MATERIAL SAFETY DATA SHEET
Prepared to U.S. OSHA, CMA, ANSI, Canadian WHMIS, Australian WorkSafe and European Community Standards
PART I What is the material and what do I need to know in an emergency?
1. PRODUCT IDENTIFICATION
Total Seal SRP 5055 Bare Metal Etch Primer
TRADE NAME (AS LABELED):
CHEMICAL NAME/CLASS: Ethyl Acetate Mixture
PRODUCT USE: Sealing Material
U.N. NUMBER: 1263
U.N. DANGEROUS GOODS CLASS/SUBSIDIARY RISK: Class 3 (Flammable)
HAZCHEM CODE (AUSTRALIA): 3[Y]E
POISONS SCHEDULE NUMBER (AUSTRALIA): Schedule 6
U.S./DISTRIBUTOR'S NAME: SHAT-R-PROOF, INC.
U.S. ADDRESS: 12800 Hwy 13 South, Suite 500
Savage, MN 55378
MEDICAL EMERGENCIES: 1-800-420-8036
TRANSPORT EMERGENCIES: 1-800-424-9300 (ChemTrec)
1-703-527-3887 (ChemTrec international)
EUROPEAN DISTRIBUTOR'S NAME: LE JOINT FRANCAIS
ADDRESS: Department Mastics, Adhesifs et Revetments
84-116 Rue Salvador Allende
95871 Bezons France
BUSINESS PHONE: 011 33 34 23 34 23
EMERGENCY NUMBER: 011 33 45 42 59 59
AUSTRALIAN DISTRIBUTOR'S NAME: TCG AUSTRALIA
ADDRESS: Australia Support Office, PO Box 1563
Eagle Farm Business Centre
Queensland, 4009, Australia
BUSINESS PHONE: 011-61-7-3866-2700
EMERGENCY NUMBER: 011-61-7-3866-2700
BUSINESS FAX: 011 61-7-3268-5333
DATE OF PREPARATION: November 7, 2006
2. COMPOSITION and INFORMATION ON INGREDIENTS
EU LABELING AND CLASSIFICATION: This product would be classified as follows, as defined by the European
Community Council Directive 67/548/EEC and subsequent Directives.
EU HAZARD CLASSIFICATION: [F]: Highly Flammable. [Xi]: Irritant.
EU RISK PHRASES: [R: 11]: Highly Flammable. [R: 36/37/38]: Irritating to eyes, respiratory system and skin. [R: 42/43]: May cause
sensitization by inhalation and skin contact. [R: 66]: Repeated exposure may cause skin dryness or cracking. [R: 67]: Vapour may cause
drowsiness and dizziness. [R: 51/53]: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
CHEMICAL NAME CAS # EINECS # % w/v EU CLASSIFICATION FOR COMPONENTS
Chlorobenzene 108-90-7 203-628-5 0.1-1.0% HAZARD CLASSIFICATION: F [Flammable]; Xn
[Harmful]; N [Dangerous for the Environment]
RISK PHRASES: R: 10; R: 24/25; R: 51/53
Triphenyl Phosphite 101-02-0 202-908-4 0.1-1.0% HAZARD CLASSIFICATION: Xi [Irritant]; N
[Dangerous for the Environment]
RISK PHRASES: R: 36/38; R: 50/53
Zeolite 1318-02-1 215-283-8 0.5-1.5% HAZARD CLASSIFICATION: Not applicable.
RISK PHRASES: Not applicable.
Acetic Acid Ethenyl Ester, Polymer 25086-48-0 Unlisted 1.0-5.0% HAZARD CLASSIFICATION: Not applicable.
with Chloroethene and Ethenol RISK PHRASES: Not applicable.
Carbon Black 1333-86-4 215-609-9 1.0-5.0% HAZARD CLASSIFICATION: Not applicable.
RISK PHRASES: Not applicable.
2-Butenedioic Acid (Z)-, Polymer with 9005-09-8 Unlisted 3.0-7.0% HAZARD CLASSIFICATION: Not applicable.
Chloroethene and Ethenyl Acetate RISK PHRASES: Not applicable.
4,4',4"-Triphenylmethane Triisocyanate 2422-01-5 219-351-8 7.0-13.0% HAZARD CLASSIFICATION: Not applicable.
RISK PHRASES: Not applicable.
Ethyl Acetate 141-78-6 205-500-4 60.0-100.0% HAZARD CLASSIFICATION: Not applicable.
RISK PHRASES: Not applicable.
Other components which are present in less than 1 percent concentration (or 0.1% Balance HAZARD CLASSIFICATION: Not applicable.
concentration for potential carcinogens, reproductive toxins, respiratory tract sensitizers, RISK PHRASES: Not applicable.
and mutagens).
NE = Not Established. NIC = Notice of Intended Change See Section 16 for Definitions of Terms Used.
NOTE (1): ALL WHMIS required information is included in appropriate sections based on the ANSI Z400.1-2004 format. This product has been classified in
accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR, EC Directives and WorkPlace Australia.
TOTALSEAL SRP 5055 Bare Metal Etch Primer
PAGE 1 OF 14
3. HAZARD IDENTIFICATION
EMERGENCY OVERVIEW: Product Description: This product is a clear, colorless, flammable liquid with a
fruity odor. Health Hazards: This product may moderately irritate contaminated tissue, especially upon
prolonged exposure. Inhalation of high concentrations of vapors may cause central nervous system depression
(e.g., dizziness, headaches, and nausea). This product contains a potential respiratory and skin sensitizer;
susceptible individuals may experience allergic reaction after inhalation exposure. Flammability Hazards: This
product is a flammable liquid which can ignite if subjected to heat, flame or other source of ignition. Vapors of the
product are heavier than air and can travel to a distant source of ignition and flashback. In the event of a fire, the
components of this product may decompose to release smoke, irritating vapors and toxic gases (e.g., carbon
dioxide, carbon monoxide, nitrogen oxides, hydrogen cyanide, reactive hydrocarbons and aldehydes). Reactivity
Hazards: This product is not normally reactive. Environmental Hazards: Releases of this product to the
environment, especially in large quantity, may result in environmental damage. Emergency Response
Considerations: Emergency responders must wear personal protective equipment, and appropriate fire
equipment suitable for the situation to which they are responding.
SYMPTOMS OF OVEREXPOSURE BY ROUTE OF
HAZARDOUS MATERIAL IDENTIFICATION SYSTEM
EXPOSURE: The most significant routes of occupational
overexposure are inhalation of vapors and contact with skin and
eyes. The symptoms of overexposure to this product, via route
(BLUE) 2*
HEALTH HAZARD
of exposure, are as follows:
INHALATION: If high concentrations of vapors of this product
are inhaled (as may occur if this material is used in a poorly
ventilated area), immediate irritation of the respiratory system can
FLAMMABILITY HAZARD (RED) 3
occur. If high vapor concentrations of this product occur,
symptoms of central nervous system depression may occur (e.g.,
headaches, dizziness, nausea). The 4,4',4"-Triphenylmethane
Triisocyanate and other trace components are potential
PHYSICAL HAZARD (YELLOW) 0
respiratory sensitizers. Inhalation of vapors of this product may
cause allergic reaction in susceptible individuals. Symptoms may
include wheezing, coughing, difficulty breathing and angina.
After initial exposure, this reaction can occur in susceptible
PROTECTIVE EQUIPMENT
individuals when exposed to very small amounts of the product.
CONTACT WITH SKIN or EYES: Skin contact may cause
reddening, discomfort, and irritation. Symptoms are generally EYES HANDS BODY
RESPIRATORY
alleviated upon rinsing. Prolonged or repeated skin contact may
cause dermatitis (dry, red skin). Direct contact with the eyes can
SEE SECTION 8 SEE SECTION 8
be moderately irritating and will result in immediate pain, tearing.
Vapors of the product may cause watering and irritation of the
eyes. Irritation should be reversible upon decontamination. The For Routine Industrial Use and Handling Applications
4,4',4"-Triphenylmethane Triisocyanate and other trace of this
product are possible skin sensitizers. Susceptible individuals Hazard Scale: 0 = Minimal 1 = Slight 2 = Moderate
may experience allergic reaction to this product with symptoms 3 = Serious 4 = Severe * = Chronic hazard
including rash, itching, welts and dry, red skin.
SKIN ABSORPTION: The isocyanate-derived compounds of this product may be absorbed via intact skin.
INGESTION: Ingestion is not anticipated to be a likely route of exposure to this product. If this material is
swallowed, it may cause nausea, diarrhea, and vomiting and symptoms of central nervous system depression, such
as described under "Inhalation". A danger of aspiration into the lungs exists after ingestion and can cause damage
to the tissues of the lungs, resulting in chemical pneumonia and edema (accumulation of fluid in the lungs).
Ingestion of large quantities of this product may be fatal.
INJECTION: Though not anticipated to be a likely route of occupational exposure, injection of this material (via
puncture or laceration by a contaminated object) may cause local reddening, tissue swelling, and discomfort in
addition to the wound.
HEALTH EFFECTS OR RISKS FROM EXPOSURE: An Explanation in Lay Terms.
ACUTE: This material may irritate the eyes, skin, and mucous membranes. Inhalation of high concentrations of this
product's vapors may cause dizziness, headaches, and nausea.
CHRONIC: Prolonged or repeated skin contact may cause dermatitis (inflammation of the skin, resulting in redness
and dryness). Due to the presence of the Isocyanate components, a risk of skin and respiratory sensitization exists
for susceptible individuals. Refer to Section 11, Toxicological Information, for additional information.
TARGET ORGANS: Acute: Skin, eyes, central nervous system. Chronic: Skin, respiratory system.
TOTALSEAL SRP 5055 Bare Metal Etch Primer
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PART II What should I do if a hazardous situation occurs?
4. FIRST-AID MEASURES
Contaminated individuals should be taken for medical attention if they feel unwell or if adverse effects occur. Take
copy of label and MSDS to physician or health professional with contaminated individual.
SKIN EXPOSURE: If this material contaminates the skin, begin decontamination with running water.
Recommended flushing is for 15 minutes if any sign of skin irritation develops. Contaminated individual should seek
immediate medical attention if any adverse exposure symptoms develop.
EYE EXPOSURE: If this product enters the eyes, open contaminated individual's eyes while under gently running
water. Use sufficient force to open eyelids. Have contaminated individual "roll" eyes. Minimum flushing is for 15
minutes. Do not interrupt flushing. Contaminated individual must seek medical attention if any adverse effect
occurs.
INHALATION: If this product is inhaled, remove contaminated individual to fresh air. If adverse effect occurs, seek
medical attention.
INGESTION: If this material is swallowed, CALL PHYSICIAN OR POISON CONTROL CENTER FOR MOST
CURRENT INFORMATION. If professional advice is not available, do not induce vomiting. Victim should drink milk,
egg whites, or large quantities of water. Never induce vomiting or give diluents (milk or water) to someone who is
unconscious, having convulsions, or unable to swallow.
MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: Skin disorders and central nervous system conditions
may be aggravated by prolonged overexposure to this product.
RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and eliminate overexposure. Consider gastric lavage
with activated charcoal in event of ingestion.
5. FIRE-FIGHTING MEASURES
FLASH POINT: -5癈 (23癋)
NFPA RATING
AUTOIGNITION TEMPERATURE: Not established for product. The
following values are for the main component, Ethyl Acetate: 426癈 FLAMMABILITY
(800癋)
FLAMMABLE LIMITS (in air by volume, %): Not established for
3
product. The following values are for the main component, Ethyl
Acetate. 2 0
HEALTH INSTABILITY
Lower: 2.0%
Upper: 11.5%
FIRE EXTINGUISHING MATERIALS: Use extinguishing material
suitable to the surrounding fire.
OTHER
Water Spray: YES (for cooling of containers) Foam: YES
Carbon Dioxide: YES Halon: YES Hazard Scale: 0 = Minimal 1 = Slight 2 =
Dry Chemical: YES Other: Any "ABC" Class Moderate
3 = Serious 4 = Severe
UNUSUAL FIRE AND EXPLOSION HAZARDS: This product is a
combustible liquid. When involved in a fire, this material may decompose and produce irritating vapors and toxic
gases (e.g., carbon dioxide, carbon monoxide, nitrogen oxides, hydrogen cyanide, reactive hydrocarbons and
aldehydes). The vapors of this product may travel to a source of ignition, and flashback to a leak or open container.
Explosion Sensitivity to Mechanical Impact: Not applicable.
Explosion Sensitivity to Static Discharge: Vapors of this product may be ignited by static discharge if a high
concentration is allowed to accumulate.
SPECIAL FIRE-FIGHTING PROCEDURES: Structural fire-fighters must wear Self-Contained Breathing Apparatus
and full protective equipment. Chemical resistant clothing may be necessary. Move containers from fire area if it
can be done without risk to personnel. Due to the low flash point of this product, water may be ineffective to
extinguish fires involving this product). Water spray can be used to cool fire-exposed containers. Water fog or spray
can also be used by trained fire-fighters to disperse this product's vapors and to protect personnel. If possible,
prevent runoff water from entering storm drains, bodies of water, or other environmentally sensitive areas. Rinse
contaminated equipment thoroughly with soapy water before returning such equipment to service.
6. ACCIDENTAL RELEASE MEASURES
SPILL AND LEAK RESPONSE: Uncontrolled releases should be responded to by trained personnel using pre-
planned procedures. Proper protective equipment should be used. In case of a spill, clear the affected area and
protect people. Eliminate all sources of ignition before clean-up begins. Use non-sparking tools. Care should be
taken as vapors of this product are heavier than air and can accumulate in low-lying pockets, creating a fire hazard.
TOTALSEAL SRP 5055 Bare Metal Etch Primer
PAGE 3 OF 14
6. ACCIDENTAL RELEASE MEASURES (Continued)
SPILL AND LEAK RESPONSE (continued): The atmosphere must have levels of components lower than those
listed in Section 8, (Exposure Controls-Personal Protection) and at least 19.5 percent oxygen before personnel can
be allowed into the area without Self-Contained Breathing Apparatus (SCBA). For small spills, absorb spilled liquid
with polypads or other suitable absorbent materials, wearing gloves, goggles and apron. In the event of a non-
incidental release, minimum Personal Protective Equipment should be Level B: triple-gloves (rubber gloves and
nitrile gloves, over latex gloves), chemically resistant suit and boots, hard-hat, and Self-Contained Breathing
Apparatus. Monitor area for combustible vapor levels. The level of vapors must be below 10% of the LEL (see
Section 5, Fire-Fighting Measures), before personnel are allowed into the spill area. Absorb spilled liquid with
activated carbon, polypads, or other suitable absorbent materials. Decontaminate the area thoroughly. Prevent
material from entering sewer or confined spaces. Place all spill residue in a double plastic bag and seal. Dispose of
in accordance with applicable U.S. Federal, State, or local procedures, or appropriate Canadian Standards and
those of European Union Member States (see Section 13, Disposal Considerations).
PART III How can I prevent hazardous situations from occurring?
7. HANDLING and STORAGE
WORK AND HYGIENE PRACTICES: As with all chemicals, avoid getting this product ON YOU or IN YOU. Wash
thoroughly after handling this product. Do not eat, drink, smoke, or apply cosmetics while handling this product.
Avoid breathing vapors or mists generated by this product. Use in a well-ventilated location. Remove contaminated
clothing immediately.
STORAGE AND HANDLING PRACTICES: All employees who handle this material should be trained to handle it
safely. Keep away from heat, sparks, and other sources of ignition. Keep container tightly closed when not in use.
Use non-sparking tools. Bond and ground containers during transfers of material. If this product is transferred into
another container, only use portable containers and dispensing equipment (faucet, pump, drip can) approved for
flammable liquids. Store containers in a cool, dry location, away from direct sunlight, sources of intense heat, or
where freezing is possible. Material should be stored in secondary containers or in a diked area, as appropriate.
Store containers away from incompatible chemicals (see Section 10, Stability and Reactivity). Containers should be
separated from oxidizing materials by a minimum distance of 20 ft. or by a barrier of non-combustible material at
least 5 ft. high having a fire-resistance rating of at least 0.5 hours. Storage areas should be made of fire resistant
materials. Post warning and "NO SMOKING" signs in storage and use areas, as appropriate. Have appropriate
extinguishing equipment in the storage area (i.e., sprinkler system, portable fire extinguishers). Inspect all incoming
containers before storage to ensure containers are properly labeled and not damaged. Refer to NFPA 30,
Flammable and Combustible Liquids Code, for additional information on storage. Empty containers may contain
residual liquid or vapors which are flammable; therefore, empty containers should be handled with care. Never
perform any welding, cutting, soldering, drilling, or other hot work on an empty container or piping until all liquid,
vapors, and residue have been cleared.
PROTECTIVE PRACTICES DURING MAINTENANCE OF CONTAMINATED EQUIPMENT: Follow practices
indicated in Section 6 (Accidental Release Measures). Make certain that application equipment is locked and
tagged-out safely, if necessary. Collect all rinsates and dispose of according to applicable U.S. Federal, State, or
local procedures and appropriate Canadian standards and those of European Union Member States.
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation. Use a mechanical fan or vent
area to outside. Where appropriate, use a non-sparking, grounded ventilation system separate from other exhaust
ventilation systems. Ensure eyewash/safety shower stations are available near areas where this product is used.
EXPOSURE LIMITS/GUIDELINES:
CHEMICAL NAME CAS # EXPOSURE LIMITS IN AIR
ACGIH-TLVs OSHA-PELs NIOSH-RELs NIOSH OTHER
TWA STEL TWA STEL TWA STEL IDLH
mg/m3 mg/m3
mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3
Acetic Acid Ethenyl Ester, Polymer with 25086-48-0 NE NE NE NE NE NE NE NE
Chloroethene and Ethenol
Benzenesulfonyl Isocyanate 4-Methyl 4083-64-1 NE NE NE NE NE NE NE NE
2-Butenedioic Acid (Z)-, Polymer with 9005-09-8 NE NE NE NE NE NE NE NE
Chloroethene and Ethenyl Acetate
NE = Not Established. NIC = Notice of Intended Change See Section 16 for Definitions of Terms Used.
TOTALSEAL SRP 5055 Bare Metal Etch Primer
PAGE 4 OF 14
8. EXPOSURE CONTROLS - PERSONAL PROTECTION
EXPOSURE LIMITS/GUIDELINES (continued):
CHEMICAL NAME CAS # EXPOSURE LIMITS IN AIR
ACGIH-TLVs OSHA-PELs NIOSH-RELs NIOSH OTHER
TWA STEL TWA STEL TWA STEL IDLH
mg/m3 mg/m3
mg/m3 mg/m3 mg/m3 mg/m3 mg/m3 mg/m3
Carbon Black 1333-86-4 3.5 NE 3.5 NE 3.5 NE 1750 DFG MAK: as inhalable fraction
Carcinogen: IARC-2B, MAK-3B,
NIOSH-Ca, TLV-A4
10 ppm
Chlorobenzene 108-90-7 NE 75 ppm NE NE NE 1000 DFG MAKs:
ppm TWA = 10 ppm
PEAK = 2稭AK 15 min. average
value, 1-hr interval
DFG MAK Pregnancy Risk
Classification: C
400 ppm
Ethyl Acetate 141-78-6 NE 400 ppm NE 400 ppm NE 2000 DFG MAKs:
ppm TWA = 400 ppm
(based PEAK = 2稭AK 15 min. average
on value, 1-hr interval
10%v DFG MAK Pregnancy Risk
of LEL) Classification: C
NE
4,4',4"- 2422-91-5 NE NE NE NE NE NE NE
Triphenylmethane
Triisocyanate
Triphenyl Phosphite 101-02-0 NE NE NE NE NE NE NE NE
Zeolite 1318-02-1 NE NE NE NE NE NE NE NE
NE = Not Established. NIC = Notice of Intended Change See Section 16 for Definitions of Terms Used.
INTERNATIONAL OCCUPATIONAL EXPOSURE LIMITS: In addition to the exposure limit values cited above, other
exposure limits have been established by various countries for the components of this mixture. Individual country
regulatory authorities should be checked to ensure no new limits are available.
CARBON BLACK: CHLOROBENZENE (continued):
Australia: TWA = 3 mg/m3, JAN 1993 Turkey: TWA = 75 ppm (350 mg/m3), JAN 1993
Belgium: TWA = 3.5 mg/m3, JAN 1993 United Kingdom: LTEL = 50 ppm (230 mg/m3), JAN 1993
Denmark: TWA = 3.5 mg/m3, JAN 1999 In Argentina, Bulgaria, Colombia, Jordan, Korea, New Zealand, Singapore,
Finland: TWA = 3.5 mg/m3, STEL = 7 mg/m3, JAN 1999 Vietnam check ACGIH TLV
France: VME = 3.5 mg/m3, JAN 1999 ETHYL ACETATE:
Norway: TWA = 3.5 mg/m3, JAN 1999 Australia: TWA = 400 ppm (1400 mg/m3), JAN 1993
The Philippines: TWA = 3.5 mg/m3, JAN 1993 Austria: MAK = 400 ppm (1400 mg/m3), JAN 1999
The Netherlands: MAC-TGG = 3.5 mg/m3, 2003 Belgium: TWA = 400 ppm (1440 mg/m3), JAN 1993
Sweden: NGV = 3 mg/m3 (dust), JAN 1999 Denmark: TWA = 150 ppm (540 mg/m3), JAN 1999
United Kingdom: TWA = 3.5 mg/m3, STEL = 7 mg/m3, SEP 2000 Finland: TWA = 300 ppm (1100 mg/m3), STEL = 500 ppm (1800 mg/m3), JAN
In Argentina, Bulgaria, Colombia, Jordan, Korea, New Zealand, Singapore, 1993
France: VME = 400 ppm (1400 mg/m3), JAN 1999
Vietnam, New Zealand, Singapore, Vietnam check ACGIH TLV
Germany: MAK = 400 ppm (1400 mg/m3), JAN 1999
CHLOROBENZENE:
Hungary: TWA = 400 mg/m3, STEL = 1200 mg/m3, JAN 1993
ARAB Republic of Egypt: TWA 1 ppm, JAN 1993
Australia: TWA = 75 ppm (350 mg/m3), JAN 1993 The Netherlands: MAC-TGG = 550 mg/m3, 2003
Austria: MAK = 50 ppm (230 mg/m3), JAN 1999 Norway: TWA = 150 ppm (550 mg/m3), JAN 1999
Belgium: TWA = 75 ppm (345 mg/m3), JAN 1993 The Philippines: TWA = 400 ppm (1400 mg/m3), JAN 1993
Denmark: TWA = 10 ppm (46 mg/m3), JAN 1999 Poland: MAC(TWA) = 200 ppm, MAC(STEL) = 600 mg/m3, JAN 1999
Finland: TWA = 50 ppm (230 mg/m3), STEL = 75 ppm (345 mg/m3), JAN 1999 Russia: TWA = 50 mg/m3, STEL = 200 mg/m3, JUN 2003
Sweden: NGV = 150 ppm (500 mg/m3), KTV = 300 ppm (1100 mg/m3), JAN
France: VME = 10 ppm, JAN 1999
Germany: MAK = 50 ppm (230 mg/m3), JAN 1999 1999
Japan: OEL = 10 ppm (46 mg/m3), JAN 1999 Switzerland: MAK-W = 400 ppm (1400 mg/m3), KZG-W = 800 ppm (2800
The Netherlands: MAC-TGG = 46 mg/m3, 2003 mg/m3), JAN 1999
Poland: MAC(TWA) = 50 mg/m3, STEL = 150 mg/m3, JAN 1999 Turkey: TWA = 400 ppm (1400 mg/m3), JAN 1993
Norway: TWA = 25 ppm (115 mg/m3), JAN 1999 United Kingdom: TWA = 400 ppm (1460 mg/m3), SEP 2000
Russia: TWA = 50 mg/m3, STEL = 100 mg/m3, Skin, JUN 2003 In New Zealand, Singapore, Vietnam check ACGIH TLV
Switzerland: MAK-W = 50 ppm (230 mg/m3), KZG-W = 100 ppm (460 mg/m3),
JAN 1999
The following information on appropriate Personal Protective Equipment is provided to assist employers in complying with
OSHA regulations found in 29 CFR Subpart I (beginning at 1910.132) or equivalent standard of Canada, EU Standards and
standards of EU member states, as well as those of Australia and its Provinces. Please reference applicable regulations and
standards for relevant details.
RESPIRATORY PROTECTION: Maintain airborne contaminant concentrations below guidelines listed in this
section, if applicable. If respiratory protection is needed, use only protection authorized in 29 CFR 1910.134 or
applicable State regulations. For operations in which mists or sprays of this product will be generated use only
respiratory protection authorized in the U.S. Federal OSHA Respiratory Protection Standard (29 CFR 1910.134), or
equivalent U.S. State standards, Canadian CSA Standard Z94.4-93, the European Standard EN149, and EU
member states, or the Australian Standard 1716-Respiratory Protective Devices, and Australian Standard 1715-
Selection, Use, and Maintenance of Respiratory Protective Devices.
TOTALSEAL SRP 5055 Bare Metal Etch Primer
PAGE 5 OF 14
8. EXPOSURE CONTROLS - PERSONAL PROTECTION (Continued)
RESPIRATORY PROTECTION (continued): The following are NIOSH respiratory protection recommendations are
for the main component in air.
ETHYL ACETATE
CONCENTRATION RESPIRATORY PROTECTION
Up to 2000 ppm: Any Supplied-Air Respirator (SAR) operated in a continuous-flow mode, or any Powered, Air-
Purifying Respirator (PAPR) with organic vapor cartridge(s), or any chemical cartridge respirator with
a full facepiece and organic vapor cartridge(s), or any air-purifying, full-facepiece respirator (gas
mask) with a chin-style, front- or back-mounted organic vapor canister, or any Self-Contained
Breathing Apparatus (SCBA) with a full facepiece, or any Supplied-Air Respirator (SAR) with a full
facepiece.
Emergency or Planned Entry into Unknown Concentrations or IDLH Conditions: Any SCBA that has a full facepiece and is
operated in a pressure-demand or other positive-pressure mode, or any SAR that has a full facepiece
and is operated in a pressure-demand or other positive-pressure mode in combination with an
auxiliary SCBA operated in pressure-demand or other positive-pressure mode.
Escape: Any air-purifying, full-facepiece respirator (gas mask) with a chin-style, front- or back-mounted
organic vapor canister, or any appropriate escape-type, SCBA.
EYE PROTECTION: If necessary, refer to U.S. OSHA 29 CFR 1910.133, the Canadian CSA Standard Z94.3-
M1982, Industrial Eye and Face Protectors, or the European Standard EN166 and the CR 13464:1999, or the
Australian Standard 1337-Eye Protection for Industrial Applications and Australian Standard 1336-Recommended
Practices for Eye Protection in the Industrial Environment for further information.
HAND PROTECTION: Natural rubber, neoprene, or nitrile rubber gloves. If necessary, refer to U.S. OSHA 29 CFR
1910.138 appropriate Standards of Canada, the European Standard CEN/TR 15419:2006 or the Australian
Standard 2161-Industrial Safety Gloves and Mittens for further information.
BODY PROTECTION: None normally needed under typical circumstances of use. If necessary, use body
protection appropriate for task (e.g., Tyvek suit, rubber apron). If necessary, refer appropriate Standards of
Canada, the European Standard CEN/TR 15419:2006 or the to Australian Standard 3765-Clothing for Protection
Against Hazardous Chemicals for further information. If a hazard of injury to the feet exists due to falling objects,
rolling objects, where objects may pierce the soles of the feet or where employee's feet may be exposed to electrical
hazards, as described in U.S. OSHA 29 CFR 1910.136 Canadian CSA Standard Z195-M1984, Protective
Footwear.
9. PHYSICAL and CHEMICAL PROPERTIES
RELATIVE VAPOR DENSITY (air = 1): Not established. EVAPORATION RATE (nBuAc = 1): Not established.
SPECIFIC GRAVITY (water = 1): < 1 MELTING/FREEZING POINT: Not established.
SOLUBILITY IN WATER: Insoluble. BOILING POINT: Not established.
VAPOR PRESSURE: > 110 kPa (1.10 bar) pH: Not established.
ODOR THRESHOLD: Not established for product. For Ethyl Acetate: 6.4-250 ppm (detection)
COEFFICIENT OF OIL/WATER DISTRIBUTION (PARTITION COEFFICIENT): Not established.
APPEARANCE, ODOR and COLOR: This product is a clear, colorless liquid with a fruity odor.
HOW TO DETECT THIS SUBSTANCE (warning properties): The odor of this product may act as a warning of this
product, but should not be relied upon conclusively.
10. STABILITY and REACTIVITY
STABILITY: Stable.
DECOMPOSITION PRODUCTS: The products of thermal decomposition of this material include irritating vapors
and toxic gases (e.g., carbon dioxide, carbon monoxide, nitrogen oxides, hydrogen cyanide, reactive hydrocarbons
and aldehydes).
MATERIALS WITH WHICH SUBSTANCE IS INCOMPATIBLE: This product is incompatible with strong oxidizing
agents (e.g. nitrates, perchlorates, peroxides), strong acids (e.g. sulfuric acid, oleum, and chlorosulfonic acid),
strong bases (decomposition [hydrolysis] can occur, releasing heat), potassium tert-butoxide.
HAZARDOUS POLYMERIZATION: Will not occur.
CONDITIONS TO AVOID: Contact with incompatible chemicals, exposure to elevated temperatures.
PART IV Is there any other useful information about this material?
11. TOXICOLOGICAL INFORMATION
TOXICITY DATA: The specific toxicology data available for the components of this product present in greater than 1
percent concentration are presented below:
CARBON BLACK: CARBON BLACK (continued): CARBON BLACK (continued):
LD50 (Oral-Rat) > 15400 mg/kg: Behavioral: TDLo (Skin-Rat) 11 gm/kg/4: Blood: pigmented or TDLo (Intravenous-Rat)10 mg/kg/2 minutes:
somnolence (general depressed activity) nucleated red blood cells; Liver: changes in liver Biochemical: Enzyme inhibition, induction, or
LD50 (Skin-Rabbit) > 3 gm/kg weight; Nutritional and Gross Metabolic: weight change in blood or tissue Levels: hepatic
TDLo (Intravenous-Rat) 10 mg/kg/2 minutes: Liver: loss or decreased weight gain microsomal mixed oxidase (dealkylation,
changes in liver weight; Blood: changes in spleen hydroxylation, etc.)
TOTALSEAL SRP 5055 Bare Metal Etch Primer
PAGE 6 OF 14
11. TOXICOLOGICAL INFORMATION (Continued)
TOXICITY DATA (continued):
CARBON BLACK (continued): CHLOROBENZENE (continued): ETHYL ACETATE (continued):
TCLo (Inhalation-Rat) 50 mg/m3/6 hours/90 days- TDLo (Oral-Rabbit) 441 mg/kg/63 weeks- Sex Chromosome Loss and Nondisjunction
intermittent: Lungs, Thorax, or Respiration: other intermittent: Gastrointestinal: gastritis; Liver: (Saccharomyces cerevisiae) 24,400 ppm
changes hepatitis (hepatocellular necrosis), zonal; Kidney, Cytogenetic Analysis (Hamster-Fibroblast) 9 gm/L
TCLo (Inhalation-Rat) 11,600 g/m3/18 hours/2 Urethra, Bladder: changes in tubules (including TRIPHENYL PHOSPHITE:
acute renal failure, acute tubular necrosis) Standard Draize Test (Skin-Human) 125 mg/48
years-intermittent: Tumorigenic: carcinogenic by
TDLo (Oral-Guinea Pig) 441 mg/kg/63 weeks- hours: Severe
RTECS criteria; Lungs, Thorax, or Respiration:
intermittent: Gastrointestinal: gastritis; Liver: Standard Draize Test (Skin-Rabbit) 500 mg:
tumors
hepatitis (hepatocellular necrosis), zonal; Kidney, Severe
Mutation in Microorganisms (Bacteria-Salmonella
Urethra, Bladder: changes in tubules (including Standard Draize Test (Skin-Rabbit) 20 mg/24
typhimurium) 1 mg/plate
DNA Adduct (Inhalation-Mouse) 6200 g/m3/16 acute renal failure, acute tubular necrosis) hours: Moderate
TDLo (Oral-Dog) 17712 mg/kg/93 days-intermittent: Standard Draize Test (Eye-Rabbit) 500 mg/24
hours/12 weeks-intermittent
DNA Damage (Human-Lymphocyte) 16 g/L/48 Blood: changes in leukocyte (WBC) count; hours: Mild
LC (Inhalation-Rat) > 6700 mg/m3/1 hour
Biochemical: Enzyme inhibition, induction, or
hours
change in blood or tissue levels: transaminases; LD50 (Oral-Rat) 444 mg/kg
CHLOROBENZENE:
Related to Chronic Data: death LD50 (Oral-Mouse) 1080 mg/kg
LC50 (Inhalation-Rat) 2965 ppm
LDLo (Subcutaneous-Rat) 7000 mg/kg LD50 (Subcutaneous-Rat) 2 gm/kg: Peripheral
LC50 (Inhalation-Mammal-species unspecified) 10
LDLo (Intraperitoneal-Guinea Pig, adult) 4100 mg/kg
gm/m3 Nerve and Sensation: flaccid paralysis without
LDLo (Intraperitoneal-guinea pig) 4100 mg/kg: anesthesia (usually neuromuscular blockage);
TCLo (Inhalation-Rat) 210 ppm/6 hours (6-15 days
Behavioral: muscle weakness; Liver: fatty liver Behavioral: tremor, muscle weakness
preg): Teratogenic effects
degeneration; Kidney, Urethra, Bladder: other LD50 (Subcutaneous-Cat) 300 mg/kg: Behavioral:
TCLo (Inhalation-Rat) 250 ppm/7 hours/24 weeks-
changes ataxia
intermittent: Liver: changes in liver weight; Blood:
Micronucleus Test (Intraperitoneal-mouse) 225 LD50 (Intraperitoneal-Rat) 250 mg/kg
other changes; Biochemical: Enzyme inhibition,
mg/kg/24 hours LD50 (Intraperitoneal-Mouse) 266 mg/kg
induction, or change in blood or tissue levels:
Cytogenetic Analysis (Intraperitoneal-mouse) 1 LD50 (Intraperitoneal-Cat) 100 mg/kg: Peripheral
transaminases
gm/kg
TCLo (Inhalation-Rat) 1 mg/m3/60 days-continuous: Nerve and Sensation: spastic paralysis with or
Mutation in Microorganisms (Lymphocyte-mouse) 70 without sensory change; Behavioral:
Brain and Coverings: recordings from specific
mg/L somnolence (general depressed activity), tremor
areas of CNS; Biochemical: Enzyme inhibition,
Mutation in Mammalian Somatic Cells (Lymphocyte- LD50 (Unreported-Rat) 1490 mg/kg: Behavioral:
induction, or change in blood or tissue levels:- true
mouse) 100 mg/L somnolence (general depressed activity),
cholinesterase, Metabolism (Intermediary):
Gene Conversion and Mitotic Recombination tremor, changes in motor activity (specific
Plasma proteins not involving coagulation
(Saccharomyces cerevisiae) 1000 ppm assay)
TCLo (Inhalation-Rat) 210 ppm/6 hours: female 6-15
Sister Chromatid Exchange (Hamster-Ovary) 300 LD50 (Intraperitoneal- Mammal: species
day(s) after conception: Reproductive: Specific
mg/L unspecified) 250 mg/kg: Brain and Coverings:
Developmental Abnormalities: hepatobiliary
other degenerative changes; Behavioral;
ETHYL ACETATE:
system
Standard Draize Test (Eye-Human) 400 ppm convulsions or effect on seizure threshold;
TCLo (Inhalation-Rabbit) 590 ppm/6 hours (6-18
TCLo (Inhalation-Human) 400 ppm: Sense Organs Cardiac: other changes
days preg): Reproductive effects
and Special Senses (Olfaction): effect, not LD50 (Unreported-Mouse) 1360 mg/kg: Behavioral:
TCLo (Inhalation-Rabbit) 250 ppm/7 hours/24
otherwise specified, (Eye): conjunctive irritation; somnolence (general depressed activity),
weeks-intermittent: Liver: changes in liver weight;
Lungs, Thorax, or Respiration: other changes tremor, changes in motor activity (specific
Blood: changes in serum composition (e.g. TP,
LD50 (Oral-Rat) 5620 mg/kg assay)
bilirubin, cholesterol); Biochemical: Enzyme
LD50 (Oral-Mouse) 4100 mg/kg: Behavioral: LDLo (Skin-Rabbit) 5 gm/kg: Behavioral:
inhibition, induction, or change in blood or tissue
somnolence (general depressed activity), changes somnolence (general depressed activity)
levels: transaminases
in motor activity (specific assay), coma LDLo (Oral-Chicken) 250 mg/kg: Behavioral:
TCLo (Inhalation-Rabbit) 10 ppm/6 hours: female 6-
LD50 (Oral-Rabbit) 4935 mg/kg ataxia
18 day(s) after conception: Reproductive: Specific
LD50 (Oral-Guinea Pig) 5500 mg/kg: Behavioral: LDLo (Subcutaneous-Chicken) 375 mg/kg:
Developmental Abnormalities: musculoskeletal
somnolence (general depressed activity), changes Behavioral: food intake (animal), ataxia
system
LCLo (Inhalation-Mouse) 15 g/m3 in motor activity (specific assay), coma LDLo (Intravenous-Chicken) 50 mg/kg: Autonomic
LD50 (Skin-Rabbit) > 20 mL/kg Nervous System: ganglion blocker
LD50 (Oral-Rat) 2290 mg/kg
LD50 (Intraperitoneal-Mouse) 709 mg/kg TDLo (Subcutaneous-Rat) 3552 mg/kg/7 days-
LD50 (Oral-Rat) 1110 mg/kg: Behavioral:
LD50 (Subcutaneous-Cat) 3 gm/kg: Behavioral: intermittent: Brain and Coverings: recordings
somnolence (general depressed activity), tremor,
somnolence (general depressed activity); from specific areas of CNS; Autonomic Nervous
ataxia
Gastrointestinal: nausea or vomiting; Blood: other System: other (direct) parasympathomimetic;
LD50 (Oral-Mouse) 2300 mg/kg
changes Behavioral: ataxia
LD50 (Oral-Rabbit, adult) 2830 mg/kg
LD50 (Subcutaneous-Guinea Pig) 3 gm/kg: TDLo (Subcutaneous-Mammal: Species
LD50 (Oral-Rabbit) 2250 mg/kg
Behavioral: somnolence (general depressed Unspecified) 1184 mg/kg: Spinal Cord: other
LD50 (Oral-Guinea Pig) 2250 mg/kg
activity) degenerative changes; Sense Organs and
LD50 (Oral-Mammal-species unspecified) 2300
LC50 (Inhalation-Rat) 200 gm/m3: Behavioral: Special Senses (Eye): optic nerve neuropathy,
mg/kg
somnolence (general depressed activity); Lungs, effect, not otherwise specified
LD50 (Intraperitoneal-Rat) 1655 mg/kg
Thorax, or Respiration: acute pulmonary edema; TDLo (Subcutaneous-Mammal: Species
LD50 (Intraperitoneal-Mouse) 515 mg/kg
Gastrointestinal: changes in structure or function Unspecified) 1184 mg/kg: Brain and Coverings:
LD50 (Unreported-Mammal-species unspecified)
of salivary glands other degenerative changes; Sense Organs and
2300 mg/kg
LC50 (Inhalation-Mouse) 45 gm/m3/2 hours Special Senses (Eye): optic nerve neuropathy,
LD (Skin-rabbit) > 2200 mg/kg
LDLo (Subcutaneous-Rat) 5 gm/kg retinal changes (pigmentary depositions,
LD (Skin-Guinea Pig) > 11 gm/kg
LCLo (Inhalation-Cat) 61 gm/m3 retinitis, other)
TDLo (Oral-Rat) 14 gm/kg/14 days-intermittent:
TCLo (Inhalation-Mouse) 200 ppm/6 minutes: TDLo (Skin-Chicken) 5 gm/kg/5 days-intermittent:
Behavioral: somnolence (general depressed
Lungs, Thorax, or Respiration: respiratory Behavioral: ataxia; Skin and Appendages:
activity); Related to Chronic Data: death
depression dermatitis, other (after systemic exposure);
TDLo (Oral-Rat) 32,500 mg/kg/13 weeks-
TCLo (Inhalation-Rat) 1500 ppm/90 days- Biochemical: Enzyme inhibition, induction, or
intermittent: Liver: changes in liver weight;
intermittent: Sense Organs and Special Senses change in blood or tissue levels: true
Biochemical: Enzyme inhibition, induction, or
(Olfaction): change in sensation of smell, effect, cholinesterase
change in blood or tissue levels: peptidases;
not otherwise specified TCLo (Inhalation- Mammal: Species Unspecified)
Related to Chronic Data: death
TCLo (Inhalation-Dog) 22 gm/m3/40 minutes/4 Blood: changes in erythrocyte (RBC) count,
TDLo (Oral-Rat) 27300 g/kg/39 weeks-intermittent:
weeks-intermittent: Behavioral: ataxia; Lungs, changes in leukocyte (WBC) count; Nutritional
Blood: pigmented or nucleated red blood cells,
Thorax, or Respiration: respiratory stimulation; and Gross Metabolic: weight loss or decreased
eosinophilia, changes in erythrocyte (RBC) count
Nutritional and Gross Metabolic: body temperature weight gain
TDLo (Oral-Rat): 61800 mg/kg/2 years-intermittent:
decrease ZEOLITES:
Tumorigenic: neoplastic by RTECS criteria; Liver:
TDLo (Intraperitoneal-Rat) 8 mL/kg/8 days- TDLo (Oral-Mouse) 1050 gm/kg/30 days-
tumors; Blood: tumors
intermittent: Liver: other changes; Biochemical: continuous: Blood: changes in leukocyte (WBC)
TDLo (Oral-Mouse) 16,250 mg/kg/13 weeks-
Enzyme inhibition, induction, or change in blood or count; Nutritional and Gross Metabolic: changes
intermittent: Liver: hepatitis (hepatocellular
tissue levels: phosphatases, Metabolism in sodium
necrosis), diffuse; Kidney, Urethra, Bladder: other
(Intermediary): other carbohydrates Cytogenetic Analysis (Human-Lymphocyte) 50
changes in urine composition; Related to Chronic
mg/L
Data: death
Cytogenetic Analysis (Intraperitoneal-Mouse) 50
mg/kg
TOTALSEAL SRP 5055 Bare Metal Etch Primer
PAGE 7 OF 14
11. TOXICOLOGICAL INFORMATION (Continued)
SUSPECTED CANCER AGENT: The components of this product are listed by agencies tracking potential
carcinogenic effects, as follows:
CARBON BLACK: ACGIH TLV-A4 (Not Classifiable as a Human Carcinogen); IARC-2B (Possibly Carcinogenic to Humans); MAK-3B (Substances Which Cause
Concern that They Could Be Carcinogenic for Man. Substances for which in vitro tests or animal studies have yielded evidence of carcinogenic effects that is not
sufficient for classification of the substances in one of the other categories. Further studies are required before a final classification can be made.)
CHLOROBENZENE: ACGIH TLV-A3 (Confirmed Animal Carcinogen); EPA-D (Not Classifiable as to Human Carcinogenicity)
The remaining components are not found on the following lists: FEDERAL OSHA Z LIST, NTP, IARC, and
CAL/OSHA, and therefore are neither considered to be nor suspected to be cancer-causing agents by these
agencies.
IRRITANCY OF PRODUCT: This product would be moderately irritating to contaminated skin, eyes and mucous
membranes.
SENSITIZATION TO THE PRODUCT: The 4,4',4"-Triphenylmethane Triisocyanate and other trace components of
this product are suspect skin and respiratory sensitizers. Subsequent exposure to susceptible individuals may result
in allergic respiratory and/or reaction.
REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product and
its components on the human reproductive system.
Mutagenicity: This product is not reported to produce mutagenic effects in humans.
Embryotoxicity: This product is not reported to produce embryotoxic effects in humans.
Teratogenicity: This product is not reported to cause teratogenic effects in humans.
Reproductive Toxicity: This product is not reported to cause reproductive effects in humans.
A mutagen is a chemical which causes permanent changes to genetic material (DNA) such that the changes will propagate
through generational lines. An embryotoxin is a chemical which causes damage to a developing embryo (i.e. within the first
eight weeks of pregnancy in humans), but the damage does not propagate across generational lines. A teratogen is a
chemical which causes damage to a developing fetus, but the damage does not propagate across generational lines. A
reproductive toxin is any substance which interferes in any way with the reproductive process.
SYNERGISTIC EFFECTS: None known.
BIOLOGICAL EXPOSURES INDICES (BEIs): Currently, there are ACGIH Biological Exposure Indices (BEIs)
determined for the trace Chlorobenzene component of this product.
CHEMICAL: SAMPLING TIME BEI
DETERMINANT
Chlorobenzene
?End of shift
?Total 4-Chlorocatechol in urine ?150 mg/g creatinine
?End of shift
?Total p-Chlorocatechol in urine ?25 mg/g creatinine
12. ECOLOGICAL INFORMATION
ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.
ENVIRONMENTAL STABILITY: The components of this product are relatively stable under ambient environmental
conditions.
EFFECT OF MATERIAL ON PLANTS or ANIMALS: This product may be harmful to contaminated terrestrial plants
and animals.
EFFECT OF CHEMICAL ON AQUATIC LIFE: This product may cause harm to an aquatic environment, especially if
released in large quantities.
13. DISPOSAL CONSIDERATIONS
PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate U.S. Federal,
State, and local regulations or with regulations of Canada and those of European Member States. This product, if
unaltered by use, may be disposed of by treatment at a permitted facility or as advised by your local waste regulatory
authority. Empty containers, as defined by appropriate sections of RCRA, are not RCRA hazardous wastes. Insure
proper management of any residuals remaining in containers.
EPA WASTE NUMBER: D001, Characteristic-Ignitability
14. TRANSPORTATION INFORMATION
THIS PRODUCT IS HAZARDOUS AS DEFINED BY 49 CFR 172.101 BY THE U.S. DEPARTMENT OF
TRANSPORTATION.
PROPER SHIPPING NAME: Paint related material
HAZARD CLASS NUMBER and DESCRIPTION: 3 (Flammable)
UN IDENTIFICATION NUMBER: UN 1263
DOT LABEL(S) REQUIRED: Class 3 (Flammable)
PACKAGING GROUP: II
NORTH AMERICAN RESPONSE GUIDEBOOK NUMBER (2004): 128
MARINE POLLUTANT: The components of this product are not listed as a marine pollutant as per D.O.T. (49 CFR 172.101,
Appendix B).
TOTALSEAL SRP 5055 Bare Metal Etch Primer
PAGE 8 OF 14
14. TRANSPORTATION INFORMATION (Continued)
TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is
classified as Dangerous Goods, per regulations of Transport Canada. The use of the above U.S. DOT information
from the U.S. 49 CFR regulations is allowed for shipments that originate in the U.S. For shipments via ground
vehicle or rail that originate in Canada, the following information is applicable.
PROPER SHIPPING NAME: Paint related material
HAZARD CLASS NUMBER and DESCRIPTION: 3 (Flammable)
UN IDENTIFICATION NUMBER: UN 1263
PACKING GROUP: II
HAZARD LABEL(S) REQUIRED: Class 3 (Flammable)
SPECIAL PROVISIONS: 59
EXPLOSIVE LIMIT & LIMITED QUANTITY INDEX: 5
ERAP INDEX: None
PASSENGER CARRYING SHIP INDEX: None
PASSENGER CARRYING ROAD OR RAIL VEHICLE INDEX: 5
MARINE POLLUTANT: Not applicable.
INTERNATIONAL AIR TRANSPORT ASSOCIATION DESIGNATION: This product is classified as dangerous
goods, per rules of IATA.
UN IDENTIFICATION NUMBER: UN 1263
PROPER SHIPPING NAME: Paint related material
HAZARD CLASS NUMBER and DESCRIPTION: 3 (Flammable)
PACKING GROUP: II
HAZARD LABEL(S) REQUIRED: Class 3 (Flammable)
PASSENGER and CARGO AIRCRAFT PACKING INSTRUCTION: 305
PASSENGER and CARGO AIRCRAFT MAXIMUM NET QUANTITY PER PKG:5 L
PASSENGER and CARGO AIRCRAFT LIMITED QUANTITY PACKING INSTRUCTION: Y305
PASSENGER and CARGO AIRCRAFT LIMITED QUANTITY MAXIMUM NET QUANTITY PER PKG: 1 L
CARGO AIRCRAFT ONLY PACKING INSTRUCTION: 307
CARGO AIRCRAFT ONLY MAXIMUM NET QUANTITY PER PKG: 60 L
SPECIAL PROVISIONS: A72
ERG CODE: 3L
INTERNATIONAL MARITIME ORGANIZATION (IMO): This product is classified as dangerous goods, per rules of
the IMO, as follows:
PROPER SHIPPING NAME: Paint related material
HAZARD CLASS NUMBER and DESCRIPTION: 3 (Flammable)
UN IDENTIFICATION NUMBER: UN 1263
PACKING GROUP: II
HAZARD LABEL(S) REQUIRED: Class 3 (Flammable)
SPECIAL PROVISIONS: 163, 944
LIMITED QUANTITIES: 5L
PACKING INSTRUCTIONS: P001
PROVISIONS: PP1
IBC INSTRUCTIONS: IBC02
IBC PROVISIONS: None
EmS: F-E, S-E
STOWAGE CATEGORY: Category B
MARINE POLLUTANT: The components of this product are not designated by the IMO to be a Marine Pollutant.
AUSTRALIAN FEDERAL OFFICE OF ROAD SAFETY CODE FOR THE TRANSPORTATION OF DANGEROUS
GOODS BY ROAD OR RAIL: This product is considered as dangerous goods, per regulations of the Federal Office
of Road Safety, as follows:
UN IDENTIFICATION NUMBER: UN 1263
NAME OF SUBSTANCE: Paint related material
HAZARD CLASS: 3 (Flammable)
PACKING GROUP: II
HAZCHEM CODE: 3[Y]E
SPECIAL PROVISIONS: SP163, SP185, SP187
PACKAGING CODE: 3.8.3 RT1
TOTALSEAL SRP 5055 Bare Metal Etch Primer
PAGE 9 OF 14
15. REGULATORY INFORMATION
U.S. STATE AND FEDERAL REGULATIONS:
U.S. SARA REPORTING REQUIREMENTS: The components of this product are subject to the reporting
requirements of Sections 302, 304, and 313 of Title III of the Superfund Amendments and Reauthorization Act as
follows:
CHEMICAL NAME SARA 302 SARA 304 SARA 313
(40 CFR 355, Appendix A) (40 CFR Table 302.4) (40 CFR 372.65)
Chlorobenzene No No Yes
U.S. SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for this
product. The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb (4,540 kg)
may apply, per 40 CFR 370.20.
U.S. CERCLA REPORTABLE QUANTITY (RQ): Chlorobenzene = 100 lb (0.45 kg); Ethyl Acetate = 5000 lb (2270
kg)
U.S. TSCA INVENTORY STATUS: The components of this product are listed on the TSCA Inventory.
OTHER U.S. FEDERAL REGULATIONS:
CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT (PROPOSITION 65): No component
of this product is on the California Proposition 65 lists.
U.S. ANSI STANDARD LABELING (Z129.1): DANGER! FLAMMABLE LIQUID AND VAPORS. FLASH POINT -
5癈 (23癋). CAUSES SKIN, AND EYE IRRITATION. HARMFUL IF INHALED OR INGESTED. CONTAINS
POSSIBLE RESPIRATORY AND SKIN SENSITIZERS. ASPIRATION HAZARD - INGESTION CAN CAUSE LIFE-
THREATENING LUNG DAMAGE. Keep away from heat, spark or flame. Do not taste or swallow. Do not get on
skin or in eyes. Avoid breathing vapors or mist. Keep container closed. Use only with adequate ventilation. Wash
thoroughly after handling. Wear gloves, goggles, respiratory protection and eye protection, as appropriate. FIRST-
AID: In case of contact, immediately flush skin or eyes with plenty of water for at least 15 minutes. If inhaled, remove
to fresh air. If ingested, do not induce vomiting and get medical attention. Get medical attention if any adverse
reaction occurs. IN CASE OF FIRE: Use water fog (for cooling of containers), dry chemical, CO2, or "alcohol" foam.
IN CASE OF SPILL: Absorb spill with inert material. Replace residue in suitable container. Consult Material Safety
Data Sheet for additional information.
ADDITIONAL CANADIAN REGULATIONS:
CANADIAN DSL INVENTORY: The components of this product are listed on the DSL Inventory.
CANADIAN WHMIS IDL DISCLOSURE STATUS:
OTHER CANADIAN REGULATIONS: Not applicable.
CANADIAN ENVIRONMENTAL PROTECTION AGENCY (CEPA) PRIORITY SUBSTANCES LISTS: The
components of this product are not on the Priority Substances Lists.
CANADIAN WHMIS CLASSIFICATION and SYMBOLS:
Class B2: Flammable Liquid
Class D2A: Poisonous and Infectious Material, Chronic effects ?Skin and Respiratory Sensitizer.
TOTALSEAL SRP 5055 Bare Metal Etch Primer
PAGE 10 OF 14
15. REGULATORY INFORMATION (Continued)
AUSTRALIAN INFORMATION FOR PRODUCT:
AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES (AICS) STATUS: The components of this product listed by CAS
number in Section 2 (Composition and Information on Ingredients) are listed on the AICS.
HAZARDOUS SUBSTANCES INFORMATION SYSTEM (HSIS): Chlorobenzene, Triphenyl Phosphite, Ethyl Acetate and
Carbon Black are listed in the HSIS.
HAZARD CLASSIFICATION: [F]: Highly Flammable. [Xi]: Irritant.
RISK PHRASES: [R: 11]: Highly Flammable. [R: 36/37/38]: Irritating to eyes, respiratory system and skin. [R: 42/43]: May
cause sensitization by inhalation and skin contact. [R: 66]: Repeated exposure may cause skin dryness or cracking. [R: 67]:
Vapour may cause drowsiness and dizziness. [R: 51/53]: Toxic to aquatic organisms, may cause long-term adverse
effects in the aquatic environment.
SAFETY PHRASES: [S: 2?]: Keep locked-up and out of reach of children. (This safety phrase can be omitted from the label
when the substance or preparation is sold for industrial use only.); [S: 16]: Keep away from sources of ignition ?No smoking.
[S: 26]: In case of contact with the eyes, rinse immediately with plenty of water and seek immediate medical attention. [S:
28]: After contact with skin wash immediately with plenty of water. [S: 33]: Take precautionary measures against static
discharges. [S: 61]: Avoid release to the environment. Refer to special instructions/Safety data sheets.
POISONS SCHEDULE NUMBERS: 6
16. OTHER INFORMATION
PREPARED BY: CHEMICAL SAFETY ASSOCIATES, Inc.
PO Box 3519, La Mesa, CA 91944-3519
(800) 441-3365
DATE OF PRINTING: June 7, 2007
The information contained herein is based on data considered accurate. However, no warranty is expressed or implied regarding the accuracy of these data or
the results to be obtained from the use thereof. Shat-R-Proof assumes no responsibility for injury to the vendee or third persons proximately caused by the
material if reasonable safety procedures are not adhered to as stipulated in the data sheet. Additionally, Shat-R-Proof assumes no responsibility for injury to
vendee or third persons proximately caused by abnormal use of the material even if reasonable safety procedures are followed. Furthermore, vendee assumes
the risk in his use of the material.
TOTALSEAL SRP 5055 Bare Metal Etch Primer
PAGE 11 OF 14
DEFINITIONS OF TERMS
A large number of abbreviations and acronyms appear on a MSDS. Some of these, which are commonly used, include the following:
CAS #: This is the Chemical Abstract Service Number that uniquely identifies EXPOSURE LIMITS IN AIR (continued):
each constituent. Time Weighted Average exposure
TWA-Time Weighted Average:
EXPOSURE LIMITS IN AIR: concentration for a conventional 8-hr (TLV, PEL) or up to a 10-hr (REL) workday
and a 40-hr workweek.
CEILING LEVEL: The concentration that shall not be exceeded during any part
of the working exposure. HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
DFG MAK Germ Cell Mutagen Categories: 1: Germ cell mutagens which have
HAZARD RATINGS: This rating system was developed by the National
been shown to increase the mutant frequency in the progeny of exposed humans.
Paint and Coating Association and has been adopted by industry to identify the
2: Germ cell mutagens which have been shown to increase the mutant
degree of chemical hazards.
frequency in the progeny of exposed mammals. 3A: Substances which have
HEALTH HAZARD:
been shown to induce genetic damage in germ cells of human of animals, or
0 (Minimal Hazard: No significant health risk, irritation of skin or eyes not
which produce mutagenic effects in somatic cells of mammals in vivo and have
anticipated. Skin Irritation: Essentially non-irritating. PII or Draize = "0". Eye
been shown to reach the germ cells in an active form. 3B: Substances which are
Irritation: Essentially non-irritating, or minimal effects which clear in < 24 hours
suspected of being germ cell mutagens because of their genotoxic effects in
[e.g. mechanical irritation]. Draize = "0". Oral Toxicity LD50 Rat: < 5000 mg/kg.
mammalian somatic cell in vivo; in exceptional cases, substances for which there
Dermal Toxicity LD50Rat or Rabbit: < 2000 mg/kg. Inhalation Toxicity 4-hrs LC50
are no in vivo data, but which are clearly mutagenic in vitro and structurally
Rat: < 20 mg/L.); 1 (Slight Hazard: Minor reversible Injury may occur; slightly or
related to known in vivo mutagens. 4: Not applicable (Category 4 carcinogenic
mildly irritating. Skin Irritation: Slightly or mildly irritating. Eye Irritation: Slightly or
substances are those with non-genotoxic mechanisms of action. By definition,
mildly irritating. Oral Toxicity LD50 Rat: > 500-5000 mg/kg. Dermal Toxicity
germ cell mutagens are genotoxic. Therefore, a Category 4 for germ cell
LD50Rat or Rabbit: > 1000-2000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 2-20
mutagens cannot apply. At some time in the future, it is conceivable that a
mg/L); 2 (Moderate Hazard: Temporary or transitory injury may occur. Skin
Category 4 could be established for genotoxic substances with primary targets
Irritation: Moderately irritating; primary irritant; sensitizer. PII or Draize > 0, < 5.
other than DNA [e.g. purely aneugenic substances] if research results make this
Eye Irritation: Moderately to severely irritating and/or corrosive; reversible corneal
seem sensible.) 5: Germ cell mutagens, the potency of which is considered to be
opacity; corneal involvement or irritation clearing in 8-21 days. Draize > 0, < 25.
so low that, provided the MAK value is observed, their contribution to genetic risk
Oral Toxicity LD50 Rat: > 50-500 mg/kg. Dermal Toxicity LD50Rat or Rabbit: >
for humans is expected not to be significant.
200-1000 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: > 0.5-2 mg/L.); 3 (Serious
DFG MAK Pregnancy Risk Group Classification: Group A: A risk of damage
Hazard: Major injury likely unless prompt action is taken and medical treatment is
to the developing embryo or fetus has been unequivocally demonstrated.
given; high level of toxicity; corrosive. Skin Irritation: Severely irritating and/or
Exposure of pregnant women can lead to damage of the developing organism,
corrosive; may destroy dermal tissue, cause skin burns, dermal necrosis. PII or
even when MAK and BAT (Biological Tolerance Value for Working Materials)
Draize > 5-8 with destruction of tissue. Eye Irritation: Corrosive, irreversible
values are observed. Group B: Currently available information indicates a risk of
destruction of ocular tissue; corneal involvement or irritation persisting for more
damage to the developing embryo or fetus must be considered to be probable.
than 21 days. Draize > 80 with effects irreversible in 21 days. Oral Toxicity LD50
Damage to the developing organism cannot be excluded when pregnant women
Rat: > 1-50 mg/kg. Dermal Toxicity LD50Rat or Rabbit: > 20-200 mg/kg.
are exposed, even when MAK and BAT values are observed. Group C: There is
Inhalation Toxicity LC50 4-hrs Rat: > 0.05-0.5 mg/L.); 4 (Severe Hazard: Life-
no reason to fear a risk of damage to the developing embryo or fetus when MAK
threatening; major or permanent damage may result from single or repeated
and BAT values are observed. Group D: Classification in one of the groups A-C
exposure. Skin Irritation: Not appropriate. Do not rate as a "4", based on skin
is not yet possible because, although the data available may indicate a trend, they
irritation alone. Eye Irritation: Not appropriate. Do not rate as a "4", based on eye
are not sufficient for final evaluation.
irritation alone. Oral Toxicity LD50 Rat: < 1 mg/kg. Dermal Toxicity LD50Rat or
IDLH-Immediately Dangerous to Life and Health: This level represents a
Rabbit: < 20 mg/kg. Inhalation Toxicity LC50 4-hrs Rat: < 0.05 mg/L).
concentration from which one can escape within 30-minutes without suffering
FLAMMABILITY HAZARD:
escape-preventing or permanent injury.
0 (Minimal Hazard-Materials that will not burn in air when exposure to a
LOQ: Limit of Quantitation.
temperature of 815.5癈 [1500癋] for a period of 5 minutes.); 1 (Slight Hazard-
SKIN: Used when a there is a danger of cutaneous absorption.
Materials that must be pre-heated before ignition can occur. Material require
STEL-Short Term Exposure Limit: Short Term Exposure Limit, usually a 15-
considerable pre-heating, under all ambient temperature conditions before
minute time-weighted average (TWA) exposure that should not be exceeded at
ignition and combustion can occur, Including: Materials that will burn in air when
any time during a workday, even if the 8-hr TWA is within the TLV-TWA, PEL-
exposed to a temperature of 815.5癈 (1500癋) for a period of 5 minutes or less;
TWA or REL-TWA.
Liquids, solids and semisolids having a flash point at or above 93.3癈 [200癋]
TLV-Threshold Limit Value: An airborne concentration of a substance that
(e.g. OSHA Class IIIB, or; Most ordinary combustible materials [e.g. wood, paper,
represents conditions under which it is generally believed that nearly all workers
etc.];
may be repeatedly exposed without adverse effect. The duration must be
considered, including the 8-hour.
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PAGE 12 OF 14
DEFINITIONS OF TERMS (Continued)
HAZARDOUS MATERIALS IDENTIFICATION SYSTEM HAZARDOUS MATERIALS IDENTIFICATION SYSTEM
HAZARD RATINGS (continued): HAZARD RATINGS (continued):
FLAMMABILITY HAZARD (continued): PHYSICAL HAZARD (continued):
2 (Moderate Hazard-Materials that must be moderately heated or exposed to 3 (continued): Compressed Gases: Pressure > 514.7 psi absolute at 21.1癈
relatively high ambient temperatures before ignition can occur. Materials in this (70癋) [500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group I Solids:
degree would not, under normal conditions, form hazardous atmospheres in air, any material that, in either concentration tested, exhibits a mean burning time less
but under high ambient temperatures or moderate heating may release vapor in than the mean burning time of a 3.:2 potassium bromate/cellulose mixture.
sufficient quantities to produce hazardous atmospheres in air, Including: Liquids Liquids: Any material that spontaneously ignites when mixed with cellulose in a
having a flash-point at or above 37.8癈 [100癋] Solid materials in the form of 1:1 ratio, or which exhibits a mean pressure rise time less than the pressure rise
course dusts that may burn rapidly but that generally do not form explosive time of a 1:1 perchloric acid (50%)/cellulose mixture. Unstable Reactives:
atmospheres; Solid materials in a fibrous or shredded form that may burn rapidly Substances that may polymerize, decompose, condense or self-react at ambient
and create flash fire hazards (e.g. cotton, sisal, hemp; Solids and semisolids that temperature and/or pressure and have a moderate potential to cause significant
readily give off flammable vapors.); 3 (Serious Hazard- Liquids and solids that can heat generation or explosion.); 4 (Water Reactivity: Materials that react
be ignited under almost all ambient temperature conditions. Materials in this explosively with water without requiring heat or confinement. Organic Peroxides:
degree produce hazardous atmospheres with air under almost all ambient Materials that are readily capable of detonation or explosive decomposition at
temperatures, or, unaffected by ambient temperature, are readily ignited under normal temperature and pressures. Explosives: Division 1.1 & 1.2-explosive
substances that have a mass explosion hazard or have a projection hazard. A
almost all conditions, including: Liquids having a flash point below 22.8癈 [73癋]
mass explosion is one that affects almost the entire load instantaneously.
and having a boiling point at or above 38癈 [100癋] and below 37.8癈 [100癋]
Compressed Gases: No Rating. Pyrophorics: Add to the definition of
[e.g. OSHA Class IB and IC]; Materials that on account of their physical form or
Flammability "4". Oxidizers: No "4" rating. Unstable Reactives: Substances that
environmental conditions can form explosive mixtures with air and are readily
may polymerize, decompose, condense or self-react at ambient temperature
dispersed in air [e.g., dusts of combustible solids, mists or droplets of flammable
and/or pressure and have a high potential to cause significant heat generation or
liquids]; Materials that burn extremely rapidly, usually by reason of self-contained
explosion.).
oxygen [e.g. dry nitrocellulose and many organic peroxides]); 4 (Severe Hazard-
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD
Materials that will rapidly or completely vaporize at atmospheric pressure and
normal ambient temperature or that are readily dispersed in air, and which will RATINGS:
burn readily, including: Flammable gases; Flammable cryogenic materials; Any HEALTH HAZARD: 0 (materials that, under emergency conditions, would offer no
liquid or gaseous material that is liquid while under pressure and has a flash point hazard beyond that of ordinary combustible materials): Gases and vapors whose
below 22.8癈 [73癋] and a boiling point below 37.8癈 [100癋] [e.g. OSHA Class LC50 for acute inhalation toxicity is greater than 10,000 ppm. Dusts and mists
IA; Material that ignite spontaneously when exposed to air at a temperature of whose LC50 for acute inhalation toxicity is greater than 200 mg/L. Materials
54.4癈 [130癋] or below [e.g. pyrophoric]). whose LD50 for acute dermal toxicity is greater than 2000 mg/kg. Materials
PHYSICAL HAZARD: whose LD50 for acute oral toxicity is greater than 2000 mg/kg. Materials that
0 (Water Reactivity: Materials that do not react with water. Organic Peroxides: are essentially non-irritating to the respiratory tract, eyes and skin. 1
Materials that are normally stable, even under fire conditions and will not react (materials that, under emergency conditions, can cause significant irritation):
with water. Substances that are Non-Explosive. Unstable
Explosives: Gases and vapors whose LC50 for acute inhalation toxicity is greater than
Compressed Gases: No Rating. Pyrophorics: No Rating. Oxidizers: No "0" 5,000 ppm but less than or equal to 10,000 ppm. Dusts and mists whose LC50
rating allowed. Unstable Reactives: Substances that will not polymerize, for acute inhalation toxicity is greater than 10 mg/L but less than or equal to
decompose, condense or self-react.); 1 (Water Reactivity: Materials that change 200 mg/L. Materials whose LD50 for acute dermal toxicity is greater than 1000
or decompose upon exposure to moisture. Organic Peroxides: Materials that are mg/kg but less than or equal to 2000 mg/kg. Materials whose LD50 for acute
normally stable, but can become unstable at high temperatures and pressures. oral toxicity is greater than 500 mg/kg but less than or equal to 2000 mg/kg.
These materials may react with water, but will not release energy. Explosives: Materials that cause slight to moderate irritation to the respiratory tract, eyes
Division 1.5 & 1.6 substances that are very insensitive explosives or that do not and skin. 2 (materials that, under emergency conditions, can cause temporary
have a mass explosion hazard. Compressed Gases: Pressure below OSHA incapacitation or residual injury): Gases and vapors whose LC50 for acute
definition. Pyrophorics: No Rating. Oxidizers: Packaging Group III; Solids: any inhalation toxicity is greater than 3,000 ppm but less than or equal to 5,000
material that in either concentration tested, exhibits a mean burning time less ppm. Dusts and mists whose LC50 for acute inhalation toxicity is greater than 2
than or equal to the mean burning time of a 3:7 potassium bromate/cellulose mg/L but less than or equal to 10 mg/L. Materials whose LD50 for acute dermal
mixture and the criteria for Packing Group I and II are not met. Liquids: any toxicity is greater than 200 mg/kg but less than or equal to 1000 mg/kg.
material that exhibits a mean pressure rise time less than or equal to the pressure Materials whose LD50 for acute oral toxicity is greater than 50 mg/kg but less
rise time of a 1:1 nitric acid (65%)/cellulose mixture and the criteria for Packing than or equal to 500 mg/kg. Any liquid whose saturated vapor concentration
Group I and II are not met. Unstable Reactives: Substances that may at 20癈 (68癋) is equal to or greater than one-fifth its LC50 for acute inhalation
decompose, condense or self-react, but only under conditions of high toxicity, if its LC50 is less than or equal to 5000 ppm and that does not meet
temperature and/or pressure and have little or no potential to cause significant the criteria for either degree of hazard 3 or degree of hazard 4. Compressed
heat generation or explosive hazard. Substances that readily undergo hazardous liquefied gases with boiling points between -30癈 (-22癋) and -55癈 (-66.5癋)
polymerization in the absence of inhibitors.); 2 (Water Reactivity: Materials that that cause severe tissue damage, depending on duration of exposure.
may react violently with water. Organic Peroxides: Materials that, in themselves, Materials that are respiratory irritants. Materials that cause severe, but
are normally unstable and will readily undergo violent chemical change, but will reversible irritation to the eyes or are lachrymators. Materials that are primary
not detonate. These materials may also react violently with water. Explosives: skin irritants or sensitizers. 3 (materials that, under emergency conditions, can
Division 1.4 ?Explosive substances where the explosive effect are largely cause serious or permanent injury): Gases and vapors whose LC50 for acute
confined to the package and no projection of fragments of appreciable size or inhalation toxicity is greater than 1,000 ppm but less than or equal to 3,000
range are expected. An external fire must not cause virtually instantaneous ppm. Dusts and mists whose LC50 for acute inhalation toxicity is greater than
explosion of almost the entire contents of the package. Compressed Gases: 0.5 mg/L but less than or equal to 2 mg/L. Materials whose LD50 for acute
Pressurized and meet OSHA definition but < 514.7 psi absolute at 21.1癈 (70癋) dermal toxicity is greater than 40 mg/kg but less than or equal to 200 mg/kg.
[500 psig]. Pyrophorics: No Rating. Oxidizers: Packing Group II Solids: any Materials whose LD50 for acute oral toxicity is greater than 5 mg/kg but less
material that, either in concentration tested, exhibits a mean burning time of less than or equal to 50 mg/kg. Any liquid whose saturated vapor concentration at
than or equal to the mean burning time of a 2:3 potassium bromate/cellulose 20癈 (68癋) is equal to or greater than one-fifth its LC50 for acute inhalation
mixture and the criteria for Packing Group I are not met. Liquids: any material toxicity, if its LC50 is less than or equal to 3000 ppm and that does not meet
that exhibits a mean pressure rise time less than or equal to the pressure rise of a the criteria for degree of hazard 4. Compressed liquefied gases with boiling
1:1 aqueous sodium chlorate solution (40%)/cellulose mixture and the criteria for
points between -30癈 (-22癋) and -55癈 (-66.5癋) that cause frostbite and
Packing Group I are not met. Unstable Reactives: Substances that may
irreversible tissue damage. Materials that are respiratory irritants. Cryogenic
polymerize, decompose, condense, or self-react at ambient temperature and/or
gases that cause frostbite and irreversible tissue damage. Materials that are
pressure, but have a low potential for significant heat generation or explosion.
corrosive to the respiratory tract. Materials that are corrosive to the eyes or
Substances that readily form peroxides upon exposure to air or oxygen at room
cause irreversible corneal opacity. Materials that are corrosive to the skin. 4
temperature); 3 (Water Reactivity: Materials that may form explosive reactions
(materials that, under emergency conditions, can be lethal): Gases and vapors
with water. Organic Peroxides: Materials that are capable of detonation or
whose LC50 for acute inhalation toxicity less than or equal to 1,000 ppm.
explosive reaction, but require a strong initiating source, or must be heated under
Dusts and mists whose LC50 for acute inhalation toxicity is less than or equal
confinement before initiation; or materials that react explosively with water.
to 0.5 mg/L. Materials whose LD50 for acute dermal toxicity is less than or
Explosives: Division 1.2 ?Explosive substances that have a fire hazard and
equal to 40 mg/kg. Materials whose LD50 for acute oral toxicity is less than or
either a minor blast hazard or a minor projection hazard or both, but do not have
equal to 5 mg/kg. Any liquid whose saturated vapor concentration at 20癈
a mass explosion hazard.
(68癋) is equal to or greater than one-fifth its LC50 for acute inhalation toxicity,
if its LC50 is less than or equal to 1000 ppm.
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PAGE 13 OF 14
DEFINITIONS OF TERMS (Continued)
NATIONAL FIRE PROTECTION ASSOCIATION HAZARD FLAMMABILITY LIMITS IN AIR:
Much of the information related to fire and explosion is derived from the National
RATINGS (continued):
Fire Protection Association (NFPA). Flash Point - Minimum temperature at
FLAMMABILITY HAZARD: 0 Materials that will not burn under typical fire
which a liquid gives off sufficient vapors to form an ignitable mixture with air.
conditions, including intrinsically noncombustible materials such as concrete,
Autoignition Temperature: The minimum temperature required to initiate
stone, and sand: Materials that will not burn in air when exposed to a
combustion in air with no other source of ignition. LEL - the lowest percent of
temperature of 816癈 (1500癋) for a period of 5 minutes in according with
vapor in air, by volume, that will explode or ignite in the presence of an ignition
Annex D. 1 Materials that must be preheated before ignition can occur.
source. UEL - the highest percent of vapor in air, by volume, that will explode or
Materials in this degree require considerable preheating, under all ambient
ignite in the presence of an ignition source.
temperature conditions, before ignition and combustion can occur: Materials
TOXICOLOGICAL INFORMATION:
that will burn in air when exposed to a temperature of 816癈 (1500癋) for a
Human and Animal Toxicology: Possible health hazards as derived from
period of 5 minutes in accordance with Annex D. Liquids, solids and
human data, animal studies, or from the results of studies with similar compounds
semisolids having a flash point at or above 93.4癈 (200癋) (i.e. Class IIIB
are presented. Definitions of some terms used in this section are: LD50 - Lethal
liquids). Liquids with a flash point greater than 35癈 (95癋) that do not sustain
Dose (solids & liquids) which kills 50% of the exposed animals; LC50 - Lethal
combustion when tested using the Method of Testing for Sustained
Concentration (gases) which kills 50% of the exposed animals; ppm
Combustibility, per 49 CFR 173, Appendix H or the UN Recommendation on
concentration expressed in parts of material per million parts of air or water;
the Transport of Dangerous Goods, Model Regulations (current edition) and
mg/m3 concentration expressed in weight of substance per volume of air; mg/kg
the related Manual of Tests and Criteria (current edition). Liquids with a flash
quantity of material, by weight, administered to a test subject, based on their body
point greater than 35癈 (95癋) in a water-miscible solution or dispersion with a
weight in kg. Other measures of toxicity include TDLo, the lowest dose to cause a
water non-combustible liquid/solid content of more than 85 percent by weight.
symptom and TCLo the lowest concentration to cause a symptom; TDo, LDLo,
Liquids that have no fire point when tested by ASTM D 92 Standard Test
and LDo, or TC, TCo, LCLo, and LCo, the lowest dose (or concentration) to
Method for Flash and Fire Points by Cleveland Open Cup, up to a boiling point
cause lethal or toxic effects. Cancer Information: The sources are: IARC - the
of the liquid or up to a temperature at which the sample being tested shows an
International Agency for Research on Cancer; NTP - the National Toxicology
obvious physical change. Combustible pellets with a representative diameter
Program, RTECS - the Registry of Toxic Effects of Chemical Substances, OSHA
of greater than 2 mm (10 mesh). Solids containing greater than 0.5 percent by
and CAL/OSHA. IARC and NTP rate chemicals on a scale of decreasing
weight of a flammable or combustible solvent are rated by the closed up flash
potential to cause human cancer with rankings from 1 to 4. Subrankings (2A, 2B,
point of the solvent. Most ordinary combustible materials. 2 Materials that
etc.) are also used. Other Information: BEI - ACGIH Biological Exposure
must be moderately heated or exposed to relatively high ambient temperatures
Indices, represent the levels of determinants which are most likely to be observed
before ignition can occur. Materials in this degree would not under normal
in specimens collected from a healthy worker who has been exposed to
conditions form hazardous atmospheres with air, but under high ambient
chemicals to the same extent as a worker with inhalation exposure to the TLV.
temperatures or under moderate heating could release vapor in sufficient
quantities to produce hazardous atmospheres with air: Liquids having a flash ECOLOGICAL INFORMATION:
point at or above 37.8癈 (100癋) and below 93.4癈 (200癋) (i.e. Class II and EC is the effect concentration in water. BCF = Bioconcentration Factor, which is
Class IIIA liquids.) Solid materials in the form of powders or coarse dusts of used to determine if a substance will concentrate in lifeforms which consume
representative diameter between 420 microns (40 mesh) and 2 mm (10 mesh) contaminated plant or animal matter. TLm = median threshold limit; Coefficient of
that burn rapidly but that generally do not form explosive mixtures in air. Solid Oil/Water Distribution is represented by log Kow or log Koc and is used to
materials in fibrous or shredded form that burn rapidly and create flash fire assess a substance's behavior in the environment.
hazards, such as cotton, sisal and hemp. Solids and semisolids that readily
REGULATORY INFORMATION:
give off flammable vapors. Solids containing greater than 0.5 percent by
U.S. and CANADA:
weight of a flammable or combustible solvent are rated by the closed cup flash
This section explains the impact of various laws and regulations on the material.
point of the solvent. 3 Liquids and solids that can be ignited under almost all
ACGIH: American Conference of Governmental Industrial Hygienists, a
ambient temperature conditions. Materials in this degree produce hazardous
professional association which establishes exposure limits. EPA is the U.S.
atmospheres with air under almost all ambient temperatures or, though
Environmental Protection Agency. NIOSH is the National Institute of
unaffected by ambient temperatures, are readily ignited under almost all
Occupational Safety and Health, which is the research arm of the U.S.
conditions: Liquids having a flash point below 22.8癈 (73癋) and having a
Occupational Safety and Health Administration (OSHA). WHMIS is the Canadian
boiling point at or above 37.8癈 (100癋) and those liquids having a flash point
Workplace Hazardous Materials Information System. DOT and TC are the U.S.
at or above 22.8癈 (73癋) and below 37.8癈 (73癋) and below 37.8癈 (100癋)
Department of Transportation and the Transport Canada, respectively. Superfund
(i.e. Class IB and IC liquids). Materials that, on account of their physical form
Amendments and Reauthorization Act (SARA); the Canadian Domestic/Non-
or environmental conditions, can form explosive mixtures with air and are
Domestic Substances List (DSL/NDSL); the U.S. Toxic Substance Control Act
readily dispersed in air. Flammable or combustible dusts with a representative
(TSCA); Marine Pollutant status according to the DOT; the Comprehensive
diameter less than 420 microns (40 mesh). Materials that burn with extreme
Environmental Response, Compensation, and Liability Act (CERCLA or
rapidity, usually by reason of self-contained oxygen (e.g. dry nitrocellulose and
Superfund); and various state regulations. This section also includes information
many organic peroxides). Solids containing greater than 0.5 percent by weight
on the precautionary warnings which appear on the material's package label.
of a flammable or combustible solvent are rated by the closed cup flash point
OSHA - U.S. Occupational Safety and Health Administration.
of the solvent. 4 Materials that will rapidly or completely vaporize at
atmospheric pressure and normal ambient temperature or that are readily EUROPEAN: EU is the European Union (formerly known as the EEC, European
dispersed in air and will burn readily: Flammable gases. Flammable Economic Community). EINECS: This the European Inventory of Now-Existing
cryogenic materials. Any liquid or gaseous materials that is liquid while under Chemical Substances. The ARD is the European Agreement Concerning the
pressure and has a flash point below 22.8癈 (73癋) and a boiling point below International Carriage of Dangerous Goods by Road and the RID are the
International Regulations Concerning the Carriage of Dangerous Goods by Rail.
37.8癈 (100癋) (i.e. Class IA liquids). Materials that ignite when exposed to
AUSTRALIAN: AICS is the Australian Inventory of Chemical Substances.
air, Solids containing greater than 0.5 percent by weight of a flammable or
NOHSC: National Occupational Health & Safety Code. MITI is the Japanese
combustible solvent are rated by the closed cup flash point of the solvent.
Minister of International Trade and Industry.
INSTABILITY HAZARD: 0 Materials that in themselves are normally stable,
even under fire conditions: Materials that have an estimated instantaneous
power density (product of heat of reaction and reaction rate) at 250癈 (482癋)
below 0.01 W/mL. Materials that do not exhibit an exotherm at temperatures less
than or equal to 500癈 (932癋) when tested by differential scanning calorimetry.
1 Materials that in themselves are normally stable, but that can become
unstable at elevated temperatures and pressures: Materials that have an
estimated instantaneous power density (product of heat of reaction and reaction
rate) at 250癈 (482癋) at or above 0.01 W/mL and below 10 W/mL. 2 Materials
that readily undergo violent chemical change at elevated temperatures and
pressures: Materials that have an estimated instantaneous power density
(product of heat of reaction and reaction rate) at 250癈 (482癋) at or above 10
W/mL and below 100W/mL. 3 Materials that in themselves are capable of
detonation or explosive decomposition or explosive reaction, but that require a
strong initiating source or that must be heated under confinement before
initiation: Materials that have an estimated instantaneous power density (product
of heat of reaction and reaction rate) at 250癈 (482癋) at or above 100 W/mL and
below 1000 W/mL. Materials that are sensitive to thermal or mechanical shock at
elevated temperatures and pressures.
TOTALSEAL SRP 5055 Bare Metal Etch Primer
PAGE 14 OF 14
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