MATERIAL SAFETY DATA SHEET
SECTION 1 ?GENERAL INFORMATION
Manufacturer: HMIS Rating
Modern Masters, Inc. HEALTH 2
7340 Greenbush Avenue FLAMMABILITY 0
North Hollywood, California 91605 REACTIVITY 1
818-765-2915
Emergency Telephone: 800-942-3166 Preparation Date: January 18, 2002
Product Name: Modern Masters "Blue Patina Aging Solution"
Product Code: PA902
SECTION 2 ?HAZARDOUS INGREDIENTS
Hazardous Component CAS # OSHA PEL ACGIH TLV
Blue Copper 7758-99-8 1 mg/m3 0.1 mg/m3
(as copper) (as copper)
(dusts and mists) (fumes)
Citric Acid 5949-29-1 N/A N/A
Sal Ammoniac 12125-02-9 20 mg/m3 10 mg/m3
SECTION 3 ?HAZARD IDENTIFICATION
Emergency Overview: This material is a reactive patinating solution. It is a stable, non-
flammable, translucent blue flowable liquid with a flash point above 200癋.
Primary Routes of Exposure:
Inhalation
Skin contact
Eye contact
Potential Acute Health Effects:
Inhalation: May cause respiratory tract irritation
Skin: Prolonged or repeated skin contact may cause irritation
Eye: May cause eye irritation
Ingestion: Not hazardous under intended use conditions
Potential Chronic Health Effects: None known
NA: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated
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MATERIAL SAFETY DATA SHEET
SECTION 4 ?FIRST AID MEASURES
Eye contact: Flush eyes with clean water for 15 minutes. Seek medical attention.
Skin contact: Thoroughly wash with soap and warm water.
Inhalation: If irritation occurs, remove to fresh air and seek medical attention if cough or
other symptoms develop.
Ingestion: If ingested, induce vomiting. Seek medical attention.
Note to Physician: Treat symptomatically.
SECTION 5 ?FIRE FIGHTING MEASURES
Flash Point (method): N/D (est. >200癋)
Extinguishing Media: Use water spray, foam, or carbon dioxide when fighting fires
involving this material.
Protection of Firefighters: As in any fire, wear NIOSH approved self-contained breathing
apparatus pressure-demand and full protective gear.
Fire and Explosion Hazards: Material will not burn.
SECTION 6 ?ACCIDENTAL RELEASE MEASURES
Personal Precautions: Slippery: can cause slips and falls if walked on.
Clean Up Methods: Contain spill with sand or other diking material. Soak up small spills with
absorbent material. Dispose of in accordance with federal, state, and local regulations.
(See also Section 8 for information on Exposure Controls and Personal Protective Equipment.)
SECTION 7 ?HANDLING AND STORAGE
Handling: Avoid prolonged or repeated contact with skin. Avoid contact with eyes. Wash
hands thoroughly with soap and warm water before eating.
Storage: Do not freeze. Keep container closed when not in use.
NA: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated
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MATERIAL SAFETY DATA SHEET
SECTION 8 ?EXPOSURE CONTROLS/PERSONAL PROTECTION
Engineering Controls: If necessary, use general room dilution ventilation, process
enclosures, local exhaust ventilation, or other engineering controls to control airborne levels below
recommended exposure limits.
Personal Protective Equipment (PPE):
Eye Protection: Eye contact should be avoided. Where eye contact is likely, wear chemical
splash goggles and/or full-face shield.
Skin Protection: Skin contact should be avoided. Wear rubber or latex gloves when using this
product.
Respiratory Protection: None needed under normally anticipated use conditions. If vapor
levels exceed allowable limits, wear a NIOSH approved air-purifying respirator with an organic
vapor cartridge.
General Hygiene Practices: Avoid eye and skin contact. Avoid breathing vapors. Wash hands
before eating and drinking.
SECTION 9 ?PHYSICAL DATA
Appearance: Odor:
Translucent blue flowable liquid Mild odor
Physical State: pH:
Liquid 4 to 10
Boiling Point: Melting Point:
Above 200癋 <32癋
Vapor Pressure: N/D Vapor Density: N/D
Odor Threshold: Viscosity:
N/D <100 cps
Solubility in Water: Dilutable in water Specific Gravity (water = 1): 1.0-1.2
SECTION 10 ?STABILITY AND REACTIVITY
Stability: Incompatibility:
Stable, non-reactive None known
Hazardous Polymerization: Will not occur
Hazardous Decomposition Products: None known
NA: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated
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MATERIAL SAFETY DATA SHEET
SECTION 11 ?TOXICOLOGICAL INFORMATION
Carcinocenicity: This material is not considered a carcinogen by IARC or NTP and is not
regulated as a carcinogen by OSHA.
Wilson's Disease, a disease associated with the inability to remove copper from the blood, is a
medical condition aggravated by exposure to Blue Copper.
(See also Section 15 for related information.)
SECTION 12 ?ECOLOGICAL INFORMATION
Chemical Effects: Blue Copper is toxic to fish and marine organisms. Do not contaminate
water destined for streams, rivers, ponds, or lakes.
Chemical Fate: No data available.
SECTION 13 ?DISPOSAL CONSIDERATIONS
Recommended Waste Disposal Method: This material is not considered hazardous waste under
Federal Hazardous Waste Regulations (40CFR 261). However, state and local requirements for
waste disposal may be more restrictive or otherwise differ from federal regulations. Chemical
additions, processing, or otherwise altering this material may render the waste management
information presented in this MSDS incomplete, inaccurate, or otherwise inappropriate. Consult all
applicable federal, state, and local regulations regarding the proper disposal of this material.
SECTION 14 ?TRANSPORTATION INFORMATION
Regulated by the DOT: Not regulated
DOT Proper Shipping Name: Paint
NA: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated
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MATERIAL SAFETY DATA SHEET
SECTION 15 ?REGULATORY INFORMATION
CERCLA:
The Comprehensive Environmental Response Compensation and Liability Act of 1980 (CERCLA)
requires notification to the National Response Center for releases of quantities of Hazardous
Substances equal to or greater than the reportable quantities (RQs) in 40 CFR 302.4 (for CERCLA
102).
Components present in this product at a level which could require reporting under the statute are:
Chemical Name CAS # Maximum Concentration (Wt. %)
none N/A N/A
SARA Title III, section 311/312:
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires emergency
planning based on Threshold Planning Quantities (TPQs) and release reporting based on Reportable
Quantities (RQs) in 40 CFR 355 (used for SARA 302, 304, 311, and 312).
Components present in this product at a level which could require reporting under the statute are:
Chemical Name CAS # Maximum Concentration (Wt. %)
none N/A N/A
SARA Title III, section 313:
The Superfund Amendments and Reauthorization Act of 1986 (SARA) Title III requires submission
of annual reports of release of toxic chemicals that appear in 40 CFR 372 (for SARA 313).
Components present in this product at a level which could require reporting under the statute are:
Chemical Name CAS # Maximum Concentration (Wt. %)
Blue Copper 7758-99-8 4%
Citric Acid 5949-29-1 2%
Sal Ammoniac 12125-02-9 6%
TSCA:
The components of this mixture are listed in the Toxic Substance Control Act Inventory of
Chemical Substances.
This product does not contain any chemicals that would require export notification under Section
12(b) of the TSCA regulation.
NA: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated
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MATERIAL SAFETY DATA SHEET
SECTION 16 ?OTHER INFORMATION
Legend: N/A: Not Applicable N/D: Not Determined
N/E: Not Established N/R: Not Required
STEL: Short Term Exposure Limit C: Ceiling Value
mg/m3: milligrams per cubic centimeter
cps: Centipoise
PPM: Parts Per Million PPB: Parts Per Billion
PEL: Permissible Exposure Limit TLV: Time Weighted Average
mppcf: million particles per cubic foot of air
ACGIH: American Conference of Governmental Industrial Hygienists
CPSC: Consumer Product Safety Commission
DOT: US Department of Transportation
FHSA: Federal Hazardous Substance Act
OSHA: Occupational Safety and Health Administration (US Dept. of Labor)
RCRA: Resource Conservation and Recovery Act
SARA: Superfund Amendment and Reauthorization Act
TSCA: Toxic Substance Control Act
HMIS Key
4 = Severe Hazard
3 = Serious Hazard
2 = Moderate Hazard
1 = Slight Hazard
0 = Minimal Hazard
Prepared by: Modern Masters Regulatory Compliance Manager,
Technical Management Department
7340 Greenbush Avenue, North Hollywood, California 91605 (818) 765-2915
Disclaimer: Modern Masters, Inc. believes, to the best of its knowledge, information, and belief,
the information contained herein to be accurate and reliable as of the date of this material safety data
sheet. However, because the conditions of handling, use, and storage of these materials are beyond
our control, we assume no responsibility or liability for personal injury or property damage incurred
by the use of these materials and make no warranty, expressed or implied, regarding the accuracy or
reliability of the data or results obtained from their use. All materials may present unknown hazards
and should be used with caution. The information and recommendations in this material safety data
sheet are offered for the users' consideration and examination. It is the responsibility of the user to
determine the final suitability of this information and data to comply with all applicable
international, federal, state, and local laws and regulations.
NA: Not Applicable N/D: Not Determined N/E: Not Established N/R: Not Required Est.: Estimated
MSDS Code: PA902 MSDS (1/18/02) Page 6 of 6 pages
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