.
: All Techno Green products contain only ELINCS or EINECS registred raw materials
Note
and do not contain any ingredients known to be mutagenic, carcinogenic,
teratogenic or reproduction toxic (R45,46,47,49,60,61,63,64, EU 97/C234, 67/548/
EEC, 88/379/EEC, OSHA, NTP, IARC (cat 1-3))
12. ECOLOGICAL INFORMATION
Ecological effects information
: No data available.
Biodegradation [%] Sapromat
respirometry test (OECD 301 F)
Ecover Belgium NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgium
Page : 4
MATERIAL SAFETY DATA SHEET Revised edition no : 2
According to 2001/58EC Date : 14 / 3 / 2006
Supersedes : 2 / 12 / 2005
Wash & Wax 32104354
12. ECOLOGICAL INFORMATION (continued)
: 43 Slightly toxic
EC50 72h Algae (Selenastrum
capricornutum) [ppm] (OECD 201)
48 Hour EC50 Daphnia magna [ppm] : 117 Hardly toxic.
(OECD 202)
: Techno Green products do not contain any bioaccumulating raw materials and no
Remarks
PCM or nitromusk perfume components.
13. DISPOSAL CONSIDERATIONS
: Dispose in a safe manner in accordance with local/national regulations.
General
: Waste of this product is considered chemical waste. The legislation concerning
Product
disposal of waste can differ from one country/state to another. The disposal should
therefore be done according to national or local waste legislation. If in doubt, ask
the local waste management authority for advice (also see ?6 and ?8 when
disposing of).
: The empty packaging of this product is not subject to ADR. Cleaned empty
Packaging
packaging (including labels and caps) is fully recycable (HDPE + PP); they may be
collected selectively for recycling according to national or local waste legislation.
Uncleaned packaging should be disposed of as chemical waste.
14. TRANSPORT INFORMATION
: Not classified.
General information
15. REGULATORY INFORMATION
: None.
R Phrase(s)
: None.
S Phrase(s)
: < 5% : - Nonionic surfactants
EEC Composition of detergents
5% - 15% : - Anionic surfactants
Perfumes - Preservatives
AMYL CINNAMAL, 2 - (4 - TERT - BUTYLBENZYL)PROPIONALDEHYDE,
LINALOOL, CITRONELLOL, LIMONENE.
2-BROMO-2-NITROPROPANE-1,3-DIOL.
16. OTHER INFORMATION
: For correct use of this product: see Technical Data Sheet.
Training advice
List of relevant R phrases (heading 3) : R10 : Flammable.
R21/22 : Harmful in contact with skin and if swallowed.
R22 : Harmful if swallowed.
R37/38 : Irritating to respiratory system and skin.
R38 : Irritating to skin.
R41 : Risk of serious damage to eyes.
R43 : May cause sensitization by skin contact.
R50 : Very toxic to aquatic organisms.
R50/53 : Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R65 : Harmful : may cause lung damage if swallowed.
: MSDS and additional literature data of the respective suppliers.
Sources of key data used
Gloxhuber C, K黱stler K, 1992. Anionic Surfactants, Surfactant Science Series 43,
ed M.Dekker.
: Revision - See : *
Revision
Ecover Belgium NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgium
Page : 5
MATERIAL SAFETY DATA SHEET Revised edition no : 2
According to 2001/58EC Date : 14 / 3 / 2006
Supersedes : 2 / 12 / 2005
Wash & Wax 32104354
16. OTHER INFORMATION (continued)
: 30 / 8 / 2007
Print date
: None.
Further information
The contents and format of this SDS are in accordance with EEC Commission Directive 2001/58EC.
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other
reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way
connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this
product. If the product is used as a component in another product, this MSDS information may not be applicable.
End of document
Ecover Belgium NV In case of emergency : +32 (0)70 245 245 (Antipoison Centre Belgium)
Industrieweg 3 2390 Malle Belgium
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