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MSDS Material Safety Data Sheet
CAS

7727-37-9 7782-44-7 108-90-7 56-23-5

File Name: 7727-37-9_7782-44-7_108-90-7_56-23.asp

                Material Safety Data Sheet
Nonflammable Gas Mixture: Carbon Tetrachloride / Chlorobenzene / Nitrogen /
Oxygen

Section 1. Chemical product and company identification
Product name : Nonflammable Gas Mixture: Carbon Tetrachloride / Chlorobenzene / Nitrogen /
Oxygen
Supplier : AIRGAS INC., on behalf of its subsidiaries
259 North Radnor-Chester Road
Suite 100
Radnor, PA 19087-5283
1-610-687-5253
Product use : Synthetic/Analytical chemistry.
MSDS # : 006477
Date of : 8/26/2009.
Preparation/Revision
In case of emergency : 1-866-734-3438

Section 2. Hazards identification
Physical state : Gas.
Emergency overview : WARNING!
CAUSES RESPIRATORY TRACT IRRITATION.
MAY BE HARMFUL IF SWALLOWED.
CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON
ANIMAL DATA.
SUSPECT CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE
CANCER.
CAUSES SEVERE SKIN IRRITATION.
CAUSES SEVERE EYE IRRITATION.
CONTENTS UNDER PRESSURE.
Do not puncture or incinerate container. Do not ingest. Avoid contact with eyes, skin
and clothing. Contains material that may cause target organ damage, based on animal
data. Risk of cancer depends on duration and level of exposure. Use only with
adequate ventilation. Wash thoroughly after handling. Keep container closed. Avoid
breathing gas.
Contact with rapidly expanding gases can cause frostbite.
Target organs : Contains material which may cause damage to the following organs: kidneys, lungs,
liver, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.
Routes of entry : Inhalation Dermal Eyes
Potential acute health effects
Eyes : Severely irritating to eyes. Risk of serious damage to eyes. Contact with rapidly
expanding gas may cause burns or frostbite.
Skin : Severely irritating to the skin. Contact with rapidly expanding gas may cause burns or
frostbite.
: Irritating to respiratory system.
Inhalation
: Ingestion is not a normal route of exposure for gases
Ingestion
Potential chronic health : CARCINOGENIC EFFECTS: Classified A3 (Proven for animals.) by ACGIH [Benzene,
effects chloro-]. Classified + (Proven.) by NIOSH [Methane, tetrachloro-]. Classified 2B
(Possible for humans.) by IARC, 3 (Possible for humans.) by European Union [Methane,
tetrachloro-]. Classified A2 (Suspected for humans.) by ACGIH, 2 (Reasonably
anticipated to be human carcinogens.) by NTP [Methane, tetrachloro-].
MUTAGENIC EFFECTS: Not available.
TERATOGENIC EFFECTS: Not available.




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Nonflammable Gas Mixture: Carbon Tetrachloride / Chlorobenzene / Nitrogen / Oxygen

Medical conditions : Pre-existing disorders involving any target organs mentioned in this MSDS as being at
risk may be aggravated by over-exposure to this product.
aggravated by over-
exposure
See toxicological information (section 11)

Section 3. Composition, Information on Ingredients
Name CAS number % Volume Exposure limits
Nitrogen 7727-37-9 74.5 - 80.5 Oxygen Depletion [Asphyxiant]
Oxygen 7782-44-7 19.5 - 23.5
Chlorobenzene 108-90-7 0.0001 - 1 ACGIH TLV (United States, 1/2009).
TWA: 46 mg/m?8 hour(s).
TWA: 10 ppm 8 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 350 mg/m?8 hour(s).
TWA: 75 ppm 8 hour(s).
OSHA PEL 1989 (United States, 3/1989).
TWA: 350 mg/m?8 hour(s).
TWA: 75 ppm 8 hour(s).
Carbon Tetrachloride 56-23-5 0.0001 - 1 ACGIH TLV (United States, 1/2009).
Absorbed through skin.
STEL: 63 mg/m?15 minute(s).
STEL: 10 ppm 15 minute(s).
TWA: 31 mg/m?8 hour(s).
TWA: 5 ppm 8 hour(s).
NIOSH REL (United States, 6/2008).
STEL: 12.6 mg/m?60 minute(s).
STEL: 2 ppm 60 minute(s).
OSHA PEL 1989 (United States, 3/1989).
TWA: 12.6 mg/m?8 hour(s).
TWA: 2 ppm 8 hour(s).
OSHA PEL Z2 (United States, 11/2006).
AMP: 200 ppm 5 minute(s).
CEIL: 25 ppm
TWA: 10 ppm 8 hour(s).

Section 4. First aid measures
No action shall be taken involving any personal risk or without suitable training.If it is suspected that fumes are still present,
the rescuer should wear an appropriate mask or self-contained breathing apparatus.It may be dangerous to the person
providing aid to give mouth-to-mouth resuscitation.
Eye contact : Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
Skin contact : In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
Frostbite : Try to warm up the frozen tissues and seek medical attention.
Inhalation : Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion : As this product is a gas, refer to the inhalation section.




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Nonflammable Gas Mixture: Carbon Tetrachloride / Chlorobenzene / Nitrogen / Oxygen


Section 5. Fire-fighting measures
Flammability of the product : Non-flammable.
Products of combustion : Decomposition products may include the following materials:
carbon dioxide
carbon monoxide
nitrogen oxides
halogenated compounds
carbonyl halides
Fire-fighting media and : Use an extinguishing agent suitable for the surrounding fire.
instructions
Apply water from a safe distance to cool container and protect surrounding area. If
involved in fire, shut off flow immediately if it can be done without risk.
Contains gas under pressure. In a fire or if heated, a pressure increase will occur and
the container may burst or explode.
Special protective : Fire-fighters should wear appropriate protective equipment and self-contained breathing
apparatus (SCBA) with a full face-piece operated in positive pressure mode.
equipment for fire-fighters

Section 6. Accidental release measures
Personal precautions : Immediately contact emergency personnel. Keep unnecessary personnel away. Use
suitable protective equipment (section 8). Shut off gas supply if this can be done safely.
Isolate area until gas has dispersed.
Environmental precautions : Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers.
Methods for cleaning up : Immediately contact emergency personnel. Stop leak if without risk. Note: see section 1
for emergency contact information and section 13 for waste disposal.

Section 7. Handling and storage
Handling : Use only with adequate ventilation. Wash thoroughly after handling. High pressure gas.
Do not puncture or incinerate container. Use equipment rated for cylinder pressure.
Close valve after each use and when empty. Do not ingest. Keep container closed. Avoid
contact with skin and clothing. Avoid contact with eyes. Protect cylinders from physical
damage; do not drag, roll, slide, or drop. Use a suitable hand truck for cylinder
movement.
Storage : Cylinders should be stored upright, with valve protection cap in place, and firmly secured
to prevent falling or being knocked over. Cylinder temperatures should not exceed 52 癈
(125 癋).

Section 8. Exposure controls/personal protection
Engineering controls : Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits.
Personal protection
Eyes : Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts.
Skin : Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Respiratory : Use a properly fitted, air-purifying or air-fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
The applicable standards are (US) 29 CFR 1910.134 and (Canada) Z94.4-93
Hands : Chemical-resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary.

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Nonflammable Gas Mixture: Carbon Tetrachloride / Chlorobenzene / Nitrogen / Oxygen

Personal protection in case : Self-contained breathing apparatus (SCBA) should be used to avoid inhalation of the
product. Full chemical-resistant suit and self-contained breathing apparatus should be
of a large spill
worn only by trained and authorized persons.
Product name
Nitrogen Oxygen Depletion [Asphyxiant]
Oxygen
Benzene, chloro- ACGIH TLV (United States, 1/2009).
TWA: 46 mg/m?8 hour(s).
TWA: 10 ppm 8 hour(s).
OSHA PEL (United States, 11/2006).
TWA: 350 mg/m?8 hour(s).
TWA: 75 ppm 8 hour(s).
OSHA PEL 1989 (United States, 3/1989).
TWA: 350 mg/m?8 hour(s).
TWA: 75 ppm 8 hour(s).
Methane, tetrachloro- ACGIH TLV (United States, 1/2009). Absorbed through skin.
STEL: 63 mg/m?15 minute(s).
STEL: 10 ppm 15 minute(s).
TWA: 31 mg/m?8 hour(s).
TWA: 5 ppm 8 hour(s).
NIOSH REL (United States, 6/2008).
STEL: 12.6 mg/m?60 minute(s).
STEL: 2 ppm 60 minute(s).
OSHA PEL 1989 (United States, 3/1989).
TWA: 12.6 mg/m?8 hour(s).
TWA: 2 ppm 8 hour(s).
OSHA PEL Z2 (United States, 11/2006).
AMP: 200 ppm 5 minute(s).
CEIL: 25 ppm
TWA: 10 ppm 8 hour(s).

Consult local authorities for acceptable exposure limits.

Section 9. Physical and chemical properties
Melting/freezing point : -210癈 (-346癋) This is based on data for the following ingredient: Nitrogen. Weighted
average: -211.94癈 (-349.5癋)
Critical temperature : Lowest known value: -146.9癈 (-232.4癋) (Nitrogen).
Vapor density : Highest known value: 1.105 (Air = 1) (Oxygen). Weighted average: 1 (Air = 1)
Gas Density (lb/ft 3) : Weighted average: 0.08

Section 10. Stability and reactivity
Stability and reactivity : The product is stable.
Incompatibility with various : Extremely reactive or incompatible with the following materials: oxidizing materials,
reducing materials and combustible materials.
substances
Highly reactive or incompatible with the following materials: alkalis.
Hazardous decomposition : Under normal conditions of storage and use, hazardous decomposition products should
not be produced.
products
Hazardous polymerization : Under normal conditions of storage and use, hazardous polymerization will not occur.

Section 11. Toxicological information
Toxicity data
Product/ingredient name Result Species Dose Exposure




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Nonflammable Gas Mixture: Carbon Tetrachloride / Chlorobenzene / Nitrogen / Oxygen

Benzene, chloro- LD Dermal Rabbit >2200 mg/kg -
LD50 Intraperitoneal Rat 1655 mg/kg -
LD50 Oral Rat 2290 mg/kg -
LD50 Oral Rat 1110 mg/kg -
LD50 Unreported Rat 2950 mg/kg -
LDLo Unreported Rat 4000 mg/kg -
TDLo Intraperitoneal Rat 1 mg/kg -
TDLo Intraperitoneal Rat 2 mg/kg -
TDLo Unreported Rat 0.026 mg/kg -
Methane, tetrachloro- LD Intraperitoneal Rat 0.1 mL/kg -
LD50 Dermal Rabbit >20 g/kg -
LD50 Dermal Rat 5070 mg/kg -
LD50 Intraperitoneal Rat 1500 uL/kg -
LD50 Oral Rat 2350 mg/kg -
LDLo Intraperitoneal Rat 3 mL/kg -
LDLo Intratracheal Rat 90 mg/kg -
TDLo Intraperitoneal Rat 3 mL/kg -
TDLo Intraperitoneal Rat 2 mL/kg -
TDLo Intraperitoneal Rat 1.5 mL/kg -
TDLo Intraperitoneal Rat 300 mg/kg -
TDLo Intraperitoneal Rat 120 mg/kg -
TDLo Intraperitoneal Rat 26 uL/kg -
TDLo Intraperitoneal Rat 0.25 mL/kg -
TDLo Intravenous Rat 3200 mg/kg -
TDLo Oral Rat 1600 mg/kg -
TDLo Oral Rat 0.8 mL/kg -
TDLo Oral Rat 1 g/kg -
TDLo Oral Rat 800 mg/kg -
TDLo Oral Rat 0.3 mL/kg -
TDLo Intraperitoneal Rat 0.2 mL/kg -
TDLo Oral Rat 1 mL/kg -
TDLo Oral Rat 300 mg/kg -
TDLo Oral Rat 0.25 mL/kg -
TDLo Intraperitoneal Rat 1 mL/kg -
TDLo Oral Rat 200 mg/kg -
TDLo Oral Rat 0.66 mg/kg -
TDLo Oral Rat 8 mg/kg -
TDLo Oral Rat 2.5 mg/kg -
TDLo Oral Rat 0.1 mL/kg -
TDLo Parenteral Rat 1 mL/kg -
TDLo Subcutaneous Rat 4000 mg/kg -
TDLo Unreported Rat 1 mL/kg -
LC50 Inhalation Rat 46000 mg/m3 6 hours
Vapor
LC50 Inhalation Rat 16000 ppm 1 hours
Gas.
LC50 Inhalation Rat 8000 ppm 4 hours
Gas.

Chronic effects on humans : CARCINOGENIC EFFECTS: Classified A3 (Proven for animals.) by ACGIH [Benzene,
chloro-]. Classified + (Proven.) by NIOSH [Methane, tetrachloro-]. Classified 2B
(Possible for humans.) by IARC, 3 (Possible for humans.) by European Union [Methane,
tetrachloro-]. Classified A2 (Suspected for humans.) by ACGIH, 2 (Reasonably
anticipated to be human carcinogens.) by NTP [Methane, tetrachloro-].
Contains material which may cause damage to the following organs: kidneys, lungs,
liver, upper respiratory tract, skin, central nervous system (CNS), eye, lens or cornea.

Other toxic effects on : No specific information is available in our database regarding the other toxic effects of
this material to humans.
humans
Specific effects
Carcinogenic effects : Contains material which may cause cancer. Risk of cancer depends on duration and
level of exposure.

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Nonflammable Gas Mixture: Carbon Tetrachloride / Chlorobenzene / Nitrogen / Oxygen

Mutagenic effects : No known significant effects or critical hazards.
Reproduction toxicity : No known significant effects or critical hazards.

Section 12. Ecological information
Aquatic ecotoxicity
Product/ingredient name Test Result Species Exposure
Benzene, chloro- - Acute LC50 10 to 12000 Fish - 96 hours
ppm Marine water Sheepshead
minnow -
Cyprinodon
variegatus -
Juvenile
(Fledgling,
Hatchling,
Weanling) - 8 to
15 mm
- Acute LC50 11100 to Daphnia - Water 48 hours
13200 ug/L Fresh water flea -
Ceriodaphnia
dubia - Neonate
- Acute LC50 11000 to Daphnia - Water 48 hours
12800 ug/L Fresh water flea -
Ceriodaphnia
dubia - Neonate
- Acute LC50 10700 to Daphnia - Water 48 hours
12400 ug/L Fresh water flea - Daphnia
magna - Neonate
- Acute LC50 10400 to Daphnia - Water 48 hours
12000 ug/L Fresh water flea -
Ceriodaphnia
dubia - Neonate
- Acute LC50 8900 to Daphnia - Water 48 hours
10500 ug/L Fresh water flea -
Ceriodaphnia
dubia - Neonate
- Acute LC50 8600 to Daphnia - Water 48 hours
10200 ug/L Fresh water flea - Daphnia
magna - Neonate
- Acute LC50 7900 to Daphnia - Water 48 hours
9300 ug/L Fresh water flea -
Ceriodaphnia
dubia - Neonate
- Acute LC50 7700 to Fish - Fathead 96 hours
8500 ug/L Fresh water minnow -
Pimephales
promelas -
LARVAE - <24
hours
- Acute LC50 7460 ug/L Fish - Rainbow 96 hours
Fresh water trout,donaldson
trout -
Oncorhynchus
mykiss - 4.6 to
6.4 cm - 1.2 to
3.8 g
- Acute LC50 7400 to Fish - Bluegill - 96 hours
7900 ug/L Fresh water Lepomis
macrochirus -
Juvenile
(Fledgling,
Hatchling,
Weanling) - 3.65

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Nonflammable Gas Mixture: Carbon Tetrachloride / Chlorobenzene / Nitrogen / Oxygen
cm - 0.9 g
- Acute LC50 4700 to Fish - Rainbow 96 hours
5300 ug/L Fresh water trout,donaldson
trout -
Oncorhynchus
mykiss
- Acute LC50 4500 to Fish - Bluegill - 96 hours
4900 ug/L Fresh water Lepomis
macrochirus -
Juvenile
(Fledgling,
Hatchling,
Weanling) - 3.65
cm - 0.9 g
- Acute LC50 3480 to Fish - Goldfish - 96 hours
3870 ug/L Fresh water Carassius
auratus - Egg
- Acute LC50 2370 to Fish - Goldfish - 96 hours
2860 ug/L Fresh water Carassius
auratus - Egg
- Acute LC50 16000 ug/L Fish - Bluegill - 96 hours
Fresh water Lepomis
macrochirus
- Acute LC50 11400 to Daphnia - Water 48 hours
13400 ug/L Fresh water flea -
Ceriodaphnia
dubia - Neonate
- Chronic NOEC 6.2 ppm Fish - 96 hours
Marine water Sheepshead
minnow -
Cyprinodon
variegatus -
Juvenile
(Fledgling,
Hatchling,
Weanling) - 8 to
15 mm
- Chronic NOEC 10000 Daphnia - Water 48 hours
ug/L Fresh water flea - Daphnia
magna - <=24
hours
Methane, tetrachloro- - Acute LC50 43.3 mg/L Fish - Fathead 96 hours
Fresh water minnow -
Pimephales
promelas -
Juvenile
(Fledgling,
Hatchling,
Weanling) - 8
weeks - 12 to 16
mm
- Acute LC50 42.9 mg/L Fish - Fathead 96 hours
Fresh water minnow -
Pimephales
promelas -
Juvenile
(Fledgling,
Hatchling,
Weanling) - 8
weeks - 12 to 16
mm
- Acute LC50 27 to 33 Fish - Bluegill - 96 hours
mg/L Fresh water Lepomis

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Nonflammable Gas Mixture: Carbon Tetrachloride / Chlorobenzene / Nitrogen / Oxygen
macrochirus -
Young of the year
- 0.32 to 1.2 g
- Acute LC50 4.8 to 5.4 Fish - English 96 hours
ml/kg Marine water sole - Parophrys
vetulus - 78.4 g
- Acute LC50 35000 to Daphnia - Water 48 hours
47000 ug/L Fresh water flea - Daphnia
magna - <=24
hours
- Acute LC50 27000 to Fish - Bluegill - 96 hours
33000 ug/L Fresh water Lepomis
macrochirus
- Acute LC50 10400 to Fish - Fathead 96 hours
11300 ug/L Fresh water minnow -
Pimephales
promelas - 30
days - 0.092 g
- Acute LC50 150000 ug/L Fish - Inland 96 hours
Marine water silverside -
Menidia beryllina
- 40 to 100 mm
- Acute LC50 125000 ug/L Fish - Bluegill - 96 hours
Fresh water Lepomis
macrochirus - 33
to 75 mm
- Acute LC50 41400 to Fish - Fathead 96 hours
47300 ug/L Fresh water minnow -
Pimephales
promelas - 30
days - 17.4 mm -
0.098 g
- Chronic NOEC 7700 Daphnia - Water 48 hours
ug/L Fresh water flea - Daphnia
magna - <=24
hours
Products of degradation : Products of degradation: carbon oxides (CO, CO2) and water, nitrogen oxides (NO, NO2
etc.), halogenated compounds.
Environmental fate : Not available.
Environmental hazards : No known significant effects or critical hazards.
Toxicity to the environment : Not available.

Section 13. Disposal considerations
Product removed from the cylinder must be disposed of in accordance with appropriate Federal, State, local
regulation.Return cylinders with residual product to Airgas, Inc.Do not dispose of locally.

Section 14. Transport information
Regulatory UN number Proper shipping Class Packing group Label Additional
information name information

DOT Classification UN1956 COMPRESSED GAS, 2.2 Not applicable (gas). -
N.O.S.




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Nonflammable Gas Mixture: Carbon Tetrachloride / Chlorobenzene / Nitrogen / Oxygen

TDG Classification UN1956 COMPRESSED GAS, 2.2 Not applicable (gas). Explosive
N.O.S. Limit and
Limited
Quantity
Index
0.125

Passenger
Carrying
Road or Rail
Index
75

Mexico UN1956 COMPRESSED GAS, 2.2 Not applicable (gas). -
N.O.S.
Classification


"Refer to CFR 49 (or authority having jurisdiction) to determine the information required for shipment of the
product."

Section 15. Regulatory information
United States
U.S. Federal regulations : TSCA 4(a) final test rules: Benzene, chloro-
TSCA 8(a) PAIR: Benzene, chloro-
United States inventory (TSCA 8b): All components are listed or exempted.
TSCA 12(b) one-time export: Benzene, chloro-
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: Oxygen; Nitrogen; Benzene, chloro-;
Methane, tetrachloro-
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
Oxygen: Fire hazard, Sudden release of pressure, Delayed (chronic) health hazard;
Nitrogen: Sudden release of pressure; Benzene, chloro-: Fire hazard, Immediate (acute)
health hazard, Delayed (chronic) health hazard; Methane, tetrachloro-: Immediate
(acute) health hazard, Delayed (chronic) health hazard
Clean Water Act (CWA) 307: Benzene, chloro-; Methane, tetrachloro-
Clean Water Act (CWA) 311: Benzene, chloro-
Clean Air Act (CAA) 112 accidental release prevention: No products were found.
Clean Air Act (CAA) 112 regulated flammable substances: No products were found.
Clean Air Act (CAA) 112 regulated toxic substances: No products were found.
SARA 313
Product name CAS number Concentration
Form R - Reporting : Chlorobenzene 108-90-7 0.0001 - 1
requirements Carbon Tetrachloride 56-23-5 0.0001 - 1
Supplier notification : Chlorobenzene 108-90-7 0.0001 - 1
Carbon Tetrachloride 56-23-5 0.0001 - 1
SARA 313 notifications must not be detached from the MSDS and any copying and redistribution of the MSDS shall
include copying and redistribution of the notice attached to copies of the MSDS subsequently redistributed.
State regulations : Connecticut Carcinogen Reporting: None of the components are listed.
Connecticut Hazardous Material Survey: None of the components are listed.
Florida substances: None of the components are listed.
Illinois Chemical Safety Act: None of the components are listed.
Illinois Toxic Substances Disclosure to Employee Act: None of the components are
listed.
Louisiana Reporting: None of the components are listed.
Louisiana Spill: None of the components are listed.
Massachusetts Spill: None of the components are listed.
Massachusetts Substances: The following components are listed: NITROGEN;
OXYGEN (LIQUID); CHLOROBENZENE; CARBON TETRACHLORIDE
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Nonflammable Gas Mixture: Carbon Tetrachloride / Chlorobenzene / Nitrogen / Oxygen
Michigan Critical Material: None of the components are listed.
Minnesota Hazardous Substances: None of the components are listed.
New Jersey Hazardous Substances: The following components are listed: NITROGEN
(COMPRESSED OR LIQUIFIED); OXYGEN; CHLOROBENZENE; CARBON
TETRACHLORIDE
New Jersey Spill: None of the components are listed.
New Jersey Toxic Catastrophe Prevention Act: None of the components are listed.
New York Acutely Hazardous Substances: The following components are listed:
Benzene chloro-; Carbon tetrachloride
New York Toxic Chemical Release Reporting: None of the components are listed.
Pennsylvania RTK Hazardous Substances: The following components are listed:
NITROGEN; OXYGEN; BENZENE, CHLORO-; METHANE, TETRACHLORO-
Rhode Island Hazardous Substances: None of the components are listed.


California Prop. 65 : WARNING: This product contains a chemical known to the State of California to cause
cancer.
Ingredient name Cancer Reproductive No significant risk Maximum
level acceptable dosage
level
Carbon Tetrachloride Yes. No. Yes. No.
Canada
WHMIS (Canada) : Class A: Compressed gas.
Class C: Oxidizing material.
Class D-1A: Material causing immediate and serious toxic effects (Very toxic).
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).
CEPA Toxic substances: The following components are listed: Tetrachloromethane
Canadian ARET: None of the components are listed.
Canadian NPRI: The following components are listed: Chlorobenzene; Carbon
tetrachloride
Alberta Designated Substances: None of the components are listed.
Ontario Designated Substances: None of the components are listed.
Quebec Designated Substances: None of the components are listed.

Section 16. Other information
United States
Label requirements : CAUSES RESPIRATORY TRACT IRRITATION.
MAY BE HARMFUL IF SWALLOWED.
CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN DAMAGE, BASED ON
ANIMAL DATA.
SUSPECT CANCER HAZARD - CONTAINS MATERIAL WHICH MAY CAUSE
CANCER.
CAUSES SEVERE SKIN IRRITATION.
CAUSES SEVERE EYE IRRITATION.
CONTENTS UNDER PRESSURE.
Canada
Label requirements : Class A: Compressed gas.
Class C: Oxidizing material.
Class D-1A: Material causing immediate and serious toxic effects (Very toxic).
Class D-2A: Material causing other toxic effects (Very toxic).
Class D-2B: Material causing other toxic effects (Toxic).




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Nonflammable Gas Mixture: Carbon Tetrachloride / Chlorobenzene / Nitrogen / Oxygen


Hazardous Material : Health * 2
Information System (U.S.A.)
0
Flammability
0
Physical hazards




National Fire Protection :
Flammability
0
Association (U.S.A.)
2 0
Health Instability
Special



Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above-named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.




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141-78-6_9016-87.asp 141-78-6 9016-87-9
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