Protective Equipment: Wear self-contained breathing apparatus and full protective suit.
Emergency Phone Number (24 hours) CHEMTREC (800-424-9300)
Outside US: 703-527-3887
SECTION 1 SECTION 6
CHEMICAL IDENTIFICATION OF THE SUBSTANCE/PREPARATION ACCIDENTAL RELEASE MEASURES
PRODUCT NAME: Organic Calibration Standard: 10 ml Chlorobenzene; 15 ml each of n- Ventilate area. Wear protective equipment. Do not allow to enter drainage systems or water ways.
Hexadecane and 2,2,4-Trimethylpentane Neutralize with soda ash, limestone etc. Wipe up and put into a sealed container for proper disposal.
COMMON NAME OR SYNONYMS: 2,2,4-Trimethylpentane, isobutyltrimethylmethane Wash spill site with water after material pick up is complete. Wear chemical resistant glasses, gloves
SPEX CATALOG NUMBER: PHC-REF-OIL-2 and clothing.
Manufacturer/Supplier SPEX CERTIPREP LTD SECTION 7
SPEX CERTIPREP 2 Dalston Gardens HANDLING & STORAGE
203 Norcross Avenue Stanmore, Middlesex HA7 1BQ
Metuchen, NJ 08840 England Ensure good ventilation/exhaustion at work place. Have an immediate availability of an eye wash in
Tel: (0) 20 8204 6656 case of emergency. Store at room temperature. Keep the container tightly closed.
SECTION 2
COMPOSITION/INFORMATION ON INGREDIENTS SECTION 8
EXPOSURE CONTROLS/PERSONAL PROTECTION
HAZARDOUS:
MATERIAL % TLV UNITS CAS # EINECS 2,2,4-Trimethylpentane: OSHA Permissible Exposure Limit (PEL): 500 ppm (TWA);
(CH3)3CCH2CH(CH3)2 ~37.5 300 ppm TWA [540-84-1] 208-759-1 Chlorobenzene: OSHA Permissible Exposure Limit (PEL): 8H TWA 75 PPM (350 MG/M3)
C6H5Cl ~25 75 ppm TWA [108-90-7] 203-628-5 Wear goggles, protective apron and acid resistant gloves. Use under fume hood. If exposure limit is
CH3(CH2)14CH3 ~37.5 N/A [544-76-3] 208-878-9 exceeded, use MSHA/NIOSH approved respirator.
SECTION 3 SECTION 9
HAZARD IDENTIFICATION PHYSICAL & CHEMICAL PROPERTIES
Warning. Extremely flammable liquid and vapor. May cause flash fire. Toxic (USA) Harmful (EU). Form: Liquid
Dangerous for the environment. Harmful by inhalation and if swallowed. Toxic to aquatic Appearance & odor: Transparent with gasoline-like odor
organisms, may cause long-term adverse effects in the aquatic environment. Risk of serious damage % volatiles by vol. @ 21C: 100
to eyes. Target organ(s): Liver. Kidneys. Solubility: negligible
pH: No information found
Melting point: -107C
SECTION 4
Boiling Point: 99C
FIRST AID MEASURES
Vapor Pressure (mm Hg): 97 @ 20C
General: Remove contaminated clothing, wash thoroughly before reuse.
Eyes: Flush with water for at least 15 minutes occasionally lifting upper and lower eyelids. SECTION 10
Skin: Remove contaminated clothing and flush with water thoroughly. STABILITY & REACTIVITY
Inhalation: Move to fresh air. Get medical attention immediately.
Ingestion: Get immediate medical attention immediately. If the patient is conscious, give large Stability: Stable under ordinary conditions of use and storage.
quantities of water. Do not induce vomiting. Hazardous Decomposition Products: Carbon dioxide and carbon monoxide may form when heated
to decomposition.
Hazardous Polymerization: Will not occur.
SECTION 5
Incompatibilities: Strong oxidizing agents, strong reducing agents, strong acids or bases.
FIRE FIGHTING MEASURES
Conditions to Avoid: Heat, flames, ignition sources and incompatibles.
Flash Point: -12C (10F) CC
Extinguishing media: Dry chemical, foam or carbon dioxide. Water may be ineffective. Water
spray may be used to keep fire-exposed containers cool.
Special Hazards and Procedure: Vapor can spread along the ground and collect in low or confined
areas.
203 NORCROSS AVE. METUCHEN, NJ 08840 TEL: 732-549-7144 FAX: 732-494-1747 INTERNET: Safety@spexcsp.com
R: 10-20-51/53
PHC-REF-OIL cont'd
Risk Statements: Flammable. Harmful by inhalation. Toxic to aquatic organisms, may cause long-
SECTION 11
term adverse effects in the aquatic environment.
TOXICOLOGICAL INFORMATION
S: 24/25-61
Safety Statements: Avoid contact with skin and eyes. Avoid release to the environment. Refer to
Slightly toxic by ingestion and inhalation . May be irritating to the respiratory tract and narcotic in
special instructions/safety data sheets.
high concentrations.
US CLASSIFICATION AND LABEL TEXT
TOXICITY DATA:
Indication of Danger: Flammable. Toxic (USA) Harmful (EU). Dangerous for the environment.
Concentrated (CH3)3CCH2CH(CH3)2 --RTECS#-SA3320000
Risk Statements: Harmful by inhalation and if swallowed. Toxic to aquatic organisms, may cause
No LD50/LC50 information found relating to normal routes of occupational exposure. Investigated
long-term adverse effects in the aquatic environment. Risk of serious damage to eyes. Safety
as a mutagen.
Statements: In case of contact with eyes, rinse immediately with plenty of water and seek medical
advice. Wear eye/face protection. Avoid release to the environment. Refer to special
Concentrated C6H5Cl - RTECS #: CZ0175000
instructions/safety data sheets.
Oral Rat 1110 mg/kg LD50
US Statements: Target organ(s): Liver. Kidneys.
Remarks: Behavioral: Somnolence (general depressed activity). Behavioral: Tremor. Behavioral:
UNITED STATES REGULATORY INFORMATION
Ataxia.
SARA LISTED: Yes
Inhalation Rat 2,965 ppm LC50
DEMINIMIS: 1 %
NOTES: This product is subject to SARA section 313 reporting requirements.
SECTION 12
TSCA INVENTORY ITEM: Yes
ECOLOGICAL INFORMATION
CANADA REGULATORY INFORMATION
WHMIS Classification: This product has been classified in accordance with the hazard criteria of the
Do not allow product to reach ground water, water bodies or sewage system.
CPR, and the MSDS contains all the information required by the CPR.
DSL: Yes
SECTION 13
NDSL: No
DISPOSAL CONSIDERATIONS
SECTION 16
Contact local Hazardous or Chemical waste disposal agency for regulations.
OTHER INFORMATION
SECTION 14 SPEX CERTIPREP ASSUMES NO RESPONSIBILITY AND MAKES NO WARRANTIES,
TRANSPORT INFORMATION EXPRESS OR IMPLIED, AS TO THE ACCURACY OR COMPLETENESS OF THE DATA
CONTAINED HEREIN. INDICATED SAFETY MEASURES MAY NOT REFLECT ALL
Air & Ground: APPROPRIATE SAFETY MEASURES. SPEX CERTIPREP ASSUMES THAT ONLY
CLASS 3, 6.1 QUALIFIED INDIVIDUALS, TRAINED AND FAMILIAR WITH PROCEDURES SUITABLE
UN/ID # 1992 TO THIS PRODUCT, WILL HANDLE THIS PRODUCT.
Packing Group: II
Proper Shipping Name: Flammable liquids, Toxic, n.o.s. (2,2,4-Trimethylpentane/Chlorobenzene References:
Mixture) The Sigma/Aldrich Library of Chemical Safety Data, Ed.I, (1985)
Registry of Toxic Effects of Chemical Substances, 1981-82
For inner package volumes of 30 mL or less (Not to exceed outer package volume of 29 kg): Patty's Industrial Hygiene and Toxicology, 3rd Revised Edition, Vol. 2A, 1981
UPS and/or Domestic Shipments, ship under the "Small Quantity" rule and attach label: "this Threshold Limit Values and Biological Exposure Indices for 1988-89, ACGIH
package conforms to 49CFR..." Dangerous properties of Industrial Materials by N. Irving Sax and Richard J. Lewis, Sr. (Ninth
For inner package volumes of 1 mL or less (Not to exceed outer package volume of 500 mL): Edition) *
FedEx and/or International Shipments: ship as "Excepted Quantity" attach "Excepted Quantity"
label and specify UN number(s) and hazard class(es) Date: March 5, 2009
SECTION 15
REGULATORY INFORMATION
EU DIRECTIVES CLASSIFICATION
Symbol of Danger: Xn-N
Indication of Danger: Harmful. Dangerous for the environment.
203 NORCROSS AVE. METUCHEN, NJ 08840 TEL: 732-549-7144 FAX: 732-494-1747 INTERNET: Safety@spexcsp.com
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