?br>
rev. 05-20-09
supercedes. 01-05-07
MSDS
PREMIUM POLYURETHANE SEAL ANT
SECTION 1. Company Information WHMIS Protective Clothing TDG and DOT
Product Description Not regulated as dangerous
goods
Polyurethane Sealant
Use
Construction Adhesive
EMERGENCY OVERVIEW!!!
Cas Number
This product is irritating to the eyes and skin. Thermal decomposition/burning may produce
Mixture toxic gases and fumes. Closed containers may rupture when exposed to high temperatures,
Manufacturer or when the product has been contaminated with water.
International Building Components, Inc. Avoid breathing hot mists and vapors. This product contains a respiratory and skin sensitizer.
21428 Woods Creek Road
Causes respiratory tract irritation and may cause allergic respiratory reaction. May cause
Monroe, WA, 98272 USA
permanent respiratory damage. Product vapors are potentially irritating to skin. May cause
Telephone - (360)794.2151
allergic skin reaction and dermatitis.
Fax - (360)863.8434
Toll Free - 1.888.610.2151
Web - www.waterblocksystems.com
In Case of Emergency
Toll Free: 1.888.610.2151
Poison Control Center: Consult local telephone directory
SECTION 2. Composition / Information Ingredients
Hazardous component(s) CAS # Percent
Butyl benzyl phthalate 85-68-7 7- 13
Xylenes (0-, m-, p- isomers) 1330-20-7 1-5
Ethyl benzene 100-41-4 0.5 - 1.5
Methylene Diphenyllsocyanate (MDI) 101-68-8 0.1 - 1
SECTION 3. Hazards Identification
Skin
Skin contact may cause irritation. Isocyanates may react with skin protein and moisture to cause itching, reddening, swelling, scaling or blistering.
Individuals previously sensitized to this material may experience these symptoms from exposure to very small amounts of liquid or vapor.
Eyes
This product may cause irritation to the eyes.
Inhalation
No hazard known at this time
Ingestion
No hazard known at this time
Target organs
None Known for product as a whole
SECTION 4. First Aid Measures
Skin
For skin contact, wash immediately with soap and water. For severe exposure, immediately get under a safety shower and begin rinsing.
Eye
Immediately flush eyes with plenty of water for at least 15 minutes.
Inhalation
Remove to fresh air. Administer oxygen or artificial respiration as needed.
the leader in INNOVATIVE CONSTRUCTION PRODUCTS
Page 1 / 4
Toll Free 1-888-610-2151 | www.waterblocksystems.com
Ingestion
If ingested, get immediate medical attention. Do not induce vomiting unless instructed to do so by medical personnel. Never give anything by mouth to
a victim who is unconscious or is having convulsions.
Notes to physician
Treat symptomatically and supportively. Contact WaterBlock to determine whether any additional information is available.
SECTION 5. Fire Fighting Measures
Extinguishing media Use dry chemical, carbon dioxide, or foam. Water spray (fog).
Dust explosion hazard None Known
Sensitivity to mechanical impact None Known
Sensitivity to static discharge None Known
Flash Point 143?F (61.7?C)
SECTION 6. Accidental Release Measures
Emergency action
Appropriate safety measures and protective equipment should be used. See Section 8. Do not discharge to lakes, streams, ponds, or sewers. Dispose
of in compliance with local, state, and federal regulations.
Spill or leak procedure
Scrape up paste and place in steel drums that are in good condition. Thoroughly clean area where spill occurred.
Reporting
See Federal reporting requirements listed in Section 15. We recommend you contact local authorities to determine if there may be other local reporting
requirements.
SECTION 7. Handling and Storage
Handling
Wash hands thoroughly after handling, especially before eating, drinking, smoking, and using restroom facilities. Wash contaminated goggles, face
shields, and gloves. Professionally launder contaminated clothing before re-use. Do not breathe vapors, mists or dusts. Do not breathe fumes generated
when the material is overheated or burned. Use adequate ventilation. Wear respiratory protection if the material is heated, sprayed, used in a confined
space or if exposure limit is exceeded. This product can produce asthmatic sensitization. Individuals with lung or breathing problems or prior allergic
reactions to isocyanates must avoid fumes from this product. Wear appropriate protective equipment to avoid contact with skin and eyes.
Storage
Store in a cool, dry, well-ventilated area away from heat, ignition sources and direct sunlight. Water contamination should be avoided. Cool location
should be 60-80 degrees For 15-30 degrees C.
Empty container precaution
Attention! Follow label warnings even after container is emptied since empty containers may retain product residues. Do not reuse empty container
without professional cleaning for food, clothing, or products for human or animal consumption, or where skin contact can occur.
SECTION 8. Exposure Controls / Personal Protection
Engineering controls
Use local exhaust or general ventilation where the potential exists to exceed the PEL or TL V exposure limits.
Eye protection Wear goggles or safety glasses with side shields.
Skin and body protection Wear appropriate clothing to minimize skin contact with this product.
Respiratory protection
Avoid breathing vapor and/or mists. If airborne concentrations are above the applicable exposure limits, use NIOSH approved respiratory protection.
High airborne concentrations may necessitate the use of self-contained breathing apparatus (SCBA) or a supplied air respirator.
Exposure limits
ACGIH Threshold Limits Values Time Weighted Averages (TLV-TWA)
Ethyl benzene 100-41-4 100 ppm TWA
Methylene Oiphenyl Isocyanate (MOl) 101-68-8 0.005 ppm TWA
Xylenes (0-, m-, p- isomers) 1330-20-7 100 ppm TWA
OSHA Vacated PELs Ceilings
Methylene Oiphenyl Isocyanate (MOl) 101-68-8 0.02 ppm Ceiling; 0.2 mg/m3 Ceiling
OSHA Vacated PELs TWAs
Ethyl benzene 100-41-4 100 ppm TWA; 435 mg/m3 TWA
Xylenes (0-, m-, p- isomers) 1330-20-7 100 ppm TWA; 435 mg/m3 TWA
the leader in INNOVATIVE CONSTRUCTION PRODUCTS
Page 2 / 4
Toll Free 1-888-610-2151 | www.waterblocksystems.com rev. 01-05-07
SECTION 9. Physical and Chemical Properties
Solubility (H20): 0%
Density: 1.777 g/cc
Odor: Slight
Color: White
Physical state: Paste
Freeze protect: No
VOC: 3.9% (69.8 g/l) (Volatile Organic Compounds)
SECTION 10. Stability and Reactivity
Hazardous reactions/decomposition products
Unknown due to the complex nature of this material. Fumes from complete or incomplete combustion may include carbon dioxide, carbon monoxide,
water vapor, oxides of nitrogen and a wide variety of innocuous or toxic fumes.
Hazardous polymerization
Wil not occur.
Conditions to avoid
Avoid Strong Acids. Avoid water, amines, strong bases, alcohols and metallic hydrides.
Stability
This is a stable material.
SECTION 11. Toxicological
LD50
Toxicology Data Selected LD50s LC50s
Butyl benzyl phthalate 85-68-7 Inhalation LC50 Rat: >6.7 mg/L/4H;
Oral LD50 Rat: 2330mg/kg; Dermal LD50 Rabbit: >10 g/kg
Ethyl benzene 100-41-4 Inhalation LC50 Rat: 17.2 mg/L/4H;
Oral LD50 Rat: 3500 mg/kg; Dermal LD50 Rabbit: 15354 mg/kg
Methylene Diphenyl Isocyanate (MOl) 101-68-8 Oral LD50 Rat: 9200 mg/kg
Xylenes (0-, m-, p- isomers) 1330-20-7 Inhalation LC50 Rat: 5000 ppm/4H;
Oral LD50 Rat: 4300 mg/kg; Dermal LD50 Rabbit: >1700 mg/kg
Carcinogenicity (If this product contains any carcinogens, they will be noted below) :
IARC Group 28 (Possibly Carcinogenic to Humans)
Ethyl benzene 100-41-4 Monograph 77, 2000
OSHA Hazard Communication Carcinogens
Ethyl benzene 100-41-4 Present
SECTION 12. Ecological Information
VOC (Volatile Organic Compounds) 3.9%
Ecotoxicological Information No data available for this product
SECTION 13. Disposal Considerations
It is the obligation of each user of the product mentioned herein to determine and comply with the requirements of all applicable local, state and federal
regulations.
Waste disposal
Dispose of waste material according to Local, State, Federal, and Provincial Environmental Regulations. When intending to dispose of this material,
the user is advised that this product would not be classified as a Hazardous Waste under U.S. Federal Regulations in effect at the time this MSDS was
created.
SECTION 14. Transport Information
Department of Transportation (DOT) Requirements Not regulated as dangerous goods.
lATA
Not regarded as dangerous goods.
IMDG
Not regarded as dangerous goods.
the leader in INNOVATIVE CONSTRUCTION PRODUCTS
Page 3 / 4
Toll Free 1-888-610-2151 | www.waterblocksystems.com rev. 01-05-07
SECTION 15. Regulatory Information
This MSDS is prepared and distributed pursuant to the Federal Hazard Communication Standard, 29 CFR 1910.1200.
Federal regulations (All components are on the U.S. EPA TSCA Inventory List.)
CERCLA / SARA - Hazardous Substances and their Reportable Quantities
Butyl benzyl phthalate 85-68-7 100 Ib final RQ; 45.4 kg final RQ
Ethyl benzene 100-41-4 1000 Ib final RQ; 454 kg final RQ
Methylene Diphenyl Isocyanate (MOl) 101-68-8 5000 Ib final RQ; 2270 kg final RQ
Xylenes (0-, m-, p- isomers) 1330-20-7 100 Ib final RQ; 45.4 kg final RQ
CERCLA / SARA - Section 313 - Emission Reporting
Ethyl benzene 100-41-4 0.1 % de minimis concentration
Methylene Diphenyl Isocyanate (MOl) 101-68-8 1.0 % de minimis concentration (Listed under Chemical
Category N120, Oiisocyanatesl
Xylenes (0-, m-, p- isomers) 1330-20-7 1.0 % de minimis concentration
TSCA (Toxic Substances Control Act) - Section 12(b) - Export Notification
Chlorobenzene 108-90-7 Section 4
Xylenes (0-, m-, p- isomers) 1330-20-7 Section 4
State regulations
If this product contains any ingredients listed under California Proposition 65, they will be noted below.
California - Proposition 65 - Carcinogens List
Ethyl benzene 100-41-4 carcinogen, initial date 6/11/04
California - Proposition 65 - Developmental Toxicity
Butyl benzyl phthalate 85-68-7 developmental toxicity, initial date 12/2/05
International regulations
This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and contains all the information required
by the Controlled Products Regulations.
HMIS Ratings SARA 311/312 HAZARD
Health: 1 Immediate Hazard - Yes
CATEGORIES
Flammability: 2 Delayed Hazard - No
Physical hazard: 0 Fire Hazard - No
Personal protection: G Pressure Hazard - No
Reactivity Hazard - No
WHMIS status WHMIS labeling
Controlled
WHMIS classification D2A - Other Toxic Effects-VERY TOXIC
D2B - Other Toxic Effects-TOXIC
SECTION 16. Other Information
Disclaimer
The data in this MSDS has been compiled from publicly available sources. This data relates only to the designated product and not to the use of said
product in combination with other materials. All materials may present unknown hazards and should be used with caution. Although certain hazards
are described herein, we cannot guarantee that these are the only hazards which exist. Responsibility for proper precautions and safe use of the product
lies with the user. All data in this MSDS is typical of the product as a whole, and does not represent any individual lot or batch, therefore, WaterBlock
makes no warranty about the accuracy of the data herein and assumes no liability for the use of such data. It is the responsibility of the user to comply
with all applicable federal, state, and local laws and regulations.
Issue date 09 - 01 - 2006
Supercedes 05 - 09 - 2006
the leader in INNOVATIVE CONSTRUCTION PRODUCTS
Page 4 / 4
Toll Free 1-888-610-2151 | www.waterblocksystems.com rev. 01-05-07
|