Material Safety Data Sheet CS: 1.4.21
Page: 1 of 3
CS: 1.4.21
Infosafe NoTM 1HASA Issue Date :March 2007 RE-ISSUED by HAYMES
Product Name DESIGNER FINISHES OXIDISING PATINA
Not classified as hazardous according to criteria of NOHSC
COMPANY DETAILS
HAYMES PAINT
Company Name
P.O Box 167 WENDOUREE
Address
VICTORIA 3355 Australia
Tel: 03 5342 6200
Tel/Fax
IDENTIFICATION
DFOP
Product Code
DESIGNER FINISHES OXIDISING PATINA
Product Name
OXIDIZING LIQUID, CORROSIVE, N.O.S.
Proper Shipping
Name
3098
UN Number
5.1
DG Class
8
Sub. Risk
III
Packing Group
Not Scheduled
Poisons Schedule
Magic Effects Oxidising Patina is used in conjunction with Real Iron and
Product Use
Real Copper Paints. When brushed onto dried films of these paints it reacts
with the metal particles present in the paints causing the formation of
red-brown coloured Rust(on Real Iron Paint) or blue-green coloured
Verdigris(on Real Copper Paint).
Physical Data
Blue-green coloured, viscous liquid
Appearance
As for water
Boiling Point
As for water
Vapour Pressure
Approx: 1.1
Specific Gravity
Soluble
Solubility in Water
Other Properties
Approx: 82% by weight
Volatile Component
As for water
Vapour Density
7-9
pH Value
Liquid
Form
Ingredients
Name CAS Proportion
Ingredients
Water 7732-18-5 80-90 %
Ammonium chloride 12125-02-9 10-20 %
Cupric Nitrate 3251-23-8 1-10 %
Thickener, PROPRIETARY 1-10 %
biocide,
surfactant and
defoamer
HEALTH HAZARD INFORMATION
Health Effects
Slightly toxic.
Acute - Swallowed
Large amounts have to be ingested before toxic effects are manifested. Such
amounts are unlikely to be available during normal applications of this
Print Date: 14/04/2008 CS: 1.4.21
Material Safety Data Sheet CS: 1.4.21
Page: 2 of 3
CS: 1.4.21
Infosafe NoTM 1HASA Issue Date :March 2007 RE-ISSUED by HAYMES
Product Name DESIGNER FINISHES OXIDISING PATINA
Not classified as hazardous according to criteria of NOHSC
product.
Effects from ingestion include vomiting, dizziness, convulsions, abdominal
pains and diarrhea.
A moderate eye irritant.
Acute - Eye
Repeated or prolonged skin contact may lead to dermatitic effects.
Acute - Skin
Dried residue may irritate the mucous membranes.
Acute - Inhaled
Chronic exposure resulting in copper accumulation may give rise to
Chronic
damage of the kidneys, liver, bone and vision, together with various
symptoms attributed to damage of the nervous system and anaemia.
First Aid
May be harmful by ingestion. Symptoms include: vomiting, gastric pain,
Swallowed
dizziness,
convulsions, shock, coma and possibly death. Poisoning by the ingestion of
large amounts is unlikely, because copper salts tend to cause vomiting,
before toxic amounts are consumed. Have victim drink 240 to 300mL of water
to dilute material in stomach. Seek medical advice immediately.
Immediately irrigate with copious quantity of water for at least 15 minutes.
Eye
Eyelids to be held open. Seek medical attention.
Wash affected areas with copious quantities of water immediately. If
Skin
irritation occurs seek medical advice.
Not applicable.
Inhaled
An eye wash and a shower or safety shower should be available in case of
First Aid Facilities
large scale contact with eyes or skin.
Advice to Doctor
Treat symptomatically. Lavage if large quantity ingested.
Advice to Doctor
Other Health Hazard Information
PRECAUTIONS FOR USE
The product contains cupric nitrate and ammonium chloride. Cupric nitrate
Exposure Limits
does not have a WES(*), but ammonium chloride(fume) has TWA of 10mg/m3 and
STEL of 20 mg/m3.
The effects of ammonium chloride are unlikely to be observed during normal
handling procedures. Forced drying of Oxidising Patina will create ammonium
chloride fumes.
(*) WES = Workplace Exposure Standard, Worksafe Australia,
2nd Edit., October 1991.
Use in a well ventilated area only.
Eng. Controls
Personal Protection
Wearing of the following personal protective equipment is recommended. Safety
Protective Equip.
glasses. Elbow-length PVC gloves. Overalls or similar protective apparel.
Enclosed footwear. Avoid skin and eye contact. Always wash hands before
smoking, eating, drinking or using the toilet. Prevent generation of mists!
Flammability
Non combustible. Non flammable.
Fire Hazards
Product residue following evaporation of water may react with other
materials assisting further combustion. Toxic fumes may be produced from
this material if it is involved in a fire.
SAFE HANDLING INFORMATION
Storage and Transport
Dangerous Goods of Class 5.1 Oxidising Agents are incompatible in a placard
Storage and
load with any of the following: - Class 1, Class 2.1, Class 2.3, Class 3,
Transport
Class 4, Class 5.2, Class 7, Class 8, Fire risk substances and combustible
liquids.
Store away from incompatible materials, reducing agents, solvents and other
Print Date: 14/04/2008 CS: 1.4.21
Material Safety Data Sheet CS: 1.4.21
Page: 3 of 3
CS: 1.4.21
Infosafe NoTM 1HASA Issue Date :March 2007 RE-ISSUED by HAYMES
Product Name DESIGNER FINISHES OXIDISING PATINA
Not classified as hazardous according to criteria of NOHSC
flammable or combustible materials.
Oxidising Patina reacts with iron, steel, aluminium and copper containers.
It should not be transferred into or stored in these types of containers.
Transport and store in accordance with dangerous goods requirements.
OXIDIZING LIQUID, CORROSIVE, N.O.S.
Proper Shipping
Name
5C2
EPG Number
31
IERG Number
3.8.5.1
Packaging Method
Spills and Disposal
In event of large spill: Contain using sand and earth - prevent runoff into
Spills & Disposal
drains and waterways.
Collect and seal in properly labelled plastic containers for disposal by
incineration.
In the event of a small spill:
Wipe up residue with a cloth(use full length gloves)and rinse cloth with
copious amounts of water. Cloth may then be disposed of in normal waste.
Fire/Explosion Hazard
Releases oxygen upon decomposition, assisting combustion of other materials.
Fire/Explos. Hazard
Decomposes on heating emitting toxic fumes. Hazardous decomposition products
of heating and/or burning: Metal oxides. Hydrogen chloride. Chlorides
Extinguish fire with the following: Use carbon dioxide. Water. In case of fire
in the surroundings: all extinguishing agents allowed. Keep containers cool
with water spray. If safe to do so, remove containers from path of fire.
Heating can cause expansion or decomposition leading to violent rupture of
containers. Evacuate immediate area.
The product attacks many metals causing corrosion by oxidation.
Hazardous Reaction
OTHER INFORMATION
Ammonium chloride: LD50(oral, rat) 1650 mg/Kg
Toxicology
Eye(rabbit) 500mg/24 hours
No data available for cupric nitrate
Highly toxic to aquatic life/ birdlife. Avoid contaminating waterways.
Environ. Protection
Proper Shipping Name: OXIDISING LIQUID, CORROSIVE, N.O.S (Cupric Nitrate)
Pkg. & Labelling
UN No; 3098
Class: 5.1
Subsidiary Risk 8
Packing Group: III
Special Provisions: SP109, SP129, SP274
Packaging Method: 3.8.5.1
CONTACT POINT
...End Of MSDS...
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Print Date: 14/04/2008 CS: 1.4.21
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