MATERIAL SAFETY DATA SHEET
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ELASTUFF 101 Aromatic Basecoat
3/4/2008
PRODUCT NAME: ELASTUFF 101 Aromatic Basecoat
PRODUCT CODE: EF-101-BC
~~~~ SECTION 1 ~~~~ MANUFACTURER IDENTIFICATION ~~~~
Manufacturer's Name : UNITED COATINGS MANUFACTURING CO
Address : 19011 EAST CATALDO AVE.
: SPOKANE VALLEY, WASHINGTON 99016-9423
: INITIAL(FIRST CALL)CHEMTREC(800)424-9300
INFORMATION PHONE : (509)926-7143
TOLL FREE : BACKUP(800)541-4383
DATE PRINTED : 3/4/2008
DATE REVISED : March 2008
~~~~ SECTION 2 ~~~~ HAZARDOUS INGREDIENTS/SARA III INFORMATION ~~~~
Reportable Components CAS Number MM HG @ Temp Weight %
Aluminum trihydroxide 21645-51-2 N/A N/A 26
OSHA, PEL 15mg/m3 total dust, 5mg/m3 respirable dust.
ACGIH, TLV 10mg/m3 total dust
~
* Xylol (Xylene mixture) 1330-20-7 5.1 20C 17
Xylol contains:
* Xylene (mixed isomers) CAS# 1330-20-7
ACGIH TLV, TWA: 100ppm STEL: 150ppm,
OSHA PEL, TWA: 100ppm, STEL: 150ppm. (75%)
~
* Ethylbenzene, CAS#100-41-4, ACGIH TLV, TWA: 100ppm, STEL: 125ppm,
OSHA PEL, TWA: 100ppm, STEL: 125ppm. (25%).
~
* Toluene CAS#108-88-3, (0.6%) ACGIH TLV, TWA: 50ppm (SKIN),
OSHA PEL, TWA: 100ppm, STEL: 150ppm. (.3%-1.5%).
~
Polyether diol 25322-69-4 <1 77F/25C 17
OSHA PEL: N/E, ACGIH TLV: N/E, STEL: N/E
AIHA WEEL: 10mg/m3, TWA as aerosol
~
Chlorinated paraffin waxes 63449-39-8 N/A N/A 15
Good industrial practice suggests observing the ACGIH-OSHA TWA exposure
limit for oil mists of 5mg/m3.
~
* Polymeric Diphenylmethane diisocyanate (pMDI)25686-28-6<0.000177F/25C 11
Also contains:
4-4' Diphenylmethane diisocyanate (MDI) (CAS# 101-68-8) and
Diphenylmethane diisocyanate (MDI) Homopolymer (CAS# 25686-28-6)
Diphenylmethane Diisocyanate(MDI) Mixed Isomers (26447-40-5)
The following OEL's are for CAS# 101-68-8:
ACGIH TLV TWA: 0.005ppm, OSHA PEL, ceiling: 0.02ppm.
~
Titanium dioxide 13463-67-7 N/A N/A 3
Contains: Titanium dioxide, CAS#13463-67-7,
ACGIH TLV TWA: 10mg/m3, total dust, OSHA PEL TWA: 15mg/m3, total dust.
Aluminum hydroxide, CAS#21645-51-2, no exposure limits established.
Note: Titanium Dioxide has been classified in accordance with hazard
criteria of the Controlled Product Regulations and the MSDS contains all
the information required by the Controlled Products Regulations.
WHMIS: D2A-Very toxic material causing other toxic effects.
~
Tris(monochloropropyl)phosphate 13674-84-5 UKN UKN 3
No exposure guidelines have been established
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ELASTUFF 101 Aromatic Basecoat
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~
#* Decabromodiphenyloxide (DBDPO)1163-19-5 N/A N/A 2.1
Exposure limits not established by ACGIH or OSHA.
AIHA WEEL (workplace environmental exposure level) 5 mg/m3 8 hour TWA.
~
Silicon Dioxide (Synthetic) 67762-90-7 N/A N/A 1
Silicon Dioxide (Synthetic) CAS#67762-90-7,
No OEL's for this specific ingredient, OEL's for Silica CAS# 7631-86-9:
OSHA PEL: 6mg/m3, ACGIH TLV: 10mg/m3
~
*# Antimony oxide 1309-64-4 N/A N/A 1.1
Antimony Oxide Contains the following:
Antimony Oxide, CAS#1309-64-4
Antimony Oxide is a IARC Group IIB listed CARCINOGEN
ACGIH: 0.5 mg/m3 TWA OSHA PEL: 0.5 mg/m3
Arsenic, (<0.10%) CAS#7440-38-2
ACGIH: 0.01mg/m3 TWA , OSHA PEL: 0.01mg/m3
Lead CAS#7439-92-1, (<0.10%) ACGIH/TWA: 0.05mg/m3 OSHA PEL: 0.05mg/m3
~
* Indicates toxic chemical(s) subject to the reporting
requirements of section 313 of Title III and of 40 CFR 372.
# Indicates carcinogenic chemical.
NOTE: If tinted may contain Carbon Black CAS#1333-86-4 AND/OR
Crystalline Silica CAS#14808-60-7. If tinted DARK GRAY or BLACK
consider these levels to be reportable.
This MSDS may be used for other colors and container sizes
of this product.
~~~~ SECTION 3 ~~~~ HAZARDS IDENTIFICATION ~~~~
Potential Health Effects
Eyes:
MAY CAUSE MODERATE IRRITATION. VAPORS WILL IRRITATE EYES.
Skin:
May cause allergic reactions. Sensitization may develop
after repeated and/or prolonged contact with human skin.
Ingestion:
ASPIRATION OF MATERIAL INTO THE LUNGS CAN CAUSE CHEMICAL
PNEUMONITIS, WHICH CAN BE FATAL. INGESTION CAN RESULT IN IRRITATION
OR CHEMICAL BURNS OF THE MOUTH, PHARYNX, ESOPHAGUS AND
STOMACH/DIGESTIVE TRACT. INJURY MAY BE SEVERE AND CAUSE DEATH. KEEP
PERSON WARM AND QUIET.
Inhalation:
Repeated or prolonged exposure to vapors or mists are
irritating to the respiratory tract. Inhalation of vapors and mists
of isocyante at concentrations above recommended exposure limits can
irritate the mucous membranes in the respiratory tract (nose, throat,
lungs) causing runny nose,sore throat, coughing, chest discomfort,
shortness of breath and reduced lung function. Persons with a
preexisting,nonspecific bronchial hyperreactivity can respond to
concentrations below the intended recommended exposure level with
similar symptoms as well as an asthma attack. Exposure to higher
levels may lead to bronchitis, bronchial spasm and pulmonary edema
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(fluid in the lungs). These effects are usually reversible.Chemical
or hypersensitive pneumonitis,with flu-like symptoms (e.g., fever,
chills) has also been reported.
~~~~ SECTION 4 ~~~~ FIRST AID MEASURES ~~~~
Eyes:
For eye exposure, irrigate the exposed eyes with copious
amounts of tepid water for at least 15 minutes. If the victim is
wearing contact lenses, they should be removed, provided such removal
does not cause further damage to the eyes. Consult a physician or
ophthalmologist immediately.
Skin:
Remove product and immediately flush affected area with
water for at least 15 minutes. Cover the affected area with a sterile
dressing or clean sheeting and consult a physician immediately,
except for the most minor, superficial and localized burns. Do not
apply greases or ointments. Control shock if present. Discard or
launder contaminated clothing before reuse. Contaminated leatherwear
should be discarded.
Ingestion:
Do not induce vomiting. Give 1 to 2 cups milk or water. If
vomiting occurs, keep victim's head below the hips to prevent
breathing vomit into the lungs. Consult a physician immediately.
Inhalation:
Move to fresh air; administer oxygen by a qualified
individual or artificial respiration as needed. Consult a physician
immediately. Asthmatic-type symptoms may develop and may be
immediate or delayed several hours. Treatment is essentially
symptomatic.
Note to Physician:
Eyes - Stain for evidence of corneal injury. If cornea is
burned, instill antibiotic/steroid preparation frequently. Workplace
vapors could produce reversible corneal epithelial edema impairing
vision.
Skin- this compound is a potent skin sensitizer. Treat
symptomatically as for contact dermatitis or thermal burn.
Ingestion - Treat symptomatically. There is no specific antidote.
Inducing vomiting is contraindicated because of the irritating nature
of the compound.
Inhalation- treatment is essentially symptomatic. An individual
having a dermal or pulmonary sensitization reaction to this material
should be removed from any exposure to Issocyanate. Throughout a
symptomatic victim's treatment course, monitor the ECG, chest x-ray,
pulse oximetry, peak airflows, arterial blood gases, serum
electrolytes, and renal and hepatic function
~~~~ SECTION 5 ~~~~ FIRE FIGHTING MEASURES ~~~~
Flammable Properties
Flash Point: 26.7C
Lower Flammable Limits: 1
Upper Flammable Limit: 7
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Auto Ignition Temperature: Not available
Extinguishing Media:
Foam, CO2, dry chemical, water fog
Special Fire Fighting Procedures:
Isolate fire area and deny unnecessary entry. Move container
from fire area if this is possible without hazard. Stay upwind. Keep
out of low areas where gases (fumes) can accumulate.
Personnel engaged in fighting Issocyanate fires must be protected
against nitrogen dioxide fumes as well as Issocyanate vapors.
Firefighters must wear self-contained breathing apparatus and turnout
gear.
~~~~ SECTION 6 ~~~~ ACCIDENTAL RELEASE MEASURES ~~~~
Small Spill:
Clean up personnel must be equipped with self contained
breathing apparatus and butyl rubber protective clothing. Evacuate
area of all non-essential personnel. Extinguish all nearby sources of
ignition and ventilate area using explosion proof mechanical exhaust
ventilation as vapors are heavier than air and are combustible or
flammable and may migrate to a source of ignition.
Clear the area of unnecessary personnel. Insure a trained response
team is in emergency protective equipment. Prevent further spillage
and contain the spill using dikes made of sand, earth or spill
pillows. Cover the spill area with a non-combustable absorbant
material (e.g., absorbant clay, earth, sand) to absorb as much liquid
as possible. Shovel the absorbant into open top containers. Do not
fill to the top or cover the containers. Prepare a decontaminating
solution as follows:
Option 1: consists of a solution 90% water, 8% concentrated ammonia
solution and 2% liquid detergent.
Option 2: consists of a solution 90-95% water, 5-10% sodium carbonate
and 0.2-0.5% liquid detergent.
Pour the liquid decontaminant liberally over the remaining spill area
and spread with a broom or squeegee to insure contact. Let stand 10-
15 minutes @25c(77f), longer at lower temperatures. Then wash down
the area with plenty of water. In a well ventilated area, add enough
liquid decontaminent solution to the containers with the absorbed
spill material to obtain an approximate 10:1 ratio of decontaminate
solution to spill material. Mix the liquid-absorbant slurry and let
stand for 12-24 hours. Stir periodically, or the liquid-absorbant
slurry may solidify. Leave the lids on loosely. After decontamination
solution has been in contact with the spilled material for 24-48
hours, and the evolved carbon dioxide has vented away, tighten down
the lids and dispose of the mixture in accordance with local, state
and federal regulations. Test the area for residual isocyanate vapors
before allowing workers to re-enter the area. When safe working
conditions have been re-established, remove and decontaminate all
equipment used.
Large Spill:
Clear the area of all non-essential personnel. Stay up-wind
to avoid breathing vapor. If inside a building, or near HVAC
equipment, shut down the HVAC system and ventilate the area as vapors
are harmful and flammable or combustible and may migrate to a source
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of ignition.(if mechanical ventilation equipment is to be used to
ventilate the area, use only explosion proof equipment). Prevent
access to area.
If transportation spill involved call Chemtrec, (800) 424-9300.if
temporary control of isocyanate vapor is required, a blanket of
protein foam (available at most fire departments) may be placed over
the spill. Large quantities may be pumped into closed but not sealed
containers for disposal. Dike spill to prevent entry into sewers,
storm drains, surface waters or soil.
Notify the appropriate state, local and federal authorities as well
as the material supplier. Insure a trained response team is in
appropriate emergency equipment. Prevent further spillage. Contain
the spill using sand bags; spill pillows, dirt dikes, etc. It is
important that this material not be allowed to enter drains. The
reaction with water can be violent and forms an insoluble material,
which may cause blockage. If this material does enter drains, flush
with ample quantities of water and notify the sewer authority
immediately.
For further information see Small Spill.
Solidified spillage:
Where spills have solidified, sandblasting is the preferred removal
method, particularly for road spills. Wear special protective
clothing for sandblasting, along with self-contained breathing
equipment. Contaminated sand must be collected for decontamination
and disposal.
~~~~ SECTION 7 ~~~~ HANDLING AND STORAGE ~~~~
Handling & Storage:
Store in a cool, dry, well ventilated area in tightly closed
containers to prevent moisture contamination. Unused product
remaining in opened containers must be purged with dry nitrogen
before resealing to prevent CO2 pressure build-up due to moisture
contamination. If moisture or water contamination is suspected, do
not reseal. Open sealed drums slowly to release any pressure due to
possible CO2 pressure build-up.
Other Precautions:
DO NOT PUNCTURE, CUT, GRIND, WELD, BRAZE, SOLDER OR DRILL ON
OR NEAR THIS CONTAINER OR OTHERWISE EXPOSE SUCH CONTAINER TO HEAT,
FLAME, SPARKS, STATIC ELECTRICAL CHARGES, ELECTRICITY OR OTHER
SOURCES OF IGNITION. THEY MAY EXPLODE AND/OR EMIT TOXIC VAPORS
RESULTING IN INJURY OR DEATH. CLOSED CONTAINERS MAY EXPLODE DUE TO
PRESSURE BUILD-UP IF EXPOSED TO WATER OR MOISTURE OR EXTREME HEAT.
CONTAINERS, EVEN THOSE THAT HAVE BEEN EMPTIED, WILL RETAIN PRODUCT
RESIDUE AND VAPORS. ALWAYS OBEY HAZARD WARNINGS AND HANDLE EMPTY
CONTAINERS AS IF THEY WERE FULL. DO NOT GET IN EYES, ON SKIN OR ON
CLOTHING. AVOID PROLONGED OR REPEATED BREATHING OF VAPOR OR SPRAY
MIST. USE ONLY IN A WELL VENTILATED AREA. KEEP OUT OF THE REACH OF
CHILDREN.
~~~~ SECTION 8 ~~~~ EXPOSURE CONTROLS/PERSONAL PROTECTION ~~~~
MATERIAL SAFETY DATA SHEET
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Engineering Controls:
In outside spray, mixing and rolling applications situate
workers upwind of operation & provide airflow in a downwind direction
so as to carry fumes and residual spray away from workers.
In confined spaces, mechanical exhaust ventilation, with volume and
pattern capable of maintaining a fresh air supply or airline
respirator, may be necessary. Refer to OSHA standard 29 CFR 1910.94
and/or ACGIH industrial ventilation for guidance about adequate
ventilation. Turn off heating and/or air conditioning equipment to
prevent contaminating building. When possible spray when building or
structure is unoccupied.
Respiratory Protection:
The hazards of both part A and part B will be exhibited when
combined.
Good industrial hygiene practice dictates that when Isocyanate-based
coatings are mixed/sprayed and applied, some Type of respiratory
protection should be worn.
A properly fitted air-purifying (combination organic vapor and
particulate) respirator, proven by test to be effective in isocyanate
containing spray/vapors during coating operations, and used in
accordance with the recommendations of the manufacturer, can be used
when the following conditions are met:
-concentration of vapors is unknown.
-or concentrations exceed those in section II.
-or the airborne Isocyanate (polymeric, oligomeric) concentration
exceeds 5mg/m3 Averaged Over 8 Hours) OR 10mg/m3 average over 15
Minutes
-or operations are being performed in confined space.
-and a NIOSH certified end of service life indicator or a change
schedule based upon objective information or data is used to ensure
that cartridges are replaced before the end of their service life.
In addition, pre-filters should be changed whenever breathing
resistance increases due to particulate buildup.
if a NIOSH certified end of service life indicator or a change
schedule based upon objective information or data cannot be met, then
a supplied air respirator must be used.
Monitoring: Refer To Patty's Industrial Hygiene And Toxicology-Volume
1(3rd Edition) Chapter 17 Volume III (First Edition) Chapter 3, for
guidance concerning appropriate air sampling strategy to determine
airborne concentrations of Isocyanate.
Medical surveillance: Supervision of all employees who handle or come
in contact with this product is recommended. This should include pre-
employment and periodical medical examinations with respiratory
function test (fev, fvc as a minimum). Persons with asthma-type
conditions, chronic bronchitis, other chronic respiratory diseases or
recurrent skin eczema or sensitization should be excluded from
working with Isocyanate. Once a person is diagnosed as sensitized to
Isocyanate, no further exposure can be permitted
Additional protective measures safety showers and eyewash stations
should be readily available to work area. Educate and train employees
in safe use of product. Follow all MSDS and label instructions.
MATERIAL SAFETY DATA SHEET
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Skin Protection:
The use of gloves impermeable to the specific material
handled is advised to prevent skin contact and possible irritation.
Note that PVA degrades in water.
Eye Protection:
Isolate the area immediately; prevent unauthorized entry.
~~~~ SECTION 9 ~~~~ PHYSICAL AND CHEMICAL PROPERTIES ~~~~
Boiling Range: 138.9C - 2597F@760Hg
Melting Point: N/A
Specific Gravity(H2O=1): 1.351
Vapor Density(Air=1): Heavier than air
Vapor Pressure: NO DATA
Evaporation Rate(N-Butyl Acetate=1) : Unknown
Coating V.O.C.: 2.01 lb/gl Coating V.O.C.: 241 g/l
Material V.O.C.: 2.01 lb/gl Material V.O.C.: 241 g/l
Solubility in Water: Insoluble-reacts.
Appearance: Moderately viscous pigmented liquid, various
colors.
Odor: Aromatic odor.
pH: N/A
~~~~ SECTION 10 ~~~~ STABILITY & REACTIVITY DATA ~~~~
Stability:
Stable
Conditions To Avoid:
AVOID HEAT, SPARKS, OPEN FLAME AND OTHER IGNITION SOURCES,
EXTREME HEAT CONDITIONS AND WATER CONTACT. REACTION WITH WATER CAN
RESULT IN PRESSURE BUILDUP OF THE CONTAINER RESULTING IN RUPTURE OF
THE CONTAINER.
Incompatible Materials:
Avoid water, alcohol, ammonia, amines, alkalies and acids.
Some reactions can be violent.
Hazardous Decomposition Products
Products of combustion include isocyanate vapor & mist,
carbon monoxide, carbon dioxide, hydrogen cyanide, nitrogen oxides
and sulfur oxides and unidentified products in fumes and smoke.
Hazardous Polymerization:
May occur. Contact with moisture or other materials, which
react with isocyanates, may cause polymerization.
~~~~ SECTION 11 ~~~~ TOXICOLOGICAL INFORMATION ~~~~
*Data is for individual components of preparation.
Materials having a known chronic/acute effects on eyes:
Eye irritation-irritating
Materials having a known dermal toxicity.
SKIN IRRITATION- IRRITATING
Materials having a known oral toxicity.
Rat, oral LD50-10,000 mg/kg.
Materials having a known Inhalation hazard:
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Rat, 4hr inhalation LC50-aerosol 490mg/m3
Highly toxic
Rat, 4hr inhalation LC50-vapor 11mg/L.
Identified Acute/ Short-term Effects:
EYE IRRITATION AND TEARING. SKIN IRRITATION AND POSSIBLY
SENSITIZATION. IRRITANT TO RESPIRATORY PASSAGES. IF SWALLOWED,
IRRITATION OR CHEMICL BURNS TO MOUTH, PHARYNX, ESOPHAGUS AND STOMACH
CAN DEVELOP. INJURY MAY BE SEVERE AND CAUSE DEATH.
Identified Carcinogens/Longterm Effects:
RESULTS FROM A LIFETIME INHALATION STUDY IN RATS INDICATE
THAT MDI AEROSOL WAS CARCINOGENIC AT 6MG/M3, THE HIGHEST DOSE TESTED.
THIS IS WELL ABOVE THE RECOMMENDED TLV OF 5PPB (0.05 MG/M3). ONLY
IRRITATION WAS NOTED AT THE LOWER CONCENTRATION OF 0.2 AND 1 MG/M3.
AS A RESULT OF PREVIOUS REPEATED OVER EXPOSURES OR A SINGLE LARGE
DOSE, CERTAIN INIDIVIDUALS WILL DEVELOP ISOCYANATE SENSITIZATION
(CHEMICAL ASTHMA) WHICH WILL CAUSE THEM TO REACT TO A LATER EXPOSURE
TO ISOCYANATE AT LEVELS WELL BELOW THE PEL/TLV. THESE SYMPTOMS,
WHICH INCLUDE CHEST TIGHTNESS, WHEEZING, COUGH, SHORTNESS OF BREATH,
OR ASTHMATIC ATTACK, COULD BE IMMEDIATE OR DELATED UP TO SEVERAL
HOURS AFTER EXPOSURE. SIMILAR TO MANY NON-SPECIFIC ASTHMATIC
RESPONSES, THERE ARE REPORTS THAT ONCE SENSITIZED AN INDIVIDUAL CAN
EXPERIENCE THESE SYMTOMS UPON EXPOSURE TO DUST, COLD AIR, OR OTHER
IRRITANTS. THIS INCREASED LUNG SENSITIVITY CAN PERSIST FOR WEEKS AND
IN SEVERE CASES FOR SEVERAL YEARS. CHRONIC OVEREXPOSURE TO
ISOCYANATES HAS ALSO BEEN REPORTED TO CAUSE LUNG DAMAGE, INCLUDING A
DECREASE IN LUNG FUNCTION, WHICH MAY BE PERMANENT. SENSITIZATION MAY
BE EITHER TEMPORARY OR PERMANENT. PROLONGED CONTACT CAN CAUSE
REDDENING, SWELLING, RASH, SCALING, OR BLISTERING. IN THOSE WHO HAVE
DEVELOPED A SKIN SENSITIZATION, THESE SYMPTOMS CAN DEVELOP AS A
RESULT OF CONTACT WITH VERY SMALL AMOUNTS OF LIQUID MATERIAL, OR EVEN
AS A RESULT OF VAPOR-ONLY EXPOSURE.
PROLONGED OR REPEATED EXPOSURE TO HIGH CONCENTRATIONS OF XYLENE MAY
CAUSE NEURAL DYSFUNCTION. LABORATORY ANIMALS EXPOSED TO HIGH DOSES
OF XYLENE SHOWED EVIDENCE OF EFFECTS IN THE LIVER, KIDNEYS, LUNGS,
SPLEEN, HEART AND ADRENALS. RATS EXPOSED DURING PREGNANCY SHOWED
EMBRYO/FETOTOXIC EFFECTS. XYLENE HAS ALSO BEEN SUGGESTED TO CAUSE
HEARING LOSS.
Identified Teratogens:
Xylene has been shown to cause birth defects in laboratory
animal studies. The relevance of these findings to humans is
uncertain.
Identified Reproductive toxins :
NO DATA.
Identified Mutagens:
NO DATA.
~~~~ SECTION 12 ~~~~ ECOLOGICAL INFORMATION ~~~~
Ecotoxicological effects on plants and animals:
DAPHNIA MAGNA, 24 HR LC50->5000 MG/L.
PRACTICALLY NONTOXIC
ZEBRA FISH, STATIC 24 HR LC50->500 MG/L.
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PRACTICALLY NONTOXIC
TOXICITY TO BACTERIA->100MG/L
PRACTICALLY NONTOXIC.
Chemical Fate :
In outside spray, mixing and rolling applications situate
workers upwind of operation & provide airflow in a downwind direction
so as to carry fumes and residual spray away from workers.
Local exhaust ventilation recommended if generating vapor, dust or
mist. Turn off heating and/or air conditioning equipment to prevent
contaminating building.
If exhaust ventilation is not adequate, use MSHA or NIOSH approved
respirator. Refer to OSHA standard 29 CFR 1910.94 for guidelines.
~~~~ SECTION 13 ~~~~ DISPOSAL CONSIDERATIONS ~~~~
Instructions:
Dispose of unused product or contaminated product and
materials used in cleaning up spills or leaks in a manner approved
for this material. Consult appropriate federal, state and local
regulatory agencies to ascertain proper disposal procedures.
Incineration is acceptable and the preferred method of disposal,
however; nitrogen oxide emissions controls may be required to meet
specifications. Chemical and biological degradation is possible.
~~~~ SECTION 14 ~~~~ TRANSPORT INFORMATION ~~~~
Shipping Information:
U.S. DOT TRANSPORT INFORMATION 49 CFR 172.101
PROPER SHIPPING NAME: PAINT
DOT DESCRIPTION:UN 1263 Class: 3 Packing Group III
~~~~ SECTION 15 ~~~~ REGULATORY INFORMATION ~~~~
(Not meant to be all inclusive-selected regulations represented)
US Regulations:
Status Of Substances Lists:
The Concentrations Shown In Section II Are Maximum Ceiling Levels
(Weight %) to be used for calculations for regulations.
A reportable quantity is a quantity of a hazardous substance that
triggers reporting requirements under the Comprehensive Environmental
Response Compensation And Liability Act (CERCLA).
If a spill of a substance exceeds it's reportable quantity (RQ) in
CFR 302.3,Table 40 302.4 Appendix A & 302.4 Appendix B,
the release must be reported to The National Response Center
At (800) 424-8802, The State Emergency Response Commission
(SERC), And community emergency coordinators likely to be affected.
Components present that could require reporting under the statute are:
Xylene CAS# 1330-20-1 RQ: 100 lbs
Ethylbenzene CAS# 100-41-4 RQ: 1,000 lbs
SEE SECTION II FOR PERCENTAGES
*TOXIC: NOT REPORTABLE IN QUANTITIES LESS THAN 1%
#CARCINOGEN: NOT REPORTABLE IN QUANTITIES LESS THAN .1%
ANTIMONY OXIDE CAS#1309-64-4 RQ 5000 #
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Superfund Amendments And Reauthorization Act Of 1986 (SARA) Title III
Requires emergency planning based on the Threshold Quantities(TPQ'S)and
release reporting based on Reportable Quantities (RQ'S) In 40 CFR 355
Appendix A&B Extremely Hazardous Substances. The emergency planning and
release requirements of 40 CFR 355 apply to any facility at which there is
present any amount of any extremely hazardous substance(EHS)
equal to or in excess of it's Threshold Planning Quantity(TPQ).
Components present that could require reporting under the statute are:
Xylene CAS#1330-20-7
De minimis Concentration (%): 1.0
Reporting Threshold: Standard
Ethylbenzene CAS# 100-41-4
De minimis Concentration: 1.0%
Reporting Threshold: Standard
EPCRA 40 CFR 372(Section 313) Requires EPA and the States to
annually collect data on releases of certain toxic materials from
industrial facilities, and make the data available to the public in the
Toxics Release Inventory(TRI). This information must be included in all
MSDS'S that are copied and distributed or compiled for this material.
Reporting Threshold: Standard: A facility must report if it manufactures
(including imports) or processes 25,000 pounds or more or otherwise uses
10,000 pounds or more of a listed toxic chemical during the calendar year.
Components present that could require reporting under the statute are:
See Section II
The components of this product are listed or excluded from listing on the
US Toxic Substance Control Act (TSCA) chemical substance inventory.
Mixtures shall be assumed to present the same health hazards as do the
components which comprise one percent (by weight or volume) or
greater of the mixture, except that the mixture shall be assumed to present a
carcinogenic hazard if it has a component in concentrations of 0.1 percent or
greater. The remaining percentage of unspecified ingredients, if any, are not
contained in above DeMinimis concentrations and/or are believed to
be non-hazardous under the OSHA Hazard Communication Standard
(29 CFR 1910.1200), and may consist of pigments, fillers, defoamers,
wetting agents, resins, dryers,anti-bacterial agents, water and/or solvents
in varying concentrations.
International Regulations:
Canadian WHMIS:
This Product Contains the following in recordable amounts:
Titanium Dioxide CAS#13463-67-7
WHMIS Classification: D2A
WHMIS Health Effects Criteria Met by this Chemical:
Very toxic material causing other toxic effects
Canadian Environmental Protection Act (CEPA):
NONE KNOWN
EINECS:
ALL OF THE COMPONENTS OF THIS PRODUCT ARE LISTED IN THE
EINECS INVENTORY OR ARE EXEMPT FROM NOTIFICATION REQUIREMENTS. (THE
EINECS NUMBER FOR QUARTZ: 231-545-4).
MATERIAL SAFETY DATA SHEET
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State Regulations:
California:
California Proposition 65: The following Statement is made in order
to comply with The California Safe Drinking Water and Toxic
Enforcement Act of 1986
"WARNING:This product contains the chemical(s) appearing below known to the
State of California to:
A: Cause Cancer
Ethylbenzene CAS# 100-41-4 Proposition 65 Code:C
ANTIMONY OXIDE CAS#1309-64-4
*If tinted contains Carbon Black:CAS#1333-86-4 and may also contain trace
amounts of Crystalline Silica:CAS#14808-60-7
B: Cause Birth Defects or other Reproductive Harm :
Toluene CAS#108-88-3 this substance is listed as having
developmental toxicity.
In addition to the above named chemical(s)(if any),this product may contain
trace amounts of chemicals, known to the State of California, to cause
Cancer or Birth Defects and other Reproductive Harm
Delaware:
Toluene CAS# 108-88-3 DRQ: 1,000.
Xylene CAS#1330-20-7 DRQ 100
Ethylbenzene CAS# 100-41-4 DRQ: 1,000.
Listed on the Delaware Air Quality Management List:
DECABROMODIPHENYLOXIDE CAS#1163-19-5 DRQ 100#
Listed on the Delaware Air Quality Management List:
ANTIMONY OXIDE CAS#1309-64-4 DRQ 1000#
Florida:
TOLUENE CAS#108-88-3 LISTED AS TOXIC
XYLENE CAS # 1330-20-1 LISTED AS TOXIC
ETHYLBENZENE CAS#100-41-4 LISTED AS TOXIC
Listed as Toxic:
Antimony Oxide CAS#1309-64-4
Idaho:
Toluene CAS# 108-88-3
Idaho Air Pollutant List:
Title 585--AAC: 18.75 Title 586--AAAC: --
Title 585--EL: 25 Title 586--EL: --
Title 585--OEL: 375 TItle 586--OEF: --
Xylene (Mixed Isomers) CAS# 1330-20-7
Idaho Air Pollutant List:
Title 585--AAC: -- Title 586--AAAC: --
Title 585--EL: -- Title 586--EL: --
Title 585--OEL: -- TItle 586--OEF: --
Ethyl Benzene CAS# 100-41-4
Idaho Air Pollutant List:
Title 585--AAC: 21.75 Title 586--AAAC: --
Title 585--EL: 29 Title 586--EL: --
Title 585--OEL: 435 TItle 586--OEF: --
Massachusetts:
Toluene CAS#108-88-3 Substance Codes:2,4,5,6,F7,F8,F9
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Xylene CAS #1330-20-7 Substance Codes:2,4,F8,F9
Ethylbenzene CAS#100-41-4 Substance Codes:2,4,5,6,F7,F8,F9
Titanium Dioxide CAS#13463-67-7 SUBSTANCE CODES:4
DECABROMODIPHENYLOXIDE CAS#1163-19-5 SUBSTANCE CODES:F9
ANTIMONY OXIDE CAS#1309-64-4 SUBSTANCE CODES:2,4,F8,F9
Michigan:
Toluene CAS#108-88-3 Report: -- Class: --
Michigan Critical Material:
Xylene (mixed isomers) CAS# 1330-20-7
Note: -- CMR#: 44 Parameter #: 01330-20-7 AUP: 100
Minnesota:
Toluene CAS# 108-88-3 Codes: ANO Ratings: 8.64 Status:
Air Pollutant Title III, TRI, Water Pollutant
Xylene CAS#1330-20-7
Codes: ANO
Ratings: 8.77
Status: Air pollutant Title III, TRI
Ethylbenzene CAS# 100-41-4
Codes: AO
Ratings: 8.95
Status: Air Pollutant Title III, TRI, Water Pollutant.
Titanium Dioxide CAS#13463-67-7
Listed In The Minnesota Hazardous Substances List:
Codes: A
Hazards: --
Carcinogen? NO
DECABROMODIPHENYLOXIDE CAS#1163-19-5
LISTED IN THE MINNESOTA HAZARDOUS SUBSTANCES LIST:
CODES: I
HAZARDS: --
CARNINOGEN? NO
ANTIMONY OXIDE CAS#1309-64-4
LISTED IN THE MINNESOTA HAZARDOUS SUBSTANCES LIST:
CODES: A
HAZARDS: --
CARNINOGEN? YES
New Jersey:
MATERIAL SAFETY DATA SHEET
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Toluene CAS#108-88-3 DOT#: 1294 Substance#: 1866, TPQ:--
Xylene CAS#1330-20-1
DOT#: 1307
Substance#: 2014
TPQ --
EHS:
Ethylbenzene CAS#100-41-4 DOT#: 1175, Substance#: 0851 TPQ: --
NEW JERSEY RTK HAZARDOUS SUBSTANCE
DECABROMODIPHENYLOXIDE CAS#1163-19-5
DOT# -- SUBSTANCE # 0598 TPQ <500lbs
New York:
Toluene CAS#108-88-3 RQ (air): 1000, RQ (land/water): 1
Xylene CAS# 1330-20-1
RQ air: 1000
RQ land/water: 1
Ethylbenzene CAS#100-41-4 RQ (air): 1000, RQ (land/water): 1
ANTIMONY OXIDE CAS#1309-64-4 RQ--AIR 1000, RQ--LAND 100
Pennsylvania:
Toluene CAS#108-88-3 CODE:E
Xylene CAS#1330-20-1 CODE:E
Ethylbenzene CAS#100-41-4 CODE:E
Titanium Dioxide CAS#13463-67-7 CODE:--
DECABROMODIPHENYLOXIDE CAS#1163-19-5 CODE:E
ANTIMONY OXIDE CAS#1309-64-4 CODE:E
Washington:
Toluene CAS#108-88-3
Washington air contaminant: ppm mg/m3
TWA 100 375
STEL 150 560
Ceiling --- ---
Skin: --
Xylene CAS# 1330-20-1
Washington Air Contaminant: ppm mg/m3
TWA 100 435
STEL 150 655
Ceiling --- ---
Skin: ---
Ethylbenzene CAS#100-41-4
MATERIAL SAFETY DATA SHEET
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Washington air contaminant: ppm mg/m3
TWA 100 435
STEL 125 545
Ceiling --- ---
Skin: ---
Titanium Dioxide(Total Dust) CAS#13463-67-7
Washington Air Contaminant: ppm mg/Cubic Meter
TWA UNK 10
STEL UNK UNK
CEILING UNK UNK
SKIN:UNK
Wisconsin:
NONE KNOWN
West Virginia
The follwing is on the West Virginia Toxic Air Pollutant
List:
Titanium Dioxide CAS#13463-67-7 (Pounds per Year):
~~~~ SECTION 16 ~~~~ OTHER INFORMATION ~~~~
HMIS?III
Health : 3*
Flammability :3
Physical Hazard :1
*Following Health rating Indicates Chronic/Carcinogenic Effects
HMIS?III Personal Protection :K
This rating is for the product as it is packaged. This rating will need
to be adjusted by the user based on conditions of use.
The information contained herein is furnished without
warranty of any kind. Users should consider these data only as a
supplement to other information gathered by them & determine the
suitability & completeness of information from all sources to assure
proper use & disposal of these materials & the safety & health of
employees & customers
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