MATERIAL SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI and Canadian WHMIS Standards .This Material Safety Data Sheet is offered pursuant to OSHA's Hazard
Communication Standard (29 CFR 1910.1200). Other government regulations must be reviewed for applicability to these products.
WARNING: PRODUCT COMPONENTS PRESENT HEALTH AND SAFETY HAZARDS. READ AND UNDERSTAND THIS MATERIAL SAFETY DATA
SHEET (M.S.DS.). ALSO, FOLLOW YOUR EMPLOYER'S SAFETY PRACTICES. This product may contain Chromium and/or Nickel which are listed
by OSHA, NTP, or IARC as being a carcinogen or potential carcinogen. Use of this product may expose you or others to fumes and gases at levels
exceeding those established by the American Conference of Governmental Industrial Hygienists (ACGIH) or the Occupational Safety and Health
Administration (OSHA) The information contained herein relates only to the specific product. If the product is combined with other materials, all
component properties must be considered. BE SURE TO CONSULT THE LATEST VERSION OF THE MSDS. MATERIAL SAFETY DATA SHEETS ARE
salesinfo@jwharris.com 513-754-2000
AVAILABLE FROM HARRIS PRODUCTS GROUP
www.harrisproductsgroup.com
STATEMENT OF LIABILITY-DISCLAIMER
To the best of the Harris Products Group knowledge, the information and recommendations contained in this publication are reliable and accurate as of the
date prepared. However, accuracy, suitability, or completeness are not guaranteed, and no warranty, guarantee, or representation, expressed or implied,
is made by Harris Products Group. as to the absolute correctness or sufficiency of any representation contained in this and other publications; Harris
Products Group assumes no responsibility in connection therewith; nor can it be assumed that all acceptable safety measures are contained in this and
other publications, or that other or additional measures may not be required under particular or exceptional conditions or circumstances . Data may be
changed from time to time.
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
TRADE NAME (AS LABELED): BRIDGIT?PASTE FLUX
CHEMICAL NAME/CLASS: Inorganic Chloride/ Mineral Oil Mixture
SYNONYMS: Not Applicable
PRODUCT USE: Metal Soldering Operations
DOCUMENT NUMBER: 0018
SUPPLIER/MANUFACTURER'S NAME: HARRIS PRODUCTS GROUP
ADDRESS: 4501 Quality Place, Mason, Ohio 45040
EMERGENCY PHONE: CHEMTREC: 1-800-424-9300
BUSINESS PHONE: 513-754-2000 FAX 513-754-8778
DATE OF PREPARATION: February 4, 2009
2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR
ACGIH OSHA NIOSH OTHER
TLV STEL PEL STEL IDLH
3 3 3 3 3 3
mg/m mg/m mg/m mg/m mg/m mg/m
Ammonium Chloride 12125-02-9 5 10 20 10 20 NE NIOSH RELs:
The exposure limits (Vacated (Vacated TWA = 10
provided are for 1989 1989 PEL) STEL = 20
"Ammonium Chloride PEL)
Fumes".
Ethylene Glycol 107-21-1 10 100 NE NE 125 NE DFG MAKs:
(ceiling) [ceiling] TWA = 26 (skin)
Aerosol (Vacated PEAK = 2稭AK, 5 min.,
1989 PEL) momentary value
Carcinogen: TLV-A4
Isopropyl Alcohol 67-63-0 10 983 1230 980 1225 2000 ppm NIOSH REL:
(Vacated (based on TWA = 980
NIC-491 NIC-984
1989 PEL) 10% of STEL = 1225
LEL) DFG MAKs:
TWA = 500
PEAK = 2稭AK, 30 min.,
average value
DFG MAK Pregnancy Risk
Classification: C
Carcinogen: IARC-3
NE = Not Established. See Section 16 for Definitions of Terms Used. Single values shown are maximum, unless otherwise noted
BRIDGIT?SOLDERING FLUX MSDS EFFECTIVE DATE: June 24, 2002
PAGE 1 OF 10
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in
accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
2. COMPOSITION and INFORMATION ON INGREDIENTS
CHEMICAL NAME CAS # % w/w EXPOSURE LIMITS IN AIR
ACGIH-TLV OSHA-PEL NIOSH OTHER
TWA STEL TWA STEL IDLH
3 3 3 3 3 3
mg/m mg/m mg/m mg/m mg/m mg/m
Zinc Chloride 7646-85-7 20 1 2 1 2 (Vacated 50 NIOSH RELs:
The exposure limits provided 1989 PELs) TWA = 1
are for "Zinc Chloride Fumes". STEL = 2
Carcinogen: EPA-D
Mineral Oil 8012-95-1 > 30 5 10 5 NE 2500 NIOSH RELs:
NIC-delete TWA = 5
The exposure limits provided
STEL STEL = 10
are for "Oil Mist, Mineral".
NE = Not Established. See Section 16 for Definitions of Terms Used. Single values shown are maximum, unless otherwise noted
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-1998 format. This product has been classified in
accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR.
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: This product consists of an off-white paste with a slight alcohol odor. This mixture can be
irritating, and may damage contaminated tissues (especially after prolonged over-exposures). This product must be
substantially preheated before ignition can occur. If involved in a fire, this product may decompose to produce irritating
vapors and toxic gases, including hydrogen chloride. This product is not reactive under normal circumstances.
Emergency responders must wear the proper personal protective equipment suitable for the situation to which they are
responding.
SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE:
The most significant routes of over-exposure for this product are by HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
skin or eye contact and inhalation of dusts of fumes of this product.
INHALATION: If vapors of this product are inhaled, irritation of
HEALTH
the nose and respiratory system can occur. This paste contains a
2
(BLUE)
central nervous system depressant (Isopropyl Alcohol).
Depending on the duration of inhalation over-exposure, symptoms
such as coughing, sneezing headache, difficulty breathing, and
dizziness may develop. Though not anticipated to occur during
use of this paste when the proper precautions are taken, extreme
FLAMMABILITY 1
(RED)
inhalation over-exposure to the Zinc Chloride component of this
product can have adverse effects on the lungs (i.e. causing
pulmonary edema and pneumonitis, life threatening lung
conditions). Inhalation of Zinc Chloride fumes can cause metal
REACTIVITY
fume fever. Symptoms of such over-exposures include (YELLOW) 0
headache, fever, rapid breathing, sweating and pains in legs and
chest. Extreme over-exposures to the fumes of this product
cause liver and kidney disorders, and may be fatal.
X
PROTECTIVE EQUIPMENT
CONTACT WITH SKIN or EYES: Contact with the eyes will cause
irritation, pain, and reddening. Prolonged exposure of the eyes may
result in permanent eye damage. Skin contact can cause reddening
EYES HANDS BODY
and irritation. Prolonged over-exposures can result in ulceration of RESPIRATORY
the contaminated tissues, which could leave scars. There are some
reports that the Ethylene Glycol component of this product may
See See
cause allergic skin reaction in susceptible individuals. Symptoms Section 8 Section 8
may include dryness, redness, itching, rash or welts.
SKIN ABSORPTION: The Isopropyl Alcohol and Ethylene Glycol For routine industrial applications
See Section 16 for Definition of Ratings
components of this product can be absorbed via intact skin.
Although toxicity via this route of exposure is expected to be low,
other compounds may be carried into the system that could have adverse effect.
BRIDGIT?SOLDERING FLUX MSDS EFFECTIVE DATE: June 24, 2002
PAGE 2 OF 10
3. HAZARD IDENTIFICATION (Continued)
INGESTION: Ingestion is not anticipated to be a route of occupational exposure for this product. If this flux is ingested,
nausea, vomiting, and diarrhea may occur (depending on the amount of the product swallowed). Severe ingestion
exposures may result in damage to the tissues of the gastrointestinal system, kidney failure and death.
INJECTION: Though not a likely route of occupational exposure for this product, injection of this product (via punctures or
lacerations in the skin) may cause local reddening, tissue swelling, and discomfort. Symptoms such as those described for
"Ingestion" may occur.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms. Symptoms associated with over-
exposure to this product are as follows:
ACUTE: This product is irritating to contaminated eyes, skin, and mucous membranes, and any other exposed tissue.
Prolonged over-exposures may result in burns. If vapors or fumes from this product are inhaled, irritation of the respiratory
system may occur, with coughing, and breathing difficulty. Inhalation of higher levels may cause significant irritation and
adverse effects of the central nervous system. Ingestion of small amounts will result in nausea, vomiting, abdominal pain and
adverse effects on the central nervous system. Ingestion of large amounts may be fatal or cause kidney failure.
CHRONIC: Chronic skin exposure to this product may result in dermatitis or cause allergic reaction in susceptible
individuals. Chronic ingestion may cause damage to the kidneys. Based on animal data, exposure to products containing
Ethylene Glycol may cause adverse reproductive effects. Refer to Section 11 (Toxicology Information) for additional data
TARGET ORGANS: ACUTE: Skin, eyes, respiratory system, kidneys, central nervous system. CHRONIC: Skin,
kidneys.
PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
Victims of chemical exposure must be taken for medical attention. Rescuers should be taken for medical attention, if
necessary. Take copy of label and MSDS to health professional with victim.
SKIN EXPOSURE: If these products contaminate the skin, begin decontamination with running water. Minimum flushing is
for 15 minutes. Victim must seek medical attention if any adverse reaction occurs.
EYE EXPOSURE: If this product enters the eyes, open victim's eyes while under gently running water. Use sufficient force
to open eyelids. Have victim "roll" eyes. Minimum flushing is for 15 minutes. Victim must seek immediate medical attention.
INHALATION: If vapors or fumes of this product are inhaled, remove victim to fresh air. If necessary, use artificial
respiration to support vital functions. Seek medical attention if adverse effect occurs.
INGESTION: If swallowed call physician immediately! Do not induce vomiting unless directed by medical personnel. Rinse
mouth with water if person is conscious. Never give fluids or induce vomiting if person is unconscious, having convulsions,
or not breathing.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin, respiratory and liver or kidney disorders may be
aggravated by prolonged over-exposures to this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. Provide oxygen, if necessary.
Pulmonary function tests, chest X-rays, and nervous system evaluations may prove useful. Consultation with an
ophthalmologist is recommended if eye exposure leads to tissue damage. Prompt diagnosis and initiation of treatment,
including ethanol therapy and hemodialysis is necessary to ameliorate the effects of Ethylene Glycol ingestion.
5. FIRE-FIGHTING MEASURES
FLASH POINT: Not determined.
AUTOIGNITION TEMPERATURE: Not determined.
FLAMMABLE LIMITS (in air by volume, %):
Lower (LEL): Not applicable.
Upper (UEL): Not applicable.
BRIDGIT?SOLDERING FLUX MSDS EFFECTIVE DATE: June 24, 2002
PAGE 3 OF 10
5. FIRE-FIGHTING MEASURES (Continued)
FIRE EXTINGUISHING MATERIALS:
NFPA RATING
Water Spray: YES (for cooling) Carbon Dioxide: YES
Halon: YES Foam: YES
FLAMMABILITY
Dry Chemical: YES Other: Any "B" Class.
UNUSUAL FIRE AND EXPLOSION HAZARDS: This product must be
1
substantially preheated before ignition can occur. During a fire, this material
may decompose and produce irritating fumes and toxic gases (including hydrogen
0
2
chloride, zinc oxides, carbon monoxide, carbon dioxide, and nitrogen oxides). HEALTH REACTIVITY
Explosion Sensitivity to Mechanical Impact: Not sensitive.
Explosion Sensitivity to Static Discharge: Not sensitive.
SPECIAL FIRE-FIGHTING PROCEDURES: Incipient fire responders should
wear eye protection. Structural fire fighters must wear Self-Contained OTHER
Breathing Apparatus and full protective equipment. If possible, prevent run-off See Section 16 for
water from entering storm drains, bodies of water, or other environmentally Definition of Ratings
sensitive areas.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-planned
procedures. Proper protective equipment should be used. In case of a spill, clear the affected area, protect people, and
respond with trained personnel. Incidental releases of this product can be cleaned-up by personnel wearing gloves and
goggles (or safety glasses). In the event of a non-incidental release, minimum Personal Protective Equipment should be
Level B: triple-gloves (rubber gloves and nitrile gloves, over latex gloves), chemically resistant suit and boots, hard-
hat, and Self-Contained Breathing Apparatus. Pick-up paste with polypad or other absorbent agent. Rinse area with a
soap and water solution. Decontaminate the area thoroughly. Place all spilled residues in a suitable container and seal.
Dispose of in accordance with applicable U.S. Federal, State, or local procedures or appropriate standards of Canada (see
Section 13, Disposal Considerations).
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU.
Wash hands after handling this product. Do not eat or drink while handling this material. Remove contaminated clothing
immediately.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it safely.
Avoid breathing fumes generated by this product. Use in a well-ventilated location. Open containers slowly, on a stable
surface. Containers of this product must be properly labeled. Store this product in a cool, dry location, away from direct
sunlight, sources of intense heat, or where freezing is possible. Store away from incompatible materials (see Section 10,
Stability and Reactivity). Inspect all incoming containers before storage to ensure they are properly labeled and not
damaged. Wash thoroughly after using this material. Storage areas should be made of fire-resistant materials. Empty
containers may contain residual material; therefore, empty containers should be handled with care.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices indicated in
Section 6 (Accidental Release Measures). Make certain application equipment is locked and tagged-out safely. Always use
this product in areas where adequate ventilation is provided. Decontaminate equipment using soapy water before
maintenance begins. Collect all rinsates and dispose of according to applicable Federal, State, or local procedures.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained
below the limits provided in Section 2 (Composition and Information on Ingredients). Prudent practice is to ensure
eyewash/safety shower stations are available near areas where this product is used.
BRIDGIT?SOLDERING FLUX MSDS EFFECTIVE DATE: June 24, 2002
PAGE 4 OF 10
8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below guidelines listed in Section 2
(Composition and Information on Ingredients). If respiratory protection is needed, Use only respiratory protection authorized
in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134) or equivalent U.S. State standards, or
Canadian CSA Standard Z94.4-93. Oxygen levels below 19.5% are considered IDLH by OSHA. In such atmospheres, use
of a full-facepiece pressure/demand SCBA or a full facepiece, supplied air respirator with auxiliary self-contained air supply is
required under OSHA's Respiratory Protection Standard (1910.134-1998). For additional information the NIOSH
recommended respiratory protection guidelines for Oil Mist, Mineral and Zinc Chloride are provided, as follows:
OIL MIST, MINERAL
CONCENTRATION RESPIRATORY PROTECTION
Up to 50 mg/m3: Any Air-Purifying Respirator with a high-efficiency particulate filter, or any Supplied-Air Respirator
(SAR).
Up to 125 mg/m3: Any SAR operated in a continuous-flow mod, or any Powered, Air-Purifying Respirator with a
(PAPR) high-efficiency particulate filter.
Up to 250 mg/m3: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any SAR
that has a tight-fitting facepiece and is operated in a continuous-flow mode, or any PAPR with a
tight-fitting facepiece and a high-efficiency particulate filter, or any Self-Contained Breathing
Apparatus (SCBA) with a full facepiece, or any SAR with a full facepiece.
Up to 2500 mg/m3: Any SAR operated in a pressure-demand or other positive-pressure mode.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and
is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full
facepiece and is operated in a pressure-demand or other positive-pressure mode in combination
with an auxiliary SCBA operated in pressure-demand or other positive-pressure mode.
Escape: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any
appropriate escape-type, SCBA.
ZINC CHLORIDE, FUME
CONCENTRATION RESPIRATORY PROTECTION
Up to 10 mg/m3: Any dust, mist, and fume respirator, or any Supplied-Air Respirator (SAR).
Up to 10 mg/m3: Any SAR operated in a continuous-flow mode, or any Powered, Air-Purifying Respirator (PAPR)
with a dust, mist, and fume .
Up to 50 mg/m3: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any PAPR
with a tight-fitting facepiece and a high-efficiency particulate filter, or any Self-Contained
Breathing Apparatus (SCBA) with a full facepiece, or any SAR with a full facepiece.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and
is operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full
facepiece and is operated in a pressure-demand or other positive-pressure mode in combination
with an auxiliary SCBA operated in pressure-demand or other positive-pressure mode.
Escape: Any Air-Purifying, Full-Facepiece Respirator with a high-efficiency particulate filter, or any
appropriate escape-type, SCBA.
EYE PROTECTION: Safety glasses. When this product is used in conjunction with soldering, wear safety glasses, goggles
or face-shield with filter lens of appropriate shade number (per ANSI Z49.1-1988, "Safety in Welding and Cutting"). If
necessary, refer to U.S. OSHA 29 CFR 1910.133, or appropriate Canadian Standards. If necessary, refer to U.S. OSHA
29 CFR 1910.138, or appropriate Standards of Canada.
HAND PROTECTION: Wear neoprene gloves for routine industrial use. Use triple gloves for spill response, as stated in Section 6
(Accidental Release Measures) of this MSDS. When this product is used in conjunction with soldering, wear gloves that protect
from sparks and flame (per ANSI Z49.1-1988, "Safety in Welding and Cutting"). If necessary, refer to U.S. OSHA 29 CFR
1910.138, or appropriate Standards of Canada.
BODY PROTECTION: Use body protection appropriate for task. When this product is used in conjunction with soldering, wear
clothing that protects from sparks and flame, such as arm protectors, apron, hats, and shoulder protection (per ANSI Z49.1-
1988, "Safety in Welding and Cutting"). If a hazard of injury to the feet exists due to falling objects, rolling objects, where
objects may pierce the soles of the feet or where employee's feet may be exposed to electrical hazards, use foot protection,
as described in U.S. OSHA 29 CFR 1910.136.
9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): Not applicable. EVAPORATION RATE (nBuAc = 1): Not applicable.
SPECIFIC GRAVITY (water = 1): Not available. FREEZING/MELTING POINT: Not available.
SOLUBILITY IN WATER: Insoluble. BOILING POINT: Not available.
VAPOR PRESSURE, mm Hg @ 20 癈: Not applicable pH: Not applicable.
BRIDGIT?SOLDERING FLUX MSDS EFFECTIVE DATE: June 24, 2002
PAGE 5 OF 10
9. PHYSICAL and CHEMICAL PROPERTIES (Continued)
ODOR THRESHOLD: Not applicable.
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not applicable.
APPEARANCE AND COLOR: This product consists of an off-white paste with a slight alcohol odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): The appearance is a distinctive characteristic of this product.
10. STABILITY and REACTIVITY
STABILITY: Stable.
DECOMPOSITION PRODUCTS: Hydrogen chloride, zinc oxides, nitrogen oxides and ammonia.
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is not compatible with strong oxidizing agents.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Avoid uncontrolled exposure to extreme temperatures and incompatible materials.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The following human toxicological data are available for the components of this product. Other data for
animals are available but are not presented in this Material Safety Data Sheet.
ZINC CHLORIDE: ETHYLENE GLYCOL: ISOPROPYL ALCOHOL:
DNA Inhibition System (human, lymphocyte) = DNA Inhibition System (human, lymphocyte) = TDLo (oral, man) = 14432 mg/kg; central nervous
0.360 mmol/L 320 mmol/L system, cardiovascular, pulmonary effects
3
TCLo (inhalation, man) = 4800 mg/m / 30 LDLo (oral, human) = 786 mg/kg TDLo(oral, human) = 223 mg/kg, central nervous
minutes; pulmonary effects LDLo (oral, human) = 398 mg/kg; central nervous system, cardiovascular effects
3
TCLo (inhalation, human) = 4800 mg/m / 3 hours system, gastrointestinal, liver effects LDLo(oral, man) = 7272 mg/kg
3
TCLo (inhalation, human) = 10000 mg/m ; eye LDLo(oral, human) = 3570 mg/kg; central
MINERAL OIL:
3
and pulmonary effects nervous system, pulmonary, gastrointestinal
TCLo (inhalation, man) = 5 mg/m /5 yr-
LDLo (unreported, man) = 1637 mg/kg effects
intermittent; carcinogenic, teratogenic, and
LDLo(unreported, man) = 2770 mg/kg
gastrointestinal effects.
SUSPECTED CANCER AGENT: Components of this product are listed as follows:
ETHYLENE GLYCOL: ACGIH TLV-A4 (Not Classifiable as a Human Carcinogen)
ISOPROPYL ALCOHOL: IARC-3 (Unclassifiable as to Carcinogenicity in Humans)
ZINC CHLORIDE: EPA-D (Not Classifiable as to Human Carcinogenicity (inadequate human and animal evidence of carcinogenicity or no data available)
The remaining components of this product are not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC,
CAL/OSHA and therefore are not considered to be, nor suspected to be, cancer-causing agents by these agencies.
IRRITANCY OF PRODUCT: This product can be irritating to contaminated skin and eyes.
SENSITIZATION TO THE PRODUCT: No component of this product is known to be a skin or respiratory sensitizer.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and its
components on the human reproductive system.
Mutagenicity: This product is not reported to produce mutagenic effects in humans. Animal mutation data is available for
the Zinc Chloride and Ammonium Chloride components of this product and was obtained during clinical studies on
specific animal tissues exposed to high doses of these compounds. Mutagenic data have been obtained in clinical studies
involving bacteria exposed to high doses of the Isopropyl Alcohol component of this product).
Embryotoxicity This product is not reported to produce embryotoxic effects in humans. Animal embryotoxic data is
available for the Zinc Chloride component of this product.
Teratogenicity: This product is not reported to cause teratogenic effects in humans. Studies on test animals exposed to
relatively high doses of the Isopropyl Alcohol and Zinc Chloride components of this product indicate teratogenic effects.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans. Studies on test animals
exposed to relatively high doses of the Isopropyl Alcohol and Zinc Chloride components of this product indicate adverse
reproductive effects.
A mutagen is a chemical, which causes permanent changes to genetic material (DNA) such that the changes will propagate
through generational lines. An embryotoxin is a chemical, which causes damage to a developing embryo (i.e. within the first eight
weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a chemical, which
causes damage to a developing fetus, but the damage does not propagate across generational lines. A reproductive toxin is
any substance, which interferes in any way with the reproductive process.
BIOLOGICAL EXPOSURE INDICES: Currently there are no Biological Exposure Indices (BEIs) associated with any
component of this product.
BRIDGIT?SOLDERING FLUX MSDS EFFECTIVE DATE: June 24, 2002
PAGE 6 OF 10
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: The components of this product will slowly react with water, oxygen, and other substances to
form a wide variety of inorganic compounds. The following environmental data are available for the components of this product:
ETHYLENE GLYCOL: Log Kow = 1.36. The bioconcentration factor of Ethylene Glycol in fish was reported to be 10 after 3 days of exposure; this suggests
that it will not bioconcentrate in fish. Biological Oxygen Demand, 0.47 g oxygen/ g Ethylene Glycol; Chemical Oxygen Demand - 1.29 g oxygen/ g
Ethylene Glycol.
ISOPROPYL ALCOHOL: Water Solubility = Miscible. Isopropyl Alcohol occurs naturally as a plant volatile and during microbial degradation of animal
wastes. When released on land or water, it is apt to volatilize and biodegrade. The estimated half-life in water is 5.4 days Isopropyl alcohol is not
expected to bioconcentrate.
65
ZINC CHLORIDE: Water solubility: 432 g/ 100 mL (25癈), 614 g/ 100 mL (100癈). Zinc can persist indefinitely as a cation. Radioactive zinc ( Zn) has
been found to concentrate in plants and milk. Acute Hazard Level Threshold: For vegetables and other crops - 750 ppm (Zn).
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product can be harmful or fatal to plant and animals, depending on
the quantity and duration of over-exposure.
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product may alter the alkalinity of the water, causing adverse effects on
aquatic life. Additionally, odorless zinc poisoning causes inflamed gills in fish. Laboratory studies of Atlantic salmon, rainbow
trout, carp, and goldfish have shown avoidance reactions by these fish to zinc in water. Additional aquatic toxicity information
for the components of this product is as follows:
ISOPROPYL ALCOHOL: ETHYLENE GLYCOL:
LC50 (Crassus auratus, goldfish) = 5000 mg/L/24 hours, 29.4 mg/L/ 96 LD50 (Carassius auratus, goldfish) = 5000 mg/L/24 hour modified ASTM
hours D 1345
LD100 (Semolitus atromaculatus, creek chub) = 1,100 mg/L/24 hours LC50 (Poecilia reticulata, guppies) = 49300 ppm/7 days
LC50 (Poecilia reticulata, guppies) = 7060 ppm/7 days LC50 (rainbow trout) = 18,500 mg/L/96 hours
LC50 (rainbow trout) = 41000 mg/L/96 hours at 20 C
LC50 (Crangon crangon, brown shrimp) = 1150 mg/L/96 hours
LC50 (Crassus auratus, goldfish) = 5000 mg/L/24 hours, 29.4 mg/L/ 96 LC50 (Crangon crangon, brown shrimp) = 100 mg/L 48 hours - aerated
hours salt water
LC50 (Carassius auratus, goldfish) = 5000 mg/L/24 hours/ 20 C/ static
LC50 (Pimephales promelas, fathead minnow) = 11830 mg/L/1 hour
LC50 (Pimephales promelas, fathead minnow) = 11160 mg/L/24 hours conditions
LC50 (Pimephales promelas, fathead minnow) = 11130 mg/L/72/96 hours Toxicity threshold, cell multiplication test (Pseudomonas pudita, bacteria)
LC50 (Pimephales promelas, fathead minnow) = 9.64 g/L/96 hours = 10,00 mg/L
LC50 (Pimephales promelas, fathead minnow) = 10.4 g/L/96 hours Toxicity threshold, cell multiplication test (Entosiphon sulcatum,
LC50 (Pimephales promelas, fathead minnow) = 6.55 g/L/96 hours protozoan) = 10,00 mg/L
LC50 (Pseudomonas pudita) = 1050 mg/L Toxicity threshold, cell multiplication test (Uronema parduzi Chatton-
Cell Multiplication Test (Microcytis aeruginosa, algae) = 1000 mg/L Lwoff, protozoan) = 10,00 mg/L
Cell Multiplication Test (Scenedesmus gadricauda, green algae) = 1800 Toxicity threshold, cell multiplication test (Chorella pyrenoidasa, algae) =
mg/L 180,000 mg/L; toxic
Cell Multiplication Test (Entosiphon sulcatum) = 4930 mg/L Toxicity threshold, cell multiplication test (Microcystis aeruginosa, algae)
Cell Multiplication Test (Uronema parduczi Chatton-Lwoff) = 3425 mg/L = 2,000 mg/L
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State, and local
regulations. This product, if unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your
local hazardous waste regulatory authority.
EPA WASTE NUMBER: Not applicable to wastes consisting only of this product.
14. TRANSPORTATION INFORMATION
THIS PRODUCT IS NOT HAZARDOUS (Per 49 CFR 172.101) BY THE U.S. DEPARTMENT OF TRANSPORTATION.
PROPER SHIPPING NAME: Not Regulated
HAZARD CLASS NUMBER and DESCRIPTION: Not Applicable
UN IDENTIFICATION NUMBER: Not Applicable
PACKING GROUP: Not Applicable
DOT LABEL(S) REQUIRED: Not Applicable
NORTH AMERICAN EMERGENCY RESPONSE GUIDEBOOK NUMBER, 2000: Not Applicable
MARINE POLLUTANT: No component of this product is designated as a marine pollutant by the Department of
Transportation (49 CFR 172.101, Appendix B).
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is not considered
as dangerous goods, per regulations of Transport Canada.
BRIDGIT?SOLDERING FLUX MSDS EFFECTIVE DATE: June 24, 2002
PAGE 7 OF 10
15. REGULATORY INFORMATION
ADDITIONAL U.S. REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: The components of this product are subject to the reporting requirements of
Sections 302, 304 and 313 of Title III of the Superfund Amendments and Reauthorization Act, as follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
Zinc Chloride NO YES NO
Ammonium Chloride NO YES NO
YES (Manufacturing, Strong
Isopropyl Alcohol NO NO
Acid Process)
YES
Ethylene Glycol NO YES
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for any component
of this product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg) may
apply, per 40 CFR 370.20.
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Ammonium Chloride = 5000 lbs (2270 kg), Zinc Chloride = 1000 lbs (454
kg). A statutory 1 lb Reportable Quantity is applicable for Ethylene Glycol under Clean Air Act Section 112 (b), until this value
is adjusted.
OTHER U.S. FEDERAL REGULATIONS: Not applicable.
U.S. STATE REGULATORY INFORMATION: The components of this product are covered under specific State regulations,
as denoted below:
Alaska - Designated Toxic and Hazardous Massachusetts - Substance List: Zinc Chloride North Dakota - List of Hazardous Chemicals,
fume, Ammonium Chloride, Ammonium
Substances: Zinc Chloride fume, Ammonium Reportable Quantities: Zinc Chloride,
Chloride fume Chloride, Isopropyl Alcohol,
Chloride, Isopropyl Alcohol, Ethylene Glycol, Ammonium Chloride.
Ethylene Glycol, Mineral Oil Mist.
Mineral Oil Mist. Pennsylvania - Hazardous Substance List:
Michigan - Critical Materials Register: None..
California - Permissible Exposure Limits for Zinc Chloride, Zinc Chloride fume, Ammonium
Minnesota - List of Hazardous Substances: Chloride, Isopropyl Alcohol, Ethylene Glycol,
Chemical Contaminants: Zinc Chloride fume,
Zinc Chloride fume, Ammonium Chloride, Mineral Oil Mist.
Ammonium Chloride, Isopropyl Alcohol,
Isopropyl Alcohol, Ethylene Glycol, Mineral Oil
Ethylene Glycol, Mineral Oil Mist. Rhode Island - Hazardous Substance List:
Mist. Zinc Chloride fume, Ammonium Chloride fume,
Florida - Substance List: Zinc Chloride fume,
Missouri - Employer Information/Toxic Isopropyl Alcohol, Ethylene Glycol, Mineral Oil
Ammonium Chloride, Ammonium Chloride
Mist.
fume, Isopropyl Alcohol, Ethylene Glycol. Substance List: Zinc Chloride, Ammonium
Chloride, Isopropyl Alcohol, Ethylene Glycol, Texas - Hazardous Substance List: Zinc
Illinois - Toxic Substance List: Zinc Chloride
and Mineral Oil Mist. Chloride fume, Isopropyl Alcohol, Mineral Oil
fume, Ammonium Chloride vapor Chloride,
Mist.
Isopropyl Alcohol, Ethylene Glycol, Mineral Oil New Jersey - Right to Know Hazardous
Mist. West Virginia - Hazardous Substance List:
Substance List: Zinc Chloride fume,
Zinc Chloride fume, Isopropyl Alcohol, Mineral
Kansas - Section 302/313 List: Isopropyl Ammonium Chloride, Isopropyl Alcohol,
Oil Mist.
Alcohol, Ethylene Glycol. Ethylene Glycol, Mineral Oil Mist.
Wisconsin - Toxic and Hazardous
Substances: Zinc Chloride fume, Isopropyl
Alcohol, Mineral Oil Mist.
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): The components of
this product are not on the California Proposition 65 lists. WARNING: This product when used may produce fumes or
gases containing chemicals, known to the State of California to cause cancer, and/or birth defects (or other
reproductive harm)
ANSI LABELING (Z129.1) (Precautionary Statements): WARNING! SKIN AND EYE IRRITANT. MAY BE FATAL IF
SWALLOWED. MAY BE HARMFUL IF DUSTS OR FUMES ARE INHALED. MAY CAUSE ALLERGIC SKIN REACTIONS IN
HYPERSENSITIVE INDIVIDUALS. Avoid contact with skin, eyes, and clothing. Use only with adequate ventilation. Avoid
breathing dust or fumes. Keep container closed. Wash thoroughly after handling. Wear gloves and safety goggles when
using this product. FIRST AID: In case of contact , immediately flush skin or eyes for at least 15 minutes. If inhaled, move to
fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If ingested, do not induce vomiting.
Seek medical attention. IN CASE OF FIRE: Use fog, foam, dry chemical or CO2. IN CASE OF SPILL: Absorb material and
remove. Flush area with water. Refer to MSDS for additional information.
BRIDGIT?SOLDERING FLUX MSDS EFFECTIVE DATE: June 24, 2002
PAGE 8 OF 10
15. REGULATORY INFORMATION (Continued)
WARNING:
PROTECT yourself and others. Read and understand this information.
FUMES AND GASES can be hazardous to your health.
ARC RAYS can injure your eyes and burn skin.
ELECTRIC SHOCK can kill.
HEAT RAYS (INFRARED RADIATION) from flame or hot metal can injure eyes.
?Before use, read and understand the manufacturer's instructions. Material Safety Data Sheets (MSDSs), and your
employer's safety policies.
?Keep your head out of the fumes.
?Use enough ventilation, exhaust at the arc, or both, to keep fumes and gases from your breathing zone and the
general area.
?FOR MAXIMUM SAFETY, BE CERTIFIED FOR AND WEAR A RESPIRATOR AT ALL TIMES WHEN WELDING
OR BRAZING
?Wear correct eye, ear, and body protection.
?Do not touch live electrical parts.
See American National Standard Z49.1 Safety in Welding, Cutting, and Allied Processes, published by the American Welding
Society, 550 N.W. LeJeune Road, Miami, Florida 33126. OSHA Safety and Health Standards, 29 CFR 1910, available from
the U.S. Government Printing Office, Superintendent office, P.O. Box 371954, Pittsburgh, PA 15250-7954.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL/NDSL INVENTORY STATUS: The components of this product are on the DSL Inventory.
OTHER CANADIAN REGULATIONS: Not applicable.
CANADIAN ENVIRONMENTAL PROTECTION ACT (CEPA) PRIORITIES SUBSTANCES LISTS: No components of this
product are on the CEPA Priority Substances Lists.
CANADIAN WHMIS SYMBOLS: D2B: Poisonous and Infectious Material/Other Toxic Effects.
16. OTHER INFORMATION
DATE OF PRINTING: February 5, 2009
This Material Safety Data Sheet is offered pursuant to OSHA's Hazard Communication Standard (29 CFR 1910.1200). Other government regulations
must be reviewed for applicability to this product. The information contained herein relates only to the specific product. If the product is combined with
other materials, all component properties must be considered. To the best of the Harris Products Group knowledge, the information and
recommendations contained in this publication are reliable and accurate as of the date of issue. However, accuracy, suitability, or completeness are not
guaranteed, and no warranty, guarantee, or representation, expressed or implied, is made by Harris Products Group as to the absolute correctness or
sufficiency of any representation contained in this and other publications; Harris Products Group assumes no responsibility in connection therewith; nor
can it be assumed that all acceptable safety measures may not be required under particular or exceptional conditions or circumstances. Data may be
changed from time to time. Be sure to consult the latest edition.
BRIDGIT?SOLDERING FLUX MSDS EFFECTIVE DATE: June 24, 2002
PAGE 9 OF 10
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following:
CAS #: This is the Chemical Abstract Service Number, which uniquely identifies each constituent.
EXPOSURE LIMITS IN AIR: FLAMMABILITY LIMITS IN AIR:
Much of the information related to fire and explosion is derived from the
ACGIH - American Conference of Governmental Industrial Hygienists, a
professional association which establishes exposure limits. National Fire Protection Association (NFPA). Flash Point - Minimum
temperature at which a liquid gives off sufficient vapors to form an ignitable
IARC-International Agency for Research on Cancer TLV - Threshold Limit
mixture with air. Autoignition Temperature: The minimum temperature
Value - an airborne concentration of a substance, which represents
required to initiate combustion in air with no other source of ignition. LEL -
conditions under which it is generally believed that nearly all workers, may
the lowest percent of vapor in air, by volume, that will explode or ignite in the
be repeatedly exposed without adverse effect. The duration must be
presence of an ignition source. UEL - the highest percent of vapor in air, by
considered, including the 8-hour Time Weighted Average (TWA), the 15-
volume, that will explode or ignite in the presence of an ignition source.
minute Short Term Exposure Limit, and the instantaneous Ceiling Level (C).
Skin absorption effects must also be considered. TOXICOLOGICAL INFORMATION:
OSHA - U.S. Occupational Safety and Health Administration. Human and Animal Toxicology: Possible health hazards as derived from
PEL - Permissible Exposure Limit - This exposure value means exactly the human data, animal studies, or from the results of studies with similar
same as a TLV, except that it is enforceable by OSHA. The OSHA compounds are presented. Definitions of some terms used in this section
Permissible Exposure Limits are based in the 1989 PELs and the June, are: LD50 - Lethal Dose (solids & liquids) which kills 50% of the exposed
1993 Air Contaminants Rule (Federal Register: 58: 35338-35351 and 58: animals; LC50 - Lethal Concentration (gases) which kills 50% of the exposed
40191). Both the current PELs and the vacated PELs are indicated. The animals; ppm concentration expressed in parts of material per million parts
phrase, "Vacated 1989 PEL," is placed next to the PEL, which was vacated 3
of air or water; mg/m concentration expressed in weight of substance per
by Court Order. IDLH - Immediately Dangerous to Life and Health - This volume of air; mg/kg quantity of material, by weight, administered to a test
level represents a concentration from which one can escape within 30- subject, based on their body weight in kg. Other measures of toxicity include
minutes without suffering escape-preventing or permanent injury. The DFG - TDLo, the lowest dose to cause a symptom and TCLo the lowest
MAK is the Republic of Germany's Maximum Exposure Level, similar to the concentration to cause a symptom; TDo, LDLo, and LDo, or TC, TCo,
U.S. PEL. NIOSH is the National Institute of Occupational Safety and LCLo, and LCo, the lowest dose (or concentration) to cause lethal or toxic
Health, which is the research arm of the U.S. Occupational Safety and effects. Cancer Information: The sources are: IARC - the International
Health Administration (OSHA). NIOSH issues exposure guidelines called Agency for Research on Cancer; NTP - the National Toxicology Program,
Recommended Exposure Levels (RELs). When no exposure guidelines are RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA and
established, an entry of NE is made for reference. NTP- National CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing
Toxicology Program potential to cause human cancer with rankings from 1 to 4. Subrankings
(2A, 2B, etc.) are also used. Other Information: BEI - ACGIH Biological
Exposure Indices, represent the levels of determinants which are most likely
HAZARD RATINGS:
to be observed in specimens collected from a healthy worker who has been
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM: Health Hazard: 0
exposed to chemicals to the same extent as a worker with inhalation
(minimal acute or chronic exposure hazard); 1 (slight acute or chronic
exposure to the TLV. Ecological Information: EC is the effect
exposure hazard); 2 (moderate acute or significant chronic exposure
concentration in water. BCF = Bioconcentration Factor, which is used to
hazard); 3 (severe acute exposure hazard; onetime overexposure can result
determine if a substance will concentrate in lifeforms which consume
in permanent injury and may be fatal); 4 (extreme acute exposure hazard;
contaminated plant or animal matter. Coefficient of Oil/Water Distribution
onetime overexposure can be fatal). Flammability Hazard: 0 (minimal
is represented by log Kow or log Koc and is used to assess a substance's
hazard); 1 (materials that require substantial pre-heating before burning); 2
behavior in the environment.
(combustible liquid or solids; liquids with a flash point of 38-93癈 [100-
REGULATORY INFORMATION:
200癋]); 3 (Class IB and IC flammable liquids with flash points below 38癈
This section explains the impact of various laws and regulations on the
[100癋]); 4 (Class IA flammable liquids with flash points below 23癈 [73癋]
material. U.S.: EPA is the U.S. Environmental Protection Agency. DOT is
and boiling points below 38癈 [100癋]. Reactivity Hazard: 0 (normally
the U.S. Department of Transportation. SARA is the Superfund
stable); 1 (material that can become unstable at elevated temperatures or
Amendments and Reauthorization Act. TSCA is the U.S. Toxic Substance
which can react slightly with water); 2 (materials that are unstable but do not
Control Act. CERCLA (or Superfund) refers to the Comprehensive
detonate or which can react violently with water); 3 (materials that can
Environmental Response, Compensation, and Liability Act. Labeling is per
detonate when initiated or which can react explosively with water); 4
the American National Standards Institute (ANSI Z129.1). CANADA:
(materials that can detonate at normal temperatures or pressures).
CEPA is the Canadian Environmental Protection Act. WHMIS is the
NATIONAL FIRE PROTECTION ASSOCIATION: Health Hazard: 0
Canadian Workplace Hazardous Materials Information System. TC is
(material that on exposure under fire conditions would offer no hazard
Transport Canada. DSL/NDSL are the Canadian Domestic/Non-Domestic
beyond that of ordinary combustible materials); 1 (materials that on
Substances Lists. The CPR is the Canadian Product Regulations. This
exposure under fire conditions could cause irritation or minor residual injury);
section also includes information on the precautionary warnings, which
2 (materials that on intense or continued exposure under fire conditions
appear, on the materials package label.
could cause temporary incapacitation or possible residual injury); 3
(materials that can on short exposure could cause serious temporary or
residual injury); 4 (materials that under very short exposure causes death or
major residual injury). Flammability Hazard and Reactivity Hazard: Refer to
definitions for "Hazardous Materials Identification System".
BRIDGIT?SOLDERING FLUX MSDS EFFECTIVE DATE: June 24, 2002
PAGE 10 OF 10
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