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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 30.10.2008 Revision: 30.10.2008
1 Identification of the substance/preparation and of the company/undertaking
?Product details
?Trade name: 40987 10 Minute Universal Urethane
?Article number: 40987
?Application of the substance / the preparation Adhesives
?Manufacturer/Supplier:
SEM Products Inc.
651 Michael Wylie Dr.
Charlotte, NC 28217
(704)522-1006
?Further information obtainable from:
labsupport@sem.ws : SEM Products 651 Michael Wylie Dr. Charlotte, NC 28217 : phone 1-704-522-1006, M -
TH 7am - 4pm EDT
?Information in case of emergency: 24 HR EMERGENCY CHEMTREC 1-800-424-9300
2 Hazards identification
?Hazard description:
Xn Harmful
?Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of the "General Classification guideline for
preparations of the EU" in the latest valid version.
R 20 Harmful by inhalation.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 42/43 May cause sensitisation by inhalation and skin contact.
R 52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Contains isocyanates. See information supplied by the manufacturer
?Classification system:
The classification is according to the latest editions of the EU-lists, and extended by company and literature data.
?GHS label elements
Danger
3.4/1 - May cause allergy or asthma symptoms or breathing difficulties if inhaled.
3.2/2 - Causes skin irritation.
3.3/2A - Causes serious eye irritation.
3.4/1 - May cause an allergic skin reaction.
Warning
3.1/4 - Harmful if inhaled.
3.8/3 - May cause respiratory irritation.
4.1/3 - Harmful to aquatic life with long lasting effects.
?Prevention:
Avoid breathing dust/fume/gas/mist/vapours/spray.
Wash thoroughly after handling.
(Contd. on page 2)
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Page 2/7
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 30.10.2008 Revision: 30.10.2008
Trade name: 40987 10 Minute Universal Urethane
(Contd. of page 1)
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Avoid release to the environment.
Wear protective gloves/protective clothing/eye protection/face protection.
In case of inadequate ventilation wear respiratory protection.
?Response:
IF ON SKIN: Wash with plenty of soap and water.
IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing.
IF INHALED: If breathing is difficult, remove to fresh air and keep at rest in a position comfortable for
breathing.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.
Continue rinsing.
Call a POISON CENTER or doctor/physician if you feel unwell.
Specific treatment (see label).
If skin irritation occurs: Get medical advice/attention.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician.
Take off contaminated clothing and wash before reuse.
Wash contaminated clothing before reuse.
?Storage:
Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
?Disposal:
Dispose of contents/container in accordance with local/regional/national/international regulations.
3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of substances listed below with nonhazardous additions.
?Dangerous components:
CAS: 101-68-8 4,4'-methylenediphenyl diisocyanate 13 - 30%
EINECS: 202-966-0 Xn, Xi; R 20-36/37/38-42/43
Danger: 3.4.R/1, 3.2/2, 3.3/2A, 3.4.S/1
Warning: 3.1.I/4, 3.8/3
Polyurethane prepolymer/ Proprietary 13 - 30%
Xi; R 36/37/38
Warning: 3.2/2, 3.3/2A, 3.8/3
Polyurethane prepolymer / Proprietary 5 - 7%
Xi; R 36/37/38
Warning: 3.2/2, 3.3/2A, 3.8/3
CAS: 26447-40-5 methylenediphenyl diisocyanate 1-1.5%
EINECS: 247-714-0 Xn, Xi; R 20-36/37/38-42/43
Danger: 3.4.R/1, 3.2/2, 3.3/2A, 3.4.S/1
Warning: 3.1.I/4, 3.8/3
CAS: 9046-10-0 POLYOXYPROPYLENEDIAMINE 1-1.5%
T, C, Xi; R 20/22-34-36/37/38-39
Danger: 3.1.O/3, 3.1.I/4, 3.8/3; 3.2/1B
(Contd. on page 3)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 30.10.2008 Revision: 30.10.2008
Trade name: 40987 10 Minute Universal Urethane
(Contd. of page 2)
CAS: 122-51-0 triethyl orthoformate 1-1.5%
EINECS: 204-550-4 R 10
Warning: 2.6/3
1%
CAS: 68479-98-1 diethylmethylbenzenediamine
EINECS: 270-877-4 Xn, Xi, N; R 21/22-36-48/22-50/53
Danger: 3.1.O/3, 3.1.D/3, 3.3/2A
Warning: 3.9/2; 4.1.C/1
?Additional information: For the wording of the listed risk phrases refer to section 16.
4 First aid measures
?General information:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours
after the accident.
?After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
?After skin contact: Immediately wash with water and soap and rinse thoroughly.
?After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
?After swallowing: If symptoms persist consult doctor.
5 Fire-fighting measures
?Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
?Protective equipment: Mouth respiratory protective device.
6 Accidental release measures
?Person-related safety precautions: Not required.
?Measures for environmental protection:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
?Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13.
Ensure adequate ventilation.
7 Handling and storage
?Handling:
?Information for safe handling:
Ensure good ventilation/exhaustion at the workplace.
Prevent formation of aerosols.
?Information about fire - and explosion protection: No special measures required.
(Contd. on page 4)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 30.10.2008 Revision: 30.10.2008
Trade name: 40987 10 Minute Universal Urethane
(Contd. of page 3)
?Storage:
?Requirements to be met by storerooms and receptacles: No special requirements.
?Information about storage in one common storage facility: Not required.
?Further information about storage conditions: Keep container tightly sealed.
8 Exposure controls/personal protection
?Additional information about design of technical facilities: No further data; see item 7.
?Ingredients with limit values that require monitoring at the workplace:
101-68-8 4,4'-methylenediphenyl diisocyanate
WEL Short-term value: 0.07 mg/m?br>
Long-term value: 0.02 mg/m?br>
Sen; as -NCO
?Additional information: The lists valid during the making were used as basis.
?Personal protective equipment:
?General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Avoid contact with the eyes and skin.
?Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use
self-contained respiratory protective device.
?Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the
chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer. As the product is a preparation of several substances, the resistance
of the glove material can not be calculated in advance and has therefore to be checked prior to the application.
?Penetration time of glove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be
observed.
?Eye protection:
Tightly sealed goggles
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(Contd. on page 5)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 30.10.2008 Revision: 30.10.2008
Trade name: 40987 10 Minute Universal Urethane
(Contd. of page 4)
9 Physical and chemical properties
?General Information
Liquid
Form:
According to product specification
Colour:
Characteristic
Odour:
?Change in condition
Melting point/Melting range: Undetermined.
Boiling point/Boiling range: 208癈
94癈
?Flash point:
520癈
?Ignition temperature:
Product is not selfigniting.
?Self-igniting:
Product does not present an explosion hazard.
?Danger of explosion:
In use, may form flammable/explosive vapour-air mixture.
?Explosion limits:
0.4 Vol %
Lower:
0 hPa
?Vapour pressure at 20癈:
1.1 g/cm?br>
?Density at 20癈:
?Solubility in / Miscibility with
Not miscible or difficult to mix.
water:
?Solvent content:
0.7 %
Organic solvents:
8.7 g/l
VOC (EC)
99.2 %
?Solids content:
10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Dangerous reactions No dangerous reactions known.
?Dangerous decomposition products: No dangerous decomposition products known.
11 Toxicological information
?Acute toxicity:
?LD/LC50 values relevant for classification:
101-68-8 4,4'-methylenediphenyl diisocyanate
Oral LD50 2200 mg/kg (mouse)
68479-98-1 diethylmethylbenzenediamine
Oral LD50 738 mg/kg (rat)
Dermal LD50 >2000 mg/kg (rat)
?Primary irritant effect:
?on the skin: Irritant to skin and mucous membranes.
(Contd. on page 6)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 30.10.2008 Revision: 30.10.2008
Trade name: 40987 10 Minute Universal Urethane
(Contd. of page 5)
?on the eye: Irritating effect.
?Sensitization:
Sensitization possible through inhalation.
Sensitization possible through skin contact.
?Additional toxicological information:
The product shows the following dangers according to the calculation method of the General EU Classification
Guidelines for Preparations as issued in the latest version:
Harmful
Irritant
?Sensitisation May cause sensitisation by inhalation and skin contact.
12 Ecological information
?Ecotoxical effects:
?Remark: Harmful to fish
?General notes:
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water
Do not allow undiluted product or large quantities of it to reach ground water, water course or sewage system.
Harmful to aquatic organisms
13 Disposal considerations
?Product:
?Recommendation
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packaging:
?Recommendation: Disposal must be made according to official regulations.
14 Transport information
?Land transport ADR/RID (cross-border)
?ADR/RID class: -
?Maritime transport IMDG:
-
?IMDG Class:
?Marine pollutant: No
?Air transport ICAO-TI and IATA-DGR:
?ICAO/IATA Class: -
?UN "Model Regulation": -
15 Regulatory information
?Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous
Materials.
(Contd. on page 7)
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Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 30.10.2008 Revision: 30.10.2008
Trade name: 40987 10 Minute Universal Urethane
(Contd. of page 6)
?Code letter and hazard designation of product:
Xn Harmful
?Hazard-determining components of labelling:
4,4'-methylenediphenyl diisocyanate
methylenediphenyl diisocyanate
?Risk phrases:
20 Harmful by inhalation.
36/37/38 Irritating to eyes, respiratory system and skin.
42/43 May cause sensitisation by inhalation and skin contact.
52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Safety phrases:
23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
24/25 Avoid contact with skin and eyes.
37 Wear suitable gloves.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
61 Avoid release to the environment. Refer to special instructions/safety data sheets.
?Special labelling of certain preparations:
Contains isocyanates. See information supplied by the manufacturer
16 Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any
specific product features and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
10 Flammable.
20 Harmful by inhalation.
20/22 Harmful by inhalation and if swallowed.
21/22 Harmful in contact with skin and if swallowed.
34 Causes burns.
36 Irritating to eyes.
36/37/38 Irritating to eyes, respiratory system and skin.
39 Danger of very serious irreversible effects.
42/43 May cause sensitisation by inhalation and skin contact.
48/22 Harmful: danger of serious damage to health by prolonged exposure if swallowed.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Department issuing MSDS: Environment protection department.
?Contact: Steve Gaver
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises Dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
RID: Reglement internationale concernent le transport des merchandises dangereuses par chemin de fer (Regulations Concerning the
International Transport of Dangerous Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
VOC: Volatile Organic Compounds (USA, EU)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
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