Page 1/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
* 1 Identification of substance:
?Product details:
?Trade name: Certanium 934 Flux 16500
?Article number: 16500
?Application of the substance / the preparation Flux
?Manufacturer/Supplier:
Barnes Group KENT Limited
Pitreavie Crescent
Pitreavie Business Park
Dunfermline
Fife
KY11 8UQ
Tel: 01383 737393
Fax: 01383 620079
Monday - Thursday 8.30am - 5.30pm, Friday 9.00am - 3.00pm
?Informing department: Product Safety Department
?Emergency information: fullertonj@kenteurope.com
* 2 Hazards identification
?Hazard designation:
@@
??
AD C Corrosive
N Dangerous for the environment
?Information pertaining to particular dangers for man and environment
R 34 Causes burns.
R 50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Classification system
The classification is in line with current EC lists. It is expanded, however, by information from technical literature and by information
furnished by supplier companies.
?GHS label elements
~
Danger
H314 - Causes severe skin burns and eye damage.
~ Warning
H400 - Very toxic to aquatic life.
~
Warning
H335+H336 - May cause respiratory irritation. May cause drowsiness or dizziness.
?Prevention:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash thoroughly after handling.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
GB
(Contd. on page 2)
Page 2/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Certanium 934 Flux 16500
(Contd. of page 1)
* 3 Composition/information on ingredients
?Chemical characterization
?Description: Mixture of the substances listed below with harmless additions.
?Dangerous components:
@
? C, ? Xn, ? N; R 22-34-50/53
A G
@ @
D
CAS: 7646-85-7 zinc chloride 20-40%
Danger: ~ 3.2/1B
EINECS: 231-592-0
Warning: ~ 4.1.C/1; ~ 3.1.O/4
@
? Xn, ? Xi; R 22-36
G @
G
CAS: 12125-02-9 ammonium chloride 5-20%
Warning: ~ 3.1.O/4, 3.3/2
EINECS: 235-186-4
A
@
? C, ? Xi; R 34-37
G
@
CAS: 7647-01-0 hydrogen chloride 5-10%
Danger: ~ 3.2/1B
EINECS: 231-595-7
Warning: ~ 3.8/3
* 4 First aid measures
?General information Instantly remove any clothing soiled by the product.
?After inhalation Supply fresh air or oxygen; call for doctor.
?After skin contact
Instantly wash with water and soap and rinse thoroughly.
Seek immediate medical advice.
?After eye contact Rinse opened eye for several minutes under running water. Then consult doctor.
?After swallowing
Do not induce vomiting; instantly call for medical help.
Rinse out mouth and then drink plenty of water.
* 5 Fire fighting measures
?Suitable extinguishing agents
Carbon dioxide
Foam
Fire-extinguishing powder
?Special hazards caused by the material, its products of combustion or resulting gases:
Hydrogen chloride (HCl)
Formation of toxic gases is possible during heating or in case of fire.
?Protective equipment:
Wear self-contained breathing apparatus.
Wear full protective suit.
?Additional information Collect contaminated fire fighting water separately. It must not enter drains.
* 6 Accidental release measures
?Person-related safety precautions:
Wear protective equipment. Keep unprotected persons away.
Keep away from ignition sources
?Measures for environmental protection:
Do not allow product to reach sewage system or water bodies.
Inform respective authorities in case product reaches water or sewage system.
?Measures for cleaning/collecting:
Use neutralizing agent.
Treat with 2 % sodium hydroxide solution.
Dispose of contaminated material as waste according to item 13.
Ensure adequate ventilation.
GB
(Contd. on page 3)
Page 3/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Certanium 934 Flux 16500
(Contd. of page 2)
* 7 Handling and storage
?Handling
?Information for safe handling: Ensure good ventilation/exhaustion at the workplace.
?Information about protection against explosions and fires: Keep ignition sources away - Do not smoke.
?Storage
?Requirements to be met by storerooms and containers: No special requirements.
?Information about storage in one common storage facility:
Do not store together with oxidizing and acidic materials as well as heavy-metal compounds.
Do not store together with alkalis (caustic solutions).
Store away from flammable substances.
Store away from metals.
?Further information about storage conditions: Store in cool, dry conditions in well sealed containers.
* 8 Exposure controls and personal protection
?Additional information about design of technical systems: No further data; see item 7.
?Components with limit values that require monitoring at the workplace:
zinc chloride
WEL Short-term value: 2 mg/m?br>
Long-term value: 1 mg/m?br>
ammonium chloride
WEL Short-term value: 20 mg/m?br>
Long-term value: 10 mg/m?br>
hydrogen chloride
WEL Short-term value: 8 mg/m? 5 ppm
Long-term value: 2 mg/m? 1 ppm
(gas and aerosol mists)
?Additional information: The lists that were valid during the compilation were used as basis.
?Personal protective equipment
?General protective and hygienic measures
Take off immediately all contaminated clothing
Keep away from foodstuffs, beverages and food.
Wash hands during breaks and at the end of the work.
Avoid contact with the eyes and skin.
Do not inhale gases / fumes / aerosols.
?Breathing equipment:
In case of brief exposure or low pollution use breathing filter apparatus. In case of intensive or longer exposure use breathing
apparatus that is independent of circulating air.
?Protection of hands:
Impervious gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
?Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer.
?Penetration time of glove material
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
?Eye protection: Tightly sealed safety glasses.
?Body protection: Protective work clothing.
* 9 Physical and chemical properties:
?General Information
Form: Liquid
Viscous
Colour: Transparent
(Contd. on page 4)
GB
Page 4/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Certanium 934 Flux 16500
(Contd. of page 3)
Odour: Pungent
?Change in condition
Melting point/Melting range: Not determined
Boiling point/Boiling range: 102癈
?Flash point: Not applicable
?Self-inflammability: Product is not selfigniting.
?Danger of explosion: Product is not explosive.
?Density at 20癈 1.3 g/cm?br>
?Solubility in / Miscibility with
Water: Fully miscible
?pH-value at 20癈: <3
* 10 Stability and reactivity
?Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
?Materials to be avoided:
?Dangerous reactions
Reacts with alkali and metals
Reacts with oxidizing agents
?Dangerous products of decomposition:
Corrosive gases/vapours
Hydrogen chloride (HCl)
Carbon dioxide
* 11 Toxicological information
?Acute toxicity:
?LD/LC50 values that are relevant for classification:
zinc chloride
Oral LD50 350 mg/kg (rat)
ammonium chloride
Oral LD50 1650 mg/kg (rat)
?Primary irritant effect:
?on the skin: Caustic effect on skin and mucous membranes.
?on the eye: Strong caustic effect.
?Sensitization: No sensitizing effect known.
?Additional toxicological information:
Swallowing will lead to a strong caustic effect on mouth and throat and to the danger of perforation of esophagus and stomach.
Corrosive
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
The product shows the following dangers according to the calculation method of the General EC Classification Guidelines for
Preparations as issued in the latest version:
12 Ecological information:
?Additional ecological information:
?General notes:
Must not reach sewage water or drainage ditch undiluted or unneutralized.
Water hazard class 1 (German Regulation) (Self-assessment): slightly hazardous for water.
Do not allow undiluted product or large quantities of it to reach ground water, water bodies or sewage system.
GB
(Contd. on page 5)
Page 5/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Certanium 934 Flux 16500
(Contd. of page 4)
* 13 Disposal considerations
?Product:
?Recommendation Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
?Uncleaned packagings:
?Recommendation: Disposal must be made according to official regulations.
* 14 Transport information
?Land transport ADR/RID (cross-border)
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ad
d?br>
?ADR/RID-GGVS/E Class: 8 (C1)
?UN-Number: 3264
?Packaging group: III
?Label 8
?Special marking: ?
?Designation of goods: 3264 CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC ACID, ZINC
CHLORIDE)
?Maritime transport IMDG:
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}
d
?IMDG Class: 8
?UN Number: 3264
?Label 8
?Packaging group: III
?EMS Number: F-A,S-B
?Marine pollutant: No
?Correct technical name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC ACID, ZINC CHLORIDE)
?Air transport ICAO-TI and IATA-DGR:
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}
a
d
?ICAO/IATA Class: 8
?UN/ID Number: 3264
?Label 8
?Packaging group: III
?Correct technical name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (HYDROCHLORIC ACID, ZINC CHLORIDE)
?UN "Model Regulation": UN3264, CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S., 8, III
* 15 Regulatory information
?Designation according to EC guidelines:
The product has been classified and labelled in accordance with EC Directives / Ordinance on Hazardous Materials (GefStoffV)
(Contd. on page 6)
GB
Page 6/6
Safety Data Sheet
according to 1907/2006/EC, Article 31
Printing date 11.03.2010 Revision: 03.02.2010
Trade name: Certanium 934 Flux 16500
(Contd. of page 5)
?Code letter and hazard designation of product:
@@
??
AD C Corrosive
N Dangerous for the environment
?Hazard-determining components of labelling:
zinc chloride
?Risk phrases:
34 Causes burns.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Safety phrases:
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
36/37/39 Wear suitable protective clothing, gloves and eye/face protection.
45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
57 Use appropriate container to avoid environmental contamination.
?National regulations
?Water hazard class: Water hazard class 1 (Self-assessment): slightly hazardous for water.
* 16 Other information:
These data are based on our present knowledge. However, they shall not constitute a guarantee for any specific product features
and shall not establish a legally valid contractual relationship.
?Relevant R-phrases
22 Harmful if swallowed.
34 Causes burns.
36 Irritating to eyes.
37 Irritating to respiratory system.
50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
?Department issuing data specification sheet: Environment protection department.
?Contact: Marketing Department
?Abbreviations and acronyms:
ADR: Accord europ閑n sur le transport des marchandises dangereuses par Route (European Agreement concerning the International Carriage of Dangerous Goods by Road)
RID: R鑗lement international concernant le transport des marchandises dangereuses par chemin de fer (Regulations Concerning the International Transport of Dangerous
Goods by Rail)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
IATA-DGR: Dangerous Goods Regulations by the "International Air Transport Association" (IATA)
ICAO: International Civil Aviation Organization
ICAO-TI: Technical Instructions by the "International Civil Aviation Organization" (ICAO)
GHS: Globally Harmonized System of Classification and Labelling of Chemicals
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
GB
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