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CAN-CRANK
MSDS Preparation Date (dd/mm/yyyy): 14/12/2007
MATERIAL SAFETY DATA SHEET
SECTION 1 - PRODUCT AND COMPANY IDENTIFICATION
Product identifier : CAN-CRANK
: 12PP-20, 12PP-30, 12PP-50, 24PP-30, 24PP-40, 24PP-50
Product Code(s)
: Electrochemical supercapacitor.
Product Use
: Mixture.
Chemical Family
Supplier's name and address: Manufacturer's name and address:
ELIT ?Refer to Cantec for further information.
Cantec Systems Ltd.
1573 Laperriere Ave.
Ottawa, Ontario, Canada
K1Z 7T3
Information Telephone No. : 613-725-3704 (8 AM to 5 PM, EST, Monday to Friday)
: (613) 996-6666 (CANUTEC)
24 Hr. Emergency Tel #
SECTION 2 - COMPOSITION/INFORMATION ON INGREDIENTS
OSHA PEL
ACGIH TLV
TWA STEL PEL STEL
Ingredients % (weight)
CAS #
Carbon 15.00 - 20.00 N/Av N/Av N/Av N/Av
7440-44-0
Iron 10.00 - 20.00 N/Av N/Av N/Av N/Av
7439-89-6
Epoxy compound 10.00 - 20.00 N/Av N/Av N/Av N/Av
N/Av
Potassium hydroxide 10.00 - 20.00 N/Av N/Av
2 mg/m? 2 mg/m?br>
1310-58-3
(Ceiling) (Ceiling)
(final rule
limit)
Copper 7.00 - 13.00 N/Av N/Av
0.2 mg/m? 0.1 mg/m?br>
7440-50-8
(fumes); 1 (fumes); 1
mg/m?(dust) mg/m?(dust)
Polyvinyl chloride 1.00 - 5.00 N/Av N/Av N/Av N/Av
9002-86-2
Asbestos paper 1.00 - 4.00 N/Av N/Av N/Av N/Av
N/Av
Nickel 1.00 - 3.00 N/Av 1 mg/m? N/Av
1.5 mg/m?br>
7440-02-0
(inhalable)
Epoxy fiberglass 0.50 - 1.50 N/Av N/Av N/Av N/Av
N/Av
Tetrafluoroethylene 0.50 - 1.50 2 ppm N/Av N/Av N/Av
116-14-3
Rubber 0.10 - 0.80 N/Av N/Av N/Av N/Av
308075-06-1
Polyethylene 0.10 - 0.20 N/Av N/Av N/Av N/Av
9002-88-4
*Note: This product is not a WHMIS controlled product in Canada. This product is considered to be a 'manufactured article'. All
chemicals are sealed inside the unit and pose no hazard unless the unit is disassembled or damaged.
SECTION 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
This product is not a WHMIS controlled product in Canada. This product is considered to be a 'manufactured article'.
All chemicals are sealed inside the unit and pose no hazard unless the unit is disassembled or damaged.
However, if the article is damaged and/or material is released, contents are harmful. If outer containers are damaged and leaking:
Corrosive - Causes burns. Possible sensitizer.
Contains particles which may cause lung damage or cancer if inhaled in large quantities.
***POTENTIAL HEALTH EFFECTS***
: Eyes, skin, respiratory system and digestive system.
Target organs
: Inhalation: YES Skin Absorption: NO Skin & Eyes: YES Ingestion: YES
Routes of exposure
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CAN-CRANK
MSDS Preparation Date (dd/mm/yyyy): 14/12/2007
Signs and symptoms of short-term (acute) exposure
Inhalation : None expected, when used as intended. All chemicals are sealed inside the unit and pose no hazard unless
the unit is disassembled or damaged. If outer containers are damaged and leaking: May cause irritation to
the nose, throat and upper respiratory tract. Extremely high exposures may lead to inflammation of lung
tissue (chemical pneumonitis), chemical bronchitis and accumulation of fluid in the lungs (pulmonary
edema). Inhalation of fumes, may result in metal fume fever, a flu-like illness. Symptoms of metal fume
fever may include fever, fatigue, vomiting, muscle aches and shortness of breath.
: None expected, when used as intended. All chemicals are sealed inside the unit and pose no hazard unless
Skin
the unit is disassembled or damaged. If outer containers are damaged and leaking: Direct skin contact may
cause corrosive skin burns, deep ulcerations and possibly permanent scarring.
: None expected, when used as intended. All chemicals are sealed inside the unit and pose no hazard unless
Eyes
the unit is disassembled or damaged. If outer containers are damaged and leaking: Severely irritating or
corrosive. Chemical burns, corneal damage, and possibly blindness can result from direct contact.
: Harmful effects are not expected under normal usage. All chemicals are sealed inside the unit and pose
Ingestion
no hazard unless the unit is disassembled or damaged. However, if the article is damaged and/or material
is released product may be considered: May cause severe irritation and corrosive damage in the mouth,
throat and stomach. Symptoms may include severe pain, vomiting, diarrhea, collapse and death.
Effects of long-term (chronic) exposure
: None expected, when used as intended. All chemicals are sealed inside the unit and pose
no hazard unless the unit is disassembled or damaged. If outer containers are damaged and
leaking: Prolonged skin contact may cause dermatitis (rash), characterized by red, dry,
itching skin. Dust causes fibrosis.
Conditions aggravated by overexposure
: None known or reported by the manufacturer.
: Possible cancer hazard . See TOXICOLOGICAL INFORMATION, Section 11.
Carcinogenic status
: Possible sensitizer. See TOXICOLOGICAL INFORMATION, Section 11.
Additional health hazards
Potential environmental effects
: See ECOLOGICAL INFORMATION (Section 12).
SECTION 4 - FIRST AID MEASURES
: None required under normal conditions. If outer containers are damaged and leaking:
Inhalation
Immediately remove person to fresh air. If breathing is irregular or stopped, administer
artificial respiration. If breathing is difficult, give oxygen by qualified medical personnel only.
Seek immediate medical attention/advice.
: None required under normal conditions. If outer containers are damaged and leaking: Flush
Skin contact
affected skin with gently flowing lukewarm water for at least 20 minutes. Seek immediate
medical attention/advice.
: None required when used as intended. If outer containers are damaged and leaking:
Eye contact
Immediately flush eyes thoroughly with running water for at least 20 to 30 minutes. Seek
immediate medical attention/advice.
: None required when used as intended. If outer containers are damaged and leaking: Do
Ingestion
NOT induce vomiting. Have victim rinse mouth with water, then give one to two glasses of
water to drink. Seek immediate medical attention/advice. Never give anything by mouth to
an unconscious person.
: Treat symptomatically.
Notes For Physician
SECTION 5 - FIRE FIGHTING MEASURES
Fire hazards/conditions of flammability
: Not flammable under normal conditions of handling. Battery should not be over-charged or
over-discharged to prevent possibility of oxygen and/or hydrogen generation. If outer
containers are damaged and leaking: May react with water, generating heat.
Flammability classification (OSHA 29 CFR 1910.1200)
: Non-flammable.
: Not available.
Flash point
: Not available. : Not available.
Flash point Method Auto-ignition temperature
Upper flammable limit (% by vol.)
Lower flammable limit (% by vol.)
: Not available. : Not available.
: None known.
Oxidizing properties
: Not applicable. : Not applicable.
Flame Projection Length Flashback observed
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CAN-CRANK
MSDS Preparation Date (dd/mm/yyyy): 14/12/2007
Explosion data: Sensitivity to mechanical impact / static discharge
: Not expected to be sensitive to mechanical impact or static discharge.
Use media suitable to the surrounding fire such as water fog or fine spray, alcohol foams,
Suitable extinguishing media :
carbon dioxide and dry chemical.
Special fire-fighting procedures/equipment
: Firefighters should wear an approved full-face, self-contained breathing apparatus (SCBA)
and impervious clothing. Evacuate personnel to safe areas. Fight fires from a safe distance.
Water spray may be useful in cooling equipment exposed to heat and flame.
Hazardous combustion products
: Carbon oxides; nitrogen oxides (NOx); Acrolein; Hydrogen chloride gas; Aldehydes; metal
oxides; other unidentified organic compounds.
0 - Minimal 1 - Slight 2 - Moderate 3 - Serious 4 - Severe
NFPA Rating
: Health: 1 Flammability: 1 Instability: 0 Special Hazards: None
SECTION 6 - ACCIDENTAL RELEASE MEASURES
: Remove all sources of ignition. Restrict access to area until completion of clean-up.
Personal precautions
Individuals involved in the cleanup must wear appropriate personal protective equipment.
Refer to Section 8, EXPOSURE CONTROLS AND PERSONAL PROTECTION, for
additional information on acceptable personal protective equipment.
: Prevent product from entering drains, sewers, waterways and soil.
Environmental precautions
: Ventilate area of release. All chemicals are sealed inside the unit and pose no hazard unless
Spill response/cleanup
the unit is disassembled or damaged. Avoid overcharging. If outer containers are damaged
and leaking: Absorb material with inert absorbent, and place into labelled containers for
disposal. Refer to Section 13 for disposal of contaminated material. Notify the appropriate
authorities as required.
: None known.
Prohibited materials
Special spill response procedures
: In case of a transportation accident, in the United States contact CHEMTREC at
1-800-424-9300 or International at 1-703-527-3887. If a spill/release in excess of the EPA
reportable quantity is made into the environment, immediately notify the national response
center in the United States (phone: 1-800-424-8002).
US CERCLA Reportable quantity (RQ): Nickel (100 lbs / 45.4 kg); Potassium hydroxide
(1000 lbs / 454 kg); Copper (5000 lbs / 2270 kg).
SECTION 7 - HANDLING AND STORAGE
: All chemicals are sealed inside the unit and pose no hazard unless the unit is disassembled
Safe Handling procedures
or damaged. Keep away from heat and sources of ignition. Avoid overcharging. If outer
containers are damaged and leaking: Wear suitable protective equipment during handling.
Use with adequate ventilation. Avoid contact with skin and eyes. Keep away from
incompatibles. Avoid breathing vapors, fumes or dust.
Keep away from incompatibles. Store in a cool, dry, well ventilated area, away from heat
Storage requirements :
and ignition sources. Storage area should be clearly identified, clear of obstruction and
accessible only to trained and authorized personnel.
: Strong oxidizing agents; Acids; Conductive liquids.
Incompatible materials
: No special precautions required.
Special packaging materials
SECTION 8 - EXPOSURE CONTROLS AND PERSONAL PROTECTION
Ventilation and engineering measures
: Under normal conditions of use, general ventilation should be sufficient. If outer containers
are damaged and leaking: Local exhaust ventilation is preferred to prevent contaminant
dispersion into work area.
: None required when used as intended. In the case of vapour formation use a respirator with
Respiratory protection
an approved filter. Advice should be sought from respiratory protection specialists.
: None required when used as intended. If outer containers are damaged and leaking:
Skin protection
Gloves impervious to the material are recommended. Wear long sleeved shirt and pants to
minimize exposed skin.
: None required when used as intended. If outer containers are damaged and leaking:
Eye / face protection
Chemical splash goggles are recommended. A full face shield may also be necessary.
: Emergency showers and eyewash facilities should be nearby.
Other protective equipment
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CAN-CRANK
MSDS Preparation Date (dd/mm/yyyy): 14/12/2007
General hygiene considerations
: Wash thoroughly after handling. When using, do not eat, drink or smoke. Handle in
accordance with good industrial hygiene and safety practice.
: See ingredients listed in section 2.
Permissible exposure levels
SECTION 9 - PHYSICAL AND CHEMICAL PROPERTIES
: Solid article. Not available.
Physical state Appearance :
: No odour. Not available.
Odour Odour threshold :
: Not available.
pH
: Not available. Not available.
Boiling point Specific gravity :
: Not available.
Melting/Freezing point Coefficient of water/oil distribution
: Not available.
: Insoluble.
Vapour pressure (mmHg @ 20?C / 68?F) Solubility in water
: Not available.
: Not available.
Vapour density (Air = 1) Evaporation rate (n-Butyl acetate = 1)
: Not available.
: Not available.
Volatile organic Compounds (VOC's) Volatiles (% by weight)
: Not available.
SECTION 10 - REACTIVITY AND STABILITY DATA
: Stable under the recommended storage and handling conditions prescribed.
Stability and reactivity
: Will not occur.
Hazardous polymerization
: Keep away from excessive heat, open flames, sparks and other possible sources of ignition.
Conditions to avoid
Materials To Avoid And Incompatibility
: See Section 7 (Handling and Storage) section for further details.
Hazardous decomposition products
: None known, refer to hazardous combustion products in Section 5.
SECTION 11 - TOXICOLOGICAL INFORMATION
: There is no available data for the product itself, only for the ingredients. See
Toxicological data
below for individual ingredient acute toxicity data.
LC50(4hr) LD50
Ingredients inh, rat oral dermal
N/Av > 5000 mg/kg (rat)
Carbon N/Av
N/Av 30,000 mg/kg (rat)
Iron N/Av
N/Av N/Av
Epoxy compound N/Av
N/Av 273 mg/kg (rat)
Potassium hydroxide N/Av
N/Av N/Av
Copper N/Av
N/Av N/Av
Polyvinyl chloride N/Av
N/Av N/Av
Asbestos paper N/Av
> 2550 mg/m? > 9000 mg/kg (rat)
Nickel N/Av
N/Av N/Av
Epoxy fiberglass N/Av
4000 ppm N/Av
Tetrafluoroethylene N/Av
N/Av N/Av
Rubber N/Av
N/Av > 3000 mg/kg (rat)
Polyethylene N/Av
Not applicable in the product's present form. All chemicals are sealed inside the unit and
Carcinogenic status :
pose no hazard unless the unit is disassembled or damaged. If outer containers are
damaged and leaking: Contains the following chemical(s) listed as Group 2B (possibly
carcinogenic) by IARC: Nickel; Tetrafluoroethylene. This product may contain trace levels of
the following ingredients: Asbestos (IARC - Group 1; NTP - Group 1).
None known.
Reproductive effects :
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MSDS Preparation Date (dd/mm/yyyy): 14/12/2007
None known.
Teratogenicity :
None known.
Mutagenicity :
Not available.
Epidemiology :
Not a hazard under normal conditions of use. All chemicals are sealed inside the unit and
Sensitization to material :
pose no hazard unless the unit is disassembled or damaged. If outer containers are
damaged and leaking: May cause severe skin sensitization with allergic contact dermatitis
symptoms such as swelling, rash and eczema. No data available to indicate product or
components may be respiratory sensitizers.
: None known or reported by the manufacturer.
Synergistic materials
: None expected, when used as intended.
Irritancy
: None known or reported by the manufacturer.
other important hazards
SECTION 12 - ECOLOGICAL INFORMATION
: The ecological characteristics of this product have not been fully investigated. The product
Environmental effects
should not be allowed to enter drains or water courses, or be deposited where it can affect
ground or surface waters. Provincial/state and federal regulations may require that
environmental and/or other agencies be notified of a spill incident.
Important environmental characteristics
: No information available.
: No data is available on the product itself.
Ecotoxicological
SECTION 13 - DISPOSAL CONSIDERATIONS
: Handle waste according to recommendations in Section 7.
Handling for Disposal
: Dispose in accordance with all applicable federal, state, provincial and local regulations.
Methods of Disposal
Contact your local, state, provincial or federal environmental agency for specific rules.
: If this product, as supplied, becomes a waste in the United States, it may meet the criteria of
RCRA
a hazardous waste as defined under RCRA, Title 40 CFR 261. It is the responsibility of the
waste generator to determine the proper waste identification and disposal method.
SECTION 14 - TRANSPORTATION INFORMATION
Packing
Regulatory
Group
UN Number Shipping Name
Information Class Label
not regulated
Not regulated.
None
49CFR/DOT none
This product has been tested in accordance with 49 CFR section 173.159(d)(3). No fluid leakage was found following the
49CFR/DOT
vibration and pressure differential tests. The product, therefore, meets the requirements of 49 CFR sections 173.159.d)(3)(i)
Additional
and (ii).The product is excepted from shipping requirements provided the requirements of 49 CFR Sections 173.159(d)(1),
information
173.159(d)(2) and 173.159(d)(4) are met.
TDG Not regulated. not regulated none
none
TDG
This product is not subject to TDG requirements, in accordance with Special Provision 39(2).
Additional
information
SECTION 15 - REGULATORY INFORMATION
US Federal Information:
OSHA: This material is not classified as hazardous under OSHA regulations (29 CFR Part 1910.1200). This product is
considered an 'article' under 29 CFR Part 1910.1200.
TSCA: All ingredients appear on the Toxic Substances Control Act (TSCA) inventory (information provided by the Manufacturer,
"ELIT").
CERCLA Reportable Quantity (RQ) (40 CFR 117.302): See Section 6
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CAN-CRANK
MSDS Preparation Date (dd/mm/yyyy): 14/12/2007
SARA TITLE III: Sec. 302, Extremely Hazardous Substances, 40 CFR 355: No Extremely Hazardous Substances are present in
this material.
SARA TITLE III: Sec. 311 and 312, MSDS Requirements, 40 CFR 370 Hazard Classes: No hazards resulting from the material
as supplied. Under SARA Sections 311 and 312, the EPA has established threshold quantities for the reporting of hazardous
chemicals. The current thresholds are 500 pounds for the threshold planning quantity (TPQ), whichever is lower, for extremely
hazardous substances and 10,000 pounds for all other hazardous chemicals.
SARA TITLE III: Sec. 313, Toxic Chemicals Notification, 40 CFR 372: This product may be subject to SARA notification
requirements, since it contains Toxic Chemical constituents above their de minimus concentrations. This product contains:
Nickel; Copper; potassium hydroxide.
US State Right to Know Laws:
California Proposition 65: This product contains a chemical known to the State of California to cause cancer and/or reproductive
harm. This product contains: Nickel; Tetrafluoroethylene. This product may contain trace levels of the following ingredients:
Di(2-ethylhexyl)phthalate; Vinyl chloride monomer; Isoprene; Asbestos.
Other U.S. State "Right to Know" Lists: The following chemicals are specifically listed by individual States: Iron (CA); Nickel (MA,
MN, NJ, PA, RI); potassium hydroxide (CA, MA, MN, NJ, PA, RI); Tetrafluoroethylene (MA, NJ, PA, RI); carbon (RI);
Polyvinylchloride (NJ); Copper (CA, MA, MN, NJ).
International Information:
Canadian Environmental Protection Act (CEPA) information: All ingredients appear on the Domestic Substances List (DSL)
(information provided by the Manufacturer, "ELIT").
WHMIS classification: This product is not a WHMIS controlled product in Canada. This product is considered to be a
'manufactured article'.
This product has been classified according to the hazard criteria of the CPR and the MSDS contains all of the
information required by the CPR.
SECTION 16 - OTHER INFORMATION
- Chronic hazard 0 - Minimal 1 - Slight 2 - Moderate 3 - Serious 4 - Severe
*
HMIS Rating :
Health: 1 Flammability: 1 Reactivity: 0
: ACGIH: American Conference of Governmental Industrial Hygienists
Legend
CA: California
CAS: Chemical Abstract Services
CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act of
1980
CFR: Code of Federal Regulations
DOT: Department of Transportation
EPA: Environmental Protection Agency
EST: Eastern Standard Time
HMIS: Hazardous Materials Identification System
HSDB: Hazardous Substances Data Bank
IARC: International Agency for Research on Cancer
IATA: International Air Transport Association
ICAO: International Civil Aviation Organisation
IMDG: International Maritime Dangerous Goods
Inh: Inhalation
MA: Massachusetts
MN: Minnesota
N/Ap: not applicable
N/Av: not available
NFPA: National Fire Protection Association
NIOSH: National Institute of Occupational Safety and Health
NJ: New Jersey
NTP: National Toxicology Program
OSHA: Occupational Safety and Health Administration
PA: Pennsylvania
PEL: Permissible exposure limit
RCRA: Resource Conservation and Recovery Act
RI: Rhode Island
RTECS: Registry of Toxic Effects of Chemical Substances
SARA: Superfund Amendments & Reauthorization Act
STEL: Short Term Exposure Limit
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MSDS Preparation Date (dd/mm/yyyy): 14/12/2007
TDG: Canadian Transportation of Dangerous Goods Act & Regulations
TLV: Threshold Limit Values
TSCA: Toxic Substance Control Act
TWA: Time Weighted Average
WHMIS: Workplace Hazardous Materials Identification System
: 1. ACGIH, Threshold Limit Values and Biological Exposure Indices for 2007.
References
2. International Agency for Research on Cancer Monographs, searched 2007.
3. Canadian Centre for Occupational Health and Safety, CCInfoWeb databases, 2007
(Chempendium, HSDB and RTECs).
4. US EPA Title III List of Lists - January 27, 2005 version.
5. California Proposition 65 List - September 28, 2007 version.
Prepared for:
Cantec Systems Ltd.
1573 Laperriere Avenue
Ottawa, Ontario, Canada, K1Z 7T3
Telephone: 613-725-3704
Direct all enquiries to: Cantec.
Prepared by:
ICC The Compliance Center Inc.
Canada: 1-888-977-4834
USA: 1-888-442-9628
http://www.thecompliancecenter.com
DISCLAIMER OF LIABILITY
The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its
publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other materials or in any process,
unless specified in the text.
MSDS Preparation Date (dd/mm/yyyy)
: 14/12/2007
END OF DOCUMENT
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