OFI TESTING EQUIPMENT, INC. Effective Date:02/25/02
MATERIAL SAFETY DATA SHEET
SECTION I - PRODUCT IDENTIFICATION
Chemical Name: AMMONIUM HYDROXIDE SOLUTION (10% - 35% NH3)
Trade Name: BUFFER SOLUTION, HARDNESS
OFI Part No. 205-04,205-05,205-05-10,205-05-20,205-04-1,205-04-5
Chemical Family: Ammonium hydroxide soluitons; ammonia aqueous; ammonia solutions
Formula: NH4OH:H 2O
SECTION II - HAZARDOUS CONSTITUENTS
CAS #: CHEMICAL NAME
1336-21-6 Ammonium Hydroxide 21.0 to 72.0% (10 to 35% ammonia)
12125-02-9 Ammonium Chloride 6.0 to 7.5%
SECTION III - PHYSICAL PROPERTIES
Clear Colorless Liquid / Ammonia Odor
Appearance / Odor:
Infinitely Soluble
Solubility:
0.9 (28% NH4OH)
Specific Gravity:
11.6
pH:
No Information Found.
% Volatiles by Vol.:
-98 0 F (-72 0C)
Melting Point:
ca. 97 0 F (36 0C)
Boiling Point:
0.60 NH3
Vapor Density (Air=1):
115 @ 68 0F (20 0C)
Vapor Pressure (mmHg):
SECTION IV - FIRE, EXPLOSION AND REACTIVITY
Autoignition Temperature: 1204 0F (651 0C), Flammable Limits in Air % by Volume: lel-16, uel-
Fire:
25.
Explosion: Flammable Vapors may Accumulate in Confined Spaces.
Fire Extinguishing Media: Use any means Suitable for Extinguishing Surrounding Fire. Use Water Spray to Blanket Fire,
Cool Fire Exposed Containers, and to Flush Non-Ignited Spills or Vapors away from Fire.
Special Information: In the Event of Fire, Wear Full Protective Clothing and NIOSH-Approved Self-Contained
Breathing Apparatus with Full Facepiece Operated in the Pressure Demand or Other Positive
Pressure Mode.
General Reactivity: Stable Under Ordinary Conditions of Use and Storage.
Hazardous Decomposition: Burning may Produce Ammonia, Nitrogen Oxides.
Incompatibilities: Acids, Acrolein, Dimethyl Sulfate, Halogens, Silver Nitrate, Propylene Oxide, Nitromethane,
Silver Oxide, Silver Permanganate, Oleum, Beta-Propiolactone. Most Common Metals.
Will Not Occur.
Hazardous Polymerization:
SECTION V - HEALTH HAZARD INFORMATION
Inhalation: Vapors and Mists Cause Irritation to the Respiratory Tract. Higher Concentrations can Cause
Burns, Pulmonary Edema and Death. Brief Exposure to 5000 ppm can be FATAL.
Ingestion: TOXIC! May Cause Corrosion to the Esophagus and Stomach with Perforation and Peritonitis.
Symptoms may Include Pain in the Mouth, Chest, and Abdomen, with Coughing, Vomiting and
Collapse. Ingestion of as Little as 3 to 4 mL may be FATAL.
Skin: Causes Irritation and Burns to the Skin.
Eye Contact: Vapors Cause Irritation. Splashes Cause Severe Pain, Eye Damage, and Permanent
Blindness.
Chronic Exposure: Repeated Exposure may Cause Damage to Tissues of the Mucous Membranes, Upper
Respiratory Tract, Eyes and Skin.
SECTION V - HEALTH, HAZARD INFORMATION (cont.)
Carcinogenic References: IARC Category- None, NTP Carcinogen - Known: No
Aggravated by Exposure: Persons with Pre-Existing Eye Disorders or Impaired Respiratory Function may be More
Susceptible to the Effects of this Material.
SECTION VI - EMERGENCY & FIRST AID PROCEDURES
Inhalation: Remove to Fresh Air. If Not Breathing, Give Artificial Respiration. If Breathing is Difficult, Give
Oxygen. Call a Physician Immediately.
Ingestion: If Swallowed, DO NOT INDUCE VOMITING! Give Large Quantities of Water. Never Give
Anything by Mouth to an Unconscious Person. Get Medical Attention Immediately.
Skin: Immediately Flush Skin with Plenty of Water for at Least 15 Minutes while Removing
Contaminated Clothing and Shoes. Call a Physician, Immediately. Wash Clothing before
Reuse.
Eyes: Immediately Flush Eyes with Plenty of Water for at Least 15 Minutes, Lifting Lower and Upper
Eyelids Occasionally. Get Medical Attention Immediately.
SECTION VII - INDUSTRIAL HYGIENE MEASURES
Ventilation System: A System of Local and/or General Exhaust is Recommended to Keep Employee Exposures
Below the Airborne Exposure Limits. Local Exhaust Ventilation is Generally Preferred Because
it can Control the Emissions of the Contaminant at its Source, Preventing Dispersion of it into
the General Work Area.
Airborne Exposure Limits: OSHA Permissible Exposure Limit (PEL): 50 ppm NH3 (STEL), ACGIH Threshold Limit Value
(TLV): 25 ppm NH3 (TWA) 35 ppm (STEL).
Personal Respirators: If the Exposure Limit is Exceeded, a Full-Facepiece Respirator with an Ammonia/Methylamine
(NIOSH APPROVED) Cartridge may be Worn up to 50 times the Exposure Limit or the Maximum use Concentration
Specified by the Appropriate Regulatory Agency or Respirator Supplier, Whichever is Lowest.
For Emergencies or Instances where the Exposure L evels are not Known, use a Full-
Facepiece Positive-Pressure, Air Supplied Respirator.
Skin Protection: Wear Impervious Protective Clothing, Including Boots, Gloves, Lab Coat, Apron or Coveralls,
as Appropriate, to Prevent Skin Contact. Neoprene and Nitrile Rubber are Recommended.
Eye Protection: Use Chemical Safety Goggles and/or Full Face Shield where Splashing is Possible. Maintain
Eye Wash Fountain and Quick-Drench Facilities in Work Area.
SECTION VIII - INDUSTRIAL HYGIENE MEASURES
Accidental Release: Ventilate Area of Leak or Spill. Keep Unnecessary and Unprotected People away from Area of
of Spill. Wear Appropriate Personal Protective Equipment as Specified in Section 7. Contain
and Recover Liquid when Possible. Do Not Flush Caustic Residues to the Sewer. Residues
from Spills can be Diluted with Water, Neutralized with Dilute Acid such as Acetic, Hydrochloric
Disposal: or Sulfuric. Absorb Neutralized Caustic Residue on Clay, Vermiculite or other Inert Substance
and Package in a Suitable Container for Disposal. US Regulations (CERCLA) require
Reporting Spills and Releases to Soil, Water and Air in Excess of Reportable Quantities.
Environmental Fate: This Material is Not Expected to Significantly Bioaccumulate.
SECTION IX - SPECIAL PRECAUTIONS
Handling and Storage: Keep in Tightly Closed Container, Stored in a Cool, Dry, Ventilated Area. Protect Against
Physical Damage. Separate from Incompatibilities. Store below 77 0F (25 0C). Protect from
Direct Sunlight. Containers of this Material May be Hazardous when Empty
Since they Retain Product Residues (Vapors, Liquid).
SECTION X - DOT SHIPPING REQUIREMENTS
Shipping Name: AMMONIA, SOLUTION (WITH 10 - 35% AMMONIA)
Hazard Class: 8
Identification No.: UN2672, Packing Group III
NFPA Rating: HEALTH-3, FLAMMABILITY-1, REACTIVITY-2
SECTION XI - IN CASE OF EMERGENCY
(713) 880 - 9884 OFI TESTING EQUIPMENT, INC. - Regular Business Hours
(713) 880 - 9885 OFI TESTING EQUIPMENT, INC. - After Regular Business Hours
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