TRUFLEX/PANG RUBBER PRODUCTS COMPANY, INC. EFFECTIVE: 12/19/00
1667 NORTH MAIN STREET SUPERCEDES: 8/27/97
LOS ANGELES, CA 90012 MSDS NO.: ACTMSD
(323) 224-6300 (phone) REVISION NO.: 1
(323) 225-0672 (fax)
ACTIVATOR/HARDNER
_____________________________________________________________________
MATERIAL SAFETY DATA SHEET
SECTION 1. CHEMICAL PRODUCT AND COMPANY INFORMATION
PRODUCT NAME: ACTIVATOR/HARDNER
CATALOG NUMBER(S): 968F, 969F, 970F, 973F
PRODUCT USE: CEMENT ADDITIVE
MANUFACTURED FOR TRUFLEX/PANG BY:
Tech International
200 East Coshocton Street
Johnstown, OH 43031
(740) 967-9015 phone
(740) 967-1039 fax
FOR CUSTOMER SERVICE INFORMATION, CONTACT:
(323) 224-6300
EMERGENCY TELEPHONE NUMBER (24 hrs.):
CHEMTREC (800) 424-9300
MSDS PREPARED BY:
John Gramza, Jr.
Regulatory Affairs Director
Tech International
200 East Coshocton Street
Johnstown, OH 43031
(740) 967-9015
SECTION 2. CHEMICAL COMPOSITION/HAZARDOUS INGREDIENTS
CAS NO. % (by vol.) OSHA PEL ACGIH TLV NOTES
INGREDIENT (COMMON NAME)
Tris-(4-Isocyanatophenyl) Thiophosphate 4151-51-3 27 0.005 ppm 400 ppm 1
Ethyl Acetate 141-78-6 70 - 72.5 400 ppm 400 ppm
Monochlorobenzene 108-90-7 0.5 - 3.0 75 ppm 75 ppm
NOTES
1 An exposure guideline of 0.005 ppm TWA, and 0.02 ppm STEL is suggested based upon the established exposure
limits for Toluene Diisocyanate.
1
TRUFLEX/PANG RUBBER PRODUCTS COMPANY, INC. EFFECTIVE: 12/19/00
1667 NORTH MAIN STREET SUPERCEDES: 8/27/97
LOS ANGELES, CA 90012 MSDS NO.: ACTMSD
(323) 224-6300 (phone) REVISION NO.: 1
(323) 225-0672 (fax)
ACTIVATOR/HARDNER
_____________________________________________________________________
MATERIAL SAFETY DATA SHEET
SECTION 3. PHYSICAL CHARACTERISTICS
o o
171 F (77 C) @ 760.00 mm Hg
INITIAL BOILING POINT
o
54.6 mm Hg @ 68.00 F
VAPOR PRESSURE
Heavier than air
VAPOR DENSITY (air = 1)
o
1.0 @ 68.00 F
SPECIFIC GRAVITY (water = 1)
75.5%
% VOLATILES
VOC CONTENT 5.69 lbs/gal (682.5 g/L)
Slower than Ether
EVAPORATION RATE
N/A
pH
Yellow to brown liquid
APPEARANCE
Strong solvent
ODOR
SECTION 4. FIRE AND EXPLOSION DATA
o o
23 F (-5 C)
FLASH POINT AND METHOD
2.2%
LEL
11%
UEL
Foam, carbon dioxide or dry chemical
EXTINGUISHING MEDIA
Wear self-contained breathing apparatus with a full-face piece operated in the positive
SPECIAL FIREFIGHTING
pressure demand mode when fighting fires.
PROCEDURES
Never use a welding or cutting torch on or near container (even when empty) because
UNUSUAL FIRE AND EXPLOSION
product (even just residue), can ignite explosively. All 5-gallon or larger metal
HAZARDS
containers should be grounded and bonded when material is being transferred. Vapors
are heavier than air and may travel along the ground or may be moved by ventilation
and ignited by pilot lights, other flames, sparks, heaters, smoking or other ignition
sources distant from the material handling point.
2
TRUFLEX/PANG RUBBER PRODUCTS COMPANY, INC. EFFECTIVE: 12/19/00
1667 NORTH MAIN STREET SUPERCEDES: 8/27/97
LOS ANGELES, CA 90012 MSDS NO.: ACTMSD
(323) 224-6300 (phone) REVISION NO.: 1
(323) 225-0672 (fax)
ACTIVATOR/HARDNER
_____________________________________________________________________
MATERIAL SAFETY DATA SHEET
SECTION 5. REACTIVITY AND STABILITY DATA
Stable
STABILITY
May occur
HAZARDOUS POLYMERIZATION
Strong oxidizers, strong acids, water, alcohols, acids, alkalis
INCOMPATABILITY (materials or conditions to avoid)
Carbon dioxide, carbon monoxide, various hydrocarbons,
HAZARDOUS DECOMPOSITION PRODUCTS
isocyanate vapors, phosgene, chlorine and small amounts of HCN
SECTION 6. HEALTH HAZARD INFORMATION
Exposure to product may cause eye irritation. Symptoms include stinging, tearing, redness
EYE CONTACT
and swelling.
Exposure to vapor or mist is possible. Isocyanate vapors or mist above the exposure
INHALATION
guidelines can irritate the mucous membranes in the respiratory tract. Chronic exposure to
isocyanates can cause sensitization (chemical asthma) to the chemical, causing symptoms
to occur at levels below the published guidelines. Symptoms typically seen at air
concentrations above the recommended exposure limits may include: irritation to nose,
throat and respiratory system, metallic taste, muscle weakness. Initial central nervous
system (CNS) excitation (euphoria, exhilaration, light-headedness) followed by CNS
depression (dizziness, drowsiness, weakness, fatigue, nausea, headache,
unconsciousness) and other CNS effects (confusion, impaired coordination, coma and
possibly death).
Single dose oral toxicity is low. Symptoms may include: gastrointestinal irritation (nausea,
INGESTION
vomiting, diarrhea), CNS depression.
Exposure may cause mild skin irritation. Prolonged or repeated exposure may dry skin.
SKIN CONTACT
Symptoms include: redness, burning, drying, cracking and skin burns.
CNS, liver, kidneys, skin, eyes
TARGET ORGANS EFFECTED
CARCINOGENICITY - LISTED BY:
No No No No
ACGIH IARC NTP OSHA
3
TRUFLEX/PANG RUBBER PRODUCTS COMPANY, INC. EFFECTIVE: 12/19/00
1667 NORTH MAIN STREET SUPERCEDES: 8/27/97
LOS ANGELES, CA 90012 MSDS NO.: ACTMSD
(323) 224-6300 (phone) REVISION NO.: 1
(323) 225-0672 (fax)
ACTIVATOR/HARDNER
_____________________________________________________________________
MATERIAL SAFETY DATA SHEET
SECTION 7 EMERGENCY AND FIRST AID INFORMATION
If symptoms develop, move individual away from exposure and into fresh air. Flush eyes with water for at
EYE CONTACT
least 15 minutes while holding eyelids apart. If symptoms persist, seek medical attention.
If symptoms develop, immediately move individual away from exposure and into fresh air. Seek
INHALATION
immediate medical attention. If person is not breathing, begin artificial respiration. If breathing is difficult,
administer oxygen. Keep person warm and quiet.
If swallowed, DO NOT induce vomiting. This material is an aspiration hazard. If person is drowsy or
INGESTION
unconscious, place on left side with head down. Seek immediate medical attention.
Remove contaminated clothing. Wash exposed area with soap and water. Launder contaminated
SKIN CONTACT
clothing before reuse. If symptoms persist, seek medical attention.
SECTION 8. PROTECTIVE EQUIPMENT AND OTHER CONTROL MEASURES
Chemical splash goggles in compliance with OSHA regulations are advised, however
EYE PROTECTION
OSHA regulations also permit other types of safety glasses. Consult your safety equipment
representative.
If workplace exposure limit (s) of product or any component is exceeded (See Section 2), a
RESPIRATORY
NIOSH/MSHA approved respirator is advised in the absence of proper environmental
PROTECTION
control. A supplied-air respirator is recommended. Engineering or administrative controls
should be implemented to reduce exposure.
Wear resistant gloves, such as: polyvinyl alcohol, nitrile
SKIN PROTECTION
Provide sufficient mechanical (general or local exhaust) ventilation to maintain exposure
ENGINEERING CONTROLS
below TLV(s). Explosion-proof ventilation system is acceptable.
To prevent repeated or prolonged skin contact, wear impervious clothing and boots.
OTHER PROTECTIVE
EQUIPMENT
Use good personal hygiene work practices. Wash hands before eating, drinking, smoking
OTHER HYGIENIC AND
or using toilet facilities. Promptly remove soiled clothing and wash before reuse.
WORK PRACTICES
4
TRUFLEX/PANG RUBBER PRODUCTS COMPANY, INC. EFFECTIVE: 12/19/00
1667 NORTH MAIN STREET SUPERCEDES: 8/27/97
LOS ANGELES, CA 90012 MSDS NO.: ACTMSD
(323) 224-6300 (phone) REVISION NO.: 1
(323) 225-0672 (fax)
ACTIVATOR/HARDNER
_____________________________________________________________________
MATERIAL SAFETY DATA SHEET
SECTION 9. SPILL OR RELEASE PROCEDURES
Eliminate all sources of ignition (flames, pilot lights, electrical sparks) and absorb material on vermiculite,
SMALL SPILL
floor absorbent or other absorbent material.
Eliminate all sources of ignition (flames, pilot lights, electrical sparks, etc.). Persons not wearing appropriate
LARGE SPILL
protective equipment should be excluded from area of spill until cleanup has been completed. Stop spill at
source. Prevent material from entering drains, sewers, streams, or other bodies of water. Prevent from
spreading by using dikes, booms, etc. If runoff occurs, notify authorities as required. Pump or vacuum
transfer spilled material into clean, approved containers for recovery or disposal. Absorb unrecoverable
material onto vermiculite, floor absorbent or other absorbent material, and transfer into clean approved
containers for disposal.
SECTION 10. DISPOSAL CONSIDERATIONS
Disposal of material should be done in accordance with all Federal (40 CFR Part 261), State and Local environmental control
regulations. In its unused state, the product exhibits the EPA hazardous waste characteristic for ignitability (RCRA waste code
D001).
SECTION 11. TRANSPORTATION INFORMATION
Flammable Liquid, N.O.S.
DOT PROPER SHIPPING NAME (49 CFR 172.101)
3
HAZARD CLASS (DOT, IATA)
3.2
HAZARD CLASS (IMO)
UN 1993
ID NUMBER
II
PACKING GROUP
Triisocyanate in Ethyl Acetate
ADDITIONAL DESCRIPTION
Flammable Liquid (49 CFR 172.419)
LABELS REQUIRED
128
1996 NORTH AMERICAN EMERGENCY RESPONSE
GUIDEBOOK NUMBER
3-07
EmS NUMBER
330
MFAG TABLE NO.
1000 lbs. (454 kg.)
REPORTABLE QUANTITY (DOT)
SECTION 12. OTHER REGULATORY INFORMATION
5
TRUFLEX/PANG RUBBER PRODUCTS COMPANY, INC. EFFECTIVE: 12/19/00
1667 NORTH MAIN STREET SUPERCEDES: 8/27/97
LOS ANGELES, CA 90012 MSDS NO.: ACTMSD
(323) 224-6300 (phone) REVISION NO.: 1
(323) 225-0672 (fax)
ACTIVATOR/HARDNER
_____________________________________________________________________
MATERIAL SAFETY DATA SHEET
This product contains the following toxic substances subject to the reporting requirements of Section 313 of Title III of the Superfund
Amendments and Reauthorization Act (Emergency Planning and Community Right-To-Know Act) of 1986 and of
40 CFR Part 372:
CHEMICAL CAS NO. % COMPOSITION (by vol.)
Tris-(Isocyanatophenyl) Thiophosphate 4151-51-3 27
Ethyl Acetate 141-78-6 70 - 72.5
Monochlorobenzene 108-90-7 0.5 - 3.0
TOXIC SUBSTANCES CONTROL ACT: The chemical substances in this product are listed on the TSCA Section 8 Chemical
Substance Inventory List (40 CFR Part 710).
SECTION 13. NFPA RATINGS
3 3 0
HEALTH FLAMMABILITY REACTIVITY
SECTION 14. ADDITIONAL INFORMATION
Containers of this product may be hazardous when emptied. Since emptied containers retain product residues (vapors, liquid,
and/or solids), all hazard precautions given in this data sheet must be observed.
Hydrocarbon solvents are basically non-conductors of electricity and can become electrostatically charged during mixing, filtering,
pouring or pumping at high flow rates. If this charge reaches a sufficiently high level, sparks can form which may ignite the vapors of
the flammable liquids.
The information contained herein is information received from our raw material suppliers and other sources believed to be reliable. This data is not warranted whether
originating with Truflex/Pang, or not. Recipients are advised to confirm in advance of the need that the information is current, applicable and suitable to their
circumstances. It is the responsibility of the user to comply with all applicable Federal, State and Local laws and regulations.
This MSDS complies with the OSHA Hazard Communication Standard (29 CFR 1910.1200).
6
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