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F MATERIAL SAFETY DATA SHEET Revised edition no : 1
Date : 3 / 11 / 2008
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CHURCHILL H-0378.UK
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
: CHURCHILL
Trade name
: Diflufenican: N-(2,4-difluorophenyl)-2-{3-trifluormethyl phenoxy}-3-
Chemical description
pyridinecarboxamide.
Pendimethalin: N-1(Ethylpropyl)-2,6-dinitro-3,4-xylidine
: Herbicide.
Use
: Agan Chemical Manufacturers P.O.B. 262 Ashdod Israel
Company identification
: +972-8-8515211
Emergency phone nr
: MSDS@ma-industries.com
Email
2. HAZARDS IDENTIFICATION
: Flammable.
Physical/Chemical Hazards
: Harmful by inhalation
Human health hazards
Irritating to eyes, respiratory system and skin.
May cause sensitization by skin contact.
May cause harm to the unborn child
: Very toxic to aquatic organisms, may cause long-term adverse effects in the
Environmental hazard
aquatic environment.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Substance name Value(s) CAS No EC No Index No Classification
Diflufenican : 2 - 2.6 % 83164-33-4 ----- 616-032-00-9 R52-53
Pendimethalin : 26 - 29 % 40487-42-1 254-938-2 609-042-00-X R43
N; R50-53
Xylene : 4 -5% 1330-20-7 215-535-7 601-022-00-9 R10
Xn; R20/21
Xi; R38
Chlorobenzene : 44 - 48 % 108-90-7 203-628-5 602-033-00-1 R10
Xn; R20
N; R51-53
N-methyl-2-pyrolidone : 9 - 10 % 872-50-4 212-828-1 606-021-00-7 Repr. Cat. 2; R61
Xi; R36/37/38
4. FIRST AID MEASURES
First aid
: Remove victim to fresh air. If breathing is difficult: artificial respiration .
Inhalation
Get medical attention.
: Wash out mouth with plenty of water. Never give anything by mouth to an
Ingestion
unconscious person. Get medical attention.
: Remove contaminated clothing and shoes. Wash away remainder with plenty of
Skin contact
water.
: Wash out with plenty of water with the eyelid held wide open for at least 15
Eye contact
minutes. Get medical attention.
: No specific antidote known. Treat symptomatically and give supportive therapy.
Note to physician
5. FIRE-FIGHTING MEASURES
: For small fire : dry chemical powder , carbon dioxide
Extinguishing media
For large fire : foam , water fog , water spray.
: Carbon oxides (CO, CO2) , fluorides , nitrogen oxides (NO, NO2...)
Hazardous decomposition products
Agan Chemical Manufacturers Ltd.
P.O.B. 262 ASHDOD Israel
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F MATERIAL SAFETY DATA SHEET Revised edition no : 1
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6. ACCIDENTAL RELEASE MEASURES
: Wear suitable protective clothing, gloves and eye/face protection.
Personal precautions
: Do not discharge into the environment.
Environmental precautions
Do not empty into drains.
: Collect spilled material. Absorb in sand or other inert material. Dispose of this
After spillage and/or leakage
material and its container at hazardous or special waste collection point.
7. HANDLING AND STORAGE
: Ventilation required.
Handling
: Keep in original containers. Keep away from food, drink and animal feeding stuffs.
Storage
Store in dry, well-ventilated area.
Precautions in handling and storage : Handle in accordance with good industrial hygiene and safety procedures.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
: Wash hands thoroughly after handling. When using do not eat, drink or smoke.
Industrial hygiene
Wash clothing before re-using.
Personal protection
: No special respiratory protection equipment is recommended under normal
- Respiratory protection
conditions of use with adequate ventilation.
: Wear suitable protective clothing Wear safety boots.
- Skin protection
: Wear suitable gloves.
- Hand protection
: Chemical goggles or safety glasses.
- Eye protection
Occupational Exposure Limits : Diflufenican: No data available.
: Pendimethalin: No data available.
TLV : Xylene: 100 ppm ; NMP: 25 ppm(skin)
; Chlorobenzene: 10 ppm
9. PHYSICAL AND CHEMICAL PROPERTIES
: Liquid
Physical state
: Orange-brown.
Colour
: Aromatic
Odour
: 5-7
pH value
: 1.10 ?.02 @ 20癈
Density [g/ml]
: 4.25*10^-3@ 25癈 (Diflufenican) ; 4.00 @ 25癈 (Pendimethalin)
Vapour pressure [mPa]
: Miscible
Solubility in water
: 45
Flash point [癈]
: >600 (Chlorobenzene)
Auto-ignition temperature [癈]
: 4.9 (Diflufenican)
Log P octanol / water
5.18 @ 25癈 (Pendimethalin)
: Flammable
Flammability
: Vapours- Chlorobenzene: May form explosive mixtures with air.
Explosion properties
: 1.3
Explosion limits - lower [%]
: 11
Explosion limits - upper [%]
: Not oxidizing
Oxidation properties
Agan Chemical Manufacturers Ltd.
P.O.B. 262 ASHDOD Israel
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10. STABILITY AND REACTIVITY
: Carbon oxides (CO, CO2) , fluorides , nitrogen oxides (NO, NO2...)
Hazardous decomposition products
: Will not occur.
Hazardous Polymerization
: oxidizing agents , acids , alkali .
Materials to avoid
11. TOXICOLOGICAL INFORMATION
On product : Based on data of ingredients
: >2,000
Rat oral LD50 [mg/kg]
: > 2000
Rat dermal LD50 [mg/kg]
: >2.0 Maximum concentration attainable.
Rat inhalation LC50 [mg/l/4h]
: Non sensitizer
Sensitization
Carcinogenicity : Diflufenican:
: EPA , EU : Not classified
: Pendimethalin:
: EPA Group C: Possible human carcinogen ,
EU : Not classified
: not mutagenic.
Mutagenicity
: Not considered to be toxic for the reproductive system.
Reproductive toxicity
: Not teratogenic in animal experiments
Teratogenicity
12. ECOLOGICAL INFORMATION
: 5700
96 H-LC50 - Rainbow trout [礸/l]
: 6800
48 H-EC50 - Daphnia magna [礸/l]
: 7.5
EC50 72 H Algae [礸/l]
: Diflufenican: Bobwhite quail >2,150
LD50 Birds [mg/kg]
Pendimethalin: Mallard duck >2,100
Persistence and degradability : Diflufenican:
: Half-life time (t1/2) : 105-210 days
: Pendimethalin: Soil :
: Moderately persistent in soil Half-life time (t1/2) : 25-30 days.
: Water :
: Half-life time (t1/2) <21 days Product does not leach to ground water.
: Not- Low mobility
Mobility
: Chlorotoluron: Soil
: Moderately mobile
Adsorbed on organic matter and clay.
13. DISPOSAL CONSIDERATIONS
: Dispose of in a pesticide approved landfill, or in a chemical incinerator equipped
Disposal
with scrubbers. Dispose in a safe manner in accordance with local/national
regulations.
Agan Chemical Manufacturers Ltd.
P.O.B. 262 ASHDOD Israel
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14. TRANSPORT INFORMATION
: 1993
- UN No.
: UN1993 FLAMMABLE LIQUID, N.O.S.(Chlorobenzene, Xylene), 3, III
- Proper shipping name
: III
- Packing group
: 3
- Class
: 30
- H.I. nr :
: NO
- IMDG-Marine pollution
15. REGULATORY INFORMATION
: T: Toxic
Symbol(s)
N: Dangerous for the environment.
: R10 - Flammable.
R Phrase(s)
R20 - Harmful by inhalation.
R36/37/38 - Irritating to eyes, respiratory system and skin.
R43 - May cause sensitization by skin contact.
R61 - May cause harm to the unborn child.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
: S02 - Keep out of the reach of children.
S Phrase(s)
S13 - Keep away from food, drink and animal feedingstuffs.
S23- Do not breathe gas/fumes/vapor/spray
S29/35- Do not empty into drains; dispose of this material and its container in a
safe way.
S36/37/39- Wear suitable protective clothing, gloves and eye/face protection.
S46 - If swallowed seek medical advice immediately and show this container or
label.
S57- Use appropriate containment to avoid environmental contamination.
S61 - Avoid release to the environment. Refer to special instructions/Safety data
sheets.
16. OTHER INFORMATION
: R10 - Flammable.
Text of R-phrases in heading 2
R20 - Harmful by inhalation.
R20/21 - Harmful by inhalation and in contact with skin.
R36/37/38 - Irritating to eyes, respiratory system and skin.
R38 - Irritating to skin.
R43 - May cause sensitization by skin contact.
R50/53 - Very toxic to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R52/53 - Harmful to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R61 - May cause harm to the unborn child.
: 3 / 11 / 2008
Print date
DISCLAIMER OF LIABILITY The information in this SDS was obtained from sources which we believe are reliable. However,
the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of
handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and
Agan Chemical Manufacturers Ltd.
P.O.B. 262 ASHDOD Israel
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F MATERIAL SAFETY DATA SHEET Revised edition no : 1
Date : 3 / 11 / 2008
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16. OTHER INFORMATION (continued)
other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in
any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used
only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
End of document
Agan Chemical Manufacturers Ltd.
P.O.B. 262 ASHDOD Israel
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