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TFP-401 One Step Solvent Cement
MSDS (Material Safety Data Sheet)
MSDS No: TYC010E6 Issue Date: 11 May 2006
SECTION 1 PRODUCT AND COMPANY IDENTIFICATION
TradeName: BLAZEMASTERCPVCCEMENTTFP-401
ProductUse: CementforCPVCPipe
Formula: CPVCResininSolventSolution
Synonyms: CPVCPlasticPipeCement
FirmName& TYCOc/oOATEYCO.4700West160thStreetP.O.Box35906
MailingAddress: Cleveland,Ohio44135,U.S.A.http://www.oatey.com
OateyPhoneNumber:(216)267-7100or(800)321-9532
EmergencyPhone ForEmergencyFirstAidcall1-877-740-5015.For
Numbers: chemicaltransportationemergenciesONLY,callChemtrecat
1-800-424-9300.OutsidetheU.S.1-703-527-3887.
PreparedBy: CorporateDirector璖afetyandEnvironmentalCompliance
PreparationDate: May11,2006
SECTION 2 COMPOSITION/INFORMATION ON INGREDIENTS
INGREDIENTS: %wt/wt: CASNUMBER:ACGIHTLVTWA: OSHAPELTWA:OTHER:
Acetone 5?5% 67-64-1 500ppm 1000ppm
750ppmSTEL
Tetrahydrofuran40-55% 109-99-9 50ppm(skin) 200ppm 25ppm(Mfg)
100ppmSTEL
MethylEthylKetone 5-15% 78-93-3 200ppm 200ppm None
300ppmSTEL
Cyclohexanone 5-15% 108-94-1 20ppm(skin) 50ppm None
50ppmSTEL
CPVCResin15-30% 68648-82-8 10mg/m3 None None
(Non-hazardous) Established
AmorphousFumedSilica 1-5% 112945-52-5 10mg/m3 None None
(Non-hazardous) Established
OSHA Hazard Classification: Flammable, irritant, organ effects
SECTION 3 HAZARDS IDENTIFICATION
EmergencyOverview:
Red liquid with an ether-like odor. Extremely flammable liquid and vapor. Vapors
may cause flash fire. May cause eye and skin irritation. Inhalation of vapors or mist
maycauserespiratoryirritationandcentralnervoussystemeffects.Swallowing
maycauseirritation,nausea,vomiting,diarrheaandkidneyorliverdisorders.
Aspirationhazard.Maybefatalifswallowed.Symptomsmaybedelayed.
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SECTION 4 FIRST AID MEASURES
CALL1-877-740-5015
Skin: Removecontaminatedclothingimmediately.Washallexposedareaswith
soapandwater.Getmedicalattentionifirritationdevelops.Remove
driedcementwithOateyPlumber'sHandCleanerorbabyoil.
Eyes: Ifmaterialgetsintoeyesoriffumescauseirritation,immediately
flush eyes with plenty of water until chemical is removed. If
irritationpersists,getmedicalattentionimmediately.
Inhalation: Ifsymptomsofexposuredevelop,removetofreshair.Ifbreathing
becomes difficult, administer oxygen. Administer artificial respiration
ifbreathinghasstopped.Seekimmediatemedicalattention.
Ingestion: DO NOT INDUCE VOMITING. Rinsemouthwithwater.Nevergiveanything
bymouthtoapersonwhoisunconsciousordrowsy.Getimmediatemedical
attentionbycallingaPoisonControlCenter,orhospitalemergency
room.Ifmedicaladvicecannotbeobtained,thentakethepersonand
producttothenearestmedicalemergencytreatmentcenterorhospital.
SECTION 5 FIRE FIGHTING MEASURES
Flashpoint/Method: 0-5DegreesF.(-18--15DegreesC)/PMCC
Flammability: LEL=1.8%Volume,UEL=11.8%Volume
Extinguishing Use dry chemical, CO2, or foam to extinguish fire. Cool fire
Media: exposedcontainerwithwater.Watermaybeineffectiveasan
extinguishingagent.
Special Fire Firefighters should wear positive pressure self-contained
Fighting breathing apparatus and full protective clothing for fires in
Procedure: areaswherechemicalsareusedorstored
Unusual Fire and Extremely flammable liquid. Keep away from heat and all
Explosion sources of ignition including sparks, flames, lighted
Hazards: cigarettesandpilotlights.Containersmayruptureor
explode in the heat of a fire. Vapors are heavier than air
and may travel to a remote ignition source and flash back.
Thisproductcontainstetrahydrofuranthatmayformexplosive
organicperoxidewhenexposedtoairorlightorwithage.
Hazardous Combustionwillproducetoxicandirritatingvaporsincluding
Decomposition carbonmonoxide,carbondioxideandhydrogenchloride.
Products:
SECTION 6 ACCIDENTAL RELEASE MEASURES
Spillor Removeallsourcesofignitionandventilatearea.Stopleakifit
Leak canbedonewithoutrisk.Personnelcleaningupthespillshould
Procedures: wearappropriatepersonalprotectiveequipment,includingrespirators
ifvaporconcentrationsarehigh.Soakupspillwithaninert
absorbentsuchassand,earthorothernon-combustingmaterial.Put
absorbentmaterialincovered,labeledmetalcontainers.Prevent
liquidfromenteringwatercourses,sewersandnaturalwaterways.
Reportreleasestoauthoritiesasrequired.SeeSection13for
disposalinformation.
SECTION 7 HANDLING AND STORAGE
Handling: Avoidcontactwitheyes,skinandclothing.Avoidbreathingvapors
ormists.Usewithadequateventilation(equivalenttooutdoors).
Washthoroughlyafterhandling.Donoteat,drinkorsmokeinthe
work area. Keep product away from heat, sparks, flames and all other
sourcesofignition.Nosmokinginstorageoruseareas.Keep
containersclosedwhennotinuse.
Storage: Storeinacool,dry,well-ventilatedareaawayfromincompatible
materials.Keepcontainersclosedwhennotinuse.
Other: "Empty"containersretainproductresidueandcanbehazardous.
FollowallMSDSprecautionsinhandlingemptycontainers.Donotcut
orweldonornearemptyorfullcontainers.
TFP992 Page of 6
SECTION 8 EXPOSURE CONTROLS/PERSONAL PROTECTION
Ventilation: Opendoors&windows.Provideventilationcapableofmaintaining
emissionsatthepointofusebelowrecommendedexposurelimits.If
usedinenclosedarea,useexhaustfans.Exhaustfansshouldbe
explosion-proof or set up in a way that flammable concentrations of
solvent vapors are not exposed to electrical fixtures or hot
surfaces.
Respiratory Foroperationswheretheexposurelimitmaybeexceeded,aNIOSH
Protection: approvedorganicvaporrespiratororsuppliedairrespiratoris
recommended.Equipmentselectiondependsoncontaminanttypeand
concentration,selectinaccordancewith29CFR1910.134andgood
industrial hygiene practice. For firefighting, use self-contained
breathingapparatus.
Skin Rubberglovesaresuitablefornormaluseoftheproduct.Forlong
Protection: exposureschemicalresistantglovesmayberequiredsuchas4H(tm)
orSilverShield(tm)toavoidprolongedskincontact.
Eye Safetyglasseswithsideshieldsorsafetygoggles.
Protection:
Other: Eyewashandsafetyshowershouldbeavailable.
SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES
BoilingPoint: 151DegreesF/66DegreesC
MeltingPoint: Notapplicable
VaporPressure: 145mmHg@20DegreesC
VaporDensity: (Air=1)2.5
VolatileComponents: 70-80%
SolubilityInWater: Negligible
pH: Notapplicable
Specific Gravity: 0.98 +/- 0.02 @ 20 Degrees C
EvaporationRate: (BUAC=1)=5.5-8.0
Appearance: RedLiquid
Odor: Ether-Like
WillDissolveIn: Tetrahydrofuran
MaterialIs: Liquid
SECTION 10 STABILITY AND REACTIVITY
Stability: Stable.
Conditions To Avoid: Avoid heat, sparks, flames and other sources of ignition.
Hazardous Combustionwillproducetoxicandirritatingvapors
Decomposition includingcarbonmonoxide,carbondioxideandhydrogen
Products: chloride.
Incompatibility/ Oxidizingagents,alkalis,amines,ammonia,acids,chlorine
MaterialsToAvoid: compounds,chlorinatedinorganics(potassium,calciumand
sodiumhypochlorite)andhydrogenperoxides.Mayattack
plastic,resinsandrubber.
Hazardous
Polymerization: Willnotoccur.
SECTION 11 TOXICOLOGICAL INFORMATION
Inhalation: Vaporsormistsmaycausemucousmembraneandrespiratory
irritation,coughing,headache,dizziness,dullness,nausea,
shortnessofbreathandvomiting.Highconcentrationsmaycause
centralnervoussystemdepression,narcosisandunconsciousness.
Maycausekidney,liverandlungdamage.
Skin: Maycauseirritationwithredness,itchingandpain.Methyl
ethylketoneandcyclohexanonemaybeabsorbedthroughtheskin
causingeffectssimilartothoselistedunderinhalation.
Eye: Vaporsmaycauseirritation.Directcontactmaycauseirritation
withredness,stingingandtearingoftheeyes.Maycauseeye
damage.
Ingestion: Swallowingmaycauseabdominalpain,nausea,vomitingand
diarrhea.Aspirationduringswallowingorvomitingcancause
chemicalpneumoniaandlungdamage.Maycausekidneyandliver
damage.
Chronic Prolongedorrepeatedoverexposurecausedermatitisanddamage
Toxicity: tothekidney,liver,lungsandcentralnervoussystem.
Continued...
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ToxicityData: Cyclohexanone: OralratLD50:1,620mg/kg
InhalationratLC50:8,000ppm/4hours
SkinrabbitLD50:1mL/kg
Tetrahydrofuran: OralratLD50:1,650mg/kg
InhalationratLC50:21,000ppm/3hours
MethylEthylKetone: OralratLD50:2,737mg/kg
InhalationratLC50:23,500mg/m3/8hours
SkinrabbitLD50:6,480mg/kg
Sensitization: Noneofthecomponentsareknowntocausesensitization.
Carcinogenicity: Noneofthecomponentsarelistedasacarcinogenorsuspect
carcinogenbyNTP,IARCorOSHA.TheNationalToxicologyProgram
hasreportedthatexposureofmiceandratstotetrahydrofuran
(THF)vaporlevelsupto1800ppm6hr/day,5days/weekfor
theirlifetimecausedanincreasedincidenceofkidneytumors
in male rats and liver tumors in female mice. The significance
of these findings for human health is unclear at this time, and
may be related to "species specific" effects. Elevated incidences
oftumorsinhumanshavenotbeenreportedforTHF.ACGIH
has classified cyclohexanone (CYH) and tetrahydrofuran as "A3,"
Confirmed Animal Carcinogens with Unknown Relevance to Humans.
Mutagenicity: Cyclohexanonehasbeenpositiveinbacterialandmammalian
assays.Methylethylketoneandtetrahydrofuranare
generallythoughtnottobemutagenic.
Reproductive Methylethylketoneandcyclohexanonehavebeenshowntocause
Toxicity: embryofetaltoxicityandbirthdefectsinlaboratoryanimals.
Tetrahydrofuranhasbeenfoundtocauseadversedevelopmental
effectsonlywhenexposurelevelscauseothertoxiceffectstothe
mother.
Medical Personswithpre-existingskin,lung,kidneyorliverdisorders
Conditions maybeatincreasedriskfromexposuretothisproduct.
AggravatedBy
Exposure:
SECTION 12 ECOLOGICAL INFORMATION
Thisproductisnotexpectedtobetoxictoaquaticorganisms.
Cyclohexanone: 96 hour LC50 values for fish is over 100 mg/l.
Tetrahydrofuran:96hourLC50fatheadminnow:2160mg/L.
Methyl Ethyl Ketone: 96 hour LC50 for fish is greater than 100 mg/L.
VOC ThisproductemitsVOC's(volatileorganiccompounds)initsuse.
Information: MakesurethatuseofthisproductcomplieswithlocalVOCemission
regulations,wheretheyexist.
VOCLevel: 490g/lperSCAQMDTestMethod316A.
SECTION 13 DISPOSAL CONSIDERATIONS
WasteDisposal: Disposeinaccordancewithcurrentlocal,stateandfederal
regulations.
RCRAHazardousWasteNumber: U057,U159,U213
EPAHazardousWasteIDNumber: D001,D035,F003,F005
EPAHazardWasteClass: IgnitableWaste.ToxicWaste(MethylEthylKetonecontent)
SECTION 14 TRANSPORT INFORMATION
DOT Lessthan1Liter(0.3gal)Greaterthan1Liter(0.3gal)
ProperShippingName: ConsumerCommodity Adhesives
HazardClass/PackingGroup: ORM-D 3,PGII
UN/NANumber: None UN1133
HazardLabels: None FlammableLiquid
IMDG
ProperShippingName: Adhesives Adhesives
HazardClass/PackingGroup: 3,II 3,II
UNNumber: UN1133 UN1133
Label: None(LimitedQuantities Class3(Flammable
areexcepted Liquid)
fromlabeling)
2004NorthAmericanEmergencyResponseGuidebookNumber:127or128
TFP992 Page of 6
SECTION 15 REGULATORY INFORMATION
HazardCategoryforSection AcuteHealth,ChronicHealth,Flammable
311/312:
Section302Extremely Thisproductdoesnotcontainchemicalsregulated
HazardousSubstances(TPQ): underSARASection302.
Section313ToxicChemicals: Thisproductcontainsthefollowingchemicals
subjecttoSARATitleIIISection313Reporting
requirements:
Chemical CAS# %bywt.
MethylEthylKetone 78-93-3 5-15%
CERCLA103Reportable SpillsofthisproductovertheRQ(reportable
Quantity: quantity)mustbereportedtotheNationalResponse
Center.TheRQfortheproduct,basedontheRQfor
Tetrahydrofuran(45%maximum)of1,000lbs,is2,222
lbs.Manystateshavemorestringentrelease
reportingrequirements.Reportspillsrequiredunder
federal,stateandlocalregulations.
CaliforniaProposition65: Thisproductcontainstraceamountsofchemicals
knowntotheStateoftocausecancer.Undernormal
Useconditions,exposuretothesechemicalsatlevels
above the State of California "No Significant Risk
Level"(NSRL)areunlikely.Oateystrongly
encouragestheuseofproperpersonalprotective
equipment(PPE)andventilationguidelinesnotedin
Section8tominimizeexposuretothesechemicals.
TSCAInventory: Allofthecomponentsofthisproductarelistedon
theTSCAinventory.
Canadian WHIMS Classification: Class B, Division 2; Class D, Division 2,
Subdivision B; Class D, Division 2, Subdivision A.
This product has been classified in accordance with
thehazardcriteriaoftheControlledProducts
Regulations(CPR)andtheMSDScontainsallthe
informationrequiredbytheCPR.
SECTION 16 OTHER INFORMATION
NFPAandHMIS:
NFPAHazardSignal: Health:2 Flammability:3Reactivity:1 Special:None
HMISHazardSignal: Health:2* Flammability:3Reactivity:1 PPE:H
Disclaimer:
Theinformationhereinhasbeencompiledfromsourcesbelievedtobereliable,up-
to-date,andisaccuratetothebestofourknowledge.However,Oateycannotgive
anyguaranteesregardinginformationfromothersources,andexpresslydoesnotmake
warranties,norassumesanyliabilityforitsuse.
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?2008 TYCO FIRE & BUILDING PRODUCTS, 451 North Cannon Avenue, Lansdale Pennsylvania 19446
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