MATERIAL SAFETY DATA SHEET
TM
FOR CHEMICAL
EMERGENCY
CHROMATE INDUSTRIAL CORPORATION? Call ChemTrec day/night:
5250-A Naiman Parkway, Solon, OH 44139 ?888-567-2206 ?www.chromate.com 1-800-424-9300
SECTION 1 ?PRODUCT AND COMPANY IDENTIFICATION
PRODUCT NAME: ELMERS POLYURETHANE GLUE DATE PREPARED: April 1, 2009
PART NUMBER: 74558
CHROMATE INDUSTRIAL CORPORATION
5250-A Naiman Parkway, Solon, OH 44139 ?(888) 567-2206
SECTION 2 ?COMPOSITION / INFORMATION ON INGREDIENTS
COMPONENT CAS NUMBER PERCENTAGE
POLYMETHYLENE POLYPHENYL ISOCYANATE 9016-87-9 30-50
METHYLENE BISPHENYL ISOCYANATE 101-68-8 30-50
NON-HAZARDOUS SUBSTANCE Not assigned 10-30
CHLOROBENZENE 108-90-7 <0.01
SECTION 3 ?HAZARD IDENTIFICATION
NFPA RATINGS (SCALE 0-4): HEALTH: 2 FIRE: 1 REACTIVITY: 1
EMERGENCY OVERVIEW:
COLOR: Brown PHYSICAL FORM: Liquid
ODOR: Musty odor
MAJOR HEALTH HAZARDS: harmful if inhaled, respiratory tract irritation, skin irritation, eye irritation, allergic reactions
PHYSICAL HAZARDS: May react on contact with water.
POTENTIAL HEALTH EFFECTS
INHALATION: Irritation, allergic reactions, chest pain, difficulty breathing
Short Term Exposure:
Allergic reactions, difficulty breathing
Long Term Exposure:
SKIN CONTACT: Short Term Exposure: Irritation, allergic reactions, skin disorders, itching, rash
Irritation, allergic reactions, rash, itching
Long Term Exposure:
EYE CONTACT: Irritation
Short Term Exposure:
Irritation
Long Term Exposure:
INGESTION: Gastrointestinal irritation
Short Term Exposure:
No information on significant adverse effects
Long Term Exposure:
SECTION 4 ?FIRST AID MEASURES
Inhalation: If adverse effects occur, remove to uncontaminated area. Give artificial respiration if not breathing. If breathing is difficult, oxygen
should be administered by qualified personnel. Get immediate medical attention.
Skin Contact: If bonding occurs, immerse the bonded surfaces in warm soapy water. Peel or roll the surfaces apart using a blunt edge, such
as a spatula or spoon handle. Do not pull surfaces apart with a direct opposing action. If burns occur, treat as thermal burns.
Get medical attention, if needed.
Eye Contact: If bonding to tissues occurs, wash with large amounts of warm water. Cover both eyes with sterile, dry bandages. The eye
will open without further action. Do not pull surfaces apart with a direct opposing action. If burns occur, treat as thermal burns.
Get medical attention.
Ingestion: Wet lips with water. Peel or roll the surfaces apart using a blunt edge, such as a spatula or spoon handle. Do not pull surfaces
apart with a direct opposing action. If a lump forms in the mouth, turn head to side. If burns occur, treat as thermal burns. Get
medical attention.
NOTE TO PHYSICIAN: For inhalation, consider oxygen. Mineral oil, vegetable oil, or petroleum jelly may help soften the bonding between
skin surfaces. For skin contact, consider acetone or nitromethane.
N/A -- NOT APPLICABLE N/D -- NOT DETERMINED N/E -- NONE ESTABLISHED N/R -- NOT REGULATED
N/L -- NOT LISTED
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RED LION RESEARCH-CHROMATE INDUSTRIAL CORPORATION ELMERS POLYURETHANE GLUE P/N 74558
SECTION 5 ?FIRE-FIGHTING MEASURES
FIRE AND EXPLOSION HAZARDS: Slight fire hazard.
EXTINGUISHING MEDIA: Carbon dioxide, regular dry chemical, regular foam, water.
FIRE-FIGHTING: Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion by-products.
Stay upwind and keep out of low areas.
FLASH POINT: >230篎 (>110篊) (CC)
AUTO-IGNITION: >1112篎 (>600篊)
FLAMMABILITY CLASS (OSHA): IIIB
HAZARDOUS COMBUSTION PRODUCTS: Thermal decomposition or combustion products: cyanides, oxides of carbon, oxides of nitrogen
SECTION 6 ?ACCIDENTAL RELEASE MEASURES
OCCUPATIONAL RELEASE: Stop leak if possible without personal risk. Small spills: Absorb with sand or other non-combustible material.
Collect spilled material in appropriate container for disposal. Notify Local Emergency Planning Committee and
State Emergency Response Commission for release greater than or equal to RQ (U.S. SARA Section 304).
If release occurs in the U.S. and is reportable under CERCLA Section 103, notify the National Response Center
at (800)424-8802 (USA) or (202)426-2675 (USA).
SECTION 7 ?HANDLING AND STORAGE
STORAGE: Store and handle in accordance with all current regulations and standards. Keep container tightly closed. Store in a well-
ventilated area. Avoid contact with water or moisture. Store between 16 C and 38 C. A hazardous build-up of pressure could
result due to a reaction with water producing carbon dioxide gas if contaminated containers are resealed. Do not reseal
contaminated containers. Reseal uncontaminated containers that are free of moisture only after placing under a nitrogen blanket.
Do not store in containers made of copper, copper alloys, or galvanized surfaces. See original container for storage
recommendations. Keep separated from incompatible substances.
HANDLING: Use only with adequate ventilation. Avoid breathing vapor or mist. Avoid prolonged or repeated contact with skin or eyes.
Wash thoroughly after handling. Do not get in eyes.
SECTION 7 ?EXPOSURE CONTROLS / PERSONAL PROTECTION
EXPOSURE LIMITS: OSHA CEILING ACGIH TWA NIOSH RECOMMENDED NIOSH RECOMMENDED
TWA 10 HOUR(S) CEILING 10 MINUTE(S)
POLYMETHYLENE POLYPHENYL- 0.02 ppm (0.2 mg/m3) 0.005 ppm 0.005 ppm (0.05 mg/m3) 0.020 ppm (0.2 mg/m3)
ISOCYANATEMETHYLENE-
BISPHENYL ISOCYANATE
METHYLENE BISPHENYL- 0.02 ppm (0.2 mg/m3) 0.005 ppm 0.005 ppm (0.05 mg/m3) 0.020 ppm (0.2 mg/m3)
ISOCYANATE
VENTILATION: Provide local exhaust or process enclosure ventilation system. Ensure compliance with applicable exposure limits.
EYE PROTECTION: Wear splash resistant safety goggles with a faceshield. Provide an emergency eye wash fountain and quick drench
shower in the immediate work area.
CLOTHING: Wear appropriate chemical resistant clothing.
GLOVES: Wear appropriate chemical resistant gloves.
PROTECTIVE MATERIAL TYPES: Noprene, nitrile, butyl rubber
RESPIRATOR: Under conditions of frequent use or heavy exposure, respiratory protection may be needed. Respiratory protection is ranked
in order from minimum to maximum. Consider warning properties before use. Any dust, mist, and fume respirator. Any
air-purifying respirator with a high-efficiency particulate filter. Any powered, air-purifying respirator with a dust, mist, and fume
filter. Any powered, air-purifying respirator with a high-efficiency particulate filter.
FOR UNKNOWN CONCENTRATIONS OR IMMEDIATELY DANGEROUS TO LIFE OR HEALTH
Any supplied-air respirator with full facepiece and operated in a pressure-demand or other positive-pressure mode in combination with a
separate escape supply. Any self-contained breathing apparatus with a full facepiece.
N/A -- NOT APPLICABLE N/D -- NOT DETERMINED N/E -- NONE ESTABLISHED N/R -- NOT REGULATED
N/L -- NOT LISTED
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SECTION 9 ?PHYSICAL / CHEMICAL PROPERTIES
PHYSICAL STATE: Liquid COLOR: Brown
ODOR: Musty odor BOILING POINT: >572篎 (>300篊) (decomposes)
FREEZING POINT: N/A VAPOR PRESSURE: 0.000004 mmHg
VAPOR DENSITY (air=1): 8.5 SPECIFIC GRAVITY (water=1): 1.129
WATER SOLUBILITY: Reacts, immiscible PH: N/A
VOLATILITY: N/A ODOR THRESHOLD: N/A
EVAPORATION RATE: N/A VISCOSITY: 2311 cP
COEFFICIENT OF WATER/OIL DISTRIBUTION: N/A
SECTION 10 ?STABILITY AND REACTIVITY
REACTIVITY: May react on contact with water. Closed containers may rupture.
CONDITIONS TO AVOID: Avoid heat, flames, sparks and other sources of ignition. Avoid contact with incompatible materials.
INCOMPATIBILITIES: acids, alcohols, amines, bases, combustible materials, metal salts, metals, oxidizing materials
HAZARDOUS DECOMPOSITION: Decomposition products on contact with water or moisture: oxides of carbon.
Thermal decomposition or combustion products: cyanides, oxides of carbon, oxides of nitrogen.
POLYMERIZATION: Polymerization may occur in the presence of metal compounds, alkalies, and tertiary amines at elevated temperatures.
SECTION 11 ?TOXICOLOGICAL INFORMATION
ELMER'S ULTIMATE GLUE:
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin disorders, respiratory system (including asthma and other breathing disorders)
POLYMETHYLENE POLYPHENYL ISOCYANATE:
IRRITATION DATA: 100 mg eyes-rabbit mild
TOXICITY DATA: 490 mg/m3/4 hour(s) inhalation-rat LC50; >5 ml/kg skin-rabbit LD50; >10000 mg/kg oral-rat LD50
CARCINOGEN STATUS: IARC: Human No Adequate Data, Animal No Adequate Data, Group 3
LOCAL EFFECTS:
Irritant: inhalation, skin, eye
ACUTE TOXICITY LEVEL: Highly Toxic: inhalation
Relatively Non-Toxic: ingestion
TARGET ORGANS: Immune system (sensitizer)
TUMORIGENIC DATA: Available.
REPRODUCTIVE EFFECTS DATA: Available.
ADDITIONAL DATA: May cross react with similar compounds.
METHYLENE BISPHENYL ISOCYANATE:
IRRITATION DATA: 500 mg/24 hour(s) skin-rabbit; 100 mg eyes-rabbit moderate
TOXICITY DATA: 178 mg/m3 inhalation-rat LC50; 9200 mg/kg oral-rat LD50
CARCINOGEN STATUS: IARC: Human Inadequate Evidence (Monomer), Group 3
LOCAL EFFECTS:
Irritant: inhalation, skin, eye
ACUTE TOXICITY LEVEL: Highly Toxic: inhalation
Slightly Toxic: ingestion
TARGET ORGANS: immune system (sensitizer)
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: respiratory disorders
MUTAGENIC DATA: Available.
REPRODUCTIVE EFFECTS DATA: Available.
N/A -- NOT APPLICABLE N/D -- NOT DETERMINED N/E -- NONE ESTABLISHED N/R -- NOT REGULATED
N/L -- NOT LISTED
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SECTION 12 ?ECOLOGICAL INFORMATION
Not available
SECTION 13 ?DISPOSAL CONSIDERATIONS
Dispose in accordance with all applicable regulations.
SECTION 14 ?TRANSPORT INFORMATION
U.S. DEPARTMENT OF TRANSPORTATION: No classification assigned.
CANADIAN TRANSPORTATION OF DANGEROUS GOODS: No classification assigned.
SECTION 15 ?REGULATORY INFORMATION
U.S. REGULATIONS:
CERCLA SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4):
METHYLENE BISPHENYL ISOCYANATE: 5000 LBS RQ
CHLOROBENZENE: 100 LBS RQ
SARA TITLE III SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.30): Not regulated.
SARA TITLE III SECTION 304 EXTREMELY HAZARDOUS SUBSTANCES (40 CFR 355.40): Not regulated.
SARA TITLE III SARA SECTIONS 311/312 HAZARDOUS CATEGORIES (40 CFR 370.21):
ACUTE: Yes CHRONIC: Yes
FIRE: No REACTIVE: No SUDDEN RELEASE: No
SARA TITLE III SECTION 313 (40 CFR 372.65):
POLYMETHYLENE POLYPHENYL ISOCYANATE
METHYLENE BISPHENYL ISOCYANATE
OSHA PROCESS SAFETY (29CFR1910.119): Not regulated.
STATE REGULATIONS:
California Proposition 65: Not regulated.
CANADIAN REGULATIONS:
WHMIS CLASSIFICATION: N/D
NATIONAL INVENTORY STATUS:
U.S. INVENTORY (TSCA): All the components of this substance are listed on or are exempt from the inventory.
TSCA 12(b) EXPORT NOTIFICATION: CHLOROBENZENE SECTION 4
108-90-7
CANADA INVENTORY (DSL/NDSL): N/D
SECTION 16 ?OTHER INFORMATION
SELLER MAKES NO WARRANTY, EXPRESS OR IMPLIED, CONCERNING THE PRODUCT OR THE MERCHANTABILITY OR FITNESS
THEREOF FOR ANY PURPOSE, except that the product shall conform to contracted specifications, and that the product does not
infringe any valid United States or Canadian patent. No claim of any kind shall be greater in amount than the purchase price of
the quantity of product in respect of which damages are claimed. In no event shall Seller be liable for incidental or consequential
damages, whether Buyer's claim is based on contract, breach of warranty, negligence or otherwise.
N/A -- NOT APPLICABLE N/D -- NOT DETERMINED N/E -- NONE ESTABLISHED N/R -- NOT REGULATED
N/L -- NOT LISTED
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